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Using support vector machines to predict cation exchange capacity of different soil horizons in Qingdao City,China
Authors:Kaihua Liao  Shaohui Xu  Jichun Wu  Qing Zhu  Lesheng An
Affiliation:1. Key Laboratory of Watershed Geographic Sciences, Nanjing Institute of Geography and Limnology, Chinese Academy of Sciences, 210008 Nanjing, China;2. Department of Environmental Science, Qingdao University, 266071 Qingdao, China;3. Department of Hydrosciences, Nanjing University, 210093 Nanjing, China;4. Department of Environmental Engineering, Anqing Normal University, 246011 Anqing, China
Abstract:Agricultural, environmental and ecological modeling requires soil cation exchange capacity (CEC) that is difficult to measure. Pedotransfer functions (PTFs) are thus routinely applied to predict CEC from easily measured physicochemical properties (e.g., texture, soil organic matter, pH). This study developed the support vector machines (SVM)‐based PTFs to predict soil CEC based on 208 soil samples collected from A and B horizons in Qingdao City, Shandong Province, China. The database was randomly split into calibration and validation datasets in proportions of 3:1 using the bootstrap method. The optimal SVM parameters were searched by applying the genetic algorithm (GA). The performance of SVM models was compared to those of multiple stepwise regression (MSR) and artificial neural network (ANN) models. Results show that the accuracy of CEC predicted by SVM improves considerably over those predicted by MSR and ANN. The performance of SVM for B horizon (R2 = 0.85) is slightly better than that for A horizon (R2 = 0.81). The SVM is a powerful approach in the simulation of nonlinear relationship between CEC and physicochemical properties of widely distributed samples from different soil horizons. Sensitivity analysis was also conducted to explore the influence of each input parameter on the CEC predictions by SVM. The clay content is the most sensitive parameter, followed by soil organic matter and pH, while sand content has the weakest influence. This suggests that clay is the most important predictor for predicting CEC of both soil horizons.
Keywords:cation exchange capacity  support vector machines  artificial neural network  sensitivity analysis
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