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1.
The effects of high temperature steam pretreatment on the change in wood moisture content (MC) and characteristics of vacuum drying were investigated in this study. Poplar and manchurian walnut woods were pretreated with high temperature steam at 100°C and 140°C, prior to vacuum drying. A comparison of the characteristics of vacuum drying between steam pretreated wood and untreated wood was carried out. The results show that during steam pretreatment, the MC of wood decreased within a few hours. The reduction of MC varied with the temperature; the higher the temperature, the faster the MC dropped. During the vacuum drying stage, the rates of drying of pretreated samples were higher than those of untreated samples when MC was below the fiber saturation point. Furthermore, the total drying time of samples treated at a steam temperature of 140°C was lower than that of untreated samples. Therefore, a vacuum procedure after steam pretreatment can effectively shorten the drying time when drying wood.  相似文献   

2.
Previously we showed that the relaxation modulusEt of water-saturated wood during temperature reduction maintained its initial value despite the decrease in temperature, although during temperature elevationEt showed a marked decrease. In the present study, to clarify the mechanism of relaxation during temperature elevation and reduction, Young's modulus was measured in stress relaxation experiments with changes in temperature, and relaxation behavior was simulated using a Maxwell model consisting of five elements. Furthermore, the dynamic Young's modulus and dynamic loss modulus were measured during both temperature elevation and reduction. The results obtained suggested that the unique relaxation behavior during temperature reduction was caused by decreases in Young's modulus and coefficient of viscosity (i.e., an increase in fluidity) compared with those during elevation of temperature. The decrease in Young's modulus and increase in fluidity were considered to be due to an unstable structure in wood that occurred during temperature reduction. This unstable structure probably develops in the nonequilibrium state of temperature toward a true equilibrium state. Wood should be more unstable during temperature reduction than during temperature elevation because of the decrease in molecular motion when the temperature is lowered.Part of this report was presented at the 49th annual meeting of the Japan Wood Research Society, Tokyo, April 1999  相似文献   

3.
In order to clarify the relationship between the microstructural changes and the rheological behaviors of four chemically treated woods (delignified wood, hemicellulose-removed wood, DMSO swollen and decrystallization treated wood), the stress relaxation of wood with three different moisture contents was determined during periodic temperature changes. The experimental results show that after wood relaxation for 4 h at 25℃, the stress decays sharply when the temperature increases and 2 h later the stress recovers again when the temperature drops back to the original point. The additional stress relaxation, produced after temperature begins to increase, is mainly caused by the thermal swelling, molecular thermal movement and the break of a part of residual hydrogen bonds. The number of hydrogen bonds and the size and amount of cavities in various treated woods greatly affect themagnitude of the additional relaxed stress and the recovery stress.  相似文献   

4.
针对木材干燥过程中因干缩不均导致开裂等干燥质量问题,提出将模糊控制和PID控制相结合构成模糊自整定PID切换控制,以有效控制干缩力。在大误差时采用模糊控制,使实际干缩力值尽快达到设定值,提高干燥速度;在小误差时采用模糊自整定PID控制,使实际干缩力值与设定值基本保持一致,避免产生内裂。验证试验设置介质温度分别为70、80、90℃,相对湿度为30%,结果显示:松木试件在干缩力值分别达到最大值338、424、398N后开始减小,说明木材产生了开裂使干缩力得到释放;在同等试验条件下,采用切换控制后干缩力值在达到预设值后没有减小,保持稳定不变。MATLAB仿真与验证试验结果均表明:模糊自整定PID切换控制可以实现对干缩力的有效控制。  相似文献   

5.
The drying kinetics of reaction woods in Picea abies (compression wood) and Fagus sylvatica (tension wood) in comparison with their corresponding normal woods was investigated under constant convective drying conditions. Moisture profiles along the thickness of small flat-sawn boards taken from reaction and opposite wood zones were evaluated using a polychromatic X-ray system, a non-destructive method. The results revealed substantial differences in the drying behavior between the reaction and opposite woods. Both reaction woods represented slower drying rate than their matching normal woods mainly during the period of free water loss. However, the reaction and opposite woods reached the final moisture content (MC) of about 12% at the same time due to higher initial MC in the opposite woods. In the case of reaction wood, it took a longer time for the moisture profile to become approximately uniform. Overall, a more striking difference was observed in the drying behavior of compression and opposite wood in P. abies. Some important anatomical differences like the cell and pit dimensions and their proportion give some explanations for these drying behaviors.  相似文献   

6.
木材干燥应力连续监测方法的研究   总被引:4,自引:0,他引:4  
高建民  余雁  刘志军 《木材工业》2004,18(3):1-3,13
本文在卡普法的基础上,提出了木材干燥应力连续监测方法,并设计了所需的配套装置。该方法采用涡流传感器对干燥过程中卡普片的矢高进行连续测试,同时通过计算机自动采集、存储数据。结果表明:矢高与干燥时间存在精密的相关性,它们之间的相关系数大部分达到0.99以上,从而实现了木材干燥应力的自动与连续监测。  相似文献   

7.
Using Masson pine as specimens, when drying mediums are overheated steam and hot-air respectively, preheating characteristics of wood under vacuum-floating pressure drying are discussed by measurement of internal temperature field and variation of moisture content during period of preheating. The relationship between drying medium conditions and drying rate of wood reveals that, firstly, compared with process of air-drying, time needed to be preheated under vacuum-floating decreased dramatically, meanwhile, the magnitude of condensation on the surface is relatively larger. Secondly, drying rate of wood under vacuum-floating pressure increases coupled with temperature of medium, reduction of absolute pressure, and raise of fluctuation rate of pressure. The sequence of factors contribution to drying rate is listed as following: temperature of medium (t) > fluctuation rate of pressure (f)> absolute pressure (p).  相似文献   

8.
Stress relaxation of water-saturated wood was examined at various temperatures and during the processes of elevation and lowering of temperature. The difference between relaxation at a lower temperature and that at a higher temperature was almost same as the increase in relaxation during temperature elevation. Similar results were obtained regardless of the elevating speed of the temperature and regardless of preheating the samples. On the other hand, relaxation behavior during temperature lowering was quite different from that during temperature elevation. The relaxation moduli during the process of lowering the temperature scarcely changed, although those at various constant temperatures decreased with increases in temperature. Marked sets occurred after relaxation measurements under temperature lowering, whereas only slight sets occurred during the process of elevating the temperature or at a constant temperature of 80°C. Furthermore, it was found that the sets that occurred during the process of temperature reduction were almost recovered when the samples were heated again in water. The mechanism of the relaxation behaviors observed in the present study under nonequilibrium temperature is discussed in relation to the occurrence of set after relaxation measurements.Part of this report was presented at the 48th annual meeting of the Japan Wood Research Society, Shizuoka, April 1998  相似文献   

9.
Abstract

Wood drying experiments were conducted in which the temperature and the drying rate were controlled independently. The mechanical properties of dried wood in radial loading were analysed in relation to drying parameters. Mass loss, due to thermal degradation of the wood structural components, occurred predominantly in slow high-temperature drying processes. Despite the higher mass loss, slowly dried wood showed similar radial strength and stiffness to rapidly dried wood. The formation of irreversible hydrogen bonds (hornification) within the wood structure may compete with the effects of mass loss on the radial mechanical behaviour of wood. However, both the mass loss and the hornification resulted in wood specimens with lower hygroscopicity. Application of slow high-temperature drying to reduce microscopic cell-wall damage, caused by anisotropic shrinkage of cell-wall layers, did not seem to affect the radial mechanical properties of wood. The effects of stress relaxation within the wood cell wall on the mechanical behaviour of wood may be offset by the degradation of structural components along with drying. Radial mechanical properties may be improved by rapid high-temperature drying up to high final dryness.  相似文献   

10.
Changes in the modulus of elasticity (MOE), modulus of rupture (MOR), and stress relaxation in the radial direction of wood (hinoki:Chamaecyparis obtusa) moisture-conditioned by the adsorption process from a dry state and by the desorption process from a moisture content slightly below the fiber saturation point were investigated. The MOE and MOR of wood conditioned by the adsorption process showed significant increases during the later stages of conditioning when the moisture content scarcely changed. However, with the desorption process they did not increase as much during later stages of conditioning, though they increased during early stages of conditioning when the moisture content greatly decreased. The stress relaxation of wood decreased with an increase in the conditioning period with both the adsorption and desorption processes. These results suggest that wood in an unstable state, caused by the existing state of moisture differed from that in a true equilibrium state shows lower elasticity and strength and higher fluidity than wood in a true equilibrium state. Furthermore, the present study demonstrates that the unstable states of wood induced during the course of drying, desorption, and possibly adsorption of moisture are slowly modified as wood approaches a true equilibrium state.  相似文献   

11.
Wood drying experiments are conducted in which the temperature and the drying rate are controlled independently. In relationship to drying processes, at least three mechanisms are believed to contribute to the properties of dried wood. However, only two of these are found to affect the properties of macroscopic specimens, the third mechanism being observable in microtomed earlywood sections, and possibly in specimens loaded in the radial direction. Degradation of structural components and irreversible hydrogen bonding (hornification) are found to contribute to both the hygroscopicity and the mechanical properties of macroscopic wood specimens. Mass loss from thermal degradation occurs predominantly in slow high-temperature drying processes. Irreversible hydrogen bonding takes place in high-temperature drying, in particular with high ultimate dryness. Regarding the effect on strength and stiffness, mass loss and hornification appear to compete. The third identified mechanism, microscopic cell wall damage caused by incompatible drying shrinkage of cell wall elements, does not seem to affect the mechanical properties of macroscopic wood specimens. Consequently, slow high-temperature drying processes do not provide much benefit regarding the mechanical behavior of dried wood. The reasons for this are discussed.  相似文献   

12.
Change in the colour of silver birch wood is a serious problem in the mechanical wood industry. Here, colour was correlated with microscopic characteristics of wood, such as cell types and dimensions, by drying processes. In conventional drying, with lower temperature than in vacuum drying used here, the most important factor causing darkened wood was wide latewood. In vacuum drying, thickness of the vessel walls affected wood darkening, as did broad rays and large amount of axial parenchyma. Axial and terminal parenchyma cells contained very small amounts of phenolics, but after drying at elevated temperature, a thin dark layer could be observed on the innerside of their walls. Phenolics were abundant in ray parenchyma; these compounds darkened at elevated temperatures, less in conventional drying than in vacuum drying. Phenolics were observed only inside cells, mainly in the parenchyma, but in vacuum-dried wood also in fibres and vessels. Anatomical characteristics are known to be affected by both environmental and genetic factors. Thus it might be possible to influence the colour reaction of birch wood during the drying process by choosing wood according to growing-site conditions, or by choosing the seed source for birch plantations according to given anatomical characteristics.  相似文献   

13.
 Steam conditioning of softwood boards after kiln drying is of critical importance for relief of residual drying stresses and to improve distribution of final moisture content. The conditioning practice in New Zealand includes two steps: immediately after high temperature (HT) drying the load is cooled until the core wood temperature is 75 to 90°C, and then the stack is steam conditioned for a period of 1 to 4 hours depending on the lumber thickness and moisture content after drying. In this work, experimental and theoretical studies were performed to better understand the conditioning process and to investigate factors which influence its effectiveness. In the experiment, 50 mm thick Pinus radiata sapwood boards were first dried at 120/70°C for 11, 12, 13, 16 and 18 hours, respectively, to varying moisture contents, and then cooled and steam conditioned for 1 hour. To assess the effectiveness of conditioning, moisture pick-up, moisture gradient, and transverse residual drying stress (indicated by cup and strain) were measured. It was found that drying wood to a low moisture content (below 6%) increased the conditioning effectiveness. A separate matched stack was conditioned for 4 hours after 13 hours drying which showed better results than 1 hour conditioning. A mathematical model for wood drying was extended to include both the cooling and conditioning phases. The model was numerically solved to examine the wood temperature and moisture content changes during the whole process of drying, cooling and final steam conditioning. Increase in wood temperature, moisture pickup and moisture gradient during steam conditioning were predicted and validated by the experimental data. This information is currently being used at the New Zealand Forest Research Institute in simulation of stress development and relief for drying of Pinus radiata lumber. Received 6 July 1998  相似文献   

14.
Unmodified and acetylated cedar wood specimens were swollen in various liquids and dried under radial compression. Two stress relaxation processes were observed during drying, and the second process observed below the fiber saturation point was responsible for the drying-set and the temporary fixation of compressive deformation. The fixed shape of acetylated wood was partly recovered by soaking it in water and toluene and completely recovered in acetone. The effective shape fixation and recovery of toluene-swollen samples implied that the intermolecular hydrogen bonding was not necessary for the drying-set of acetylated wood. The degree of shape recovery was not explained by initial softening, while the acetylated wood always exhibited greater recoverability than unmodified wood. Although 85% stiffness was lost after large compression set and recovery of unmodified wood, such a stiffness loss was limited to 39% when the acetylated wood was processed with organic liquids. This indicated that the swelling of the hydrophobic region in the acetylated wood was effective in preventing mechanical damage due to large compressive deformation.  相似文献   

15.
木材热分解动力学的研究   总被引:8,自引:0,他引:8  
用TG-DTA热分析联用技术测定了4种常用木材的TG-DTA-5曲线,并用热动力学方法处理的TG曲线,获得了相应动力学参数。发现各种木材在干燥阶段和煅烧阶段的热性质大致相似,而炭化阶段的热性质则因木材人化学组成不同而有较大差异。  相似文献   

16.
Abstract

Change in the colour of silver birch wood is a serious problem in the mechanical wood industry. Here, colour was correlated with microscopic characteristics of wood, such as cell types and dimensions, by drying processes. In conventional drying, with lower temperature than in vacuum drying used here, the most important factor causing darkened wood was wide latewood. In vacuum drying, thickness of the vessel walls affected wood darkening, as did broad rays and large amount of axial parenchyma. Axial and terminal parenchyma cells contained very small amounts of phenolics, but after drying at elevated temperature, a thin dark layer could be observed on the innerside of their walls. Phenolics were abundant in ray parenchyma; these compounds darkened at elevated temperatures, less in conventional drying than in vacuum drying. Phenolics were observed only inside cells, mainly in the parenchyma, but in vacuum-dried wood also in fibres and vessels. Anatomical characteristics are known to be affected by both environmental and genetic factors. Thus it might be possible to influence the colour reaction of birch wood during the drying process by choosing wood according to growing-site conditions, or by choosing the seed source for birch plantations according to given anatomical characteristics.  相似文献   

17.
The present study is focused on analysing the suitability of different Streptomyces strains for biomechanical pulping purposes using spruce wood (Picea abies) as substrate. After 2 weeks of incubation, no apparent variations in lignin Klason content of treated woods were detected compared with the control. However, the increase in acid-soluble lignin fraction pointed out chemical alterations in lignin moiety. Through Py-GC/MS analysis enrichment in cellulose and lignin molecule modifications were detected in treated woods. The increase in the relative abundance of the most G-type phenol units with a higher oxidation degree suggests that some oxidation occurred in the lignin C3-alkyl chain. In addition, the decrease in the phenylmethane + phenylethane/phenylpropane (phC1 + ph C2/ph C3) ratio would indicate the ability of Streptomyces strains to breakdown the C3-alkyl chain linkages once carbons had been oxidized. From this study it could be concluded that the assayed strains are able to produce a delignification of spruce wood which may improve mechanical pulping processes.  相似文献   

18.
The effects of high temperature, moisture, and mechanical action during the thermo-hydro-mechanical (THM) processing, on the changes in surface properties of poplar, namely, surface color, roughness, wettability, and microstructure, were investigated in this study. The correlation between observed changes in surface properties and chemical characteristics was also analyzed. Poplar woods with high moisture content were compressed using different pressures at temperature of 160 °C for four different periods. The wood surfaces became darker and smoother, and their surface free energy decreased significantly after the THM process. THM process markedly reduced surface hygroscopicity compared to the control wood. The cell lumens of THM wood became narrow with increasing compression ratio due to the enhancing high pressure. Collapse and fractures of cell walls developed during THM treatment. Furthermore, results indicated that a series of chemical reactions in different components of wood took place during THM process, such as degradation of hemicelluloses, condensation of lignin, and decomposition of extractives. In turn, these chemical modifications contributed to the darkening of color as well as the reduction of wettability and surface free energy of THM wood.  相似文献   

19.
木材干燥机理和应用的研究   总被引:3,自引:1,他引:3  
通过对木材干燥机理和应用的研究,提高木材的干燥速度并选择合理的干燥方法,从而实施科学的木材干燥作业。  相似文献   

20.
Tree growth stress, resulted from the combined effects of dead weight increase and cell wall maturation in the growing trees, fulfills biomechanical functions by enhancing the strength of growing stems and by controlling their growth orientation. Its value after new wood formation, named maturation stress, can be determined by measuring the instantaneously released strain at stem periphery. Exceptional levels of longitudinal stress are reached in reaction wood, in the form of compression in gymnosperms or higher-than-usual tension in angiosperms, inspiring theories to explain the generation process of the maturation stress at the level of wood fiber: the synergistic action of compressive stress generated in the amorphous lignin–hemicellulose matrix and tensile stress due to the shortening of the crystalline cellulosic framework is a possible driving force. Besides the elastic component, growth stress bears viscoelastic components that are locked in the matured cell wall. Delayed recovery of locked-in components is triggered by increasing temperature under high moisture content: the rheological analysis of this hygrothermal recovery offers the possibility to gain information on the mechanical conditions during wood formation. After tree felling, the presence of residual stress often causes processing defects during logging and lumbering, thus reducing the final yield of harvested resources. In the near future, we expect to develop plantation forests and utilize more wood as industrial resources; in that case, we need to respond to their large growth stress. Thermal treatment is one of the possible countermeasures: green wood heating involves the hygrothermal recovery of viscoelastic locked-in growth strains and tends to counteract the effect of subsequent drying. Methods such as smoke drying of logs are proposed to increase the processing yield at a reasonable cost.  相似文献   

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