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1.
Nitrate resulting from nitrogen fertilisers used in Agriculture is a widespread contaminant of shallow groundwater and causes adverse effects on human, animal and ecosystem health. In order to evaluate the full extent of groundwater nitrate contamination, and how it might evolve in time, it is essential to understand controls on aquifer assimilative capacity. This level of understanding will also help to better target policies and incentives aimed at controlling the amount of nitrate entering downstream water systems.The potential for nitrate attenuation in groundwater was assessed by examining the concentration and distribution pattern of electron donors such as dissolved organic carbon (DOC), ferrous iron, and redox indicators such as dissolved oxygen (DO) and Eh in 57 monitoring bores on the lower Burdekin coastal floodplain, one of Queensland's and Australia's premier irrigation districts. Nitrate concentrations ranged from 0.1 to 14.4 mg/L NO3-N but were mostly undetectable in bores close to the coast. Groundwater age dates suggest that while there are nitrate ‘hot spots’ in certain areas, some or most of the nitrate is being consumed on its way to the ocean. Low nitrate concentrations were coupled with high ferrous concentrations. The low DO concentrations (<2 mg/L) and high ferrous concentrations found in 55% of the bores indicate that redox conditions are suitable for nitrate attenuation by either denitrification or dissimilatory nitrate reduction to ammonium. The reducing environment may be associated with the high DOC concentrations (up to 82 mg C/L) found in these groundwaters. Furthermore, high levels of ferrous iron found in the Ayr area combined with the wide spread geographical distribution of DOC indicate that these areas have a high potential for sustaining geochemical processes that reduces nitrate levels. The distribution of geochemical indicators also suggests that the shallower depths (<15 m) of the groundwater systems have more potential for nitrate reduction than the deeper depths. The map identifying areas within the lower Burdekin with most potential for denitrification is a valuable first step in helping to understand and manage the fate of nitrate entering the groundwater.  相似文献   

2.
We present the results from a sensitivity analysis and a preliminary short-term, site-scale performance assessment of the analytical soil and groundwater nitrate transport RISK-N. The study was carried out in the Central Valley of Chile, on a 2.6 ha corn (Zea mays L.) field underlain by a shallow unconfined aquifer during the cropping season 2000–2001. Nitrogen levels in soils as well as NO3−–N irrigation water and groundwater concentrations were monitored through the crop-growing period, the latter by a network of 16 monitoring wells. A sensitivity analysis shows that both the nitrate flux from the vadose zone and NO3−–N groundwater concentration are mainly influenced by the initial soil nitrogen levels, water input, and soil porosity. Also, simulated groundwater NO3−–N levels are sensitive to changes on the saturated zone denitrification constant. An additional analysis further reveals the significance of the latter parameter, in conjunction with the amount of applied nitrogen fertilizer. We obtained a good agreement between observed average and simulated values. While the model performs well when spatially averaged values are used (root mean square error, RMSE = 1.4 mg l−1 of NO3−–N), the prediction error increases (RMSE = 1.9 mg l−1 of NO3−–N) when the concentration in each well is considered. This fact could be explained by the time and space scale of the experiment and the characteristics of the RISK-N model. The model is easy to use and seems appropriate for mid- and long-term studies of nitrogen contamination in groundwater for agricultural conditions in the Central Valley of Chile and under limited field data availability conditions. However, it needs to be tested for longer periods and under different climatic conditions, soil types, and aquifer characteristics, before its range of applicability can be fully established and recognized.  相似文献   

3.
Identification of nitrate (NO3) leaching hot spots is important in mitigating environmental effect of NO3. Once identified, the hot spots can be further analyzed in detail for evaluating appropriate alternative management techniques to reduce impact of nitrate on groundwater. This study was conducted to identify NO3 leaching hot spots in an approximately 36,000 ha area in Serik plain, which is used intensively for agriculture in the Antalya region of Southern Turkey. Geo-referenced water samples were taken from 161 wells and from the representative soils around the wells during the period from late May to early June of 2009. The data were analyzed by classical statistics and geostatistics. Both soil and groundwater NO3-N concentrations demonstrated a considerably high variation, with a mean of 10.2 mg kg−1 and 2.1 mg L−1 NO3-N for soil and groundwater, respectively. The NO3-N concentrations ranged from 0.01 to 102.5 mg L−1 in well waters and from 1.89 to 106.4 mg kg−1 in soils. Nitrate leaching was spatially dependent in the study area. Six hot spots were identified in the plain, and in general, the hot spots coincided with high water table, high sand content, and irrigated wheat and cotton. The adverse effects of NO3 can be mitigated by switching the surface and furrow irrigation methods to sprinkler irrigation, which results in a more efficient N and water use. Computer models such as NLEAP can be used to analyze alternative management practices together with soil, aquifer, and climate characteristics to determine a set of management alternatives to mitigate NO3 effect in these hot spot areas.  相似文献   

4.
The impact of agricultural practices on soil-groundwater quality in the sub-humid Bekaa plain of Lebanon-East Mediterranean was monitored in four fields (F) between July 2007 and July 2009. These were occupied by continuous mint (F1), summer potato/wheat/potato (F2), lettuce/lettuce/potato/wheat/summer potato (F3) and table grapes (F4). N input calculated on a two-year basis, was in the following ascending order F4, F2, F3 and F1. Soil samples, analyzed down to 200 cm depth, showed high nitrate and chloride concentrations at the end of the 2007 and 2008 seasons. Soil chloride and nitrate peaks recorded in October 2007 and 2008 disappeared below 200 cm overwinter. The calculated N biannual discharge ranged from 130 (F4), to 516 (F2), to 778 (F1), to 879 kg ha−1 (F3). Groundwater quality was studied in 21 wells distributed along a sequence stretching from the Litani River to the eastern water dividing line. Based on the nitrate concentrations, the well located at the top of the water dividing line was the only one suitable for drinking purposes. Eight wells were mildly contaminated, therefore suitable for irrigation purposes except for sensitive crops. Twelve wells, positioned in the plain, showed a nitrate level exceeding 200 mg L−1. Protecting the soil and groundwater quality is a top priority to maintain the ecological and agricultural functions of water.  相似文献   

5.
In Queensland the subtropical strawberry (Fragaria × ananassa) breeding program aims to combine traits into novel genotypes that increase production efficiency. The contribution of individual plant traits to cost and income under subtropical Queensland conditions was investigated, with the overall goal of improving the profitability of the industry through the release of new strawberry cultivars. The study involved specifying the production and marketing system using three cultivars of strawberry that are currently widely grown annually in southeast Queensland, developing methods to assess the economic impact of changes to the system, and identifying plant traits that influence outcomes from the system.From May through September P (price; $ punnet−1), V (monthly mass; tonne of fruit on the market) and M (calendar month; i.e. May = 5) were found to be related (r2 = 0.92) by the function (±SE) P = 4.741(±0.469) − 0.001630(±0.0005)V − 0.226(±0.102)M using data from 2006 to 2010 for the Brisbane central market. Both income and cost elements in the gross margin were subject to sensitivity analysis.‘Harvesting’ and ‘Handling/Packing’ ‘Groups’ of ‘Activities’ were the major contributors to variable costs (each >20%) in the gross margin analysis. Within the ‘Harvesting Group’, the ‘Picking Activity’ contributed most (>80%) with the trait ‘display of fruit’ having the greatest (33%) influence on the cost of the ‘Picking Activity’. Within the ‘Handling/Packing Group’, the ‘Packing Activity’ contributed 50% of costs with the traits ‘fruit shape’, ‘fruit size variation’ and ‘resistance to bruising’ having the greatest (12-62%) influence on the cost of the ‘Packing Activity’. Non-plant items (e.g. carton purchases) made up the other 50% of the costs within the ‘Handling/Packing Group’. When any of the individual traits in the ‘Harvesting’ and ‘Handling/Packing’ groups were changed by one unit (on a 1-9 scale) the gross margin changed by up to 1%. Increasing yield increased the gross margin to a maximum (15% above present) at 1320 g plant−1 (94% above present). A 10% redistribution of total yield from September to May increased the gross margin by 23%. Increasing fruit size increased gross margin: a 75% increase in fruit size (to ≈30 g) produced a 22% increase in the gross margin.The modified gross margin analysis developed in this study allowed simultaneous estimation of the gross margin for the producer and gross value of the industry. These parameters sometimes move in opposite directions.  相似文献   

6.
Excessive irrigation and nitrogen applications result in substantial nitrate leaching into groundwater in intensively cropped oases in desert areas of Alxa, Inner Mongolia. An integrated modelling approach was developed and applied to compare policy incentives to reduce nitrate leaching. The integrated model consists of a process-based biophysical model, a meta-model, a farm economic model and an assessment of policy incentives. The modelling results show that there are “win-win” opportunities for improving farm profitability and reducing nitrate leaching. We found that 4471 Yuan ha−1 of farm gross margin could be obtained with a reduction in nitrate leaching of 373 kg ha−1. Farmers’ lack of knowledge about water and nitrogen in soil, and on crop requirements for water and nitrogen could explain the differences, so that agricultural extension is an appropriate policy incentive for this area. When the economic optimum is obtained reductions in nitrate leaching are not achievable without profit penalties and there is a “trade-off” relationship between farm profitability and groundwater quality protection. The combination of low elasticity of nitrate leaching and large elasticity of farm gross margin against water price increases results in very high costs for reducing nitrate leaching (105.6 Yuan kg−1). It is suggested that if the water price increases were coupled with subsidies for adopting nitrate leaching mitigation practices, environmental gains could come at a lower cost.  相似文献   

7.
Excess salinity in irrigation water reduces sugarcane yield and juice quality. This study was conducted to compare the effect of irrigation with water of 1.3 dS m−1 vs. 3.4 dS m−1 on sugarcane yield and quality, and to evaluate whether an electrostatic conditioning treatment of the water influenced the salt effects. The study was conducted in a commercial field divided into large plots ranging from 1.0 to 1.2 ha in size. Cane and sugar yields were reduced approximately 17% by the 3.4 dS m−1 water compared to the 1.3 dS m−1 water, but juice quality parameters were not affected. Conditioning of the irrigation water using a device called an ‘electrostatic precipitator’ which claimed to affect various water properties had no effect on cane yield, juice quality or soil salinity levels. The detrimental effect of the high salt irrigation water was somewhat less than might be expected, probably due to good late summer rainfall which may have flushed the root zone from the excessive salts.  相似文献   

8.
Research addressing the interactive effects of the dual plant stress factors, excess boron and salinity, on crop productivity has expanded considerably over the past few years. The purpose of this research was to determine and quantify the interactive effects of salinity, salt composition and boron (B) on broccoli (Brassica oleracea L.) fresh head yield, biomass distribution and consumptive water use. A greenhouse experiment was conducted using a sand-tank system in which salinity-B treatment solutions were supplemented with a complete nutrient solution. Chloride-dominated salinity and salinity characteristic of California's San Joaquin valley (SJV), or sulfate-dominated, were tested at ECw levels of 2, 12 and 19 dS m−1. Each salinity treatment consisted of boron treatments of 0.5, 12 and 24 mg L−1. Plant head yield and shoot biomass were significantly reduced by both salinity and boron. Moreover, there was a significant salinity-boron interaction where increased boron was relatively less detrimental under saline conditions. These results occurred regardless of the salt solution composition (chloride or SJV). We found that an ‘interactive model’ better described our growth response than did a ‘single stressor yield model’. Salinity and boron also affected the distribution of shoot biomass. Regardless of salt type, as salinity increased, the fraction of biomass as leaf tissue increased while the biomass fraction as stems and particularly heads, decreased. However, an increase in B at low or high salinity with the SJV composition, decreased the head biomass fraction. This was not observed at moderate salinity, nor on any plants treated with Cl-dominated salinity. Cumulative evapotranspiration (ET) was also reduced by increased salinity but water use efficiency (WUE) was not. WUE was reduced by increased boron, but only at the low and high salinity levels.  相似文献   

9.
In this study deterministic, multivariate and stochastic methods are applied to a combined temporal and spatial monitoring data set, in order to assess nitrate and pesticide levels and contamination risk in shallow groundwater. The case study involves an area in the Mondego River alluvial body in central Portugal, where agriculture is the main land use, with predominantly maize, rice and some vegetable crops supported by river water irrigation. Factorial correspondence analysis (FCA), reducing the original data matrix to a small number of independent orthogonal factors, is applied to detect associations between nitrate levels, land use (crop type), lithology and groundwater depth. Indicator-geostatistical techniques are used to create maps indicating the probability of nitrate concentrations in groundwater exceeding predetermined threshold values, including the drinking water standard (98/83/EC) and vulnerable zone designation criterion (91/676/EEC) of 50 mg/l NO3−. For pesticides the leaching potential is determined by calculating the Groundwater Ubiquity Score (GUS), based on the sorption coefficient and soil half-life for each pesticide compound. Results for nitrate show an overall very low risk of exceeding 50 or 25 mg/l, whereas the risk of exceeding 9.5 mg/l (third data quartile) is particularly high in areas where FCA shows correlation of nitrate contamination with vegetable and maize crops, aerobic conditions, lower groundwater levels and to some extent, coarser grained sediments. On the contrary, nitrate levels under rice are lowest and correlated to a reduced environment, finer-grained sediments and a higher water table. Denitrification is found to be an important attenuation process, as well as dilution by surface water irrigation and precipitation. Crop type and irrigation source are seen to have a large influence on the nitrate contamination potential of groundwater. Total concentrations of the analysed pesticide compounds above the regulatory limit of 0.5 μg/l are observed in 32% of the analysed water samples, with a maximum value of 16.09 μg/l. The probability maps provide a particularly interesting example of how multiple-well monitoring results over a certain period can be condensed into single maps and used by water engineers, managers and policy-makers.  相似文献   

10.
The agro-hydrological model SWAP was used in a distributed manner to quantify irrigation water management effects on the water and salt balances of the Voshmgir Network of North Iran during the agricultural year 2006-2007. Field experiments, satellite images and geographical data were processed into input data for 10 uniform simulation areas. As simulated mean annual drainage water (312 mm) of the entire area was only 14% smaller than measured (356 mm), its distribution over the drainage units was well reproduced, and simulated and measured groundwater levels agreed well. Currently, water management leads to excessive irrigation (621-1436 mm year−1), and leaching as well as high salinity of shallow groundwater are responsible for large amounts of drainage water (25-59%) and salts (44-752 mg cm−2). Focused water management can decrease mean drainage water (22-48%) and salts (30-49%), compared with current water management without adverse effects on relative transpiration and root zone salinity.  相似文献   

11.
Changes in soil fertility status were evaluated for 10 years, from 1996 to 2006 to examine the impact of drip fertigation in a laterite soil and to determine the nutrient uptake pattern of arecanut (Areca catechu L.). Four fertigation levels (25%, 50%, 75% and 100% of recommended fertilizer dose, 100:18:117 g N:P:K palm−1 year−1), three frequencies of fertigation (10, 20 and 30 days) and two controls (control 1: drip irrigation without fertilizer application and control 2: drip irrigation with 100% NPK soil application) were studied. The soil pH increased to 6.0 at the end of experiment in 2006 compared to the pre-experimental soil pH of 5.6 in 1996. In 0-25-cm depth interval, the soil organic carbon (SOC) increased significantly from 1.06% in 1999 to 1.84% in 2006, and in 25-50-cm depth interval, it increased from 0.68% to 1.13%. Temporal variation in available P and K content in arecanut root zone was significant due to drip fertigation. Pooled analysis of data, from 2000 to 2005, revealed significant impact of level and frequency of fertigation and their interaction on available P and K content. At 0-25-cm depth interval, increase in fertigation dose from 50% to 100% NPK did not result in significant increase of Bray’s P content, which remained at par ranging from 5.24 to 5.32 mg kg−1. Fertigation every 30 days resulted in significantly higher available P (5.32 mg kg−1) than fertigation every 10 days (4.49 mg kg−1), while it was at par with fertigation every 20 days (5.09 mg kg−1). The K availability at 0-25-cm depth interval was significantly lower at 25% NPK level (114 mg kg−1) than at 75% (139 mg kg−1) and 100% (137 mg kg−1). With respect to fertigation frequency, the 30-day interval resulted in higher available K of 139 mg kg−1 than 20-day (128 mg kg−1) and 10-day intervals (120 mg kg−1). Availability of P and K at 25-50-cm depth interval followed similar trend as that of 0-25-cm depth interval. The total N uptake (g palm−1 year−1) by leaves, nuts and husk varied between 143 in 0% NPK to 198 in 75% NPK fertigation level. Similarly, the total P uptake (g palm−1 year−1) ranged between 15 for the 0% NPK and 25 for the 75% NPK treatment. The total K uptake (g palm−1 year−1) was 62 for the 75% NPK treatment followed by 56 for the 25%, 56 for the 50%, 54 for the 100% and 46 for the 0% NPK treatments. The nutrient uptake pattern and marginal availability of soil P and K highlight the importance of drip fertigation during post-monsoon season to improve and sustain the yield of arecanut in a laterite soil.  相似文献   

12.
The reuse of saline treated industrial wastewater generated by textile firms mixed with municipal domestic effluent for irrigation was used to asses its effect on the mineral content of three olive (Olea europaea L.) cultivars under greenhouse and field conditions during two complete vegetative cycles. Chemical analysis of the treated wastewater indicated that the element concentrations fall within the permissible range of irrigation water used for plants. However, little impermissible accumulation of Na and Mg higher than the recommended maximum concentration was observed. Irrigation water with six electrical conductivities (EC = 0.78, 1.0, 2.0, 3.0, 4.0 and 5.0 dS m−1 in treatments T0, T1, T2, T3, T4, T5, respectively) were compared in the greenhouse experiment. The olive trees in the field experiment were trickle irrigated with potable water and treated wastewater (average EC = 4.2 dS m−1). The results of the greenhouse experiment showed that leaf N, Cu, Mn, Fe, Pb, and Na contents increased with increasing salinity of the treated wastewater. This increase was accompanied with a decrease in K and Mg contents. Leaf Ca and Cl concentrations were not considerably affected. Ion analysis in roots indicated that the contents of P, Na, Cl, Mn, and Pb increased while K decreased as treated wastewater salinity increased. Consequently, in most cases T4 and T5 gave a highly significant increase or decrease in accumulation of the previously mentioned minerals. A considerable variation in the studied cultivars was noticed. ‘Nabali’ was considered the most tolerant cultivar for the high salinity levels of the treated wastewater; its transporting selectivity of Na from root to leaf was higher and more Na was retained in the roots. Tissue analysis of leaves indicated that the element concentrations were within the adequate levels except those of Fe in ‘Nabali’ and ‘Manzanillo’, Na in ‘Improved Nabali’ and Cu in ‘Nabali’ and ‘Manzanillo’. In view of these findings, the negligible accumulation of minerals in leaves and roots indicated that this kind of textile effluent can be used as a valid alternative for irrigation of olive orchards with continuous monitoring of mineral levels.  相似文献   

13.
Raising surface water levels in peat areas is a measure to reduce soil subsidence, to prevent decay of wooden foundations and to stimulate wet nature restoration and reduce greenhouse gas emissions. However, in these areas dairy farms are present and farming at wetter soils is difficult due to lower bearing capacity of the soil for cattle and machines. Water boards are responsible for the water management of peat areas and thus have to evaluate the effects of water management strategies for the different land use functions. Therefore the hydrological, agronomical and economic effects of different surface water levels are calculated for dairy farms. The ‘Waterpas’ model is used to simulate hydrological effects, dairy farm management and economic results for different meteorological years. The raised surface water level causes a decrease in gross grass yield and a reduction in grass quality. This leads to higher costs and less farmers’ income relative to a reference situation with a freeboard of 60 cm. Raising the surface water increases the average costs for farmers with €89 ha−1 year−1 for a freeboard of 50 cm, €170 ha−1 year−1 for a freeboard of 40 cm and €239 ha−1 year−1 for a freeboard of 30 cm.However, water boards are not only interested in the effects for individual farms, but also for an entire region. A new spatial method was developed for upscaling from farm to polder level. For grassland fields in a typical Dutch peat area classes can be distinguished using GIS data on soil type, soil surface elevation, surface water levels, locations of farms and farm characteristics. The classification is based on 4 classes of freeboards of the grassland fields and 7 typical distributions of grassland fields within a dairy farm. The farm economics were simulated for these typical classes. An increase in costs was simulated for the whole polder Zegveld (1400 ha grassland) of €119,000 year−1 at 10 cm surface water level rise; €133,000 year−1 at 20 cm surface water level rise and €185,000 year−1 at 30 cm surface water level rise.For an integral environmental evaluation of changing hydrological conditions it is advised to incorporate effects on nutrient emission to groundwater and surface water and emission of ammonia and greenhouse gases to the atmosphere.  相似文献   

14.
Carbon (C) and nitrogen (N) dynamics in agro-systems can be altered as a consequence of treated sewage effluent (TSE) irrigation. The present study evaluated the effects of TSE irrigation over 16 months on N concentrations in sugarcane (leaves, stalks and juice), total soil carbon (TC), total soil nitrogen (TN), NO3−-N in soil and nitrate (NO3−) and dissolved organic carbon (DOC) in soil solution. The soil was classified as an Oxisol and samplings were carried out during the first productive crop cycle, from February 2005 (before planting) to September 2006 (after sugarcane harvest and 16 months of TSE irrigation). The experiment was arranged in a complete block design with five treatments and four replicates. Irrigated plots received 50% of the recommended mineral N fertilization and 100% (T100), 125% (T125), 150% (T150) and 200% (T200) of crop water demand. No mineral N and irrigation were applied to the control plots. TSE irrigation enhanced sugarcane yield but resulted in total-N inputs (804-1622 kg N ha−1) greater than exported N (463-597 kg N ha−1). Hence, throughout the irrigation period, high NO3− concentrations (up to 388 mg L−1 at T200) and DOC (up to 142 mg L−1 at T100) were measured in soil solution below the root zone, indicating the potential of groundwater contamination. TSE irrigation did not change soil TC and TN.  相似文献   

15.
A 5-year field trial to assess the impact of microsprinkler irrigation and nutrition on vanilla grown as intercrop in arecanut plantation was conducted on a laterite soil. Pooled analysis indicated that microsprinkler irrigation at 1.0 Epan resulted in significantly higher green bean yield (842 kg ha−1) than 0.75 Epan (579 kg ha−1). Organic manure application in the form of vermicompost (720 kg ha−1) and FYM (768 kg ha−1) and recommended NPK (718 kg ha−1) produced green bean yield at par with recycling of gliricidia prunings (625 kg ha−1). Irrigation at 1.0 Epan proved superior by registering maximum benefit:cost (B:C) ratio of 2.25 compared to 1.62 at 0.75 Epan. The highest B:C ratio was obtained with recommended NPK (2.27) followed by recycling of gliricidia prunings (2.10), vermicompost (1.87), vermicompost + arecanut husk mulching (1.80) and FYM (1.64). The soil pH increased by 0.4 units in 2008 compared with the pre-experimental soil pH of 5.6 in 2004. Nutrition alone and in combination with irrigation had significant impact on soil pH. Organic manure application increased the soil pH (6.1-6.2) significantly over recommended NPK (5.6) at the end of experiment in 2008. Significant variation in soil organic carbon (SOC) was noticed due to different nutrition treatments. Application of vermicompost and FYM significantly increased the SOC content by 38-54% in 2008 over initial levels in 2004. Bray's P availability was influenced by nutrition and its interaction with irrigation. Application of FYM continuously for 4 years has resulted in significant increase in Bray's P content (41.3 mg kg−1) compared to other nutrition treatments (9.4-17.2 mg kg−1). Irrigation equivalent to 0.75 Epan (223 mg kg−1) increased the K availability significantly over 1.0 Epan (172 mg kg−1). The K availability was significantly higher in recommended NPK (416 mg kg−1) than in other organic treatments (98-223 mg kg−1) at 0-30 cm soil depth. Overall, vanilla responded well to irrigation and nutrition in arecanut-based cropping system with a better economic output and improved soil fertility.  相似文献   

16.
Quantification of the interactive effects of nitrogen (N) and water on nitrate (NO3) loss provides an important insight for more effective N and water management. The goal of this study was to evaluate the effect of different irrigation and nitrogen fertilizer levels on nitrate-nitrogen (NO3-N) leaching in a silage maize field. The experiment included four irrigation levels (0.7, 0.85, 1.0, and 1.13 of soil moisture depletion, SMD) and three N fertilization levels (0, 142, and 189 kg N ha−1), with three replications. Ceramic suction cups were used to extract soil solution at 30 and 60 cm soil depths for all 36 experimental plots. Soil NO3-N content of 0-30 and 30-60-cm layers were evaluated at planting and harvest maturity. Total N uptake (NU) by the crop was also determined. Maximum NO3-N leaching out of the 60-cm soil layer was 8.43 kg N ha−1, for the 142 kg N ha−1 and over irrigation (1.13 SMD) treatment. The minimum and maximum seasonal average NO3 concentration at the 60 cm depth was 46 and 138 mg l−1, respectively. Based on our findings, it is possible to control NO3 leaching out of the root zone during the growing season with a proper combination of irrigation and fertilizer management.  相似文献   

17.
Major ions and stable isotopic (δDwater, δ18Owater, δ15Nnitrate, δ18Onitrate) measurements in concert with hydrochemical modeling were used in order to elucidate the sources and geochemical processes controlling nitrate contamination of shallow alluvial groundwater underneath a riverside agricultural field in the Buyeo area, Korea. Beneath vegetable fields in the sandy soil, the mean nitrate concentration of groundwater was 148.6 mg/L, which is significantly higher than in groundwater (mean 28.8 mg/L) beneath silty soils underneath rice paddy fields. Nitrogen isotope data indicate that synthetic fertilizers are the predominant source of groundwater nitrate in the study area. Denitrification during recharge through rice paddy soils appears to be responsible for the lower nitrate concentrations in groundwater beneath the silty soil zone. The relationship between nitrogen and oxygen isotope data of nitrate also suggests mixing of two different groundwater bodies with nitrates from the silt zone and the sand zone. Geochemical mass balance modeling on hydrochemical data indicates that various agricultural chemicals such as urea, lime, magnesium sulfate and potassium chloride dissolve in vegetable fields of the sandy zone, resulting in significant enrichment of various solutes such as K+, Ca2+, Mg2+, NO3−, SO42− and Cl−. As a consequence of over-utilization of synthetic nitrogen fertilizers, the sand zone is characterized by very high nitrate concentrations in the groundwater. This study suggests that a reduction of over-fertilization especially on vegetable fields in the riverside sand zone is required to minimize the nitrate contamination of groundwater. This study also shows that combination of geochemical and isotopic techniques with simple mass balance modeling provides information about the causes and processes of nitrate contamination of groundwater underneath a riverside agricultural field. The study also provides sustainable measures to optimize fertilization rate as an important basis of eco-friendly agriculture.  相似文献   

18.
Agricultural activities are frequently associated with water contamination. The spreading and storage of fertilizers, for instance, may result in groundwater contamination due to pollutants leaching into an aquifer. Nitrates and fecal bacteria are two important contaminants associated with agriculture. Thus, the development of efficient strategies for groundwater protection in agricultural areas requires an assessment of these two contaminants. Given this perspective, groundwater quality monitoring was carried out over the whole capture zone of a municipal well located in an agricultural area in the St.-Lawrence Lowlands in Québec. Thirty-eight piezometers were installed within the roughly 2 km2 capture area of the well to measure physico-chemical parameters such as major ions, field measured parameters (pH, electrical conductivity, dissolved oxygen, water level, temperature), and isotopic ratios, bacteriological parameters (Heterotrophic Plate Count—HPC, enterococci, total coliforms, Escherichia coli) and their variations in space and time. Groundwater was sampled from the pumping well and the piezometers during 25 field campaigns in 2005, 2006 and 2007. The results demonstrate the impact of agricultural activities on nitrate contamination. They indicate high spatial and temporal variations in nitrate concentrations, from 6 to 125 mgNO3−/L within the capture area, with 40% of the samples exceeding the Québec drinking water limit of 45 mgNO3−/L. Nitrate pollution in the municipal well exceeded 45 mgNO3−/L during 2005, but no bacteriological contamination was observed. The results also show a high variability of nitrate concentration with depth within the capture zone. Electrical conductivity appears as a good indicator of the presence of nitrate and calcium ions in this capture zone. Correlations between nitrate, calcium and chloride suggest that these ions come from the same source of fertilizer. Nitrate isotopic composition suggests that nitrate in groundwater originates from both chemical and organic fertilizers. The bacteriological results show that the extracted volume of water during sampling of a piezometer has a significant impact on the bacteria count. The variability of bacteriological pollution is important in space and time, showing a higher contamination during summer. Only 2% of the raw water samples exhibit contamination exceeding the drinking water standard for treated water. Total coliforms seem to be a good precursor of E. coli or enterococci contamination. Globally, the physico-chemical and bacteriological groundwater quality within the studied capture area and the pumping well shows contamination by nitrates, but low contamination levels by fecal bacteria.  相似文献   

19.
Salt balance methods are generally applied in the root-zone and at local scales but do not provide relevant information for salinity management at irrigation scheme scales, where there are methodological impediments. A simple salt balance model was developed at irrigation scheme and yearly time scales and applied in Fatnassa oasis (Nefzaoua, Tunisia). It accounts for input by irrigation, export by drainage and groundwater flow, and provides novel computation of the influence of biogeochemical processes and variations in the resident amount of salt for each chemical component in the soil and shallow groundwater. Impediments were overcome by limiting the depth of the system so that the resident amount of salt that remained was of the same order of magnitude as salt inputs and allowed indirect and reliable estimation of groundwater flow. Sensitivity analyses as partial derivatives of groundwater salinity were carried out according to non-reactive salt balance under steady-state assumption. These analyses enabled the magnitude of the salinization process to be foreseen as a function of hydrological changes linked to irrigation, drainage, groundwater flow and extension of the irrigated area. From a salt input of 39 Mg ha−1 year−1 by irrigation, 21 Mg ha−1 year−1 (54%) and 10 Mg ha−1 year−1 (26%) were exported by groundwater flow and drainage, respectively. 7 Mg ha−1 year−1 (18%) were removed from groundwater by geochemical processes, while a non-significant 2 Mg ha−1 year−1 were estimated to have been stored in the soil and shallow groundwater where the residence time was only 2.7 years. The leaching efficiency of drainage was estimated at 0.77. With a water supply of 1360 mm by irrigation and 90 mm by rainfall, drainage, groundwater flow and actual evapotranspiration were 130, 230, and 1090 mm, respectively. The current extension of date palm plantations and salinization of groundwater resources are expected to significantly increase the salinity hazard while the degradation of the drainage system is expected to be of lesser impact. The approach was successfully implemented in Fatnassa oasis and proved to be particularly relevant in small or medium irrigation schemes where groundwater fluxes are significant.  相似文献   

20.
Olive tree (Olea europaea L.) is commonly grown under environmental conditions characterised by water deficit, high temperatures and irradiance levels typical of Mediterranean semi-arid regions. Measurement of gas exchange, chlorophyll content, chlorophyll fluorescence and photoinhibition was carried out on two-year-old olive trees (cv. ‘Coratina’) subjected to a 21-day period of water deficit followed by 23 days of rewatering. At the beginning of the experiment, plants were divided in to two groups and subjected to different light regimes: exposed plants (EP) under a mean photosynthetically active radiation (PAR) at mid-day of 1800 μmol m−2 s−1 and shaded plants (SP) under a mean PAR of 1200 μmol m−2 s−1. The effect of drought and high irradiance levels caused a reduction of gas exchange and photosystem 2 (PSII) efficiency, in terms of quantum yield of PSII (ΦPSII) both in EP and SP. Shading conditions allowed plants to maintain a high photosynthetic activity at low values of stomatal conductance, whereas in EP the reductions in photosynthetic efficiency and intrinsic water efficiency were due to non-stomatal components of photosynthesis. The decrease in photosynthetic activity and the increase of photoinhibition under drought were more marked in EP than in SP. Full sunlight caused in EP a higher non-photochemical quenching, whereas SP showed a better photochemical efficiency. The information here obtained can be important to understand the mechanisms by which olive plants can minimize photoinhibition when subjected to simultaneous abiotic stresses.  相似文献   

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