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1.
The use of calibrated near infrared (NIR) spectroscopy for measuring and predicting the advancement of wood decay in Pinus spp. sapwood wafers that were subjected to Gloeophyllum trabeum for periods ranging from 1 to 10 days was investigated. NIR spectra were obtained from the center of the cross-sectional face of each sample before and after decay tests. Mass loss and compression tests were also used to measure the progression of decay. Calibrations were created from NIR spectra, mass loss, and compression strength data using untreated and mathematically treated (multiplicative scatter correction and first and second derivative) spectra. Strong relationships were derived from the calibrations with the strongest R 2 values being 0.98 (mass loss) and 0.97 (compression strength). Calibrations for mass loss showed the strongest statistics for predicting wood decay of a separate test set (0.85 raw, second derivative to 0.76 multiplicative scatter correction (MSC), while predictions for compression strength of the decayed samples resulted in R 2 of 0.69 (raw) to 0.54 (MSC). Calibrations created from the amount of time the samples were decayed showed strong statistics, indicating that NIR spectroscopy can predict the early stages of wood decay.  相似文献   

2.
This study examined the origin of the moisture dependency of the longitudinal Youngs modulus of wood (E L ) in relation to the microfibril angle (MFA) of the S2 layer of the secondary wall. Microtomed early wood specimen of sugi (Cryptomeria japonica D.Don) were used for the experiment. The following was revealed:
1.  E L tends to decrease as the moisture content increases in the region below the fiber saturation point (FSP).
2.  The percentage reduction of E L from the oven-dried state to the FSP is almost constant regardless of the MFA.
Subsequently, the relationship between E L and the moisture content was simulated theoretically using the simplified wood fiber model proposed in our previous paper (Part 1, 2002). The simulation considered the two hypotheses proposed in Part 1 for the origin of the moisture content dependency of E L . The first is a traditional theory that the reduction of E L is caused mainly by the moisture dependency of the lignin-hemicellulose matrix. The second assumes that an intermediate domain exists between the rigid crystal and the compliant disordered amorphous regions in wood cellulose microfibril (CMF). It is assumed that such a domain fluctuates between the rigid crystal-like and the compliant amorphous-like states at which the elastic modulus is of the same order as the lignin-hemicellulose matrix in accordance with the moisture sorption.When the first hypothesis is adopted for the simulation, the percentage reduction of E L from the oven-dried state to the FSP should increase as MFA increases; this was contradicted by the experimental results (2). On the other hand, when the second hypothesis is applied to the simulation, the experimentally obtained results (1) and (2) are simulated reasonably. This suggests that the moisture dependency of E L is controlled by the second hypothesis.  相似文献   

3.
Tracheid coarseness, specific surface, wall thickness, perimeter, and radial and tangential diameter from 119 radial strips of Pinus taeda L. (loblolly pine) trees grown on 14 sites in three physiographic regions of Georgia (USA) were measured by SilviScan. NIR spectra were also collected in 10 mm increments from the radial longitudinal surface of each strip and split into calibration (9 sites, 729 spectra) and prediction sets (6 sites, 225 spectra). NIR spectra (untreated and mathematically treated first and second derivative and multiplicative scatter correction) were correlated with tracheid properties to develop calibrations for the estimation of these properties. Strong correlations were obtained for properties related to density, the strongest R 2 being 0.80 (coarseness), 0.78 (specific surface) and 0.84 (wall thickness). When applied to the test set, good relationships were obtained for the density-related properties (R p 2 ranged from 0.68 to 0.86), but the accuracy of predictions varied depending on math treatment. The addition of a small number of cores from the prediction set (one core per new site) to the calibration set improved the accuracy of predictions and, importantly, minimized the differences obtained with the various math treatments. These results suggest that density related properties can be estimated by NIR with sufficient accuracy to be used in operational settings.  相似文献   

4.
The use of calibrated near infrared (NIR) spectroscopy for predicting the chemical composition of Pinus taeda L. (loblolly pine) wood samples is investigated. Seventeen P. taeda radial strips, representing seven different sites were selected and NIR spectra were obtained from the radial longitudinal face of each strip. The spectra were obtained in 12.5 mm sections from pre-determined positions that represented juvenile wood (close to pith), transition wood (zone between juvenile and mature wood), and mature wood (close to bark). For these sections, cellulose, hemicellulose, lignin (acid soluble and insoluble), arabinan, galactan, glucan, mannan, and xylan contents were determined by standard analytical chemistry methods. Calibrations were developed for each chemical constituent using the NIR spectra, wood chemistry data and partial least squares (PLS) regression. Relationships were variable with the best results being obtained for cellulose, glucan, xylan, mannan, and lignin. Prediction errors were high and may be a consequence of the diverse origins of the samples in the test set. Further research with a larger number of samples is required to determine if prediction errors can be reduced.  相似文献   

5.
We propose a non-destructive method to predict the oven-dry density of Sugi (Cryptomeria japonica D. Don) using near infrared (NIR) spectroscopy so as to calibrate a commercial moisture meter. A prediction model for oven-dry density was developed using NIR spectra obtained from Sugi samples with a known density. The density of air-dried Sugi boards was predicted with the developed model. Then, the moisture content (MC) of the boards was measured by a hand-held capacitance-type and an in-line microwave moisture meters. For each board, the moisture meters were calibrated by the predicted density. The predicted density was correlated with the measured one with an R 2 of 0.81 and a standard error of prediction (SEP) of 15.3 kg/m3 within the measured density of 279.2–436.4 kg/m3, indicating that the developed model was applicable for predicting oven-dry density of Sugi. The MC readings of both moisture meters showed a good correlation with the oven-dry MC that ranged from 12.1 to 28.9 %. For both moisture meters, the density calibration with the NIR-predicted density gave a higher R 2 and a lower SEP than with the conventional calibration with the mean density. These results demonstrate that the present density calibration using NIR spectroscopy could improve the performance of the moisture meters for the air-dried Sugi boards with varying densities.  相似文献   

6.
Despite the exceptional position of yew among the gymnosperms concerning its elastomechanical properties, no reference values for its elastic constants apart from the longitudinal Young’s modulus have been available from literature so far. Hence, this study’s objective was to determine the Young’s moduli E L, E R and E T and the shear moduli G LR, G LT and G RT of yew wood. For that purpose, we measured the ultrasound velocities of longitudinal and transversal waves applied to small cubic specimens and derived the elastic constants from the results. The tests were carried out at varying wood moisture contents and were applied to spruce specimens as well in order to put the results into perspective. Results indicate that E L is in the same order of magnitude for both species, which means that a high-density wood species like yew does not inevitably have to have a high longitudinal Young’s modulus. For the transverse Young’s moduli of yew, however, we obtained 1.5–2 times, for the shear moduli even 3–6 times higher values compared to spruce. The variation of moisture content primarily revealed differences between both species concerning the shear modulus of the RT plane. We concluded that anatomical features such as the microfibril angle, the high ray percentage and presumably the large amount of extractives must fulfil important functions for the extraordinary elastomechanical behaviour of yew wood which still has to be investigated in subsequent micromechanical studies.  相似文献   

7.
A nondestructive technique for swiftly measuring the stress level of the surface of wood is proposed, which is important for process control in timber drying. Partial least squares (PLS) regression models for predicting surface-released strain (ε) were developed using NIR spectra obtained from Sugi (Cryptomeria japonica D. Don) samples during drying. The predictive ability of the models was evaluated by PLS analysis and by comparing NIR-predicted ε with laboratory-measured values. The PLS regression model using the NIR spectra pre-processed by MSC and second derivatives with a wavelength range of 2,000–2,220 nm showed good agreement with the measurement (R 2 = 0.72). PLS analysis identified the wavelengths around 2,035 nm as making significant contributions to the prediction of ε. Orthogonal signal correction (OSC) was an effective pre-processing technique to reduce the number of factors required for the model using the wavelength range 1,300–2,500 nm. However, the predictive ability of the OSC-corrected model was not improved. Elapsed times to reach the maximum tensile stress (T max) and the stress reversal point (T rev) at the wood surface during drying were detected correctly for 75 % of the samples. The results show that NIR spectroscopy has potential to predict the drying stress level of the timber surface and to detect critical periods in drying, such as T max and T rev.  相似文献   

8.
The transverse shrinkage variation within trees was examined for five sugi cultivars. The within-tree trends of tangential shrinkage (α T) were different by cultivar, whereas radial shrinkage (α R) increased from pith to bark in most cultivars. The tangential/radial shrinkage ratio (α T/α R) decreased from pith to bark in most cultivars, because the radial variation of α R was larger than that of α T. The cultivars showed significant differences among cultivars in α T, α R, and α T/α R, but the difference among cultivars for α T/α R was smaller. The relationships between transverse shrinkage and microfi bril angle (MFA), basic density (BD), tree ring parameters, and modulus of elasticity were examined. The α T and α R showed positive relationships with BD, latewood percentage, latewood density, and modulus of elasticity, and negative relationships with MFA and ring width. The relationships with earlywood density were weak. Sugi exhibited variation in transverse shrinkage within stem and among cultivars, with the variation affected by MFA, density, and tree ring parameters. Part of this article was presented at the 56th Annual Meeting of the Japan Wood Research Society, Akita, Japan, August 2006, and the 57th Annual Meeting of the Japan Wood Research Society, Hiroshima, Japan, August 2007  相似文献   

9.
Mechanical properties and the visible and near infrared (NIR) (350–2500 nm) spectra obtained from longitudinal and transverse face of 155 small clear wood samples of Chinese fir (Cunninghamia lanceolata) were measured, and 103 of them were used to establish calibration models. Calibrations were tested on an independent set (52 samples). Differences between calibrations developed by using the longitudinal and transverse face were small. The calibrations developed by using NIR spectra (350–2500 nm) collected from transverse face were slightly inferior to those developed by using NIR spectra collected from longitudinal face. When reducing the spectral range to between 780 and 1050 nm, the calibrations developed by using NIR spectra collected from longitudinal face were slightly inferior to those developed by using NIR spectra collected from transverse face, and reducing the spectral range causes no decrease in the quality of the models developed using NIR spectra collected from transverse face. Partial lease square (PLS) modeling and test showed that calibrations developed using the visible and NIR spectra from transverse and longitudinal faces and calibrations developed by using the reducing spectral range (780–1050 nm) from the transverse face were moderate, and have a RPD range from 1.51 to 1.90. It is concluded that NIR spectroscopy can be used as an initial screening. __________ Translated from Journal of Northwest Forestry University, 2007, 22(5): 149–154 [译自: 西北林学院学报]  相似文献   

10.
The dimension lumber （45mm×90mm×3700mm） of plantation Chinese fir （Cunninghamia lanceolata （Lamb.） Hook.） was graded to four different classes as SS, No. 1, No.2 and No.3, according to national lumber grades authority （NLGA） for structure light framing and structure joists and planks. The properties of apparent density was determined at 15% moisture content, bending strength and stiffness were tested according to American Society for Testing and Materials （ASTM） D198-99, and dynamic modulus of elasticity （Eusw） was measured by ultrasonic technique, for predicting the flexural properties of different grade lumbers. The results showed that Eosw was larger than the static MOE. The relationship between Eusw and static MOE was significant at 0.01 level, and the determination coefficients （R2） of the four grade lumbers followed the sequence as R^2No.2 （0.616）〉 R^2ss （0.567）〉 R^2No1 （0.366）〉 R^2No.3 （0.137）. The R^2 of Fusw and MOR were lower than that of the Etru and MOR for each grade. The Eusw of all the grade lumbers, except No.3-grade, had significant correlation with the static MOE and MOR, thus the bending strengthof those grade lumbers can be estimated by the E The Etru valuesof four grade lumbers followed a sequence as No.2-grade （10.701 GPa） 〉 SS-grade （10.359 GPa） 〉 No.l-grade （9.840 GPa） 〉 No.3-grade （9.554 GPa）. For the same grade dimension lumber, its Eusw value was larger than static MOE. Mean values of MOR for four grade lumbers follow a sequence as No.2-grade （48.67 MPa） 〉 SS-grade （48.16 MPa） 〉 No.3-grade （46.55 MPa） 〉 No. 1-grade （43.39MPa）.  相似文献   

11.
In our previous report, we investigated the effect of the microfibril angle (MFA) in the middle layer of the secondary wall (S2) on the longitudinal creep behavior of a thin homogeneous earlywood specimen sugi. In the present study, we investigated the role of moisture on the tensile creep behavior of wood. We discuss the creep behavior of the wood cell wall from the viewpoint of the composite structure of the cell wall and the properties of the constituent materials. A microtomed thin specimen of earlywood of sugi (Cryptomeria japonica D.Don) was used for the longitudinal tensile creep test. Creep tests were conducted at three moisture stages (oven-dry, air-dry, fiber saturation point) over a broad range of MFA. Results showed that the longitudinal tensile creep behavior was highly dependent on both the moisture content and the MFA. With a small MFA, the variation in the creep function among the three moisture states was very small. For a large MFA, the variation in the creep function was larger. At low moisture contents, the magnitude of the creep function was very small, while at high moisture content, it was very large except for the case of specimens with very small MFA. Those results show that the longitudinal tensile creep behavior was directly affected by the fine composite structure and the internal properties of the cell wall constituents.  相似文献   

12.
Near-infrared (NIR) spectroscopy coupled with multivariate analysis was applied to estimate multiple traits of sawn lumber. The effects of the lumber conveying speed (LCS) and measurement resolution of spectra (MRS) on the calibrations were examined. NIR spectra ranging from 1300 to 2300 nm were acquired at LCSs of 10, 20, and 30 m/min and at MRSs of 2, 4, and 16 nm. Prediction models of bending strength (F b), modulus of elasticity in bending tests (E b), dynamic modulus of elasticity (E fr), and wood density (DEN) were developed using partial least-squares (PLS) analysis. LCS and MRS did not significantly influence the calibration performance for any wood property. The regression coefficients also showed no clear differences for any of the conditions. This indicates that the important explanatory variables included in the models are not greatly influenced by these measurement conditions. PLS2 analysis results, when presented graphically, allowed easy interpretation of the relationships between wood mechanical properties and chemical components, e.g., bending strength and stiffness were mainly related to polysaccharides cellulose and hemicellulose. NIR spectroscopy has considerable potential for online grading of sawn lumber, despite the harsh measurement conditions.  相似文献   

13.
A use of near-infrared (NIR) spectroscopy for rapidly predicting the longitudinal growth strain (LGS), as a detector of growth stress, was described. NIR spectra and LGS were measured from peripheral locations of three Sugi (Cryptomeria japonica) green logs. Partial least squares regression model for predicting LGS was developed using the spectral range spanning 770–1200?nm. The predicted LGS was correlated with that measured by the strain gauge method. The coefficient of determination and the root mean square error of prediction were 0.61 and 0.013%, respectively. The predicted peripheral LGS distribution moderately fitted with the measured one. Our results indicate that NIR spectroscopy has a potential to evaluate the magnitude of longitudinal growth stresses on green logs.  相似文献   

14.
This study investigated near-infrared spectroscopy (NIRS) to rapidly estimate physical and mechanical properties of No. 2 2 × 4 southern pine lumber. A total of 718 lumber samples were acquired from six mills across the Southeast and destructively tested in bending. From each piece of lumber, a 25-mm-length block was cut and diffuse reflectance NIR spectra were collected from the transverse face using a FOSS 5000 scanning spectrometer. Calibrations were created using partial least squares (PLS) regression and their performance checked with a prediction set. Overall moderate predictive ability was found between NIRS and the properties for the calibration and prediction sets: block specific gravity (SG) (R 2 = 0.66 and R p 2  = 0.63), lumber SG (0.54 and 0.53), modulus of elasticity (MOE) (0.54 and 0.58), and modulus of rupture (MOR) (0.5 and 0.4). Model performance for MOE (R p 2  = 0.70) and MOR (R p 2  = 0.50) improved when performing PLS regression on a matrix containing lumber SG and NIR spectra. Overall NIRS predicted MOE better than linear models using lumber SG (R 2 = 0.46), whereas lumber SG (R 2 = 0.51) predicted MOR better than NIRS. Overall NIRS has reasonably good predictive ability considering the small volume of wood that is scanned with the instrument.  相似文献   

15.
The investigation of genetically modified trees requires rapid and reliable techniques to measure the mechanical properties at an early age in order to give timely feedback to forest geneticists. In this study, transmittance near-infrared (NIR) spectroscopy was used to predict the green mechanical properties of 1- and 2-year-old transgenic and wild-type aspen. Green modulus of elasticity (MOE) in three-point bending and green ultimate compression strength (UCS) parallel to the grain were predicted from the NIR spectra of dry wood meal pellets. Green UCS had strong correlation (R 2 = 0.91) and green MOE had good correlation (R 2 = 0.78) with the spectra. The latter could be explained by the moderate correlation of MOE with the lignin content of the transgenic samples, suggesting that besides chemical composition MOE also depends on anatomical properties. The ratio of performance to deviation value suggested that the calibration model of both UCS (2.94) and MOE (1.91) could be used for screening.  相似文献   

16.
The objectives of this study were to establish the method of evaluating wood mechanical properties by acoustic nondestructive testing at standing trees and at logs of a Chinese fir (Cunninghamia lanceolata (Lamb.) Hook.) plantation, and to compare three acoustic nondestructive methods for evaluating the static bending modulus of elasticity (MOE), modulus of rupture (MOR), and compressive strength parallel-to-grain (σc) of plantation wood as well. Fifteen Chinese fir plantation trees at 36 years of age were selected. Each tree was cut into four logs, for which three values of dynamic modulus of elasticity, i.e., E sw, of the north and south face based on stress waves to assume the measuring state of the standing tree, E fr, longitudinal vibration, and E us, ultrasonic wave, were measured in the green condition. After log measurements, small specimens were cut and air-dried to 12% moisture content (MC). Static bending tests were then performed to determine the bending MOE and MOR, and compressive tests parallel-to-grain were made to determine σc. The bending MOE of small clear specimens was about 7.1% and 15.4% less than E sw and E us, respectively, and 11.3% greater than E fr. The differences between the bending MOE and dynamic MOE of logs as determined by the three acoustic methods were statistically significant (P < 0.001). Good correlation (R = 0.77, 0.57, and 0.45) between E sw, E fr, and E us and static MOE, respectively, were obtained (P < 0.001). It can be concluded that longitudinal vibration may be the most precise and reliable technique to evaluate the mechanical properties of logs among these three acoustic nondestructive methods. Moreover, the results indicate that stress wave technology would be effective to evaluate wood mechanical properties both from logs and from the standing tree.  相似文献   

17.
The atomic ratios (14C/3H) obtained in ar-curcumene, α-zingiberene, β-bisabolene obtained from the essential oil of rhizomes of Zingiber officinale which were fed with [2-14C, 2-3H2], [2-14C, 4R-3H1] and [2-14C, 5-3H2]mevalonic acid and [1-3H2]farnesylpyrophosphate (FPP) revealed that (a) (2E,6E)-isomer of FPP is isomerised to (2Z,6E)-isomer without loss of epimeric hydrogen that means without a redox process; (b) (2Z,6E)-FPP is cyclised to bisabolyl cation which is the penultimate precursor of α-zingiberene, ar-curcumene and β-bisabolene; and (c) two 1,2-hydrogen shifts take place during the formation of α-zingiberene whereas one 1,2 shift has been observed during the formation of ar-curcumene.  相似文献   

18.
Development of optimal ways to predict juvenile wood stiffness, strength, and stability using wood properties that can be measured with relative ease and low cost is a priority for tree breeding and silviculture. Wood static modulus of elasticity (MOE), modulus of rupture (MOR), radial, tangential, and longitudinal shrinkage (RS, TS, LS), wood density (DEN), sound wave velocity (SWV), spiral grain (SLG), and microfibril angle (MFA) were measured on juvenile wood samples from lower stem sections in two radiata pine test plantations. Variation between inner (rings 1–2 from pith) and outer (rings 3–6 from pith) rings was generally larger than that among trees. MOE and MOR were lower (50%) in inner-rings than in outer-rings. RS and TS were higher (30–50%) for outer-rings than inner-rings, but LS decreased rapidly (>200%) from inner-rings to outer-rings. DEN had a higher correlation with MOR than with MOE, while MFA had a higher correlation with dry wood MOE than with MOR. SLG had higher significant correlation with MOE than with MOR. DEN and MOE had a weak, significant linear relationship with RS and TS, while MOE had a strong negative non-linear relationship with LS. Multiple regressions had a good potential as a method for predicting billet stiffness (R 2 > 0.42), but had only a weak potential to predict wood strength and shrinkage (R 2 < 0.22). For wood stiffness acoustic velocity measurements seemed to be the most practical, and for wood strength and stability acoustic velocity plus core density seemed to be the most practical measurements for predicting lower stem average in young trees.  相似文献   

19.
Near infrared (NIR) reflectance spectroscopy was tested as a fast method for characterizing the toxic effects of air pollution on trees. Fagus sylvatica was exposed to known, different levels of ozone during summer of 2003 in plant chambers. Leaves were taken from the plants and NIR spectra were recorded. In order to derive calibration models, reference analyses were carried out and soluble carbohydrates were determined by an enzymatic method. Minor components, like α-tocopherol, were measured after solvent extraction using gas chromatography-mass spectrometry. A partial least squares (PLS) algorithm was used to perform the chemometric analyses. Good or in some cases very good calibration statistics expressed in terms of root mean square error of cross validation and R2 were obtained for glucose, fructose, sucrose, and α-tocopherol. In addition, a better than expected correlation between the NIR spectra of the leaves and the ozone concentration in the plant chambers was observed. NIR spectroscopy appears to be a very useful method to simultaneously determine many components in leaves that are related to the health of trees. It is obviously able to quantitatively describe the changing patterns of constituents in leaves of trees caused by toxic substances. Thus, NIR spectroscopy can be a very effective tool for environmental biomonitoring, especially for observation of forests.  相似文献   

20.
Dynamic elastic modulus (EL) and wave velocity (V) were determined using resonance vibrations from initially green, 100 × 50 mm sample boards of Eucalyptus regnans F. Muell., and after several stages of drying to oven dry. EL and V were determined from impact induced vibrations and spectral analysis. EL and V from green wood were positively related to basic density and normal shrinkage, only V was negatively related to green density, and both EL and V were negatively related to green moisture content and the number of internal checks after drying. The latter relationship has the potential to provide a simple method of segregating highly check prone material. No significant relationships were obtained with collapse. Outside the hygroscopic range, in low shrinkage material, EL increased little or gradually, while in high shrinkage, collapse prone material, it increased more rapidly, but no clear breakpoint was evident. In the hygroscopic range, EL increased rapidly in all samples. V increased curvilinearly throughout the entire moisture range, but no difference between collapse prone and non-collapse prone material was observed. Received 16 February 1998  相似文献   

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