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1.
三种铁氧化物的磷吸附解吸特性以及与磷吸附饱和度的关系   总被引：17，自引：0，他引：17  
采用三种人工合成铁氧化物(针铁矿、赤铁矿和水铁矿)比较了结晶态和无定形铁氧化物对磷的吸附—解吸特性以及与磷吸附饱和度的关系。结果表明,三种铁氧化物的磷吸附特性均可用Langumir方程来描述,相关系数均大于0.9,达到极显著水平。从磷最大吸附量(Qm)、吸附反应常数(K)和最大缓冲容量(MBC)三项吸附参数综合考虑,水铁矿(无定形)对磷的吸附无论在容量还是强度方面均比结晶态铁氧化物针铁矿和赤铁矿大得多。水铁矿吸附的磷比针铁矿和赤铁矿所吸附的磷更难解吸;水铁矿的大量活性表面并没有表现出增加磷释放的作用。磷吸附饱和度有望作为评价土壤或铁氧化物磷吸附—解吸的强度和容量因子的一个综合指标。  相似文献   

2.
As repeatedly reported, soil flooding improves the availability of P to rice. This is in contrast with an increased P sorption in paddy soils. The effects of soil flooding on the transformation of Fe oxides and the adsorption/desorption of P of two paddy soils of Zhejiang Province in Southeast‐China were studied in anaerobic incubation experiments (submerging with water in N2 atmosphere). Soil flooding significantly increased oxalate‐extractable Fe (Feox), mainly at the expense of dithionite‐soluble Fe (FeDCB), as well as oxalate‐extractable P (Pox), but decreased the ratio of Pox/Feox. Flooding largely increased both, P adsorption and the maximum P adsorption capacity. The majority of newly sorbed P in the soils was Pox, but also more newly retained P was found to be not extractable by oxalate. Flooding also changed the characteristics of P desorption in the soils. Due to a decrease of the saturation index of the P sorption capacity, P adsorbed by flooded soils was much less desorbable than that from non‐flooded soils. There are obviously significant differences in the nature of both, the Feox and Pox fractions under non‐flooded and flooded conditions. The degree of the changes in Feox, Pox, P adsorption and P desorption by flooding depended on the contents of amorphous and total Fe oxides in non‐flooded soils. Our results confirm that the adsorption and desorption behavior of P in paddy soils is largely controlled by the transformation of the Fe oxides. The reasons of the often‐reported improved P availability to rice induced by flooding, in spite of the unfavorable effect on P desorbability, are discussed.  相似文献   

3.
Over-fertilization has caused significant phosphorus(P) accumulation in Chinese greenhouse vegetable production(GVP) soils. This study, for the first time, quantified profile P accumulation directly from soil P measurements, as well as subsoil P immobilization, in three alkaline coarse-textured GVP soil profiles with 5(S5), 15(S15), and 30(S30) years of cultivation in Tongshan, Southeast China. For each profile, soil samples were collected at depths of 0–10(topsoil), 10–20, 20–40, 40–60, 60–80, and 80–100 cm. Phosphorus accumulation was estimated from the difference in P contents between topsoil and parent material(60–100 cm subsoil). Phosphorus mobility was assessed from measurements of water-soluble P concentration(PSol). Finally, P sorption isotherms were produced using a batch sorption experiment and fitted using a modified Langmuir model. High total P contents of 1 980(S5), 3 190(S15), and 2 330(S30) mg kg~(-1) were measured in the topsoils versus lower total P content of approximately 600 mg kg~(-1) in the 80–100 cm subsoils. Likewise, topsoil PSol values were very high, varying from 6.4 to 17.0 mg L~(-1). The estimated annual P accumulations in the topsoils were 397(S5), 212(S15), and 78(S30) kg ha~(-1) year~(-1). Sorption isotherms demonstrated the dominance of P desorption in highly P-saturated topsoils, whereas the amount of adsorbed P increased in the 80–100 cm subsoils with slightly larger P adsorption capacity. The total P adsorption capacity of the 80–100 cm subsoils at a solution P concentration of0.5 mg L~(-1) was 15.7(S5), 8.7(S15), and 6.5(S30) kg ha~(-1), demonstrating that subsoils were unable to secure P concentrations in leaching water below 0.5 mg L~(-1) because of their insufficient P-binding capacity.  相似文献   

4.
《Journal of plant nutrition》2013,36(12):2259-2272
Abstract

Pot experiments were conducted in a glasshouse to investigate the effect of soil water content and phosphorus (P) supply on biomass, P uptake by rice cultivated in soils with different water regimes and soil available P. Results showed that P application rates had greater effect on P nutrition of rice than soil moisture content. Yield of rice grain was significantly decreased when soil moisture content was kept at 60% of water holding capacity (WHC) while the yields of rice grain were not significantly different when soil moistures were remained at 80% of WHC and waterlogged. This meant that it was possible for paddy rice variety to be cultivated in aerobic soil under the condition of sufficient P supply. The highest biomass of rice and highest P uptake by rice were found in the treatment with 0.0300 g P kg?1 of P application rate and with 80% of WHC. Soil available P content decreased with the decrease of both the soil moisture content and the P applied. Rice crop exhausted soil P to a great extent leading to very low available soil P content when the rice crop was harvested, especially in the soil receiving no or small amounts of P fertilizer. All the results obtained in this experiment could provide the theoretic base for water and P management of paddy rice variety cultivated in aerobic soil in the southern hilly areas of China.  相似文献   

5.
ABSTRACT

Lucerne or alfalfa (Medicago sativa L.) is grown as a forage crop on many livestock farms. In calcareous soils in eastern Turkey, lucerne production requires phosphorus (P) additions as the soils are naturally P deficient. Phosphorus sorption isotherms were used to estimate P fertilizer needs for lucerne grown for two years in a 3-cut system on a calcareous P deficient Aridisol in eastern Anatolia, Erzurum province, Turkey. Annual P applications ranged from 0–1200 kg P ha?1. The Langmuir two-surface adsorption equation was used to derive the maximum P sorption capacity of unamended soil and to determine soil solution P, maximum buffer capacity (MBC), equilibrium buffer capacity (EBC), and P saturation at the optimum economic P rate (OEPR) for dry matter (DM) production. Soils were tested for Olson P at the onset of the study and after two years of P applications. In both years, tissue was analyzed for P content at flowering prior to first cutting. The OEPR (2-year average) was 754 kg P ha?1 yr?1 corresponding with a soil solution P concentration of 0.30 mg L?1, a DM yield of 8725 kg DM ha?1, and $528 ha?1 annual profit. The P content of leaves at flowering increased linearly with P application beyond 100 kg P ha?1 and was 3.2 g kg?1 P at the OEPR. The unfertilized soil had an EBC, MBC, P saturation, and Xmax of 3304 mL g?1, 3401 mL g?1, 6%, and 1086 mL g?1, respectively, whereas two years of fertilization to the OEPR decreased EBC and MBC to 358 mL g?1 and 540 mL g?1, and increased P saturation and Olsen P to 56% and 32 mg kg?1, respectively. These results suggest a P saturation >50% or Olsen P >30 mg kg?1 are needed to maintain an optimum soil solution concentration of 0.30 mg L?1 in this calcareous Aridisol. Similar studies with different soils and initial soil test P levels are needed to conclude if these critical soil test values can be applied across the region.  相似文献   

6.
Semiarid soils are subjected to wetting and drying cycles which influence sorption and desorption of applied phosphorus fertilizer. Phosphorus desorption was determined in soils from toposequences of two soil groups (Ferralsol and Luvisol) from a semiarid area, subjected to wetting and drying cycles. Samples from surface and subsurface horizons of upslope, midslope, and downslope positions were incubated for 4 months with phosphorus doses corresponding to 0, 5, 10, 25, 50, 75, and 100% of the maximum adsorption capacity, under constant moisture (80% water retention capacity) or 12 cycles of wetting and drying. Phosphorus desorption was lower in the Ferralsol than in the Luvisol, and lower in the subsurface than in the surface horizons, probably due to greater clay, Fe, and Al oxides contents, but they were similar among slope positions, of same mineralogy. Desorption tended to be greater in samples submitted to wetting and drying cycles but differences were small. P recovery reached 40–50% in the Luvisol, and 30–40% in the Ferralsol. The relatively low P retention capacity suggests a high residual effect of the P applied. Therefore, in relation to P losses, water retention techniques are less important than those that prevent soil erosion.  相似文献   

7.
柠檬酸对三种人工合成氧化铁磷吸附特性的影响   总被引：1，自引：0，他引：1  
试验采用了3种人工合成的氧化铁为材料,研究了氧化铁对磷的吸附以及柠檬酸对氧化铁磷吸附特性的影响。结果表明:3种人工合成的氧化铁对磷的吸附特性及柠檬酸对氧化铁吸附磷的影响都可用Langumir方程来描述,都达到了极显著水平。从磷的最大吸附量(Sm)、吸附反应常数(K)和最大缓冲容量(MBC)来看,未加入柠檬酸时,水铁矿对磷的吸附在容量和强度方面均为最高;而在加入柠檬酸时,3种人工合成的氧化铁对磷的吸附能力的顺序并无差别,水铁矿和针铁矿的磷Sm和MBC要比赤铁矿大很多。  相似文献   

8.
ABSTRACT

Phosphorus (P) nutrition of the rice-wheat (RW) systems of the Indo-Gangetic Plain of South Asia has become important due to the alternate flooding and drying cycles of this crop rotation. Field experiments on the RW cropping sequence were conducted at three locations of Bangladesh on three soil types. Two fertilizer doses—farmers' practice (FP) and soil-test based (STB), containing recommended amounts of P, nitrogen (N), potassium (K), and other nutrients—were compared with mungbean or maize as a third crop. The objective of the experiments was to detect P deficiency, if any, in rice, wheat, mungbean, and maize, and to compare the FP and STB doses of fertilizers in rice-wheat-mungbean and rice-wheat-maize sequences under two mungbean management practices (residue removed or retained) and one maize management practice (residue removed) in terms of P nutrition of those crops and annual system-level P removal and apparent P balance in the soil. The apparent P balance was negative with the FP dose (?1 to ?9 kg ha?1 for mungbean sequences at Joydebpur and Nashipur) and there was soil P accumulation under both the STB dose (9–49 kg ha?1) and zero N control (13–50 kg ha?1) across sites. The effect of maize or mungbean as the pre-rice crop on the apparent P balance of various RW sequences was not significant. Phosphorus deficiency occurred at all sites in wheat and maize, and at Ishwordi in rice, suggesting that P fertilizer recommendations need to be revised for RW systems in Bangladesh. The results also suggest that long-term monitoring for P concentration, uptake, and balance would be necessary for improving not only the productivity and sustainability of this system but also the fertilizer P-use efficiency.  相似文献   

9.
Peat is commonly used as the main component of horticultural substrates, but it has a very low buffering capacity for the anionic macronutrient phosphorus (P), which can be increased by the addition of clays. The aim of this study was to characterize the P adsorption capacity of different substrate clays and to evaluate its significance for plant P uptake. Substrate clays were characterized with a single‐point batch experiment and adsorption and desorption isotherms. The data were fitted to the Langmuir equation for a calculation of the maximum adsorption capacity. Additionally, the contents of oxalate extractable Fe and Al (ΣFeox + Alox) were determined. The influence of a varying P adsorption capacity of the clays on the P availability to plants in the respective peat–clay substrates and pure peat was investigated in a growth experiment with Impatiens walleriana fertigated with 0, 17, and 35 mg P L?1 solution, respectively. The observed and calculated (Langmuir) P adsorption capacity of the clays could be well‐characterized by both the batch experiment and the adsorption isotherms and was highly correlated with the ΣFeox+Alox. A higher P adsorption capacity of the clay amendment in mixed substrates resulted in a lower P concentration in the substrate solution, while the CAT extractable P concentration (PCAT) was the same. Plant growth and shoot P concentrations were enhanced in the substrates, showing a higher P adsorption capacity, since plants were able to take up the whole amount of PCAT, and also part of the non‐CAT extractable P. However, the release rate was too low to ensure optimal plant growth, which was in accordance with the result of the desorption experiment. The absolute extent of P release was increased with the increasing P adsorption capacity of the clays and higher degree of P saturation (DPS).  相似文献   

10.
蔬菜地土壤磷饱和度及其对磷释放和水质的影响   总被引：24，自引：0，他引：24  
为了解蔬菜地土壤磷素的积累对水环境的影响,我们在浙江省选择了33个代表性蔬菜地,采集和分析了土壤、地表水和地下水样的磷素状况,从土壤磷饱和度的角度,研究了浙江省主要蔬菜土壤磷积累状况及其对地表和地下水水质和土壤磷释放潜力的影响。结果表明,半透膜渗析法测得的磷释放量与土壤磷积累呈正相关,磷释放量随土壤磷饱和度的提高而增加。蔬菜地土壤磷饱和度的增加可显著提高地表水体和地下水中磷的浓度,当土壤磷饱和度小于25%左右时,水体中磷浓度随土壤磷饱和度增加较为缓慢;但当磷饱和度大于25%时,水体中磷浓度随土壤磷饱和度提高迅速上升。地表水中磷浓度主要与表层土壤磷饱和度有关;地下水中磷浓度主要受深层土壤磷饱和度的影响,与表层土壤磷饱和度的相关性较小。土壤磷饱和度可很好地表征土壤磷释放和对环境的潜在影响。  相似文献   

11.
Abstract

Cyclophosphates are not adsorbed by soil constituents and can be mobile in the soil profile. Mobile phosphorus (P) sources are of interest in soil science and for agronomic practices. Cyclotri (Na3P3O9; C3P), and cyclotetraphosphate (Na4P4O10; C4P) were compared to linear, ortho‐, pyro‐, and tripolyphosphate in four soils with different chemical, physical, and biological properties to determine their mobility and availability to corn (Zea mays, L.) in laboratory and greenhouse experiments. Cyclophosphate (C3P and C4P) hydrolysis products were evaluated by ion chromatography after incubating for 6 to 192 h with 100 and 200 µg P g?1 soil. Phosphorus distribution and mobility, and plant availability and uptake with time, were determined in 45‐cm columns for four soils. Cyclophosphates sorbed less and moved deeper in all soils compared to the linear phosphates. The results showed that after 24 h a large proportion of cyclophosphates (34% of C3P and 37% of C4P) remained unhydrolyzed in Falba sandy acid soil. Split application of C3P and C4P at planting and at booting stage increased corn yield in sandy acid soil. Results of this experiment suggest that P deficiency after plant establishment can be corrected with cyclophosphates in soils with a low potential for cyclo‐P hydrolysis.  相似文献   

12.
Laboratory experiments were conducted to study the kinetics of phosphorus (P) desorption in different calcareous soils of Hamadan Province of Iran. Soils were fertilized with poultry manure at 50 ton ha–1 and incubated at 25 ± 1 °C at 15% moisture for 6 months. The release rate of P was studied by successive extraction with 0.5 M sodium bicarbonate (NaHCO3) over a period of 1–1752 h. Also, available P was determined. The results showed that available P in fertilized and unfertilized soils ranged from 13.3 to 55.1 and 10.0 to 50.1 mg kg–1, respectively. Phosphorus desorption from the fertilized and unfertilized soils began with a fast initial reaction, followed by a slow secondary reaction. The amount of P released after 1752 h in fertilized and unfertilized soils ranged from 319.2 to 623.9 and 309 to 586.7 mg kg–1, respectively. The amount of P released was significantly correlated with available P. The kinetics of cumulative P release were evaluated using the five kinetic equations. Phosphorus desorption kinetics were best described by the parabolic diffusion law, first order, and power function equations. Rate constants of these equations different in fertilized and unfertilized soils.  相似文献   

13.
Phosphorus(P) is a limited resource that could be depleted. Consequently, recycling the P contained in sewage sludge, including sewage sludge incineration ash(SIA), from wastewater treatment plants is a possibility to be explored. A greenhouse experiment using annual ryegrass(Lolium multiflorum L.) was performed with an experimental design of three completely randomized blocks of two soils and 29 treatments: one control without P and two levels of 9 and 26 kg total P ha~(-1) from 14 different sources: twelve SIAs(not contaminated by trace metals) from the US and Canada, one commercial synthetic fertilizer(triple superphosphate(TSP)), and one commercial rock phosphate(RP). Higher ryegrass biomass levels were achieved at the higher fertilization rate(26 kg total P ha~(-1))and when using the SIAs with the highest P solubility percentage(PSP)(≥ 54% of total P). The biomass increases following SIA application were as high as 29% and 59% more than the control for the sandy loam and clayey soil, respectively, but 40% less than in TSP for both soils. A similar behavior was observed for P uptake, with a maximum increase of 26% for the clayey soil, and 165% for the sandy loam soil. The ryegrass biomass and P uptake increases due to SIA application were larger than those due to RP application in the clayey soil, but similar to those in the sandy loam soil. The SIAs with a PSP of ≥ 54% significantly increased soil available P stocks and saturation. According to our findings, we conclude that the SIAs from municipal and agrifood industries have a potential for P agricultural recycling, but their efficiencies vary.  相似文献   

14.
Abstract

Plant‐available phosphorus (P) measured by routine soil‐test methods is poorly correlated with rice grain yield in Arkansas. Our objective was to determine whether soil water pH (pHw) and Mehlich‐3 P were correlated with growth and yield of rice grown on silt loam soils. Data from 35 field studies were used to correlate Mehlich‐3 P and pHw with relative yield, dry matter accumulation, and P concentration at the midtillering stage. Significant linear or nonlinear relationships between pHw or Mehlich‐3 P with rice growth parameters were delineated but explained less than 27% of the variability in dry matter and P concentrations at the midtillering stage and grain yield at maturity. Mehlich‐3 P and pHw together explained 61% of the variability in midtillering P concentrations. Midtillering whole‐plant P concentrations were positively related to relative grain yield and dry matter production and will be used to identify soils with limited P availability for rice in Arkansas.  相似文献   

15.
Phosphorus (P) availability in soil is closely related not only to soil P content but also to soil physicochemical and biological properties, which are closely associated with P sorption and biochemical transformation. The aims of this study were to determine the effects of pig manure compost (PMC) or decaying rice straw (DRS) added to a paddy soil on soil pH, soil organic carbon (SOC), dissolved organic carbon (DOC), acid phosphatase, microbial biomass P, soil test P (Olsen P), and P uptake by rice (Oryza sativa L. cv. ‘Liaoyan’). Phosphorus adsorption characterization affected by PMC‐ or DRS‐derived DOC was also studied. Compared with the control, both PMC and DRS treatments increased soil pH, SOM, DOC, microbial biomass P, and Olsen P, and the activity of acid phosphatase during the 110‐day incubation period. Phosphorus adsorption in soil decreased with DOC extracted from PMC and DRS and was well fit by the Langmuir equation. The Olsen P in the PMC‐ and DRS‐treated soil was correlated with both DOC content and acid phosphatase activity. Both PMC and DRS treatments significantly increased dry‐matter yield and P uptake in rice shoot. In conclusion, the increased P availability in the paddy soil was not only a result of direct P supplied following organic manure incorporation, but also an indirect result of reduction in P sorption on the solid phase of the paddy soil by DOCs which were derived from DRS or PMC.  相似文献   

16.
Abstract

Phosphorus (P) determination by the phosphomolybdate‐blue (Mo‐blue) and phosphomolybdate‐vanadate‐yellow (vandate‐yellow) color methods using NH4OH to neutralize excessive acidity were unaffected by increasing manganese (Mn) content in standard P solutions and rice plant acid digests. The vanadate‐yellow color method using sodum hydroxide (NaOH) to neutralize excessive acidity over estimated P when the Mn content exceeded 0.16 Hg/ Mn/mL in the final dilution of standard P solution and 247 fig Mn/g in rice plant tissue. Phosphorus determination by the vanadate‐yellow color method using ammonium hydroxide (NH4OH) was linearily related with P estimated by the Mo‐blue color and vanadate‐yellow color methods using NaOH for acid neutralization. Phosphorus estimated by the vanadate‐yellow color method using NH4OH could be calculated from the a regression between both methods of neutralizing the excessive acidity.  相似文献   

17.
  【目的】  比较长期不施磷与施磷黑土对外源磷的吸附–解吸特征,为黑土区磷素管理提供理论基础。  【方法】  供试黑土长期定位试验位于吉林省公主岭市,始于1990年。2018年选择其中不施肥(CK),施氮钾肥(NK),施氮磷钾肥(NPK)和氮磷钾+有机肥(NPK+M) 4个处理小区,采集0—20、20—40和40—60 cm土层的土壤样品,分析了土壤理化性质,采用恒温平衡法测定了土壤磷的吸附–解吸特征,并由此计算得到磷最大吸附量(Qm)、吸附亲和力常数(KQ)、最大缓冲容量(MBC)、磷吸附饱和度(DPS)、最大解吸量(Dm)和解吸率(Dr)。  【结果】  随着平衡溶液中磷浓度的增加,磷的吸附量与解吸量均呈先快速增加后逐渐趋于平衡的过程。与不施磷处理(CK和NK)土壤相比,施磷处理(NPK、NPK+M)减少了磷的吸附量,增加了磷的解吸量。与不施磷处理相比,施磷处理在0—60 cm剖面上的Qm和MBC值分别降低了4.94%～63.46%和15.90%～75.18%,Dr值增加了8.52%～474.0%,以NPK+M处理变化量最大。施磷处理比不施磷处理在0—60 cm土壤剖面上全磷和有机质含量分别增加了34.40%～145.5%和12.77%～50.07%,游离态铁铝氧化物(Fed+Ald)含量降低了5.14%～11.35%。冗余分析表明,不施磷处理土壤的有机质、Fed+Ald和全磷,以及施磷处理中的Fed+Ald、络合态铁铝氧化物(Fep+Alp)、pH和有机质是影响磷吸附解吸特征参数的主要土壤因子,分别解释了不施磷和施磷处理全部变异的77.59%和90.62%。土壤有效磷(Olsen-P)与磷吸附饱和度(DPS)相关关系表明,所研究的黑土DPS环境界限值为8%左右,NPK+M处理中3个土层的DPSM-P值(由Mehlich-3 浸提的磷、铁和铝计算)为7.77%～25.96%,DPSO-P值(由Olsen-P和Qm计算)为17.24%～24.75%,均高于此环境界限值,具有磷素流失的风险。  【结论】  长期施磷降低了黑土对外源磷的吸附量,增加了磷解吸量。长期不施磷肥,土壤对磷的吸附和解吸主要受有机质、游离态铁铝氧化物的影响。而长期施肥,特别是有机肥与化肥配合处理,土壤中游离态和络合态铁铝氧化物、有机质及pH是影响磷吸附解吸特征的主要因素。  相似文献   

18.
Abstract

Added P adsorbed, expressed as a percentage of total added P, was closely and inversely related to added P subsequently desorbed, expressed as a percentage of added P adsorbed. This relationship was not linear but followed a hyperbola‐like curve. For the limiting cases where adsorption was 0% and 100%, desorption was 100% and 0%, respectively. If desorption is the mechanism limiting the release of P into the soil solution for plant utilization, then the well‐established relationship between P adsorbed in the laboratory and the recovery of fertilizer P under field conditions is accounted for.  相似文献   

19.
The secretion of O2 by rice roots results in aerobic conditions in the rhizoshere compared to the bulk flooded soil. The effect of this phenomenon on the adsorption/desorption behavior and on the availability of phosphorus (P) in a flooded soil was investigated in a model experiment. An experimental set‐up was developed that imitates both O2 release and P uptake by the rice root. The results showed that O2 secretion significantly reduced P adsorption/retention and increased P desorption/release in the “rhizosphere” soil, compared to the anaerobic bulk soil. The P uptake by an anion exchange resin from both unfertilized and P‐amended soil was significantly increased. The results confirm that the O2 secretion is an important mechanism to enhance P availability and P uptake of rice under flooded conditions, where the “physico‐chemical” availability of P in the anaerobic bulk soil is strongly reduced. The decrease of P availability in the P‐amended flooded bulk soil was mainly associated with the almost complete transformation of the precedingly enriched Al‐P fraction into Fe‐bound P with extremely low desorption/release characteristics during the subsequent flooding.  相似文献   

20.
Exudation of organic acids by the roots of three rice cultivars grown in three soils of different phosphorus (P) statuses, and their impacts on the rhizospheric P dynamics and P uptake by the rice plants, were investigated. Quantum root exudates from all the rice cultivars were significantly greater at 21 days after transplantation than at panicle initiation or flowering stages. Malic acid was the most predominant organic acid present in the rice root exudates (10.3 to 89.5 μmol plant?1 d?1), followed by tartaric, citric, and acetic acids. Greater exudation of organic acids from rice grown in P-deficient soil by all the rice cultivars suggested response of rice plant to P stress. Results indicate that the release of organic acids in the root exudates of rice plants can extract P from strongly adsorbed soil P fraction, thereby increasing native soil P utilization efficiency and ensuring adequate P nutrition for the growing rice plants.  相似文献   

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