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1.
Abstract

Applications of zinc (Zn) and copper (Cu) at excessive rates may result in phytotoxicity. Experiments were conducted with mixtures of soils that were similar except for their Zn and Cu levels. The critical toxicity levels (CTL) in the soils and plants for these elements were determined. Peanut (Arachis hypogaea L.), soybean [Glycine max (L.) Merr.], corn (Zea mays L.), and rice (Oryza sativa L.) were the crops grown. One soil mixture had Mehlich 3‐extractable Zn concentrations up to 300 mg dm‐3 with no corresponding increase in soil Cu; two soil mixtures had soil Zn concentrations up to 400 and 800 mg dm‐3 with a corresponding increase in soil Cu up to 20 and 25 mg dm‐3, respectively; and four soil mixtures had no increase in soil Zn, but had Mehlich 1‐extractable Cu concentrations from 6 to 286 mg kg‐1. Under a given set of greenhouse conditions, the estimated Mehlich 3‐extractable Zn CTL was 36 mg dm‐3 for peanut, 70 mg dm‐3 for soybean, between 160 and 320 mg dm‐3 for rice, and >300 mg dm‐3 for corn. No soil Cu CTL was apparent for peanut or soybean, but for corn it was 17 mg dm‐3 and for rice 13 mg dm‐3. With different greenhouse procedures and the Mehlich 1 extractant, the soil CTL for rice was only 4.4 mg kg‐1. Therefore, peanut and soybean were more sensitive to Zn toxicity, whereas corn and rice were more sensitive to Cu toxicity. Plant Zn CTL for peanut was 230 mg kg‐1, while that for soybean was 140 mg kg‐1. Copper appeared to be toxic to corn and rice at plant concentrations exceeding 20 mg kg‐1.  相似文献   

2.
Abstract

Different chemical reagents are used to assess plant‐available nutrients from soils with similar properties. The use of different extractants is a serious limitation when comparing results between different soil‐testing laboratories, often leading to large differences in fertilizer recommendations for similar crops.

In this study, 80 samples from acid soils from Galicia (Spain) were used to compare several soil nutrient extractants. Traditional and tested extractants for acid soil such as Bray 2 and ammonium acetate were used to evaluate multielement extractants such as ethylenediaminetetraacetic acid–ammonium acetate (EDTA‐aa), ammonium bicarbonate–diethylenetriaminepentaacetic acid (AB‐DTPA), and Mehlich 3.

Linear regression analyses were performed to relate the amount of each nutrient obtained by traditional soil extractants to the amount obtained by multielement extractants. Strong correlation was found between extractable Bray 2 P and Mehlich 3 P (r2=0.97, slope=0.87, and intercept=?0.48). The slope of the regression line between EDTA‐aa‐extractable calcium (Ca) and that from ammonium acetate (Aa) approached 1∶1 (r2=0.86). Similar results were obtained for magnesium (Mg) (r2=0.99). Soil zinc (Zn) concentrations extracted by Mehlich 3 and EDTA‐aa were similar; slope of the regression line was 0.95 (r2=0.88). With regard to copper (Cu), Mehlich 3 extracted approximately 20% more Cu than EDTA‐aa.

The results showed that Mehlich 3 and EDTA‐aa are suitable for assessment of plant available phosphorus (P), potassium (K), Ca, Mg, Cu, Zn, and iron (Fe) in acid soils.  相似文献   

3.
Abstract

The Mehlich 3 (M3) extractant was introduced in 1981 to improve the efficiency of soil testing laboratories by eliminating the need for multiple extractants for P, K, Ca, Mg, Mn, Cu and Zn. The M3 was also intended to be suitable for a wide range of soils, perhaps to serve as a “universal”; soil test extractant. At present, regional soil testing committees throughout the U.S. are investigating the M3 in this regard.

Development of a field calibration data base for a new soil testing extractant is an essential, but expensive and time‐consuming process. An interim measure is the use of conversion equations between new and current extractant(s). These equations allow for use of the new extractant with existing field calibration data. The objectives of this study were (i) to develop conversion equations for the Mehlich 1 (M1) and M3 extractants for Atlantic Coastal Plain soils, and (ii) to determine the influence of soil pH and organic matter content on the relative extractability of P, K, Ca, Mg, Mn and Zn by Ml and M3.

Four hundred soil samples, obtained from field plots and commercial crop samples submitted to the University of Delaware Soil Testing Laboratory were analyzed for P, K, Ca, Mg, Mn, Cu and Zn by M1 and M3. Highly significant correlations between M3 and M1 were found for all nutrients (r=0.92*** to 0.97***) and, except for Cu and Mn, soil pH and OM did not markedly improve the linear regression equations developed for conversion between M3 and M1. Inclusion of OM in a multiple regression equation between M3 and M1 extractable Cu increased R2 from 0.46** to 0.71***; R2 for Mn+(pH+OM) was 0.48***, relative to 0.35*** for extractable Mn alone. Critical values for M3 P, K, Ca, and Mg, based on conversion equations restricted to soils testing less than high with the M1 extractant, were 41, 49, 295 and 45 mg.dm‐3, respectively. For Mn and Zn, at a pH of 6.2, M3 critical values were 9.5 and 0.6 mg.dm‐3, while for Cu, the M3 critical value ranged from 0.5 to 1.1 mgdm‐3 for soil OM of 2 to 8%.  相似文献   

4.
Abstract

Soil nutrient extraction methods, which are currently being used in Malawi, are time consuming and require too many resources. The use of a universal soil extractant would greatly reduce resource requirements. The objectives of the study were to (i) compare the universal soil extractants, Mehlich 3 (M3) and Modified Olsen (MO) with ammonium acetate (AA), Bray P1 (BPl), and diethylene triamine penta acetic acid (DTPA) in the amount of nutrients extracted, (ii) determine the relationship among the extractants for the nutrients they extract, and (iii) determine the critical soil‐test levels of phosphorus (P), potassium (K), and zinc (Zn) for a maize crop. Missing nutrient trials involving P, K, and Zn were conducted on thirty sites across Malawi using maize (Zea mays L.). Phosphorus application rates ranged from 40 to 207 kg P2O5 ha‐1. Potassium and Zn were applied at 75 kg K2O and 10 kg Zn ha‐1, respectively. Procedures of Cate and Nelson were used to identify soil nutrient critical levels. Results showed that the correlations between M3 and BP1, and MO and BPl were highly significant (r=0.93, 0.94, respectively). Mehlich 3 extractable K and AA extractable K (r=0.90), MO and AA extractable K (r=0.94) were highly significant (P<0.01) and the correlations between M3 and AA and MO and AA extractable calcium (Ca) (r=0.92, 0.90, and 0.94, respectively) were also highly significant (P<0.01). The correlations between M3, MO, and AA extractable magnesium (Mg) (r=0.99) were highly significant (P<0.01). Zinc, copper (Cu), and manganese (Mn) extracted with M3 and DTPA were significantly correlated (r=0.89, 0.87, and 0.95, respectively). Correlations between MO and DTPA extractable Zn, Cu, and Mn were also highly correlated (r=0.89,0.85, and 0.95, respectively). Maize grain yields ranged from 730 to 9,400 kg ha‐1. Mehlich 3‐P and MO‐P critical levels were 31.5 and 28.0 μg g‐1, respectively. Mehlich 3 and MO gave a similar critical level of 0.2 cmol kg‐1 for K while Zn critical levels were 2.5, and 0.8 μg g‐1 for M3 and MO, respectively. Mehlich 3 and MO were equally effective in separating responsive to none responsive soils for maize in Malawi.  相似文献   

5.
Abstract

Labor and laboratory expense could be reduce if soil extractable nitrate (NO3) was extracted simultaneously with other routinely used soil extractants. This study was conducted to compare 1M potassium chloride (KCl), saturated calcium oxide (CaO), and Bray and Kurtz P1‐extractable soil NO3, the proposed new method to 2M KCl. Nitrate was extracted from 140 selected soils with 1M KCl, saturated CaO, Bray and Kurtz P1, and 2M KCl extractants and analysed by cadmium reduction with a flow injection analyser. Nitrate extracted with 2M KCl was used as the standard. When 1M KCl, saturated CaO, and Bray and Kurtz P1 was regressed against 2M KCl, the slopes were equal to 1.0 and the intercepts were equal to 0.0 with r2>0.99. No detectable differences in extractable NO3 were measured between 1M KCl, saturated CaO, Bray and Kurtz Pl, and 2M KCl extraction procedures. Bray and Kurtz P1 can be used to simultaneously extract phosphorus (P) and NO3.  相似文献   

6.
The usefulness of Mehlich 3 (M3) reagent was evaluated as a method to extract numerous elements from coalmine soils in As Pontes (Spain) showing a wide range of physicochemical properties. Critical levels (deficiency and/or toxicity) were established for plant available elements extracted by this reagent. The M3 method was compared to 1M NH4Cl, Olsen, acid oxalate, and DTPA methods as extractants for exchangeable Ca, Mg and K, available P, non-crystalline aluminium, and available heavy metals, respectively. The M3 method correlated significantly to NH4Cl for Ca, Mg and K (r=0·76, 0·84 and 0·87, respectively), to Olsen P (r=0·77) and to oxalate Al (r=0·77). Significant correlations were found between Fe, Cu, Zn and Cd extracted by M3 and DTPA; for Mn, Ni, Co and Pb different relationship between methods were obtained for acid and alkaline samples, so that critical levels were established for M3 metals as a function of soil pH. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

7.
Abstract

Individual soil tests are used to assess plant nutrient element needs. Separate soil tests, however, are time consuming and costly. Our objective was to develop a 0.5M sodium bicarbonate (NaHCO3) soil phosphorus (P) test in combination with 0.005M diethylenetriaminepentaacetic acid (DTPA) so macronutrient dements: ammonium‐nitrogen (NH4‐N), nitrate‐nitrogen (NO3‐N), P, potassium (K), calcium (Ca), and magnesium (Mg); and micronutrients: iron (Fe), manganese (Mn), zinc (Zn), and copper (Cu) could be quantified in one extraction. The NaHCO3‐DTPA extracting solution is a combination of 0.5M NaHCO3 and 0.005M DTPA and has a pH of 7.60±0.05. Sodium in the solution enhances the NH4, K, Ca, and Mg extraction; bicarbonate (HCO3) is for P extraction; DTPA chelates Ca, Mg, and micronutrients; and the water is for NO3 extraction. Soil samples (0–15 cm depth) came from two sources. The first set was from 12 N x P dryland proso millet (Panicum miliaceum L.) experiments, conducted from 1985 through 1987 in eastern Colorado. These soils were extracted with potassium chloride (KCl), NaHCO3, ammonium acetate (CH3‐COONH4), DTPA, ammonium bicarbonate DTPA (AB‐DTPA), and with the NaHCO3‐DTPA solutions. The second set included 25 soils from Alabama, Georgia, North Carolina, and South Carolina and were analyzed only for available P with the NaHCO3 and NaHCO3‐DTPA methods. Simple linear correlations for macronutrient elements and micronutrients were highly significant. Critical levels for the macronutrient elements: NO3‐N, P, and K were 27, 11, and 144 mg kg‐1, respectively; and the critical levels for the micronutrients: Fe, Mn, Zn, and Cu were 3.9, 0.35, 0.97, and 0.24 mg kg‐1, respectively.  相似文献   

8.
This study evaluated the suitability of the Mehlic h3 universal extractant as a part of a multielement test to assess the nutrient status of Australian sugarcane soils. Soil samples from BSES Soil Exchange Programs, representing all major soil types and geographic sugarcane-growing regions, were analyzed using existing BSES, acid-based extraction methods for calcium (Ca), magnesium (Mg), sodium (Na), potassium (K), copper (Cu), zinc (Zn), iron (Fe), manganese (Mn), and phosphorus (P) and the ASPAC 10B3 method for sulfur (S). These were compared with the Mehlich 3 procedure. Mehlich 3 results for Ca, Mg, Na, S, and Mn correlated highly with the BSES procedures (R2 = 0.95, 0.98, 0.99, 0.91, and 0.91, respectively). Satisfactory correlations were also obtained with 0.1 M HCl–extracted Zn, Cu, and Fe (R2 = 0.89, 0.85, and 0.85, respectively) and with the BSES sulfuric acid (H2SO4)–extracted P (R2 = 0.81). The poorest correlation (R2 = 0.79) was observed for K. In conclusion, the Mehlich 3 procedure is suitable as a diagnostic tool to assess the basic nutrient status of Australian sugarcane soils.  相似文献   

9.
Abstract

The quantity of plant nutrient elements removed from soil by wheat (Triticum aestivum) seedlings were compared with the results of soil tests. Four soils were selected to represent the major parent material and climatic factors responsible for the formation of important agricultural soils in the central eastern Cape Province of South Africa. Acid‐washed sand was used as control. Seedlings were grown for 21 days and nutrient element content in both plant material and soil were determined. Soils derived from dolerite rocks had significantly (P<0.05) higher calcium (Ca), magnesium (Mg), potassium (K), sodium (Na), and phosphorus (P) than those derived from sedimentary rocks. However, iron (Fe), manganese (Mn), and copper (Cu) were higher in soils derived from sedimentary rocks compared to those from dolerite rocks. The differences are attributed to elemental composition of minerals in the two parent rock materials. Within each rock group, soils derived from sites with higher temperature and low rainfall (semi‐arid climate) had significantly (p<0.05) higher nutrient element content than those from sites with lower temperatures and higher rainfall (humid climate). As far as plant growth is concerned, all the soils were well supplied with Ca, Mg, K, Na, and zinc (Zn), but were deficient in P, Fe, and Mn. The trend in uptake of soil nutrient elements by wheat seedlings mirrored their concentration in the soils. Estimates of plant‐available nutrient elements as determined by soil tests and their uptake as determined by tissue concentration were highly correlated for some nutrient elements (r2=0.83, 0.79, 0.94, 0.54, 0.69, and 0.61 for Ca, Mg, K, P, Na, and Zn, respectively) and weak for others (r2=0.47, 0.35, and 0.37 for Fe, Mn, and Cu, respectively). Notwithstanding the shortcomings of extrapolating pot derived results to field conditions, it is concluded that the Neubauer technique may offer a rapid and relatively inexpensive way of relating extractable nutrient elements with plant uptake and growth. Further in country correlation studies are, however, recommended.  相似文献   

10.
Abstract

Samples of four soils having a wide range of volume weights (0.65, 1.02, 1.25, 1.62 g/cm3) were either weighed or measured by volume and extracted with: (a) the Bray P1 extractant, (b) the Mehlich double acid extractant for P, K, Ca, Mg, Mn, Zn and (c) neutral N NH4OAc for K, Ca, Mg all at a soil/extracting solution ratio of 1:10. The soil test results were recorded on a volume basis in mg/dm3 and on a weight basis in mg/kg.

The test values for all macronutrients obtained with all extractants decreased, relative to a constant volume, with increasing VW of soil when analyzed and expressed on a weight basis. Results based on the use of a volume sample (scooped) but calculated on an assumed weight of soil changed the values in direct ratio of 1/assumed VW. The use of an assumed VW has no justification, since uniform soil test results can be obtained when expressed on a volume basis by either using a scooped sample of known volume or a weighed sample followed by multiplication with the VW of each soil.  相似文献   

11.
Natural surface soils in Southern Norway are strongly contaminated by metals from atmospheric deposition. Except from local pollution with Cu, Ni and to a limited extent Pb around the town of Kristiansand, this large-scale contamination can be ascribed to long-range atmospheric transport from other parts of Europe. Zinc, As, Cu, and Pb are all found in excessive concentrations in the surface layer of natural soils throughout the region, and in particular within a zone of about 20 to 40 km from the coast. In this zone the elements appear at the following concentrations or higher in the A0 layer (typical levels in other parts of Norway little affected by air pollution in parantheses): Zn, 120(30) mg kg?1; As, 4(0.5) mg kg?1; Cd, 2(0.2) mg kg?1; Pb, 160(15) mg kg?1. Possible harmful effects to soil biological processes of this contamination cannot be excluded.  相似文献   

12.
Abstract

A study was undertaken to evaluate the agreement among different university laboratories performing the Olsen, Bray P1, and Mehlich I tests for P on a diverse group of noncalcareous agricultural soils and to develop relationships among the Olsen, Bray P1, Mehlich I, and Mehlich III soil tests. For each test, the results from the individual laboratories were highly correlated (r2 0.90) and in almost all instances the slopes of the equations describing the relationships among laboratories approached one, The results indicate that the Olsen, Bray P1 and Mehlich I soil tests may be performed with a high degree of precision when standard soil test procedures are followed.

Of the three most commonly performed tests in the U.S. (Olsen, Bray P1, and Mehlich I), the Olsen and Mehlich I tests were the most highly correlated (r2 = 0.87) although the Mehlich I test removed approximately one and one half times more P than did the Olsen test. Bray P1 and Olsen and Mehlich I P were less highly correlated (r2 ≤ 0.72) and the relationships between these variables were influenced by the texture of the soils. The quantity of P removed by the Bray P1 test was on the order of two and three times greater than that removed by the Olsen and Mehlich I tests, respectively. The Bray P1 and Mehlich III soil tests were highly correlated (r2 = 0.97) and similar quantities of P were extracted from the soil by the two tests.  相似文献   

13.
Abstract

The objectives of this study were to modify the Mehlich 2 (M2) extractant to include Cu among the extractable nutrients, retain or enhance the wide range of soils for which it is suitable and minimize it's corrosive properties. The substitution of nitrate for chloride anions and the addition of EDTA accomplished those objectives. The new extracting solution, already designated Mehlich 3 (M3) is composed of 0.2N CH3COOH‐0.25N NH4N03‐0.015NNH4F‐0.013NHN03‐0.001M EDTA. Extractions from 105 soils using M3, M2, Bray 1 (Bl) and Ammonium Acetate (AA) were compared to evaluate the new extractant. The quantity of F extracted by M3 exceeded that by M2 20% and that by Bl 4% but the results from all extractions were highly correlated. Extractions of both K and Mg by M3 were 6–8% higher than those by AA and 3–4% higher than those by M2, but, again, there was high correlation among methods. Addition of EDTA increased Cu extractions by 170%, Mn by 50% and Zn by 25%. Cu extractions by M3 correlated with those from the Mehlich‐Bowling method. High correlations between Mn, as well as Zn, extracted by M3 and M2 were shown.  相似文献   

14.
Trace elements may present an environmental hazard in the vicinity of mining and smelting activities. However, the factors controlling their distribution and transfer within the soil and vegetation systems are not always well defined. Total concentrations of up to 15,195 mg . kg –1 As, 6,690 mg . kg–1 Cu, 24,820 mg . kg–1 Pb and 9,810 mg . kg–1 Zn in soils, and 62 mg . kg–1 As, 1,765 mg . kg–1 Cu, 280 mg . kg–1 Pb and 3,460 mg . kg –1 Zn in vegetation were measured. However, unusually for smelters and mines of a similar size, the elevated trace element concentrations in soils were found to be restricted to the immediate vicinity of the mines and smelters (maximum 2–3 km). Parent material, prevailing wind direction, and soil physical and chemical characteristics were found to correlate poorly with the restricted trace element distributions in soils. Hypotheses are given for this unusual distribution: (1) the contaminated soils were removed by erosion or (2) mines and smelters released large heavy particles that could not have been transported long distances. Analyses of the accumulation of trace elements in vegetation (median ratios: As 0.06, Cu 0.19, Pb 0.54 and Zn 1.07) and the percentage of total trace elements being DTPA extractable in soils (median percentages: As 0.06%, Cu 15%, Pb 7% and Zn 4%) indicated higher relative trace element mobility in soils with low total concentrations than in soils with elevated concentrations.  相似文献   

15.
Abstract

Three different chemical extractants were evaluated as to their extraction efficiency for copper (Cu), zinc (Zn), lead (Pb), aluminium (Al), iron (Fe), chromium (Cr), manganese (Mn), potassium (K), magnesium (Mg), and calcium (Ca) on forest soil profiles from the Romanian Carpathians. The extractants were hot 14 M nitric acid (HNO3), 0.05 M hydrochloric acid (HCl), and 0.1 M sodium pyrophosphate. By comparing amounts extracted by 0.05 M HCl and 0.1 M sodium pyrophosphate relative to that dissolved by hot 14 M HNO3, some conclusions were drawn concerning the chemical forms of the metals in the extractable pool. The amount released by 0.05 M HCl was generally less than 10% of the HNO3‐extractable fraction but showed considerable variation among the elements studied. The relative amount extracted by pyrophosphate increased with organic‐matter content of the soils for Cu, Zn, Pb, Al, Fe, and Cr; stayed more or less constant for Mn, K, and Mg; and decreased for Ca. These findings are discussed with respect to the different binding forms of the metals in the soil and the processes affecting their mobility. From the present results, the metals were ranked as follows with respect to their ability to form organic complexes in natural soils: Cu>Cr, Pb>Ca>Al>Fe, Zn, Mn, K>Mg. However, the use of cold dilute HCl as a fractionation step may be questionable in cases of soils with a high content of substances possessing large neutralization capacity for protons.  相似文献   

16.
李娟  周立军 《土壤》2020,52(3):645-650
为了解在成龄胶园间作的五指毛桃根际与非根际土壤及其根中主要中、微量元素含量情况,测定了实验区根际与非根际土壤各30个和对应五指毛桃根的钙、镁、铁、锰、铜和锌含量,分析了两者之间的关系,并评价了根际与非根际土壤中、微量元素丰缺状况。结果表明,非根际土壤钙、镁、铁、锰含量的平均值都高于根际土壤的,而铜、锌含量的平均值都低于根际土壤的。土壤钙、镁含量80%以上处于缺水平,而铁、锰含量处于丰或很丰水平,铜和锌含量处于适中水平。五指毛桃根际与非根际土壤中、微量元素存在空间上的广泛变异。五指毛桃根中、微量元素的平均值从大到小的排序是钙>镁>锰>铁>锌>铜。土壤中、微量元素与五指毛桃根中相对应的中、微量元素的相关性不强,且表现复杂。本研究结果揭示,在成龄胶园间作五指毛桃应当适量施用钙肥、镁肥和喷施一些铜元素叶面肥,并实行科学施肥,减少养分淋失。  相似文献   

17.
Abstract

The objective of this research was to assess the long‐term effects of broiler litter applications on soil phosphorus (P), copper (Cu), zinc (Zn), manganese (Mn), and arsenic (As) concentrations in Chesapeake Bay watershed Coastal Plain soils. Litter and soil samples were collected from 10 farms with more than 40 years of broiler production and from wooded sites adjacent to fields and were analyzed for P and metal contents. Averaged over farms, total P and metal concentrations in the litter were 12.8 g kg?1 P and 332, 350, 334, and 2.93 mg kg?1 Cu, Zn, Mn, and As, respectively. Surface (0–15 cm) soil pH values were greater than (5.7–6.4) the 0‐ to 15‐cm depth at wooded sites (3.5–4.3). Surface soil Bray 1 P values (149–796 mg kg?1) in amended fields were greater than wooded sites (4.4–17 mg kg?1). The 1N nitric acid (HNO3)–extractable metal concentrations were higher in amended soils than in wooded areas and were 7.7–32, 5.7–26, 12.3–71, and 0.6–3.0 mg kg?1 for Cu, Zn, Mn, and As, respectively, compared to 0.76–14, 4.6–22, 1.6–70, and 0.14–0.59 mg kg?1 for the same metals, respectively, in wooded areas. Results from this study demonstrated that long‐term broiler litter applications have altered the chemical properties of the Coastal Plain soils of the Maryland Eastern Shore. Metal concentrations were low in the surface layer of amended fields and typically decreased with depth. Phosphorus additions rather than metals are most likely to contribute to the degradation of the Chesapeake Bay watershed.  相似文献   

18.
Abstract

The available (0.1M HCl‐ and DTPA‐extractable) and total forms of copper (Cu) and zinc (Zn) were determined in soils developed on various groups of basalts, namely, the Newer, Older, Lateritized‐Older, and Biu (undifferentiated) basalts. The HCl‐, DTPA‐extractable, and total Cu in the soils ranged from 0.40 to 5.60, 0.15 to 2.64, and 15 to 65 mg Cu kg‐1, respectively, with corresponding means values of 2.06, 0.89, and 41 mg Cu kg‐1. Similarly, HCl‐, DTPA‐extractable, and total Zn varied from 3.00 to 6.20, 0.14 to 2.15, and 25 to 265 mg Zn kg‐1 with respective mean values of 4.65, 0.52, and 89 mg Zn kg‐1. The soils were high in the total forms of Cu and Zn, generally sufficient in available Cu, but deficient in available Zn. Both the total and available forms of Cu and Zn were little correlated with soil properties in soils of the Lateritized‐Older and Biu basalts, while only the available forms were related mainly to silt, clay, pH, and organic carbon in soils of the Newer and Older basalts. Furthermore, the available forms were correlated with each other, but not with the total forms.  相似文献   

19.
刘慧  董颖  王玉军  俞元春  姜军  徐仁扣 《土壤》2021,53(5):1040-1047
Mehlich 3(M3)方法可同时提取土壤中磷、钾、钙、镁、铝、铁、锌、锰、铜等多种元素的有效态,提高土壤检测的效率;另外,M3法适用于钙质土、火山灰土、高度风化土等各类土壤,可作为一个“通用”型土壤有效元素提取试剂。但是硝酸铵(NH4NO3)由于管制不易获取,应用M3方法测定土壤有效元素含量时受到极大限制。因此,本研究用另一种易获取的惰性电解质氯化铵(NH4Cl)替代硝酸铵(NH4NO3),评价氯化铵替代硝酸铵M3法的适用性。Pearson相关分析结果表明,用氯化铵替代硝酸铵M3法测得的30种土壤有效磷、钾含量与M3法测定结果呈极显著正相关,其决定系数(R2)分别为0.99(P=2.31×10-55,n=60)和0.98(P=1.52×10-49,n=60)。同时,氯化铵替代硝酸铵M3法和M3法测定的有效钙、镁、铝、铁、锌、锰和铜含量极显著相关,R2值分别为0.98,1.00, 0.99,0.96,0.99,0.95和0.94。氯化铵替代硝酸铵M3–P与酸性、中性和碱性土壤的 Bray–P和Olsen–P极显著相关,R2分别为0.97和0.91 (P=1.42×10-15和1.00×10-21,n=20和40)。同时,利用氯化铵替代硝酸铵M3法测定酸性改良土壤有效磷含量,发现其得到显著提高。因此,氯化铵替代硝酸铵M3法可作为测定各种土壤,以及改良土壤中有效磷、钾和其他金属元素有效态含量的通用方法。  相似文献   

20.
Abstract

The Egnér‐Riehm method for estimating plant‐available soil phosphorus (P) has been used as the standard soil testing method in Portugal for making fertilizer recommendations. However, this method does not accurately reflect the available P status for wheat in some representative soils from the South Region of the country. Therefore, a pot experiment was established with four Luvisols (LVx, LVv, and two different LVh soils) from the South Region of Portugal in order to evaluate the Egnér‐Riehm, Bray I, Bray II, Olsen, and Anion Exchange Resin (AER) methods for their ability to estimate available P in those soils. Wheat (Triticum aestivum L., cv. Panda) was used as test the crop. The experiment was arranged into a randomized complete block design with three replications and five rates (0, 50, 100,150, and 200 mg kg‐1) of P added to each soil. Critical soil P levels for LVx were established in case for Bray I (27.9 mg kg‐1), Bray II (33.5 mg kg‐1), Egnér‐Riehm (25.4 mg kg‐1), and AER (14.7 mg kg‐1) soil test procedures. Regarding the other soils, the critical soil P levels could not be estimated. The obtained results confirm that the development of an universal soil test P exti action is of great importance, and that further research should be conducted in order to evaluate routine soil fertility tests in different pedoclimatic environments.  相似文献   

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