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1.
Abstract

The recovery of applied zinc (Zn) by plants is relatively small. Coupled with lack of leaching, this leads to accumulation of Zn in topsoil which may result in unfavorable growth conditions for the subsequent plants. Different extractants may be used for assessing the Zn status of soils previously treated with Zn sources. The extractability of retained Zn is influenced by soil properties. This experiment was conducted to study the influence of selected properties of calcareous soils on extractability of Zn by three popular Zn soil tests. Twenty samples from surface horizons (0–20 cm) of highly calcareous soils of southern Iran (pH 7.9 to 8.5; calcium carbonate equivalent 16 to 58%) previously treated with three levels of Zn (0, 10, and 20 mg Zn kg‐1 soil as ZnSO4#lb7H2O) in triplicate and under one crop of corn (Zea mays L.) were extracted with DTPA, EDTA‐(NH4)2CO3 and Na2‐EDTA. Extractability (EXT) in a particular extractant was defined as the slope of the regression line, relating extractable Zn of each soil to the rate of applied Zn, multiplied by 100. The EXT values of soils ranged from 24.9 to 73.0% for DTPA, 47.2 to 84.4% for EDTA‐(NH4)2CO3, and 28.2 to 56.7% for Na2‐EDTA. Stepwise regression equations showed that cation exchange capacity (CEC) and calcium carbonate equivalent (CCE) followed by clay content were the most influential soil properties in EXT of retained Zn of highly calcareous soils. The EXT values decreased with increase in CEC, and CCE but increased with increase in clay.  相似文献   

2.
A variety of zinc (Zn) fertilizer sources are applied with varied responses on calcareous soils in Thailand. Seed treatment is an alternative method to deliver Zn to corn and alleviate Zn deficiency. To address this Zn delivery methods we conducted greenhouse studies on corn grown in three calcareous soils of Thailand to three Zn fertilizer sources [zinc sulfate (ZnSO4), Zn-ethylenediaminetetraacetic acid (EDTA) and Zn citrate]. We also evaluated effectiveness of soaking corn seed in three concentrations of ZnSO4 (0.4, 0.8 and 1.6%) prior to planting compared to soil applied methods. Applications of zinc increased the growth, dry matter yield and zinc uptake of corn with few differences observed among the types of fertilizers. Seed soaking with ZnSO4 solution also increased Zn uptake, growth rate and yield comparable to soil-applied Zn. Seed soaking prior to planting is an effective and efficient method to supply Zn to corn grown in Zn deficient calcareous soils of Thailand.  相似文献   

3.
Abstract

Water‐soluble zinc (Zn) fertilizers are rapidly converted to insoluble forms in calcareous soils resulting in lower efficiency of such fertilizers. A knowledge of distribution of native and applied Zn in such soils is necessary for understanding the fate of applied Zn fertilizers and finding ways to increase their efficiency. This experiment was conducted to obtain such information in selected highly calcareous soils of Iran. A sequential extraction method was used to fractionate the Zn forms of surface horizons (0–20 cm) of 20 highly calcareous soils [16 to 58% calcium carbonate (CaCO3) equivalent; pH 7.9 to 8.5] which had previously received 0, 10, or 20 mg Zn/kg as zinc sulfate (ZnSO4) and had been under one corn (Zea mays L.) crop in the greenhouse. The forms determined were exchangeable (EXZN), sorbed (SRZN), organic (ORZN), carbonate (CRZN), residual (RSZN), and sum of forms (SMZN). The native SMZN ranged from 32.4 to 66.7 mg/kg with a mean of 49.9 mg/kg. Application of 10 and 20 mg Zn/kg as ZnSO4 increased the mean to 57.7 and 62.7 mg/kg, respectively. Concentration of different forms of Zn in the soils was determined to be in the following order: RSZN >>> CRZN > SRZN > EXZN > ORZN. The concentration of native EXZN+SRZN+ORZN forms constituted less than 5% of SMZN, while concentration of CRZN alone ranged from 4.37 to 16.05% with a mean of 8.36%. Application of ZnSO4, while significantly increased the concentration of all forms of Zn, had a pronounced effect on CRZN. Averaged over all soils, 58 and 60% of the applied ZnSO4 was converted to CRZN for the 10 and 20 mg Zn/kg, respectively. Regression equations relating different Zn forms to soil physical and chemical properties indicated that the Zn forms are significantly influenced by soil properties.

It was concluded that conversion of applied ZnSO4 to CRZN was mainly responsible for retention of this fertilizer in highly calcareous soils, making it temporarily unavailable to plants, and therefore decreasing its apparent recovery by the first crop.  相似文献   

4.
Abstract

Relative suitability of different extraction procedures for estimating available zinc (Zn) and copper (Cu) in soils was assessed using DTPA, 0.1 N HCl, ammonium acetate+EDTA, and double acid (HCl+ H2SO4) as extractants and rice as a test crop in Neubauer experiment. The relationships between Zn concentration and uptake of Zn by rice plants and Zn extracted by the different methods showed that DTPA‐TEA, pH 7.3, could very suitably be used to assess Zn availability in soils. However, 0.1 N HCl was better for assessing the Cu availability in soils to the rice plants. Water‐soluble and exchangeable fractions of Zn and Cu had significant positive correlations with Zn and Cu concentrations, respectively obtained by all the four extractants tested. The results also showed that DTPA and ammonium acetate+EDTA extracted organically bound Zn, whereas DTPA, 0.1 N HCl and ammonium acetate+EDTA extracted organically bound Cu. Water‐soluble, exchangeable and organic matter bound fractions exhibited significant relationships with Zn and Cu concentrations, their uptake and rice dry matter yield.  相似文献   

5.
In greenhouse studies, corn (Zea mays L.) growth increased with Zn fertilization of two alkaline calcareous soils. Zinc concentration and total uptake increased with Zn application. Very high correlations were recorded between plant tissue Zn concentration, total Zn uptake and soil Zn levels determined by DTPA and AB-DTPA soil tests. Correlation between Zn concentration in plants and relative yield was poor. However, close relationships were revealed between extractable soil Zn and relative yield. Near maximum dry matter yield of corn was associated with a fertilizer rate of 2 mg Zn/kg soil. Plant tissue Zn-requirement was 27 mg/kg in 15 days old plants and 32 mg/kg in corn shoots of 40 day age. Critical soil test Zn level was 1.2 mg/kg by DTPA and 1.7 mg/kg by AB-DTPA method. Use of AB-DTPA soil test is suggested for evaluating Zn status of calcareous soils.  相似文献   

6.
 The objective of this study was to compare the availability of Zn from granular ZnSO4, a granular Zn humate-lignosulfonate (ZnHL), and liquid Zn ethylenediaminetetraacetate (ZnEDTA). The two granular sources were applied directly (“as is”) and also powdered and mixed with the soil. A calcareous sandy loam soil with low available Zn was used. Zn rates were 0, 4, 8, 16, and 32 mg pot–1, and two crops of maize (Zea mays L.) were grown. For the first crop, all Zn sources provided an excellent dry matter response when powdered and mixed with the soil. The ZnEDTA was superior with regard to Zn uptake. The availability of ZnSO4 granules was almost zero for the first crop. The availability of the ZnHL complex was better than ZnSO4 when applied in granular form, but not when the two materials were powdered and mixed with the entire soil mass, suggesting that availability differences between these sources were due to physical, not chemical, factors. After mixing with the soil, only small differences existed between the Zn sources for the second crop. All sources provided for a good dry matter and Zn uptake response, and all Zn sources were about the same in increasing diethylenetriaminepentaacetate (DTPA)-extractable Zn levels at the end of the experiment. This research suggests that the three Zn materials were equal long-term Zn sources, but that the short-term response varied dramatically, depending on how the materials were applied. Received: 8 March 1999  相似文献   

7.
Abstract

Zinc (Zn) deficiencies have been identified in Venezuela with increasing frequency in recent years. However, there are no established critical values for available Zn in the acid soils of this country. Greenhouse studies were initiated to evaluate five extractants, DTPA, DTPA‐HCl, Na‐EDTA, 0.1N hydrochloric acid (HCl), and Mehlich 1 to predict Zn availability in 14 acid soils with corn as the test crop. Significant and positive correlations were found between Zn extracted among the five extractants. Zinc extracted was not related with soil pH and organic matter content, but with the cation exchange capacity and clay content. The Na‐EDTA extractant was found to be the most suitable as an indicator of Zn‐deficient acid soils, the critical Zn value being 2.4 mg#lbkg‐1.  相似文献   

8.
Zinc (Zn) desorption from an exchange complex to solution, the release of Zn from organic matter (OM), crystalline minerals and other precipitates into the solution phase, is the process that controls Zn mobility in soils. An experiment was conducted to determine the pattern of Zn desorption and the soil characteristics affecting it. Desorption of Zn in 15 calcareous soils from southern Iran, treated with 10 mg Zn kg soil?1 as zinc sulfate (ZnSO4?7H2O) and 10 g organic matter (OM) kg?1 as feedlot cattle manure, equilibrated and extracted with diethylenetriamine pentaacetic acid (DTPA), was studied. Eight kinetic models were evaluated to describe the rate of Zn desorption of soil extracted with DTPA. There was a rapid rate of desorption during the first 4 h followed by a slower rate during the next 12 h. Two-constant rate and simple Elovich models were determined as the best models describing Zn desorption kinetics. Zinc desorption increased as Zn was applied, whereas it decreased with applied OM. The constants of the simple Elovich (βs) and two-constant rate equations (a and b) were closely correlated with cation-exchange capacity (CEC), OM and pH, which affect Zn solubility, sorption–desorption and diffusion in soils.  相似文献   

9.
Abstract

Zinc of index corn leaves samples from 91 Minnesota sites on numerous soil types was correlated with soil Zn extracted by four routine procedures. The EDTA?(NH4)2CO3 ‐ extractable soil Zn was more closely correlated with leaf Zn than soil zinc extracted by 0.1N HCl, EDTA‐NH4OAc, or by NH4OAc ‐ dithizone. Soil pH, CaCO3 equivalent, extractable P, and organic matter of both acid and calcareous soils were negatively correlated with leaf Zn. When EDTA ? (NH4)2CO3 ‐ extractable Zn was included with routine soil tests, a prediction equation for corn leaf Zn was formulated and compared with analytical values. However, the use of 1.4 ppm EDTA ? (NH3)2CO3, ‐ extractable soil Zn alone as a critical value was equally effective in predicting leaf Zn.  相似文献   

10.
Greenhouse and field experiments were conducted to determine the influence of nitrogen (N) fertilization and DTPA‐extractable soil zinc (Zn) on Zn concentration in wheat (Triticum aestivum L., cv. Pioneer 2375) grain. Application of zinc sulfate (ZnSO4) in the range of 0 to 8 mg Zn kg‐1 increased linearly DTPA‐extractable Zn in an incubated calcareous soil from 0.3 to 5.0 mg kg‐1. Application of these rates of ZnSO4 to the same soil under greenhouse conditions increased Zn concentration of wheat grain from 26 to 101 mg kg‐1. The influence of 134 kg urea‐N ha‐1 on Zn concentration in wheat grain at eight field sites, with DTPA‐extractable soil Zn levels ranging from 0.3 to 4.9 mg kg‐1, was studied. Nitrogen fertilizer increased wheat‐grain yields in four of the eight experiments but had little effect on grain‐Zn concentration. Grain‐Zn concentration ranged from 31 to 45 mg kg‐1 in N‐fertilized plots at the various sites and was related (r=0.74*) to DTPA‐extractable soil Zn.  相似文献   

11.
Increased zinc (Zn) concentration in seed may sometimes improve human health. The influence of rate and placement of three Zn sources (ZnEDTA, ZnSO4, and Rayplex‐Zn) on Zn concentration in navy bean (Phaseolus vulgaris L.) seed grown on a Calciaquoll was studied in the greenhouse. Application of 4 and 8 mg Zn/kg mixed throughout the soil increased seed Zn concentration by approximately 60 and 68%, respectively, and the responses were similar with the three Zn sources. The mixed‐throughout‐the‐soil ZnEDTA, ZnSO4, and Rayplex‐Zn treatments applied at 8 mg Zn/kg reduced seed phosphorus (P) concentration by 10,13, and 15%, respectively. The corresponding reductions with 4 mg Zn/kg were 10, 8, and 13%, respectively. Banding ZnEDTA, ZnSO4, and Rayplex‐Zn at 4 mg Zn/kg in 17‐cm‐long, 3‐cm‐deep bands reduced seed Zn concentration by 8, 34, and 31 % compared to their mixed‐throughout‐the‐soil counterparts. A significant Zn source x placement interaction resulted from marked reduction in Zn uptake as a result of banding ZnSO4 and Rayplex‐Zn. Banding of ZnSO4 and Rayplex‐Zn in calcareous soils is less likely to increase the Zn concentration of navy bean seed than is banding of ZnEDTA.  相似文献   

12.
The application of zinc (Zn) fertilizer to lentil is an agronomic strategy that has the potential to improve yield and enhance grain Zn concentration. A pot study was conducted to determine if Zn fertilizer applied to three popular Saskatchewan lentil cultivars could increase yield and concentration of Zn in the grain. The effects of soil and foliar applied Zn forms, including ZnSO4, Zn chelated with EDTA, Zn lignosulphonate, and a control were evaluated. Forms of Zn were not found to significantly increase yield (P = 0.828) or grain Zn concentration (P = 0.708) in any of the lentil cultivars tested. Fertilization with soil applied ZnSO4 resulted in significantly (P < 0.0001) higher amounts of residual available Zn in the soil relative to other Zn treatments. Soil fertilized with ZnSO4 had 1.13 mg kg?1 diethylenetriaminepentaacetic acid (DTPA)-extractable Zn compared to 0.84 mg Zn kg?1 and 0.77 mg Zn kg?1 in the soil and foliar applied chelated Zn, respectively.  相似文献   

13.
Abstract

Maize (Zea mays L.) was greenhouse cultivated with doses of 5, 10, and 15 ppm of zinc (Zn) in order to test the effectiveness of laboratory‐prepared coated and uncoated Zn fertilizers with commercial Zn‐EDTA and Zn‐ligno‐sulphonate (LS). Large increases were achieved both in crop yield and in Zn uptake in all cases while a large part of the Zn applied remained in the soil in easily plant‐available forms. Positive significant correlations were obtained between available Zn and the first three sequentially extracted fractions (water soluble plus exchangeable, organically complexed and that associated to amorphous sesquioxides) and also between the variables, yield, Zn concentration, and plant Zn uptake. Zinc uptake by the maize plants can be fairly accurately predicted from its sequential fractioning in the soil using an equation obtained by multiple regression analysis. Consideration of the amounts of Zn remaining as available (DTPA extractable) in the soil and results of a plant analysis let us conclude that under the conditions of our tests, Zn‐EDTA is a better Zn source than Zn‐LS. In addition, coating of Zn‐EDTA products with rosin improves their performance.  相似文献   

14.
Abstract

Soil pot culture experiment was conducted on 22 soils of Balewal‐Phaguwala‐Narike (BPN) and 24 soils of Isri‐Langrian‐Narike (ILN) associations using rice (PR 106) as test crop at 0 and 7.5 ppm Zn levels. Chelating extractants 0.005M DTPA, 0.01M EDTA‐(NH4)2CO3 and 0.05M EDTA, extracted more soil Zn than double‐acid and were significantly correlated with each other as well as with soil pH and clay in BPN and only with clay in ILN soil association. Soil CaCO3 governed the double‐acid extractable Zn in these soils. Dry matter yield and Zn uptake by rice significantly increased with 7.5 ppm Zn application. The response was higher in ILN than BPN soil association, The DTPA method gave the highest correlation with Bray's yield and Zn uptake (r =0.72 and 0.55) followed by 0.05M EDTA (r ‐ 0.75 and 0.61) or EDTA‐(NH4)2CO3 (r =0.70 and 0.61). The predictability of rice yield improved from 18–27 to 27–35, 32–43, 34–44 and 51–55 percent as a result of stepwise inclusion of pH, CaCO3, organic carbon (OC) and clay respectively in the regression equation alongwith Zn extracted by chelating agents.

The critical levels of DTPA, EDTA‐(NH4)2CO3 and EDTA extractable Zn significantly differed in the two associations and were 0.69, 0.82 and 1.24 ppm in BPN and O.BC, 1.09 and 1.42 ppm in ILN soil association. Soil properties further affected the critical levels. This for DTPA available Zn was 0.80 and 1.03 ppm in soil containing less and greater than 2% CaCO3, 1.03 and 0.80 ppm in soils containing less and greater than 0.25% OC. These values for EDTA‐(NH4)2CO3 available Zn were 1.09 and 0.91 ppm Zn in soils containing less and greater than 15% clay suggesting that critical levels of Zn for each category of soil properties should be considered while making recommendations of Zn fertilization of crops.,  相似文献   

15.
Total Zn in alluvial and calcareous soils (average 138 and 70 ppm respectively) was significantly related to their contents of CaCO3 (negatively), O.M. and clay (positively). Extracting Zn by Na2EDTA gave the highest values for both soil types. Total Cu contents varied widely from 26 to 111 ppm in alluvial and from 15 to 30 ppm in calcareous soils. They were negatively correlated with the CaCO3 contents. The pot experiments showed that EDTA(NH4)2CO3, Na2EDTA and DTPA are reasonable extractants for available Zn from both soil types. DTPA was efficient for all soils investigated, while Na2 EDTA and EDTA-citrate were specific for extracting Cu from calcareous soils.  相似文献   

16.
A greenhouse experiment with 11 soil series and two zinc (Zn) rates (0 and 15 mg Zn kg?1 as zinc sulfate) was performed to determine critical deficiency level of Zn for corn (Zea mays L.) on calcareous salt-affected soils in central Iran. In addition, the most important soil properties affecting Zn phytoavailability were determined. Critical Zn deficiency levels were determined using the Cate-Nelson and Mitscherlich procedures. In most soils, application of Zn increased the dry matter yield, and Zn concentration and content in the shoot and root of corn. A positive correlation was observed between the soil electrical conductivity (EC) with Zn concentration in shoots, roots and whole plant while shoot Zn content was negatively correlated with buffer capacity of Zn in soil. Critical deficiency levels of Zn in soil for corn based on the Cate-Nelson and Mitscherlich method were 1.35 and 1.23 mg kg?1 for diethylenetriaminepentaacetic acid (DTPA)-extracted soil Zn, respectively.  相似文献   

17.
Zinc biofortification of staple food crops is essential for alleviating worldwide human malnutrition. Agronomic interventions to promote this should include fertilizer selection and management. A chelated Zn source, Zn‐EDTA, and an inorganic Zn source, ZnSO4 × 7 H2O, were applied either by banding or by broadcasting in soil, and Zn fractions in soil and Zn uptake by wheat were determined in a pot experiment. Compared to ZnSO4 × 7 H2O, Zn‐EDTA produced higher Zn concentration in grain regardless of application method and even at a lower application rate. Residual Zn fraction was the largest Zn fraction with both ZnSO4 and Zn‐EDTA amendment. ZnSO4 banded in soil caused Zn fractions to be restricted to the Zn‐amended soil band and resulted in lower grain Zn concentrations than did broadcast ZnSO4. Planting wheat slowed Zn fixation by promoting the maintenance of a high concentration of Zn fraction loosely bound to organic matter (LOM‐Zn) in soil. Zn‐EDTA was a better Zn source for Zn biofortification of wheat than was ZnSO4.  相似文献   

18.
Abstract

Humic acids have many benefits for plant growth and development, and these effects may be maximized if these materials are combined with micronutrient applications. In the present study, pot experiments were conducted to evaluate the effects of zinc (Zn) humate and ZnSO4 on growth of wheat and soybean in a severely Zn‐deficient calcareous soil (DTPA‐Zn: 0.10 mg kg?1 soil). Plants were grown for 24 (wheat) and 28 days (soybean) with 0 or 5 mg kg?1 of Zn as either ZnSO4 or Zn humate. Zinc humate used in the experiments was obtained from Humintech GmbH, Germany, and contained 5% of Zn. When Zn was not supplied, plants rapidly developed visible symptoms of Zn deficiency (e.g., chlorosis and brown patches on young leaves in soybean and necrotic patches on middle‐aged leaves in wheat). Adding Zn humate eliminated Zn‐deficiency symptoms and enhanced dry matter production by 50% in soybean and 120% in wheat. Zinc‐humate and ZnSO4 were similarly effective in increasing dry matter production in wheat; but Zn humate increased soybean dry matter more than ZnSO4. When Zn was not supplied, Zn concentrations were 6 mg kg?1 for wheat and 8 mg kg?1 for soybean. Application of Zn humate and ZnSO4 increased shoot Zn concentration of plants to 36 and 34 mg kg?1 in wheat and to 13 and 18 mg kg?1 in soybean, respectively. The results indicate that soybean and wheat plants can efficiently utilize Zn chelated to humic acid in calcareous soils, and this utilization is comparable to the utilization of Zn from ZnSO4. Under Zn‐deficient soil conditions, plant growth and yield can be maximized by the combined positive effects of Zn and humic acids.  相似文献   

19.
Abstract

The objectives of this study were to (1) characterize zinc (Zn) fractions and their relation to Zn extracted with mixed‐bed ion exchange resin capsules and (2) assess the relationships between the latter and Zn uptake by rice in 12 Mollisols from North India. The Resin Adsorption Quantity (RAQ) of Zn was measured after 1 and 14 days of anaerobic incubation. Six organic and inorganic Zn fractions were determined on anaerobic soil. Zinc uptake by rice was studied in a greenhouse experiment. Soil Zn fractions under reduced conditions followed the order residual Zn (80%)>carbonates and amorphous oxides bound Zn (12%)>weakly organically bound Zn (3%)>crystalline oxides bound Zn (2%)>strongly organically bound Zn (2%)>water soluble + exchangeable Zn (1%). RAQ‐Zn was best correlated with Zn bound to carbonates and amorphous oxides. Due to negative interactions between bicarbonate and Zn uptake, correlations between relative dry matter yield or total Zn uptake and the different Zn fractions, DTPA‐Zn measured on dry soil, or RAQ Zn were not significant. Adjusting soil test values according to soil pH improved the prediction of relative dry matter yield, but further studies are required to determine whether the resin capsule can be used as a soil test for Zn in calcareous soils.  相似文献   

20.
Although complexation with soil organic matter may improve zinc (Zn) bioavailability to plants, the effect of Zn sorbent surface on the use of complexed Zn by plants remains unknown. The objective of this research was to elucidate how Zn complexation with humic substances (HS) and phytate affects the uptake of Zn by wheat plants depending on the main sorbent surface in growth media, i.e., carbonates and Fe oxides. To this end, two pot experiments were performed, one using Fe oxide-coated siliceous as the siliceous growth medium sand and the other using a mixture of calcareous sand and siliceous sand as the calcareous growth medium. Each experiment involved three Zn sources, Zn-HS complex, Zn phytate, and ZnSO4. All sources were applied with surface irrigation at two Zn rates (0.25 and 2 mg kg-1 growth medium). The Zn-HS complex significantly increased Zn uptake by plants in both media, relative to the other two Zn sources, but no significant difference was observed between Zn phytate and ZnSO4. In the calcareous medium, Zn-HS complex and Zn phytate resulted in significantly higher dry biomass yields of wheat than ZnSO4. In the siliceous medium, spike and shoot dry biomass yields with Zn-HS complex at the low rate and Zn phytate at both rates were not significantly different from those with ZnSO4 at the high rate. After harvest, approximately 50% of the Zn applied as Zn-HS complex remained extractable by diethylenetriaminepentaacetic acid (DTPA), while this proportion was less than 20% for the other Zn sources. Thus, Zn-HS complex and Zn phytate are sources of available Zn for plants, and they are more effective than ZnSO4 in increasing plant growth, particularly when carbonates are the main Zn sorbent surface.  相似文献   

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