共查询到20条相似文献，搜索用时 46 毫秒
1.
Nine disperse dyes have been synthesized by diazotization of 2-amino-4-(p-nitrophenyl)-5-nitrothiazole and coupled to substituted
N-alkylanilines. Spectral properties in the IR and visible range of the dyes obtained were investigated. The dyeing performance
of these dyes was assessed on nylon and polyester fibers. These dyes were found to give reddish brown to bluish violet shades
on dyeing with very good depth, brightness and levelness on nylon and polyester fibers. The dyed fibers showed fairly good
light fastness, very good to excellent fastness to wash, rubbing, perspiration and excellent fastness to sublimation. The
dyebath exhaustion and fixation on the fiber were found to be very good. 相似文献
2.
A series of hot brand monoazo reactive dyes (9a-l) were obtained by the coupling of diazotized 1Hbenzo[ g]pyrazolo[3,4-b]quinoline-3-ylamine (5) with various cyanurated coupling components (8a-l) in good yield. Synthesized dyes were characterized by various spectroscopic techniques. Their dyeing performances as reactive dyes have been assessed on silk, wool, and cotton fabrics. The percentage dye bath exhaustion and fixation on different fibers were found to be very good. The dyed fabric showed moderate to very good light fastness and good to excellent washing and rubbing fastness properties. Spectral properties and colorimetric data of synthesized dyes have also been studied in detail. 相似文献
3.
The dyeing performance of the azocalix[4]pyrrole dyes on fibers like nylon, wool, acrylic, and silk have been determined.
Their fastness properties towards light, water, washing, and acid-alkali perspiration have been studied. The position of color
in CIELAB coordinates (L*, a*, b*, H, and C*) was assessed. The azocalix[4]pyrrole demonstrated good antimicrobial activity against Escherichia coli, Staphylococcus aureus, and Aspergillus niger. These super molecules exhibit bright shades on fabric with very good fastness properties. 相似文献
4.
meta-Aramid fibers have an excellent heat-resistant property and are widely used for protective clothings such as fire-fighter suit and racing suit. They can also be used as military uniforms such as flight suit or army uniform. Vat dyes are specially used for military uniforms owing to outstanding fastness properties, earth tone shade, and near infrared (NIR) camouflage. In this study, 100 % meta-aramid woven fabric was dyed with three vat dyes using an exhaustion method and their dyeing and fastness properties were investigated. Color yields of the vat dyes on the meta-aramid fabric were found to be dependent upon dyeing temperature, liquor ratio, amount of reducing agent, and amount of salt. Dyeing behavior of the vat dye on the meta-aramid fiber was very similar to that on cellulose fibers. It was found that the meta-aramid fabric dyed with 1% owf of C.I. Vat Green 1 satisfied the tolerance of the reflectance spectrum of forest green color in the Korean military standard. Thermal stability and mechanical property of the meta-aramid fabric did not significantly affected by the vat dyeing process. Wash and perspiration fastness was generally good but rubbing and light fastness was unsatisfied. 相似文献
5.
A series of polymeric dyes were synthesized by free radical addition polymerization of monomeric dyes. The 2-amino-5-mercapto-1,3,4-thiadiazole
was diazotized and coupled with various N-arylmaleimides to give monomeric dyes. All the polymeric dyes were characterized
by elemental analysis, infrared spectroscopy, visible absorption spectroscopy, viscometry, and thermogravimetric analysis.
Color and dyeing properties of the polymeric dyes were discussed by comparing them with those of the corresponding monomeric
dyes. The dyeing performance of these dyes was assessed on nylon fiber. These dyes were found to give various color shades
with good to very good depth and levelness on the fiber. The dyeing of the monomeric dyes showed moderate fastness to light
and good to excellent fastness to washing, perspiration and sublimation and their corresponding polymeric dyes showed excellent
fastness properties. The dyebath exhaustion and fixation on nylon fiber has been found to be good. 相似文献
6.
Marziyeh Sadat Javadi Javad Mokhtari Mahdi Nouri Firouzmehr Mazaheri 《Fibers and Polymers》2013,14(6):920-925
The cationic softeners containing MCT (monochloro-s-triazinyl) reactive dyes were employed on the dyeing of cotton fabrics. The substantivity, exhaustion, and fixation of the dyes were investigated. It was found that these functional dyes could be effectively introduced to cotton fibers to achieve simultaneous coloration and functional finishing effects. All the dyed fabrics exhibited softening efficacy. The dyes offered excellent washing fastness on cotton substrate. Light fastnesses of the dyes on the substrate were poor. 相似文献
7.
Due to compact structure of meta-aramid fiber caused by the intermolecular hydrogen bondings of amide groups, the degree of crystallinity increased, thus its poor dyeing properties arises. Among commercial dyes used in many previous researches, the basic dyes showed comparatively higher exhaustion yields as comparing to those of disperse dyes and acid dyes. The anthraquinone moiety was adopted for good performances of light fastness on meta-aramid fiber. In this study, eight of anthraquinone dye was synthesized. The three of them were obtained from chloro-anthraquinone, by Ullmann reactions with the corresponding heterocylic residues such as morpholine and one of them was obtained from lueco quinizarine by condensation with the corresponding heterocylic residues. The others were prepared by quaternization from dyes above. The synthesized disperse and cationic dyes were dyed on meta-aramid fibers and investigated for their build-up dyeing properties and wash fastness. 相似文献
8.
Poly(lactic acid) (PLA) is known for environmentally friendly material as it is derived from annually renewable crops and biodegradable. Dispersant-free dyeing of PLA fabric with three temporarily solubilized azo disperse dyes which contain β-sulfatoethylsulfonyl group was investigated and their dyeing and fastness properties were compared with those of commercial disperse dyes. The temporarily solubilized azo disperse dyes were successfully applied to PLA fabric without the use of dispersant. The color yield on PLA fabric was dependent on dyebath pH and dyeing temperature as well. The optimum results were obtained at pH 7-8 and 110 °C. The dyes showed markedly higher color yield on PLA fabric when compared to commercial disperse dyes. Wash fastness was very poor to poor but light fastness was good. The COD levels of the dyeing effluent from the temporarily solubilized disperse dyes were considerably lower than those from commercial disperse dyes. 相似文献
9.
Smaro Lykidou Evangelos Karanikas Ioannis Tsagalias Nikolaos Nikolaidis Eforia Tsatsaroni 《Fibers and Polymers》2017,18(9):1697-1707
Three new bis azo reactive dyes of different metallic salts (Na, K, Li) were synthesized. The synthesis was obtained by diazotization of 4-amino-2:5 di methoxy phenylene-beta hydroxyl ethyl sulphone sulphate ester and coupling with 1-amino-8-hydroxynaphthalene-3,6-disulfonic acid (H-acid) (moles ratio 2:1). The dyes were purified-concentrated by ultrafiltration technology, characterized and applied on cotton, wool and nylon 6,6 fabric by exhaustion (dyeing) and by ink-jet printing. Fastness properties of the dyeings were measured. Wash fastness was investigated according to international standard methods and was found to be very good to excellent in all cases, while light fastness values were medium to low. Ink-jet ink formulations were prepared using the ultra filtrated reactive blue dyes UF RB(a-c) and their properties pH, conductivity, surface tension and viscosity were monitored over a period of 90 days. The inks were used to print digitally cotton and nylon 6,6 samples and wash- and light fastness properties of the prints were measured. Wash fastness properties were excellent while light fastness values are low Colour measurements of the dyeings and prints were conducted. 相似文献
10.
The coloration of poly(lactic acid) (PLA) fiber with 18 carbocyclic monoazo disperse dyes bearing a hydrolyzable phthalimide
ring fused to the aromatic ring of their diazo components has been investigated. The phthalimidyl nitrogen atom was substituted
with either a n-butyl, sec-butyl, or isopropyl group, while the adjoining phenyl ring bore a substitution pattern typical of commercial colorants. There
was a broad correlation between percentage dye exhaustion onto PLA and that onto polyester (PET) fiber, although significant
differences in certain instances were apparent with no clear trends regarding dye structure. Attempts to explain the observed
percentage exhaustion values by mapping them to calculated partition coefficient or solubility parameter values were unsuccessful.
Wash fastness was relatively good compared to that of some conventional disperse dyes applied to PLA. As was found to be the
case with PET, the wash fastness of dyes on PLA tended to be highest when their diazo ring was substituted with electron acceptors. 相似文献
11.
The dyeing and color fastness properties of three reactive-disperse dyes containing a sulphatoethylsulphone group on Nylon,
cotton and N/C mixture fabrics were examined. Reduction-clearing was more effective in removing the unfixed dyes than soaping
since the reactive-disperse dye became hydrophobic during dyeing process. Nylon was dyed well with three reactive-disperse
dyes at pH 5∼8 and difference in chemical structure between dyes did not affect the final color strength of the dyed Nylon
fiber, but their build-up properties on Nylon were not so good. The color strength of the dyed cotton was not as high as that
of Nylon. The color strength of cotton increased by lowering dyeing temperature when the reactive-disperse dyes having hydroxy
group were used. Nylon absorbed more dye molecules than cotton in simultaneous dyeing, the color difference between Nylon
and cotton could be reduced as the dyeing temperature decreased. N/C mixture fabric was dyed well at 60 °C with the reactive-disperse
dyes having hydroxyl group when applied at pH 7 and 60 °C, and their build-up properties were good. It was also found that
washing fastness and rubbing fastness of dyed Nylon, cotton and N/C fabrics with the reactive-disperse dyes were excellent,
while light fastness was moderate. 相似文献
12.
A series of monoazo disperse dyes with a photostablilizing o-hydroxycarbonyl moiety was incorporated resulted in the enhancement of the light fastness properties on polyester and nylon substrates as compared to the dyes that do not possess the photostablilizing moiety. The geometries of the azo and the hydrazone tautomeric forms of all dyes were optimized at B3LYP/6-311+G(d) and electrophilicity index was calculated for propensity of the moiety to absorb electrons. The values of absorption and stability trend of the dyes were in good agreement with the trend of experimental light fastness values. These disperse dyes possess excellent wash fastness and moderate to good sublimation fastness on hydrophobic substrates. 相似文献
13.
UHMWPE fibers were dyed with yellow and red dyes having different length of alkyl substituents on monoazo chromophores. The dyeability was investigated at various conditions and fastness of the dyeings was examined. As the length of alkyl substituents increased, the dyeability toward UHMWPE fibers tends to be improved gradually up to propyl or butyl groups and then decreased for the longer alkyl substituents. Color strength of the fabrics was increased with the increase of dyeing temperature from 100 to 130 °C. From the dyeing rate, equilibrium dyeing at 130 °C was achieved at 2～3 h. The color fastnesses to washing, rubbing, and light of the dyeings were good showing higher than 4 ratings except for light fastness of the red dye. 相似文献
14.
A series of five azo acid dyes were synthesized using different diazotized aromatic amine sulfonic and carboxylic acids followed by coupling with 2H-pyrido[1,2-a]pyrimidine-2,4(3H)-dione. The dyes were characterized by 1H-NMR, 13CNMR, FTIR, and elemental analysis. They were applied on nylon, silk, and wool. Their fastness properties were evaluated and color on the fabric was assessed. Yellow, brown, and crimson dyeings with good fastness properties were obtained. The dyes are water soluble and showed absorption from 380 nm to 550 nm. Acid dyes from diazo component 4- aminonaphthalene-1-sulfonic acid (naphthionic acid) and 4-amino-5-hydroxynaphthalene-2,7-disulfonic acid (H-Acid) were found to be more red shifted as compared to the other dyes. More red shifted absorption maximum was observed in acidic pH than in alkaline pH. The trends in vertical excitations obtained from Time Dependent Density Functional Theory calculations are in good agreement with the experimental absorptions. 相似文献
15.
In this work, water-extraction of Vitis Vinifera L. (Black Grenache) leaves and analysis of aqueous extracts for anthocyanins were investigated. Vegetable leaves were cultivated in North of Tunisia at different dates. Anthocyanins were identified as main constituents in these natural dyeing materials using high performance liquid chromatography (HPCL). Dyeability of wool and its fastness properties using Vitis Vinifera L. leaves extract were also determined. Aqueous extract of Vitis Vinifera L. leaves has markedly yielded shades with good fastness properties. Thus, affordability is a point favorable for Vitis Vinifera L. leaves. Effects of dye bath pH and temperature on dyeability and fastness proprieties of wool fabrics by aqueous extract of Vitis Vinifera L. leaves were evaluated. Experimental results showed that fastness properties of dyed fabrics ranged from average to very good. Vitis Vinifera L. leaves extracts showed potential to dyeing wool fibers under highly acidic conditions (pH ≤2). The results obtained here revealed that natural dyes extracted from Vitis Vinifera L. leaves can be cost-effective for dyeing wool fabrics. 相似文献
16.
UHMWPE fibers were dyed with a series of anthrquinoid blue dyes having different length of alkyl substituents at general dyeing
condition. The dyeability was investigated at various conditions and fastness of the dyeings was examined. As the length of
alkyl substituents increased, the dyeability toward UHMWPE fibers tends to be improved gradually. Color strength of the fabrics
was increased with the increase of dyeing temperature from 100 to 130 °C. From the dyeing rate, equilibrium dyeing at 130°C
was achieved at 2–3 h. The tensile strength of UHMWPE fibers after dyeing at 130 °C for 1 h was maintained at a level of 95
% of untreated fiber. However, at prolonged dyeing time at 130 °C, the tensile strength was significantly decreased to a practically
unacceptable level. The color fastnesses to washing, rubbing and light of the dyeings were very good showing higher than 4
ratings. 相似文献
17.
The dyeability of poly(lactic acid) [PLA] with a range of commercial disperse dye was examined and compared to that of poly(ethylene
terephthalate) [PET] in addition to the colour and fastness of the resultant dyeings. A screening exercise in which twenty
dyes of differing energy types and chemical classes were applied to PLA revealed a substantial variation between the dyes
in terms of dye uptake (12–88 % at 4 %o.w.f.). Nine dyes exhausted above 70 % and were selected for further study, which involved
comparison of shade and fastness of PLA dyeings with those of the corresponding PET dyeings. Differences in shade depended
on hue while wet fastness of each of the PLA dyeings was either the same or 0.5–1.0 point lower than its PET counterpart.
In all but one case, dye photostability in PLA was found to be very similar to that in PET. Dye build-up profiles on PLA were
also investigated and from these results mixtures of compatible dyes identified. 相似文献
18.
Heterocyclic monoazo quinazolinone based azo dyes derived by the diazotization of 3-(4-aminophenyl)-2-phenylquinazolin-4(3H)-one
with various phenyl pyrazolones based coupling components. All the heterocyclic azo dyes have been characterized by their
percentage yield, UV-VIS spectroscopy, elemental analysis, IR spectroscopy, 1H NMR spectroscopy, and dyeing performance on silk, wool, nylon, and polyester fibers. All the dyes gave moderate to excellent
fastness properties on each fiber. The main focus was to synthesize heterocyclic monoazo dyes that give good dyeing property
along with pharmacological activity (anti bacterial and antifungal). Therefore, the synthesized compounds were examined for
their antimicrobial activity at various concentrations using well-known Kirby-Bauer disk diffusion method. 相似文献
19.
Diazotized 3-{4-[2-chloro-4-amino-5-carboxybenzyl]-5-chloro-2-carboxyphenyl}-6-iodo-2-phenylquinazolin-4(3H)-one (4) was coupled with various p-nitro anilino cyanurated coupling components (6a-j) to give the corresponding quinazolinone based reactive dyes (7a-j) in reasonable yields. All the reactive dyes (7a-j) were characterized by spectroscopic technique and elemental analysis. These dyes were applied to silk, wool, and cotton
fibers as reactive dyes and their spectroscopic data, colorimetric data, antimicrobial activity, thermal stability, and fastness
properties were evaluated. 相似文献
20.
Temporarily solubilized azo disperse dyes based on 1,2-substituted indoles were synthesized and characterized. Dispersant-free
dyeing of polyester by using the synthesized dyes has been investigated. The colour yields of the dyes on the polyester fabric
were found to be highly dependent on the dyeing pH, optimum results being obtained at pH 5. The dyes exhibited good to excellent
fastness properties on polyester while lightfastness was moderate. 相似文献