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1.
The objective of this study was to DTPA （complexion agent） and a sequential extraction procedure, and adsorption-desorption isotherm （competitive） evaluate the mobility and distribution of Fe, Zn, Mn, Cu, Cd, Ni, and Pb using the in surface samples of five soil great groups differing in their physicochemical properties. For determining heavy metal adsorption and desorption capacities of soil samples, six different concentrations （0, 2.5, 5, 10, 15 and 20 mg Lt） were used in a laboratory experiment with tree replications. An analytical procedure involving sequential chemical extractions has been used for partitioning of heavy metals into five fractions. Sorption isotherms were characterized using linear, Frendlich and Langmuir equations. The results indicated that the selective sequences of the metal adsorption based on the distribution coefficient was Pb〉Cu〉Ni〉Cd〉Zn〉Mn〉Fe and Pb, Cu, and Ni are the most strongly sorbed metals by these soils, whereas Cd, Zn and Mn are the least sorbed ones. The total adsorbed amount of these metals on the studied soils was well described by Langmuir equation. Calciorthid had the highset Pb, Cu, Ni, Cd, Zn, Mn, and Fe adsorption, and the sequences followed order Fluvaquent〉Argiustoll〉Pellustert〉Haplustept of the studied soil.  相似文献   

2.
This study was aimed to evaluate the potential effects of rest grazing on organic carbon storage in Stipa grandis steppe of Inner Mongolia, China. Using potassium dichromate heating method, we analyzed the organic carbon storage of plant and soil in Stipa grand＆ steppe after rest grazing for 3, 6, and 9 yr. The results indicated that as the rest grazing ages prolonged, the biomass of aboveground parts, litter and belowground plant parts （roots） of the plant communities all increased, meanwhile the C content of the biomass increased with the rest grazing ages prolonging. For RG0, RG3a, RG6a, and RG9a, C storage in aboveground vegetation were 60.7, 76.9, 82.8 and 122.2 g C m2, respectively; C storage of litter were 5.1, 5.8, 20.4 and 25.5 g C m^-2, respectively; C storage of belowground roots （0-100 cm） were 475.2, 663.0, 1 115.0 and 1 867.3 g C m^-2, respectively; C storage in 0-100 cm soil were 13.97, 15.76, 18.60 and 32.41 kg C m^-2, respectively. As the rest grazing ages prolonged, the organic C storage in plant communities and soil increased. The C storage ofbelowground roots and soil organic C was mainly concentrated in 0-40 cm soil body. The increased soil organic C for RG3a accounted for 89.8% of the increased carbon in vegetation-soil system, 87.2% for RG6a, and 92.6% for RG9a. From the perspective of C sequestration cost, total cost for RG3a, RG6,, and RG9a were 2 903.4, 5 806.8 and 8 710.2 CNY haq, respectively. The cost reduced with the extension of rest grazing ages, 0.15 CNY kg^-1 C for RG3a, 0.11 CNY kg-~ C for RG6a and 0.04 CNY kg℃ for RG9a. From the growth characteristics of grassland plants, the spring was one of the two avoided grazing periods, timely rest grazing could effectively restore and update grassland vegetation, and was beneficial to the sustainable use of grassland. Organic C storage for RG9a was the highest, while the cost of C sequestration was the lowest. Therefore, spring rest grazing should be encouraged because it was proved to be a very efficient grassland use pattern.  相似文献   

3.
The objective of the present work is characterizing some parameters in the lay phase in the lines of heavy broilers breeder Cobb Avian 48, Arbor Acres Plus and Ross 208, reared under the same commercial conditions in the tropics. Monitored three batches of approximately 18,000 females each （one for each genetic type）, from weeks 24 to 64, according to the conditions of handling and power described by the generic lines distribution companies. Although no differences were found for feed intake, Cobb Avian was presented a lower rate of feed conversion, being also that presented the highest percentage of implementation and production of incubables eggs, which meant that it was in line with the highest cumulative production of chickens by bird and week for tropical conditions studied. To adjust the lay data to a Gorssman model, in order to predict the parameters that characterize the lay modeling, estimated the best behavior for Cobb Avian 48 females, because while it takes more time to reach the level of putting constant （5.30 weeks） and maintain it for less time （2.4 weeks）, they manage to put constant high （79.11%） level, considering that the largest number of eggs per bird （171.19 vs. 164.54 and 160.11 in Arbor Acres and Ross 208, respectively）.  相似文献   

4.
Macroscopic grasp of agricultural carbon emissions status, spatial-temporal characteristics as well as driving factors are the basic premise in further research on China’s agricultural carbon emissions. Based on 23 kinds of major carbon emission sources including agricultural materials inputs, paddy ifeld, soil and livestock breeding, this paper ifrstly calculated agricultural carbon emissions from 1995 to 2010, as well as 31 provinces and cities in 2010 in China. We then made a decomposed analysis to the driving factors of carbon emissions with logarithmic mean Divisia index （LMDI） model. The results show：（1） The amount of agricultural carbon emissions is 291.1691 million t in 2010. Compared with 249.5239 million t in 1995, it increased by 16.69%, in which, agricultural materials inputs, paddy ifeld, soil, enteric fermentation, and manure management accounted for 33.59, 22.03, 7.46, 17.53 and 19.39%of total agricultural carbon emissions, respectively. Although the amount exist ups and downs, it shows an overall trend of cyclical rise; （2） There is an obvious difference among regions：the amount of agricultural carbon emissions from top ten zones account for 56.68%, while 9.84%from last 10 zones. The traditional agricultural provinces, especially the major crop production areas are the main source regions. Based on the differences of carbon emission rations, 31 provinces and cities are divided into ifve types, namely agricultural materials dominant type, paddy ifeld dominant type, enteric fermentation dominant type, composite factors dominant type and balanced type. The agricultural carbon emissions intensity in west of China is the highest, followed by the central region, and the east zone is the lowest; （3） Compared with 1995, efifciency, labor and structure factors cut down carbon emissions by 65.78, 27.51 and 3.19%, respectively;while economy factor increase carbon emissions by 113.16%.  相似文献   

5.
Upland red soils have been identified as major CO2 and N2O sources induced by human activities such as fertilization. To monitor characteristics of soil surface CO2 and N2O fluxes in cropland ecosystems after continuous fertilizer applications over decades and to separate the respective contributions of root and heterotrophic respiration to the total soil CO2 and N2O fluxes, the measurements of soil surface CO2 and N2O fluxes throughout the maize growing season in 2009 were carried out based on a fertilization experiment （from 1990） through of the maize （Zea mays L.） growing season in red soil in southern China. Five fertilization treatments were chosen from the experiment for study： zero-fertilizer application （CK）, nitrogen-phosphorus- potassium （NPK） fertilizer application only, pig manure （M）, NPK plus pig manure （NPKM） and NPK with straw （NPKS）. Six chambers were installed in each plot. Three of them are in the inter-row soil （NR） and the others are in the soil within the row （R）. Each fertilizer treatment received the same amount of N （300 kg ha-1 yr-1）. Results showed that cumulative soil CO2 fluxes in NR or R were both following the order： NPKS〉M, NPKM〉NPK〉CK. The contributions of root respiration to soil CO2 fluxes was 40, 44, 50, 47 and 35% in CK, NPK, NPKM, M and NPKS treatments, respectively, with the mean value of 43%. Cumulative soil N2O fluxes in NR or R were both following the order： NPKS, NPKM〉M〉NPK〉CK, and soil N2O fluxes in R were 18, 20 and 30% higher than that in NR in NPKM, M and NPKS treatments, respectively, but with no difference between NR and R in NPK treatment. Furthermore, combine with soil temperature at -5 cm depth and soil moisWxe （0-20 cm） together could explain 55-70% and 42-59% of soil CO2 and N2O emissions with root interference and 62- 78% and 44-63% of that without root interference, respectively. In addition, soil CO2 and N2O flUXeS per unit yield in NPKM （0.55 and 0.10 kg C t^-1） and M （0.65 and 0.13 g N t^-1） treatments were lower than those in other treatments. Therefore, manure application could be a preferred fertilization strategy in red soils in South China.  相似文献   

6.
An attempt has been made to assess the productivity as well as the carbon sequestration potential of this mixture. The grain as well as straw yields were significantly lower in poplar block plantations than in the open （14 to 64% and 13 to 66% grain and straw yield, respectively under one to six year plantation）. The annual productivity of poplars was recorded maximum after fourth year and later the annual wood increment decreased （42.4, 39.8 and 35.6 m^3/ha/yr after 4^th, 5^th and 6^th year, respectively）. The enrichment of soil through litter and roots enhanced the organic carbon in the surface layer of soil （0-15 cm） under poplar blocks as compared to open fields with wheat crop only. The carbon storage potential in agroforestry system was recorded very high in comparison to sole crop. The carbon storage in agroforestry system increased with the age of the plantation and the major contribution came from the timber, roots and litter （37.30 mg/ha after six years）. However, wheat crop yield decreased under poplar but this may be compensated by the poplar trees in terms of biomass, economic returns and the carbon sequestration potential.  相似文献   

7.
The present study aims to understand the effects of long-term fertilization on soil organic carbon （SOC）, black carbon （BC）, enzyme activity, and the relationships among these parameters. Paddy field was continuously fertilized over 30 yr with nine different fertilizer treatments including N, P, K, NP, NK, NPK, 2NPK （two-fold NPK）, NPK＋manure （NPKM）, and CK （no fertilization）, N, 90 kg urea-N ha^-1 yr^-1; P, 45 kg triple superphosphate-P205 ha^-1 yr^-1; K, 75 kg potassium chloride-K20 ha^-1 yr^-1; and pig manure, 22 500 kg ha^-1 yr^-1. Soil samples were collected and determined for SOC, BC content, and enzyme activity. The results showed that the SOC in the NPKM treatment was significantly higher than those in the K, P, and CK treatments. The lowest SOC content was found in the CK treatment. SOC content was similar in the N, NP, NK, NPK, 2NPK, and NPKM treatments. There was no significant difference in BC content among different treatments. The BC-to-SOC ratios （BC/SOC） ranged from 0.50 to 0.63, suggesting that BC might originate from the same source. Regarding enzyme activity, NPK treatment had higher urease activity than NPKM treatment. The urease activity of NPKM treatment was significantly higher than that of 2NPK, NP, N, P, K, CK, and NPKM treatment which produced higher activities of acid phosphatase, catalase, and invertase than all other treatments. Our results indicated that long-term fertilization did not significantly affect BC content. Concurrent application of manure and mineral fertilizers increased SOC content and significantly enhanced soil enzyme activities. Correlation analysis showed that catalase activity was significantly associated with invertase activity, but SOC, BC, and enzyme activity levels were not significantly correlated with one another. No significant correlations were observed between BC and soil enzymes. It is unknown whether soil enzymes play a role in the decomposition of BC.  相似文献   

8.
Soil organic carbon （SOC）, soil microbial biomass carbon （SMBC） and SMBC quotient （SMBC/SOC, qSMBC） are key indexes of soil biological fertility because of the relationship to soil nutrition supply capacity. Yet it remains unknown how these three indexes change, which limits our understanding about how soil respond to different fertilization practices. Based on a 22-yr （1990-2011） long-term fertilization experiment in northwest China, we investigated the dynamics of SMBC and qSMBC during the growing period of winter wheat, the relationships between the SMBC, qSMBC, soil organic carbon （SOC） concentrations, the carbon input and grain yield of wheat as well. Fertilization treatments were 1） nonfertilization （control）; 2） chemical nitrogen plus phosphate plus potassium （NPK）; 3） NPK plus animal manure （NPKM）; 4） double NPKM （hNPKM） and 5） NPK plus straw （NPKS）. Results showed that the SMBC and qSMBC were significantly different among returning, jointing, flowering and harvest stages of wheat under long-term fertilization. And the largest values were observed in the flowering stage. Values for SMBC and qSMBC ranged from 37.5 to 106.0 mg kg1 and 0.41 to 0.61%, respectively. The mean value rank of SMBC during the whole growing period of wheat was hNPKM〉NPK_M〉NPKS〉CK〉NPK. But there were no statistically significant differences between hNPKM and NPKM, or between CK and NPK. The order for qSMBC was NPKS〉NPKM〉CK〉hNPKM〉NPK. These results indicated that NPKS significantly increased the ratio of SMBC to SOC, i.e., qSMBC, compared with NPK fertilizer or other two NPKM fertilizations. Significant linear relationships were observed between the annual carbon input and SOC （P〈0.01） or SMBC （P〈0.05）, and between the relative grain yield of wheat and the SOC content as well （P〈0.05）. But the qSMBC was not correlated with the annual carbon input. It is thus obvious that the combination of manure, straw with mineral fertilizer may be benefit to increase SOC and improve soil quality than using only mineral fertilizer.  相似文献   

9.
Biologically produced surfactants （SACs） can mobilize and solubilize non-aqueous phase liquids （NAPL） adsorbed onto soil constituents. The interest in microbial surfactants has increased during recent years due to their lower toxicity, higher biodegradability, selectivity and specific activity under extreme conditions than synthetic SACs. Main output of the project represents preparation of this yeast biosurfactant intended for washing of matrices contaminated by NAPL. The influence of cultivation media composition on biosurfactant production was studied and basic properties （critical micelle concentration （CMC）, minimum surface tension） of isolated biosurfactants were compared with properties of synthetic surfactant with surface tension measurement. The interracial tension of the systems containing aqueous solutions of different concentrations and non-polar substances was measured with petroleum compounds （kerosene Jet A-l）, aromatic and aliphatic hydrocarbons （represented by toluene and hexane）. The solution of biosurfactant Yarrowia lipolytica （YAR） in the concentration range of 0-500 mg/L reduced interracial tension by 80% in all representative systems with model contaminants; biosurfactant Candida bombicola （CAN） was less efficient. Solubilization properties were proved with toluene and hexachlorocyclohexane （HCH） isomers alpha and gamma, and effective concentration of biosurfactants was determined as 100 mg/L for toluene and HCH. SACs produced by lipophilic yeast with non-toxic and non-pathogenic status （Yarrowia lipolytica, Candida sp., etc.） seem to be very promising. The results obtained will be used for the application of biosurfactants in the clean-up technologies as agents for the mobilization of non-polar contaminants as well as for stimulation of bioremediation processes.  相似文献   

10.
Rangelands occupy 51% of the terrestrial land surface, 23% total land of Nepal. It contains about 36% of the world＇s total carbon in above and belowground biomass. Rangelands can aid in the mitigation of rising atmospheric carbon dioxide concentrations via carbon storage in biomass and soil organic matter. A study on carbon stock on soil and vegetation at various altitudinal gradients in Milke-Jaljale rangeland area of Eastern Nepal was made. The study was carried out at three altitudinal gradients （above sea levels） Milke （3,000 m）, Gorujure （3,500 m） and Jaljale （4,000 m）. This method required establishing a transect line. Sample points were located by pacing the appropriate distances from the point of origin at a transect line. To determine distribution and quantity of plant carbon and soil organic carbon （SOC）, 45 sample points were established and 15 points were sampled from each study site. Total soil carbon was estimated as follows： 17.65 t/ha at Milke, 17.27 t/ha at Gorujure and 28.33 t/ha at Jaljale. Similarly, total vegetation carbon was estimated 22.68 t/ha at Milke, 29.79 t/ha at Gorujure and 42.54 t/ha at Jaljale. Highest elevation study site with least external disturbance （Jaljale area） had high storage of carbon in both cases vegetation and soil.  相似文献   

11.
In order to valorize olive stones and to show its potential use in the sorption of two dispersed dyes, it was transformed in activate carbon and characterized. The effects of different system variables： pH, agitation speed, temperature and initial dye concentration were studied in the batch tests. The adsorption capacity of activated carbon for the dyes removal was found to be affected by the solution＇s pH. Acidic pH was found the favour disperse dyes removal. Over 95% removal was achieved for both the dyes at pH 3. The equilibrium time for both dyes was 30 min. Both Langmuir and Freundlich isotherms could be used to describe the adsorption of the dyes. Freundlich adsorption model succeeded in fitting the adsorption isotherms of dyes on olive stones activated carbon in single-solute systems, and prediction of the competitive adsorption behavior of dyes with the Freundlich-based Sheindorf-Rebuhn-Sheintuch （SRS） model gave acceptable results.  相似文献   

12.
The accurate assessment of the spatiotemporal changes in soil nutrients influenced by agricultural production provides the basis for development of management strategies to maintain soil fertility and balance soil nutrients. In this paper, we combined spatial measurements from 2 157 soil samples and geostatistical analysis to assess the spatiotemporal changes in soil organic carbon （SOC）, total nitrogen （TN）, available phosphorus （AP） and available potassium content （AK） from the first soil survey （in the 1980s） to the second soil survey （in the 2000s） in the Taihu region of Jiangsu Province in China. The results showed that average soil nutrients in three soil types all exhibited the increased levels in the 2000s （except for AK in the yellow brown soil）. The standard deviation of soil nutrient contents increased （except for TN in the paddy soil）. Agricultural production in the 20 years led to increases in SOC, TN, AP and AK by 74, 82, 89 and 65%, respectively, of the Taihu areas analyzed. From the 1980s to 2000s all the nugget/sill ratios of soil nutrients indices were between 25 and 75% （except for AK in the yellow brown soil in the 2000s）, indicating moderate spatial dependence. The ratio of AP in the yellow brown soil in the 2000s was 88.74%, showing weak spatial dependence. The spatial correlation range values for SOC, TN, AP and AK in the 2000s all decreased. The main areas showing declines in SOC, TN and AP were in the northwest. For AK, the main region with declining levels was in the east and middle of western areas. Apparently, the increase in soil nutrients in the Taihu region can be mainly attributed to the large increase in fertilizer inputs, change in crop systems and enhanced residues management since the 1980s. Future emphasis should be placed on avoiding excess fertilizer inputs and balancing the effects of the fertilizers in soils.  相似文献   

13.
The changes in humic substances （HS） is fundamental in detecting soil carbon sequestration mechanisms in natural and cultivated environments. Based on a long-term trial, the amounts of water dissolved substances （WSS）, humic acid （HA）, fulvic acid （FA） and humin （HU） were determined to explore the impact of long-term fertilization on HS. Increases in the amounts of WSS, HA, FA and HU were significant different among the treatments with manure. A significant correlation was found between the increased soil organic carbon （SOC） and HS （R^2=0.98, P〈0.01）. The change in the E4/E6 ratio was significantly correlated with the increased SOC （R2=0.88, P〈0.01）, HA （R^2=0.91, P〈0.01）, FA （R^2=0.91, P〈0.01） and HU （R^2=0.88, P〈0.01）. The cluster was mainly divided into two parts as manure fertilization and inorganic fertilization, based on the increases in HA, FA and HU. These results suggest that long term fertilization with manure favours carbon sequestration in HS and is mainly stabilized as HU, while the HA becomes more aliphatic. We conclude that increases in SOC can be linked to changes in the molecular characteristics of HS fractions under long term fertilization.  相似文献   

14.
Long-term continuous cropping of soybean （Glycine max）, spring wheat （Triticum aesativum） and maize （Zea mays） is widely practiced by local farmers in northeast China. A field experiment （started in 1991） was used to investigate the differences in soil carbon dioxide （CO2） emissions under continuous cropping of the three major crops and to evaluate the relationships between CO2 fluxes and soil temperature and moisture for Mollisols in northeast China. Soil CO2 emissions were measured using a closed-chamber method during the growing season in 2011. No remarkable differences in soil organic carbon were found among the cropping systems （P〉0.05）. However, significant differences in CO2 emissions from soils were observed among the three cropping systems （P〈0.05）. Over the course of the entire growing season, cumulative soil CO2 emissions under different cropping systems were in the following order： continuous maize （（829±10） g CO2 m2）〉continuous wheat （（629±22） g CO2 m^2）〉continuous soybean （（474±30） g CO2 m-2）. Soil temperature explained 42-65% of the seasonal variations in soil CO2 flux, with a Q10 between 1.63 and 2.31; water-filled pore space explained 25-47% of the seasonal variations in soil CO2 flux. A multiple regression model including both soil temperature （T, ~C） and water-filled pore space （W, %）, log（]）=a＋bT log（W）, was established, accounting for 51-66% of the seasonal variations in soil CO2 flux. The results suggest that soil CO2 emissions and their Q10 values under a continuous cropping system largely depend on crop types in Mollisols of Northeast China.  相似文献   

15.
Two sets of experiments were conducted to study the chemical composition, mineralization and availability of nutrients （particularly N） of Azolla biomass and cyanohacteria blooms in submerged rice soil. One set of experiment was conducted with Azolla without soil and the other with both Azolla and cyaobacteria with soil, in laboratory condition. Large samples were collected from the rice fields. The study shows that Azolla and cyanobacterial biomass contain good amounts of C, N, P and Ca. The chemical analysis of oxidizable C, total N, P and Ca showed that Azolla biomass contain 20.7% oxidizable C, which is higher than the cyanobacterial biomass （9.18%）. The N content in Azolla biomass was found to be 4.32%, than that of cyanobacterial biomass, i.e., 2.57%, however, P and Ca contents were also found to be higher in Azolla averaging to 124.83 ppm and 345.3 mg/100 g, respectively than cyanobacteria. The leachate analysis revealed that Azolla biomass release about 39.18% to 64.48% oxidizable C and about 19.23% to 33% N after 45 days of incorporation of soil dilution. Incorporation of Azolla and cyanobacterial biomass N@ 100 kg/ha significantly improved the oxidizable organic C, total as well as available N content in soil up to 75 days of incubation. Due to the incorporation of Azolla in soil, oxidizable organic C increased 25.51%, total N 4.10% and available N 47.65%. Almost similar trend of increase was also observed with the incorporation of cyanobacterial blooms.  相似文献   

16.
Phytophthora root and crown rot was found on the fruit trees in Bulgaria for the first time in the period 1998-1999. Monitoring of the disease spread from 2000 to 2007 points out incidence between 2 and 14 per cent, in some orchards and nurseries in the Southern part of Bulgaria. The following Phytophthora species were identified based on morphological and cultural characteristics, and temperature requirements： Phytophthora cactorum, Phytophthora citrophthora, Phytophthora drechsleri, Phytophthora cryptogea, Phytophthora hybrid specie and Pythium. Prevailing specie was P. cactorum. P. cryptogea and P. cactorum were confirmed by application of molecular methods. Nutritional requirements of P. cactorum and P. citrophthora were studied. Most Nitrogen sources stimulated the mycelial growth of P. cactorum to a higher extend, and reduced the colony size ofP. citrophthora. Different Carbon sources were utilized well by P. cactorum, and only saccharose and maltose had a stimulating effect on the mycelial growth of P. citrophthora. MgSO4.7H20 was the preferred sulfur source for both fungi, as L-cysteine and L-methionine only for P. cactorum. Phytophthora infection leads to physiological changes in the.host plant tissues. The tendency traced out is： about disorders in the amino acid metabolism, increase in the total sugars and slight reduction of the cellulose content. The total nitrogen, phosphorus and potassium content are reduced and the calcium and magnesium are increased. Photosynthesis of inoculated plants was suppressed and transpiration was increased.  相似文献   

17.
Soil organic carbon （SOC） is one of the main carbon reservoirs in the terrestrial ecosystem. It is important to study SOC dynamics and effects of organic carbon amendments in paddy fields because of their vest expansion in south China. A study was carried out to evaluate the relationship between the SOC content and organic carbon input under various organic amendments at a long-term fertilization experiment that was established on a red soil under a double rice cropping system in 1981. The treatments included non-fertilization （CK）, nitrogen-phosphorus-potassium fertilization in early rice only （NPK）, green manure （Astragalus sinicus L.） in early rice only （OM1）, high rate of green manure in early rice only （OM2）, combined green manure in early rice and farmyard manure in late rice （OM3）, combined green manure in early rice, farmyard manure in late rice and rice straw mulching in winter （OM4）, combined green manure in early rice and rice straw mulching in winter （OMS）. Our data showed that the SOC content was the highest under OM3 and OM4, followed by OM1, OM2 and OM5, then NPK fertilization, and the lowest under non-fertilization. However, our analyses in SOC stock indicated a significant difference between OM3 （33.9 t ha^-1） and OM4 （31.8 t ha^-1）, but no difference between NPK fertilization （27 t ha^-1） and nonfertilization （28.1 t ha^-1）. There was a significant linear increase in SOC over time for all treatments, and the slop of linear equation was greater in organic manure treatments （0.276-0.344 g kg-1 yr^-1） than in chemical fertilizer （0.216 g kg^-1 yr^-1） and no fertilizer （0.127 g kg^-1 yr^-1）.  相似文献   

18.
Carbon unusually rich in C(13)(deltaC(13) = +5.4 to +19.0 per mil relative to the Peedee belemnite carbonate standard of the University of Chicago) is characteristic of certain diagenetic limestones and dolomites in the Miocene Monterey Shale of California and the Nye Mudstone of Oregon. This heavy carbon may have originated through low-temperature equilibration between CO(3)- - and CO(2) in migrating carbonated waters or between CH(4) and CO(2) in natural gas. Light carbon (deltaC(13) = -5.6 to -18.2 per mil) derived through nonequilibrium oxidation of organic matter also occurs in the carbonate of Monterey Shale in some localities, but at most places it is much less common than heavy carbon.  相似文献   

19.
活性炭在超声环境中用30%的H2O2氧化6h,然后用来修饰碳糊电极,利用线性扫描法同时检测水溶液中的Pb2+和Cu2+。对缓冲溶液的pH值,氧化活性炭的含量,富集时间及富集电位等参数进行了优化,使用这种方便、可靠的方法同时检测水试样中的Pb2+和Cu2+取得了满意的效果。  相似文献   

20.
The objective of this study was to evaluate the effects of elemental sulphur （S） and farmyard manure on soil pH, EC and N, S, P concentrations of tomato grown in a calcareous sandy loam soil. For this purpose, a pot experiment was conducted in greenhouse conditions. Sulphur was applied at 0, 50, 100, 150, 200, 400 mg kg~ and farmyard manure at 0, 3 ton da^-1 to the soil. Three weeks after applications, tomato seedlings were planted and 8 weeks later, the plants were harvested to determine N, S, P concentrations and dry matter yield. Soil pH and EC were determined in the soil samples taken at 3 different periods. Effects of sulphur and farmyard manure applications were not significant on N, P concentrations and dry matter yield of tomato plant. S concentration of tomato plant was increased by sulphur alone. Soil pH was decreased and soil EC was increased in both 2^nd and 3^rd soil sampling period by the sulphur applications. As a result of farmyard manure application, soil pH decreased in the 2^nd soil sampling period but increased in the 3^rd soil sampling period. Also, soil EC was significantly increased in 1^st and 3^rd soil sampling period. Farmyard manure had no significant effect on S supply to tomato plant. The N：S ratio of tomato plant was decreased by sulphur alone. However, the sulphur with farmyard manure applications decreased N：S ratio in lesser extend compared to the S applications.  相似文献   

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