首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 375 毫秒
1.
水分胁迫是潮土区玉米苗期生长的主要限制性因素,本研究采用水磷二因素完全随机设计的盆栽试验,设水分胁迫(W_1,田间持水量的70%~75%)和充分供水(W_2,田间持水量的85%~90%)2个水分处理;磷素处理设对照不施磷(P1)、施磷0.05 g·kg~(-1)土(P2)、0.10 g·kg~(-1)土(P3)、0.15 g·kg~(-1)土(P_4)和0.20 g·kg~(-1)(P5)5个处理,研究水分胁迫下施磷对玉米苗期叶片光合特性、酶活性及养分吸收的影响,为潮土区农田水分和磷素合理施用提供科学依据。研究结果表明:水分胁迫(W1)降低了玉米苗期净光合速率(Pn),W_1较W_2叶片Pn平均降低了27.96%;显著提高了玉米苗期丙二醛(MDA)含量,平均提高41.93%,水分胁迫还降低了过氧化物酶(POD)和过氧化氢酶(CAT)活性。在W1条件下施磷达到P_2水平叶片Pn即显著提高27.56%,而在W_2条件下施磷量只有达到P_4、P_5高水平时Pn才显著提高,在W_1条件下施磷对MDA的抑制效果明显弱于W_2。W_1条件下施磷量在P3水平POD和CAT活性最高,而在W_2条件下POD和CAT活性在P4达到最大值。W_1条件下适宜的施磷量(P_2至P_4)可以增加苗期玉米植株氮磷含量,但对钾含量影响较小;在W_2条件下增施磷有利于植株氮磷含量的增加,但钾素含量出现降低。综上,适宜的施磷量对潮土玉米苗期水分胁迫有一定的补偿作用,在本试验条件下,P_3处理在水分胁迫下更利于光合产物积累和玉米苗期抗逆性提高。  相似文献   

2.
The parameters of adsorption of Cu2+, Pb2+, and Zn2+ cations by soils and their particle-size fractions were studied. The adsorption of metals by soils and the strength of their fixation on the surface of soil particles under both mono- and polyelement contamination decreased with the decreasing proportion of fine fractions in the soil. The adsorption capacity of the Lower Don chernozems for Cu2+, Pb2+, and Zn2+ depending on the particle-size distribution decreased in the following sequence: clay loamy ordinary chernozem ∼ clay loamy southern chernozem > loamy southern chernozem > loamy sandy southern chernozem. According to the parameters of the adsorption by the different particle-size fractions (C max and k), the heavy metal cations form a sequence analogous to that obtained for the entire soils: Cu2+ ≥ Pb2+ > Zn2+. The parameters of the heavy metal adsorption by similar particle-size fractions separated from different soils decreased in the following order: clay loamy chernozem > loamy chernozem > loamy sandy chernozem. The analysis of the changes in the parameters of the Cu2+, Pb2+, and Zn2+ adsorption by soils and their particlesize fractions showed that the extensive adsorption characteristic, namely, the maximum adsorption (C max), was a less sensitive parameter characterizing the soil than the intensive characteristic of the process—the adsorption equilibrium constant (k).  相似文献   

3.
Previous studies have shown that carbon (C) mineralization in saline or sodic soils is affected by various factors including organic C content, salt concentration and water content in saline soils and soil structure in sodic soils, but there is little information about which soil properties control carbon dioxide (CO2) emission from saline-sodic soils. In this study, eight field-collected saline–sodic soils, varying in electrical conductivity (ECe, a measure of salinity, ranging from 3 to 262 dS m−1) and sodium adsorption ratio (SARe, a measure of sodicity, ranging from 11 to 62), were left unamended or amended with mature wheat or vetch residues (2% w/w). Carbon dioxide release was measured over 42 days at constant temperature and soil water content. Cumulative respiration expressed per gram SOC increased in the following order: unamended soil<soil amended with wheat residues (C/N ratio 122)<soil with vetch residue (C/N ratio 18). Cumulative respiration was significantly (p < 0.05) negatively correlated with ECe but not with SARe. Our results show that the response to ECe and SARe of the microbial community activated by addition of organic C does not differ from that of the less active microbial community in unamended soils and that salinity is the main influential factor for C mineralization in saline–sodic soils.  相似文献   

4.
5.
Our objectives were to determine both spatial and temporal variations in soil respiration of a mixed deciduous forest, with soils exhibiting contrasting levels of hydromorphy. Soil respiration (RS) showed a clear seasonal trend that reflected those of soil temperature (TS) and soil water content (WS), especially during summer drought. Using a bivariate model (RMSE=1.03), both optimal soil water content for soil respiration (WSO) and soil respiration at both 10 °C and optimal soil water content (RS10) varied among plots, ranging, respectively, from 0.25 to 0.40 and from 2.30 to 3.60 μmol m−2 s−1. Spatial variation in WSO was related to bulk density and to topsoil N content, while spatial variation in RS10 was related to basal area and the difference in pH measured in water or KCl suspensions. These results offer promising perspectives for spatializing ecosystem carbon budget at the regional scale.  相似文献   

6.
Kinetics of soil microbial uptake of free amino acids   总被引:8,自引:0,他引:8  
 Amino acids and proteins typically form the biggest input of organic-N into most soils and provide a readily available source of C and N for soil microorganisms. Amino acids can also be taken up directly by plant roots, providing an alternative source of available soil N. However, the degree to which plants can compete against the soil microbial population for amino acids in soil solution remains poorly understood. The aim of this study was to measure the rate of microbial uptake of three contrastingly charged 14C-labelled amino acids (glutamate1–, glycine0, lysine0.9+) over a wide concentration range (0.1–5 mM) and in two contrastingly managed soils varying in their degree of erosion, organic-C content and microbial biomass. Amino acid uptake was concentration dependent and conformed to a single Michaelis-Menten equation. The mean maximum amino acid uptake rate (V max) for the non-eroded (control) soil (high organic-C, high biomass) was 0.13±0.02 mmol kg–1 h–1, while half maximal uptake occurred at a concentration (K m) of 2.63±0.07 mM. Typically, V max was fourfold lower and K m twofold lower in the eroded soil (low available organic-C, low biomass) compared to the non-eroded (control) soil. Amino acid substrate concentration had little effect on the proportion of amino acid utilized in catabolic versus anabolic metabolism and was similar for both. While the results obtained here represent the summation of kinetics for a mixed soil population, they indicate that amino acid uptake is saturated at concentrations within the millimolar range. Because the affinity constants also were similar to those described for plant roots, we hypothesized that competition for amino acids between plants and microbes will be strong in soil but highly dependent upon the spatial distribution of roots and microbes in soil. Received: 2 March 2000  相似文献   

7.
Sulfate (SO4 2–) movement and transport in soils has received considerable attention in recent years. In most soils, SO4 2– coexists with a variety of natural organic compounds, especially organic acids. Studies were conducted to assess the effect of low-molecular-weight organic acids (eight aliphatic and five aromatic acids) on SO4 2– adsorption by variable charge soils from Chile and Costa Rica. The effects of type of organic acid, pH, type of soil, and organic acid concentration were investigated. In one experiment, a 1.0 g soil sample was equilibrated with 25 ml 0, 0.5, 1.0, 2.0, 4.0, or 6.0 mM K2SO4 in 1 mM NaCl in the presence or absence of 5 mM citric acid. In the second set of experiments, the adsorption of 2 mM SO4 2– in soils at pH 4 or pH 5 in the presence or absence of one of 13 organic acids at a concentration of 2 mM or 5 mM was studied. Results showed that citric acid significantly decreased SO4 2– adsorption by the two soils. Sulfate adsorption decreased with increasing pH of the equilibrium solution. Aliphatic acids, with the exception of cis-aconitic acid, decreased the amount of SO4 2– adsorbed by the two soils, with oxalic, tartaric, and citric acid showing the greatest effect. The differences in pH values of the equilibrium solutions in the presence and absence of organic acids were significantly, but negatively, correlated with the amount of SO4 2– adsorbed, suggesting chemisorption of SO4 2– and the release of hydroxide ions. The ionization fraction values of the organic acids at the equilibrium pH were correlated with the amounts of SO4 2– adsorbed, suggesting that the protonation of surface hydroxyl groups of the mineral phase increased as the strength of the ionization of the acid increased, thus creating more positively charged surfaces. Received: 12 February 1997  相似文献   

8.
Abstract

Improving phosphorus (P) fertilizer efficiency while minimizing environmental impacts requires better understanding of the dynamics of applied P in soils. This study assessed the fate of fertilizer P applied in Quebec Humaquepts. A pot experiment with five textural Humaquepts, each receiving 0 (P0), 10 (P10), 20 (P20) and 40 (P40) mg P kg?1 soil was conducted under barley (Hordeum vulgare L.)-soybean (Glycine max L.) rotations. A modified Hedley procedure was used for soil P fractionation. The clayey soils reached a plateau of dry matter at less P applied than the coarser-textured soils. Plant P uptake, soil labile inorganic P (resin-P?+?NaHCO3-Pi) and moderately labile inorganic P (NaOH-Pi) increased proportionally with P rate. The coarser-textured soils had lower contents of labile and moderately labile Pi, but a larger increase in labile Pi than the finer-textured soils after receiving P additions. The applied P was retained primarily as soil labile Pi, accounting for 43–69% of total soil recovery of applied P, compared to 20–30% recovered as moderately labile Pi, and 7–29% assumed to be sparingly soluble P (HCl-P?+?H2SO4-P). The labile Pi recovery of applied P was linearly depressed with clay content, compared to a quadratic relation for the moderately labile Pi recovery. The results suggest the importance of accounting for soil texture along with soil P adsorption capacity when assessing the efficiency of applied P, P accumulation in soils and subsequently P nutrient management.  相似文献   

9.
A study was conducted to investigate the effects of cow manure and sewage sludge application on the activity and kinetics of soil l-glutaminase. Soil samples were collected from a farm experiment in which 0, 25, and 100 Mg ha−1 of either cow manure or sewage sludge had been applied annually for 4 consecutive years to a clay loam soil (Typic Haplargid). A chemical fertilizer treatment had also been applied. Results indicated that the effects of chemical fertilizer and the solid waste application on pH in the 18 surface soil (0–15 cm) samples were not significant. The organic C content, however, was affected significantly by the different treatments, being the greatest in soils treated with 100 Mg ha−1 cow manure, and the least in the control treatment. l-Glutaminase activity was generally greater in solid-waste applied soils and was significantly correlated (r = 0.939, P < 0.001) with organic C content of soils. The values of l-glutaminase maximum velocity (Vmax) ranged from 331 to 1,389 mg NH4 +–N kg−1 2 h−1. Values of the Michaelis constant (K m) ranged from 35.1 to 71.7 mM. Organic C content of the soils were significantly correlated with V max (r = 0.919, P < 0.001) and K m (r = 0.763, P < 0.001) values. These results demonstrate the considerable influence that solid waste application has on this enzymatic reaction involved in N mineralization in soil.  相似文献   

10.
喀斯特石漠化山区苔藓植物水分吸收特征   总被引:4,自引:1,他引:4  
[目的]探究贵阳市花溪区石漠化地区5种优势种黑扭口藓(Barbula nigrescens)、美灰藓(Eurohypnum leptothallum)、卷叶湿地藓(Hyophila involuta)、小牛舌藓全缘亚种(Anomondon minor subsp.integerrimus)、北方紫萼藓(Grimmia decipiens)的水分吸收特征,为喀斯特石漠化地区利用苔藓植物开展水土保持工作提供理论支撑。[方法]采集样品120份,运用经典形态分类法进行鉴定;测定其生物量、饱和吸水率、吸水量、最大吸水速率(Vmax)、吸水速率常数(Km)和叶片展开时间。[结果](1)5种苔藓植物间的生物量、吸水量和饱和吸水率差异较大,最大吸水速率差异小;生物量为10.36~114.51g/m2;饱和吸水率为675.43 6%~1 125.41%;吸水量为98.21~766.13g/m2;Vmax为35.59~51.28g/(g·min);Km为69.97~101.99g;叶片展开时间为35.9~86.1s。(2)生物量和吸水量呈正极显著相关;吸水量和盖度、Vmax和Km呈正相关;Km和叶片展开时间呈负相关。[结论]在喀斯特石漠化地区干旱缺水的环境条件下,苔藓以独特的水分吸收和利用方式适应这种恶劣的环境。石生苔藓为适应该地区的先锋植物。  相似文献   

11.
利用15N同位素标记方法,研究在两种水分条件即60%和90% WHC下,添加硝酸盐(NH4NO3,N 300 mg kg-1)和亚硝酸盐(NaNO2,N 1 mg kg-1)对中亚热带天然森林土壤N2O和NO产生过程及途径的影响.结果表明,在含水量为60% WHC的情况下,高氮输入显著抑制了N2O和NO的产生(p<0.01);但当含水量增为90% WHC后,实验9h内抑制N2O产生,之后转为促进.所有未灭菌处理在添加NO2-后高氮抑制均立即解除并大量产生N2O和NO,与对照成显著差异(p<0.01),在60% WHC条件下,这种情况维持时间较短(21 h),但如果含水量高(90% WHC)这种情况会持续很长时间(2周以上),说明水分有效性的提高和外源NO2-在高氮抑制解除中起到重要作用.本实验中N2O主要来源于土壤反硝化过程,而且加入未标记NO2-后导致杂合的N2O(14N15NO)分子在实验21 h内迅速增加,表明这种森林土壤的反硝化过程可能主要是通过真菌的“共脱氮”来实现,其贡献率可多达80%以上.Spearman秩相关分析表明未灭菌土壤NO的产生速率与N2O产生速率成显著正相关性(p<0.05),土壤含水量越低二者相关性越高.灭菌土壤添加NO2-能较未灭菌土壤产生更多的NO,但却几乎不产生N2O,表明酸性土壤的化学反硝化对NO的贡献要大于N2O.  相似文献   

12.
通过田间试验研究了不施肥(CK)、施氮360 kg?hm?2(T1)、施氮720 kg?hm?2(T2)处理下茶园土壤无机氮、p H、各形态氟含量的动态变化和春、夏、秋茶树新梢一芽四叶、一芽五叶氟含量,探讨茶园施氮对土壤和茶树新梢氟含量的影响。结果表明:1)茶园施氮后短期内(20~30 d)土壤水溶态氟含量显著降低,土壤交换态氟和铁锰结合态氟含量降低;长期(45~50 d)土壤水溶态氟含量的降低作用减弱,土壤交换态氟和铁锰结合态的含量增加;在试验结束时(164 d),与CK处理相比,T1处理0~20 cm土壤各形态氟含量降低,T2处理0~20 cm土壤各形态氟含量增加。2)0~20 cm茶园土壤水溶态氟、铁锰结合态氟与NH4+-N分别呈极显著负、正相关(P0.01),20~40 cm土壤水溶态氟、交换态氟与NO3?-N分别呈极显著正、负相关(P0.01)。土壤p H与土壤水溶态氟含量极显著负相关(P0.01),与其他3种形态氟含量相关性不显著。土壤铁锰结合态氟与交换态氟、有机结合态氟呈显著、极显著正相关,但与土壤水溶态氟均无显著相关性。3)春茶前后施氮可以降低春、夏、秋茶树新梢一芽四叶、一芽五叶氟含量,但未达显著水平。T1处理新梢氟含量的降低值为夏茶(25.15~27.95 mg?kg?1)秋茶(21.06~24.31 mg?kg?1)春茶(18.58~21.03 mg?kg?1),T2处理的降低值为秋茶(18.64~22.34 mg?kg?1)夏茶(7.79~14.14 mg?kg?1)春茶(3.52~7.30 mg?kg?1)。春、夏、秋茶树新梢氟含量主要受0~20 cm土壤无机氮和20~40 cm土壤p H的影响。因此推测施氮通过影响茶树根系氟的吸收和氟在叶片中的累积过程调控茶树新梢氟含量,该研究成果为合理利用施氮技术降低茶园土壤和茶树新梢氟含量提供了理论依据。  相似文献   

13.
姜永清 《土壤学报》1985,22(1):75-84
本研究目的是了解陕西省的几种土壤吸附和解吸附砷酸盐的速率和过程,以及其吸附能量。Kuo和Lotse导出的双常数速率公式拟合试验资料优于一级、二级、三级反应公式,抛物线扩散和Elovich公式等五个公式。用双常数速率公式(C=k·C0·t1/m)分两段拟合能进一步提高拟合优度。根据Arrhenius公式计算出的吸附活化能是0.70—3.40千卡/克分子。低的活化能表明,供试土壤对砷酸盐的吸附作用是一种完全不同于真溶液条件化学反应的物理学过程。土壤吸附和解吸附砷酸盐的速度和容量受作用时间、温度、溶液∶土壤比率,加入的砷量和浓度,以及土壤特性的影响。粘土的吸附反应常数(k),吸附量比沙壤土大。而沙壤土有高的解吸附反应速度常数(k-1'),砷酸盐容易被解吸附而释放出来。  相似文献   

14.
Awareness of global warming has stimulated research on environmental controls of soil methane (CH4) consumption and the effects of increasing atmospheric carbon dioxide (CO2) on the terrestrial CH4 sink. In this study, factors impacting soil CH4 consumption were investigated using laboratory incubations of soils collected at the Free Air Carbon Transfer and Storage I site in the Duke Forest, NC, where plots have been exposed to ambient (370 μL L−1) or elevated (ambient + 200 μL L−1) CO2 since August 1996. Over 1 year, nearly 90% of the 360 incubations showed net CH4 consumption, confirming that CH4-oxidizing (methanotrophic) bacteria were active. Soil moisture was significantly (p < 0.01) higher in the 25–30 cm layer of elevated CO2 soils over the length of the study, but soil moisture was equal between CO2 treatments in shallower soils. The increased soil moisture corresponded to decreased net CH4 oxidation, as elevated CO2 soils also oxidized 70% less CH4 at the 25–30 cm depth compared to ambient CO2 soils, while CH4 consumption was equal between treatments in shallower soils. Soil moisture content predicted (p < 0.05) CH4 consumption in upper layers of ambient CO2 soils, but this relationship was not significant in elevated CO2 soils at any depth, suggesting that environmental factors in addition to moisture were influencing net CH4 oxidation under elevated CO2. More than 6% of the activity assays showed net CH4 production, and of these, 80% contained soils from elevated CO2 plots. In addition, more than 50% of the CH4-producing flasks from elevated CO2 sites contained deeper (25–30 cm) soils. These results indicate that subsurface (25 cm+) CH4 production contributes to decreased net CH4 consumption under elevated CO2 in otherwise aerobic soils.  相似文献   

15.
Abstract

The effectiveness of Stay‐N 2000 or reformulated nitrapyrin [2‐chloro‐6‐(tricholoromethyl) pyridine] was investigated in two Iowa soils representative of Clarion and Okoboji soils that differed in organic carbon, pH, and texture. A nonlinear regression was used to estimate kinetic parameters. The maximum nitrification rate (K max) and the duration of lag period (t′) were derived from the equation to characterize the nitrification process in both soils. Stay‐N 2000 appeared to be a better inhibitor than nitrapyrin to extend t′ and as effective as nitrapyrin in reducing K max. Stay‐N 2000 reduced K max an appreciable amount in the Okoboji soil at the rate of 12 µg a.i. g?1 soil or three times the recommended rate. Nitrification rates were affected by the rates of nitrogen (N) applied to both soils; the higher the N rates, the higher Kmax, and the more the nitrate (NO3 ?)‐N accumulation.  相似文献   

16.
The effects of temperature and water potential on nitrification were investigated in two Iowa soils treated with Stay‐N 2000. The soils were incubated at 10, 20, and 30 °C after soil water potentials of ?1, ?10, or ?60 kPa were applied to each soil. A first‐order equation was used to calculate the maximum nitrification rate (K max), duration of lag period (t′), period of maximum nitrification (Δt), and termination period of nitrification (t s). The highest K max were 18 and 24 mg kg?1 d?1 nitrate (NO3 ?)–nitrogen (N), respectively, at 30 °C and ?10 kPa in both the Nicollet (fine‐loamy, mixed, superactive, mesic Aquic Hapludoll) and Canisteo (fine‐loamy, mixed, superactive, calcareous, mesic Typic Endoaquoll) soils and reduced to 4 and 16 mg kg?1 d?1 NO3 ?‐N when Stay‐N 2000 was added. The extension of t′ due to the addition of Stay‐N 2000 was as high as 7 d in the Nicollet soil at 10 °C and ?1 kPa and as little as 2 d in the Canisteo soil at 20 °C and ?10 kPa.  相似文献   

17.
Effect of Irrigation and Fertilizer Placement on the N-Uptake by Wheat under Semiarid Conditions of Karadj/Iran Field and greenhouse experiments were conducted under semiarid conditions of Karadj/Iran on a sandy to silty loam of alluvial soils (pH% 8,2) to study the effects of soil moisture regimes and N-fertilizer placement on yield, N-uptake and recovery of fertilizer N from 15NH4 15NO3, (15NH2)2CO and (15NH4)2SO4. There were two moisture regimes as main plots (W1 = Irrigation at 50% and W2 = Irrigation at 25% available water in 0–30 cm depth of soil), and two methods of fertilizer placement (broadcast and band application). Irrigation at (W1) increased the grain and straw yield 11 and 19% but not total N-uptake in the field experiment. (W1)-irrigation combined with band application resulted in the highest yield and total N-uptake. Utilization of applied N, however, was higher with (W2)-irrigation in both fertilizer placements. This result was confirmed by the data of the greenhouse experiment. Band application was superior to broadcast application for fertilizer N-uptake with both water managements. Ammonium sulfate showed the highest and urea the lowest difference between the two fertilizer placements.  相似文献   

18.
Tillage systems influence soil properties and may influence the availability of applied and mineralized soil N. This laboratory study (20°C) compared N cycling in two soils, a Wooster (fine, loamy Typic Fragiudalf) and a Hoytville (fine, illitic Mollic Epiaqualf) under continuous corn (Zea mays) production since at least 1963 with no-tillage (NT), minimum (CT) and plow tillage (PT) management. Fertilizer was added at the rate of 100 mg 15N kg–1–1 soil as 99.9% 15N as NH4Cl or Ca(NO3)2 and the soils were incubated in leaching columns for 1 week at 34 kPa before being leached periodically with 0.05 M CaCl2 for 26 weeks. As expected, the majority of the 15NO3 additions were removed from both soils with the first leaching. The majority of applied 15NH4+ additions were recovered as 15NO3 by week 5, with the NT soils demonstrating faster nitrification rates compared with soils under other tillage practices. For the remaining 22 weeks, only low levels of 15NO3 were leached from the soils regardless of tillage management. In the coarser textured Wooster soils (150 g clay kg–1), mineralization of native soil N in the fertilized soils was related to the total N content (r2 0.99) and amino acid N (r2 0.99), but N mineralization in the finer textured Hoytville (400 g clay kg–1) was constant across tillage treatments and not significantly related to soil total N or amino acid N content. The release of native soil N was enhanced by NH4+ or NO3 addition compared to the values released by the unfertilized control and exceeded possible pool substitution. The results question the use of incubation N mineralization tests conducted with unfertilized soils as a means for predicting soil N availability for crop N needs.  相似文献   

19.
本试验测定了浙江省几种代表性土壤对磷的等温吸持特性。实测值与Frundlich、Langmuir、两项式Langmuir和Temkin方程都很符合,相关系数变化范围在0.919-0.999之间,都达到极显著水平。其中以简单Langmuir等温式与本实验资料最为吻合。从Langmuir方程得到的土壤吸持特性值(k×qm)被认为与土壤供磷特性有关。几种供试样品的(k×qm)值是:针铁矿21100>黄筋泥4218>黄筋泥田991>青紫泥798>粉泥田660>高岭石485>老黄筋泥田423>泥质田298。根据土壤吸持特性值以田菁进行盆栽试验来估算作物磷肥需要量,结果表明,供磷强度0.3ppm P基本能满足田菁早期生长的需要。为使不同土壤达到相同的供磷强度,(k×qm)值大的土壤要求更高的有效磷值。供试土壤的几种磷素指标:E值、Bray1-P值和(NaOH-Na2C2O4)法值对(k×qm)值的变化比较敏感,而EDTA-P和Olsen-P指标对(k×qm)值的变化较为迟钝。  相似文献   

20.
THE HIGH- AND LOW-ENERGY PHOSPHATE ADSORBING SURFACES IN CALCAREOUS SOILS   总被引:2,自引:0,他引:2  
The two-surface Langmuir equation was used to study P adsorption by 24 calcareous soils (pH 7.2-7.6; 0.8-24.2 per cent CaCO3) from the Sherborne soil series, which are derived from Jurassic limestone. High-energy P adsorption capacities (xm) ranged from 140–345 μg P/g and were most closely correlated with dithionite-soluble Fe. Hydrous oxides therefore appear to provide the principal sites, even in calcareous soils, on which P is strongly adsorbed (xm 6–51 ml/μg P). The low-energy adsorption capacities (xm) ranged from 400–663 μg P/g and were correlated with organic matter contents and the total surface areas of CaCO3 but not with per cent CaCO3, pH, or dithionite-soluble Fe. Total surface areas of CaCO3 in the soils ranged from 4.0 to 8.5 m2/g soil. Low-energy P adsorption capacities agree reasonably with values (100 pg P/m2) for the sorption of phosphate on Jurassic limestones but phosphate was bonded much less strongly by soil carbonates (k″= 0.08–0.45 ml/μg P) than by limestones (k~10.0 ml/μg P). Low-energy P adsorption in these soils is tentatively ascribed to adsorption on sites already occupied by organic anions (and probably also by bicarbonate and silicate ions) which lessen the bonding energy of co-adsorbed P.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号