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在实验室制备得到树脂型甲醛捕捉剂,考察了甲醛捕捉剂与不同F/U摩尔比脲醛树脂混合使用后制备得到的刨花板力学性能及甲醛释放量。研究结果表明,甲醛捕捉剂的添加能有效降低刨花板的甲醛释放量,但对混合树脂的最终力学强度性能不利。混合树脂的摩尔比F/U是决定相关刨花板力学性能及甲醛释放量的主要因素。当与摩尔比F/U=1的脲醛树脂混合使用时,添加占总施胶量5%甲醛捕捉剂的刨花板甲醛释放量可达到E1级,同时,内结合强度值满足室内级国家标准要求。与摩尔比F/U=1.2的脲醛树脂混合使用,当甲醛捕捉剂的添加量为20%时,刨花板性能达标。 相似文献
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以市售刨花板和三聚氰胺浸渍纸为原料,制备三聚氰胺饰面刨花板.采用L9（34）正交试验考察热压温度、热压时间、热压压力3个热压工艺参数对三聚氰胺板甲醛释放量的影响.采用国家标准（GB/T 17657-1999）《人造板及饰面人造板理化性能试验方法》干燥器法检测甲醛的释放量.试验结果表明,热压温度对甲醛释放量影响最大、热压时间其次、热压压力影响最小,其中热压温度对甲醛释放量有显著影响,热压时间和热压压力的影响并不显著.热压工艺参数提高,会引起热压后的三聚氰胺板前期的甲醛释放量明显升高.确定饰面刨花板甲醛低释放的最优化生产工艺参数为热压温度170℃、热压时间40s、热压压力2.5 MPa. 相似文献
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简述刨花板中甲醛释放的机理及检测 总被引：4，自引：0，他引：4
甲醛是甲醛系胶粘剂板制品在使用过程散发的一种污染环境的有害气体。根据国内外资料分析了我国花板甲醛释放的现状，介绍了脲醛树脂的水解和刨花板甲醛释放的机理，评述了8种检测方法和降低花板中甲醛释放量的具体措施。 相似文献
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以兴安落叶松刨花和脲醛树脂胶黏剂为原料,采用正交试验法研究热压温度、热压时间、施胶量、密度工艺因子对刨花板甲醛和其他挥发性有机化合物释放量的影响.结果表明:热压温度、热压时间、施胶量和密度4个工艺因子对刨花板甲醛的释放及其他有机挥发物的释放均影响显著;提高热压温度、延长热压时间、降低板密度能显著降低甲醛及有机挥发物的释放量;综合考虑甲醛及其他有机挥发物释放量确定优化工艺因子为热压温度180℃,热压时间37.5 s·min-1,施胶量11%,密度0.6 g·cm-3,压制出的刨花板甲醛及其他有机挥发物释放量明显下降,满足GB 18580-2001的要求. 相似文献
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新型人造板防水剂的研究 总被引：6，自引：0，他引：6
一种呈超微细粉末状的新型人造板防水剂,适用于对刨花板、中纤板及其它非木质人造板的防水处理。试验表明,新型防水剂具有提高板材防水性能和强度,减少脲醛树脂游离甲醛含量,简化工艺,降低成本和运输贮存方便诸方面的优越性。 相似文献
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用不脱水低摩尔脲醛树脂制造低游离甲醛刨花板与中密度纤维板 总被引：2，自引：0，他引：2
试验结果表明差示扫描量热仪 (DSC)能够测得NLFS - 1型捕捉剂与甲醛反应 ,并且这种捕捉剂能够捕捉脲醛树脂胶中的大部分游离甲醛 ,其捕捉量与树脂的摩尔比或游离甲醛量有关。对于低摩尔比 ,不脱水脲醛树脂刨花板和中密度纤维板 ,仅用 5 %捕捉剂就能获得较高的捕捉能力。这些板的游离甲醛释放量均能达到欧洲E1级或国标GB -T11718- 1999A级标准。刨花板后期热处理 ,对板的内结合强度提高明显 ,但板的甲醛释放量略有增加 相似文献
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George I. Mantanis Eleftheria Th. Athanassiadou Marius C. Barbu Kris Wijnendaele 《Wood material science & engineering》2018,13(2):104-116
In this work, the adhesive systems used today in the European industries of particleboard, medium density fibreboard (MDF) and oriented strand board (OSB) are discussed. The structure of particleboard, MDF and OSB markets in Europe in relation to the types of adhesives and product specifications are presented as well. It is noticeable that new markets for wood-based panels like particleboard and fibreboard, known as non-furniture markets, are growing in Europe at a fast rate. It was concluded that most of the technological changes concerning the adhesive systems applied and additives have been realised from the need for niche panel products, the obligation to reach even lower formaldehyde emissions, and the necessity to decrease production costs due to the stringent competition in the market of wood-based panels. 相似文献
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本文对国际人造板工业的原料、环境保护问题的研究和开发,以及新技术的应用作了简要回顾,并对其社会背景及前提条件作了分析。其中特别是对于原料的开拓,提出了我国应如何吸取发达国家的经验的看法。 相似文献
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Preparation and properties of waste tea leaves particleboard 总被引：4，自引：0，他引：4
Shi Jin-shu Li Jian-zhang Fan Yong-ming Ma Hong-xia 《中国林学(英文版)》2006,8(1):41-45
Urea-formaldehyde (UF) adhesive is the main source of formaldehyde emission from UF-bonded boards. The components in waste tea leaves can react with formaldehyde to serve as a raw material in the production of low formaldehyde emission boards. In our study, waste tea leaves and UF adhesive were employed in the preparation of waste tea leaves particleboard (WTLB). An orthogonal experimental method was applied to investigate the effects of process parameters on formaldehyde emission and mechanical properties of WTLB. The results indicated that: 1) waste tea leaves had the ability to abate formaldehyde emission from boards; and 2) density of the WTLB was a significant factor affecting its modulus of rupture (MOR), modulus of elasticity (MOE) and internal bonding (IB). 相似文献
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采用傅里叶变换红外光谱技术对由废弃刨花板制备的再生刨花中已固化脲醛树脂的分布及其活性进行了研究。结果表明，已固化的脲醛树脂主要分布在细刨花中，中粗刨花中极少存在，已固化的脲醛树脂仍有活性基因存在，并有助于再生刨花的再胶合及降低再生刨花板中的游离甲醛释放量。 相似文献
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Physical and mechanical properties of medium density fiberboards (MDF) made from various mixtures of wood fibers and stone pine (Pinus pinea L.) cones were evaluated using European standards. MDF panels were manufactured using standardized procedures that simulated industrial production at the laboratory. Six panel types were made from mixtures of wood fiber/cone flour, 100/0, 90/10, 80/20, 70/30, 60/40, and 50/50 percents, respectively. Addition of the cone flour into the MDF significantly reduced formaldehyde emission from the panel. In addition, the addition of 10% cone flour also improved water resistance of the MDF panels made using urea–formaldehyde (UF) resin. However, further addition of the cone flour into the panel negatively influenced their water resistance. Flexural properties and internal bond strength decreased with the increase of cone flour content in the panel. The UF resin is the main source of formaldehyde emission from the UF-bonded wood-based panels. Depending on addition of the cone flour in the panels, the formaldehyde emission values ranged from 2.6% to 55.3% lower than the panels made from 100% wood fiber. Based on the findings obtained from this study, pine cone can be used as a renewable biological formaldehyde catcher as an alternative to the traditional formaldehyde catchers for E1 Class MDF manufacture. 相似文献
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采用1 m3气候箱法测试2种浸渍胶膜纸饰面人造板甲醛释放规律以及不同处理条件对板材甲醛释放浓度的影响。结果表明,热压工艺、基材结构可能是影响甲醛释放周期的关键因素,2种饰面人造板的平衡周期基本相同;封边处理可有效降低甲醛含量得释放;温度和相对湿度与板材甲醛释放量呈正相关,空气交换率与板材甲醛释放量呈负相关。 相似文献
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国外人造板甲醛散发研究现状 总被引：16，自引：0，他引：16
本文根据大量的国外文献资料综述了人造板中游离甲醛产生的原因、甲醛散发量的定量测试方法、影响甲醛向外界散发的诸种因素以及降低人造板甲醛散发量的各种措施。 相似文献
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随着薄木饰面板在家具、装修领域中的使用量越来越大,人造板的游离甲醛释放问题也愈发引起人们关注,现有的甲醛捕捉剂一般只能在短期内发挥效果,而对人造板甲醛的长期释放控制效果并不理想。为解决人造板甲醛释放的长期性问题,以尿素为芯材、乙基纤维素为壁材制备微囊型甲醛捕捉剂,探讨不同乳化剂及芯壁比制备的微囊型甲醛捕捉剂对饰面人造板甲醛控释效果的影响。结果表明,当乳化剂为十二烷基硫酸钠、芯壁比为3∶1,乳化剂用量1%、壁材质量分数3%、搅拌速度1000 r/min时,制备出的微胶囊芯材负载效果最好,负载量达到36.24%、负载效率为8.05%。采用该微胶囊以2%的质量比与脲醛树脂胶黏剂混配进行饰面板贴面热压时,得到的薄木贴面板的甲醛释放量相比未处理饰面板降低了37.9%。经过20 d后,微胶囊对其饰面板甲醛的释放仍表现出一定的控制效果,饰面板的甲醛释放量为0.99 mg/L,仅为未处理饰面板的56.9%。说明用微囊型甲醛捕捉剂对饰面人造板进行处理不仅能够对饰面板中的甲醛进行控释,而且在长期的放置、使用过程中也能够持续发挥作用,从而达到降低室内空气中甲醛浓度的目的。 相似文献
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We studied formaldehyde emission from uncoated particle-board with 16-mm thickness using the large chamber and the desiccator method. A chamber of 28.4 m 3 was installed to simulate a mobile home. The formaldehyde off-gassing properties of particleboard were evaluated using the chamber. The relationship between the concentration obtained by the chamber and the values by the desiccator test was discussed in this study under different conditions of conditioning day, air exchange, and loading ratio. These two methods were compared and discussed regarding the formaldehyde emission level. Three loading ratios, 0.429m2/m3 , 0.264m 2/m3 , and 0.132 m2/m3 , were chosen to represent different applications of particleboard products. There was strong correlation between emissions and air exchange rates at equal product-loading ratios in the large chamber, the related coefficient R2 exceeded 0.90. There was also an indication of a generic correlation between the large chamber and the two-hour desiccator test with a single product designated loading ratio, air exchange rate, and climatic conditions. 相似文献
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人造板中的甲醛释放及其检测方法 总被引：7，自引：1，他引：7
对人造板产品中的游离甲醛问题列出了近年来抽查检验的结果及其统计分析，介绍了甲醛释放机理和６种检测方法及降低人造板中游离甲醛的具体措施。 相似文献