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1.
The Butler iron meteorite has been found to have, with respect to other iron meteorites, an unusually high cobalt content (1.4 percent by weight), unusually high germanium contents in the kamacite and the taenite phases, and an unusually low cooling rate (0.5 degrees C/10(6) years). It is suggested that Butler formed in a different environment from that of the rest of the iron meteorites.  相似文献   

2.
300只AA肉仔鸡平均分成两组,一组为对照组,另一组为高钴负荷组(从5日龄起饮含钴80mg/L的水)。于5,30和45日龄每组随机抽取20只鸡,分别检测红细胞压积(PCV)、红细胞计数(RBC)、血红蛋白浓度(HB)、全血比粘度(BRV)和腹水心脏指数(AHI);45日龄时扑杀所有试验鸡,观察腹水综合征发生情况。结果为:(1)高钴负荷鸡在30和45日龄时其PCV,RBC和HB显著高于对照鸡(P<0.05);(2)30和45日龄时高钴负荷鸡的BRV极显著高于对照鸡(P<0.01);(3)30和45日龄时高钴负荷鸡的AHI显著大于对照鸡(P<0.05),45日龄时高钴负荷鸡的腹水检出率倍增于对照鸡。本试验表明高钴负荷可诱发肉仔鸡红细胞增生,进而使血液粘度升高,最终导致右心肥大-腹水综合征。  相似文献   

3.
Bis(3-fluorosalicylaldehyde) ethylenediimine cobalt(II), a reversible oxygen-carrying compound, has been crystallized as a tetramer with two oxygen molecules bound to the four cobalt atomns, each oxygen molecule bridging between two metal atoms. These dimers are further linked by two bonds between the oxygen atom of the salicylaldehyde and the cobalt atom. The oxygen-to-oxygen distance, 1.21 angstroms in molecular oxygen, has increased to 1.308(28) angstroms (where the number in parentheses is the estimated standard deviation) in this compound, the shortest distance yet observed in sutch a bridging arrangement.  相似文献   

4.
以3,5-二叔丁基水杨醛和(1R,2R)-环己二胺为原料,合成了(R,R)-N,N-二(3,5-二叔丁基水杨醛)-1,2环己二胺钴配合物(Salen-Co(Ⅱ)配合物),并以此作为化学修饰剂,利用直接混合法将化学修饰剂、粘合剂和石墨粉按一定比例研磨混合制作成西夫碱钴配合物修饰碳糊电极(Salen-Co/CPE).实验表明,该西夫碱钴配合物修饰碳糊电极对甲醛具有良好的电催化作用.利用计时电流法,在优化的实验条件下,氧化峰电流与甲醛的浓度在3.0×10-2~1.2×10-1mol/L的范围内具有良好的线性关系,检出限为3.33×10-3mol/L.  相似文献   

5.
偏最小二乘分光光度法同时测定茶叶中良量铁、钴和镍   总被引:1,自引:0,他引:1  
痕量Fe(Ⅱ)、Co(Ⅱ)和Ni(Ⅱ)与4-(2-吡啶偶氮)-间茶二酚(PAR)在pH=8.7时发生显色反应,其吸收光谱相互严重重叠。本用偏最小二乘法(PLS)分光光度法成功地同时测定了模拟试样及茶叶是痕量铁、钴和镍。结果表明,PLS法是化学计量学中一种可适用于基体较复杂的实际试样中痕量组分同时分光光度测定的优良的多元计算方法。  相似文献   

6.
A high-throughput protocol was developed for the synthesis of zeolitic imidazolate frameworks (ZIFs). Twenty-five different ZIF crystals were synthesized from only 9600 microreactions of either zinc(II)/cobalt(II) and imidazolate/imidazolate-type linkers. All of the ZIF structures have tetrahedral frameworks: 10 of which have two different links (heterolinks), 16 of which are previously unobserved compositions and structures, and 5 of which have topologies as yet unobserved in zeolites. Members of a selection of these ZIFs (termed ZIF-68, ZIF-69, and ZIF-70) have high thermal stability (up to 390 degrees C) and chemical stability in refluxing organic and aqueous media. Their frameworks have high porosity (with surface areas up to 1970 square meters per gram), and they exhibit unusual selectivity for CO2 capture from CO2/CO mixtures and extraordinary capacity for storing CO2: 1 liter of ZIF-69 can hold approximately 83 liters of CO2 at 273 kelvin under ambient pressure.  相似文献   

7.
硫、钴对补饲尿素山羊瘤胃消化代谢的影响   总被引:1,自引:0,他引:1  
用6只装有永久性瘤胃瘘管的本地空怀母山羊进行了三期试验。试验结果表明:基础日粮中添加硫或硫加钴均可提高瘤胃液PH,而只添加钴对PH无显著影响(P>0.05)。基础日粮中添加硫或钴,特别是钴,促进了瘤胃中氨的利用;增强了瘤胃中微生物合成蛋白质的能力。基础日粮中添加硫,降低了瘤胃中总挥发性脂肪酸(TVFA)的浓度,添加钴对总挥发性脂肪酸浓度无显著影响(P>0.05)。与T_1相比,T_2趋向于丙酸型发酵;T_3和T_4趋向于乙酸型发酵。四种日粮条件下,丁酸百分率无显著变化(P>0.05)。基础日粮中添加硫或钴均可提高瘤胃细菌蛋白的含量,而对瘤胃原虫蛋白含量无显著影响(P>0.05)。在山羊对尿素的利用方面,硫和钴对瘤胃内PH,氨氮浓度,三氯乙酸沉淀蛋白(TCA-P)含量,挥发性脂肪酸(VFA),细菌和原虫蛋白的影响无协同作用。  相似文献   

8.
选某牧场患有慢性钴缺乏病症状的羊120只(5~6月龄),随机分为4组,每组30只。采用3种方法对其进行治疗。结果表明:3种方法均可防治本牧场羊钴缺乏。口服硫酸钴对提高羊的生产性能(增重)效果最好;钴丸组对增强缺钴羊机体免疫力及其造血、糖代谢等生理功能上效果最佳;施钴肥的效果稍逊色于其他方法,但因其方便、实用,也可作为本牧场防治钴缺乏的一种方法。  相似文献   

9.
喷施硫酸钴对紫花苜蓿产量及微量元素吸收的影响   总被引:1,自引:0,他引:1  
[目的]研究苜蓿对钴的吸收利用规律及苜蓿体内微量元素之间的相互关系。[方法]在叶面喷施试验中,设喷施硫酸钴3个Co水平:100、300、600mg/kg,研究了不同施钴水平对紫花苜蓿干草产量和微量元素含量及积累量的影响。[结果]喷施硫酸钴可以显著提高苜蓿干草产量,其中施钴量为300mg/kg的处理效果最好,比对照CK(清水)提高27.53%。喷施硫酸钴可显著提高苜蓿钴和锌的含量,显著降低苜蓿硼、硒的含量,对苜蓿钼、铁、锰、铜含量没有显著的影响。喷施硫酸钴可显著提高苜蓿钴、硼、铁、锰、铜、锌等微量元素营养物质积累量,除钴积累量以施钴量为600mg/kg的处理最高外,其余元素积累量都以施钴量为300mg/kg的处理最高。喷施硫酸钴可显著降低苜蓿硒的积累量,对苜蓿钼积累量没有显著的影响。[结论]不同施钴水平对苜蓿体内微量元素的含量和微量元素营养物质的积累量影响不同。  相似文献   

10.
As diamond-producing catalysts, 12 transition metals such as iron, cobalt, and nickel were first reported by General Electric researchers more than 30 years ago. Since then, no additional elemental catalyst has been reported. An investigation of the catalytic action of group V elements is of great interest from the viewpoint of producing an n-type semiconducting diamond crystal. In the present study, diamond was synthesized from graphite in the presence of elemental phosphorus at high pressure and temperature (7.7 gigapascals and 1800 degrees C). Furthermore, single-crystal diamond was grown on a diamond seed crystal.  相似文献   

11.
As part of an ongoing research program to synthesize novel pillared layered materials, nickel and cobalt hydroxyacetates were inserted between the layers of amine intercalates of alpha-zirconium phosphate. The structure of the resultant nickel composite, derived from x-ray powder data, was found to consist of a three-tiered layer of nickel atoms bridged by hydroxo and acetato groups. Heating to 420 degrees C converted the hydroxyacetate layers to oxide and imparted ordered magnetic domains to the composite. The phosphate layers appear to act as a template directing the growth of the inserted layers in this class of composite materials.  相似文献   

12.
钴对泰和母鸡生殖内分泌活动的影响   总被引:2,自引:0,他引:2  
将80只泰和母鸡随机分成4组,每组20只,分别喂给含钴0.26mg/kg,5.26mg/kg,50.26mg/kg,100.26mg/kg的日粮4个月。试验期间用放射免疫法监测鸡血浆中促黄体生成素(LH)、雌二醇(E2)和孕酮(P)含量的变化情况。观察钴对E2,P分泌的直接影响。结果表明:日粮钴能引起血浆LH和P值升高,但随着钴在机体内的蓄积,高钴组P值显下降;日粮然对E2的影响较小。  相似文献   

13.
The ferrichrome content of cells of the smut fungus Ustilago sphaerogena during growth in a medium deficient in zinc increases with increase in the cobalt of the medium from 0 to 3 X 10(-5)M. The addition of zinc to such cultures prevents the accumulation of ferrichrome. The results suggest that zinc is involved in the utilization of iron via a process which can be blocked by cobalt.  相似文献   

14.
不同保鲜液对香石竹鲜切花保鲜效果的影响   总被引:2,自引:0,他引:2  
对保鲜剂及其浓度进行筛选,为香石竹切花保鲜提供依据.在室内条件下,选用蔗糖、硼酸和柠檬酸、6-BA分别与氯化钴、氯化钾、硝酸银、硫酸铝等离子化合物配制成不同的保鲜液,4种含不同无机盐的保鲜剂均能不同程度地增加鲜花的鲜重,其中以处理3(2%蔗+0.02%硝酸银 +柠檬酸300 mg·L-1+6-BA 25 mg·L-1+...  相似文献   

15.
钴对泰和鸡产蛋性能的影响   总被引:3,自引:0,他引:3  
80只泰和鸡随机分成4组,每组20只,分别喂给含钴0.26,5.26,50.26,100.26mg/kg的日粮4个月,观察鸡的体重、采食量、产蛋率、平均蛋重、蛋壳质量,试验末期检测鸡肝钴的含量。结果表明:日粮钴的本底含量(0.26mg/kg)即能满足泰和鸡的需要,添加5mg/kg钴有利于发挥泰和鸡的最佳产蛋性能;钴对鸡的体重、平均蛋重、蛋壳质量无显性影响;肝钴含量与日粮钴含量呈高度正相关。  相似文献   

16.
氯化钴在大菱鲆饲料中的安全性评价   总被引:1,自引:0,他引:1  
通过研究饲料中的氯化钴对大菱鲆幼鱼的存活、生长性能、血清生理生化指标、抗氧化酶活力、消化酶活力、血清和肝脏中VB12含量、肌肉和肝脏中钴的残留量、肝脏和肠道组织结构的影响来评估氯化钴在海水鱼饲料中的安全性。通过在基础饲料中添加氯化钴制剂来配制4种具有不同氯化钴含量(0、8、40及80 mg/kg,不计结晶水重量)的等氮等能的实验饲料,每个饲料处理设6个重复,每个重复养殖30尾大菱鲆;养殖实验为期10周。实验结果表明:饲料中添加氯化钴对试验鱼的存活没有显著影响(P0.05),但饲料中80 mg/kg的氯化钴显著降低了大菱鲆的特定生长率、终末体重、摄食率、肝体比和脏体比(P0.05);饲料中高剂量氯化钴(40和80 mg/kg)显著降低了大菱鲆血清过氧化氢酶、谷草转氨酶和碱性磷酸酶活力以及大菱鲆胃淀粉酶和胰蛋白酶活力(P0.05);大菱鲆的血糖含量、血清和肝脏中VB12含量、肝脏和肌肉中钴的残留量均随饲料中钴的添加量增加而显著升高(P0.05);饲料中添加氯化钴对大菱鲆的肠道组织结构没有产生明显影响,但饲料中添加40和80 mg/kg的氯化钴增宽了肝脏肝血窦。研究结果表明:实验条件下,氯化钴在大菱鲆饲料中的添加量8 mg/kg是安全的。  相似文献   

17.
Single two-dimensional (2D) atomically thick magnetic particles of cobalt and iron with variable size and shape were fabricated by combining a mask technique with standard molecular beam epitaxy. Reduction of the lateral size of in-plane magnetized 2D cobalt films down to about 100 nanometers did not essentially modify their magnetic properties; although the separation of boundaries decreased greatly, neither domain penetrated the particle, nor was any sizable shape anisotropy observed. The mutual interaction of 2D cobalt particles was negligible, and the magnetic state of a single particle could be switched without modifying the state of the neighbors. Perpendicularly magnetized iron particles did not exhibit such responses. These results suggest that only a few atoms forming a 2D in-plane magnetized dot may provide a stable elementary bit for nanorecording.  相似文献   

18.
本文研究了Co(Ⅱ)在氢氧化钠介质中催化过氧化氢氧化4,5-二溴邻硝基苯基荧光酮(DBON - PF)褪色的新指示反应及影响反应速度的因素,建立了测定痕量钴的催化动力学光度新方法.方法检出限为8.5 ×10-12g/mL,Co(Ⅱ)含量在0ng/10mL~3.2ng/10mL范围内符合比尔定律,是光度法测定钴的高灵敏体系之一,本法选择性好,灵敏度高,应用于VB12中钴的测定,相对标准偏差为2.8% ~3.4%,加标回收率为96% ~ 104%,符合痕量分析的要求.  相似文献   

19.
[目的]考察不同pH、重金属钻初始浓度、陈化时间和离子强度对土壤中钴化学形态分布和生物有效性的影响。[方法]采取经典Tessier连续提取技术。[结果]随着处理土壤pH的升高,有机物结合态含量呈下降趋势,两者间有极显著的负相关(相关系数=0.800~,P〈0.01),残渣态随pH升高呈上升趋势,生物有效性在pH5时达到最大值。在研究初始钴浓度范围内,随着外源钴浓度的浓度的增加,土壤中钴的碳酸盐结合态和可交换态所占总钴的比例减小,生物有效性系数(K)呈明显的递减趋势,当钴浓度大于250mg/L时,K递减趋势较大;土壤环境离子强度在O.01mol/L附近时,除残渣态外各形态钴在土壤中分布的比例达到最大值,当离子强度大于0.01mol/L时,生物有效性系数降低,限制了土壤中钴的迁移性。在考察陈化时间内,土壤陈化10d时,钴的生物有效性系数最大。[结论]各形态含量均随土壤介质pH、重金属钴初始浓度、陈化时间和离子强度有所变化,不同程度地影响着重金属钴在土壤中的富集状况。  相似文献   

20.
为使60Co辐照装置增加总活度为28878居里(1.07PBq)由7根活度不同的进口源棒的增源顺利启用,通过测定源到辐照位置的重复性为0.14%<1%,符合标准。测定从铁皮盖板到源中心的高度为90.3cm。五次升源所得剂量率(Gy/min)分别为:11.4、10.95、10.98、10.89、10.87,相对偏差为0.55%<1%.说明辐射场空间剂量率精确性高。计算辐照场空间分布的不均匀度U0=Dmax/Dmin=1.46(U0<1.5),表明在同一参考面上,辐射源剂量场剂量分布符合要求。  相似文献   

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