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1.
Adsorption of simazine (2-chloro-4,6-bisethyl-amino-1,3,5-triazine) was 2.2–4 times greater than that of terbacil (5-chloro-6-methyl-3-t-butyl-uracil) in the same soils and adsorption of both herbicides was 2–4 times greater in the topsoils than subsoils. Adsorption was inversely correlated with herbicide movement in a thick-layer chromatography system. One year after application of 3 kg/ha to field plots, simazine residues were highest near the soil surface, whereas terbacil residues increased with soil depth in the sandy and sandy loam soils. Total residues recovered from the upper 25 cm of soils was 5% or less of the simazine originally applied, and 10% or less of the applied terbacil. In an oat seedling bio-assay, the GR50 values were generally 1.5–3 times higher for simazine than for terbacil in the same soils. 相似文献
2.
Movement and persistence of imazaquin, oxyfluorfen, flurochloridone and terbacil in soil 总被引：2，自引：0，他引：2
The movement and persistence of imazaquin, oxyfluorfen, flurochloridone and terbacil residues were studied using a bioassay based on the shoot growth of Raphanus sativus L. var, radicula DC (radish) in a sandy loam soil under field conditions in 1992 and 1993. Imazaquin (0.3 kg a.i. ha-1) was more mobile in the soil than the other three compounds. In 1992, under heavy rainfall conditions, the herbicide was distributed down to 60 cm in amounts of about 0.01 mg kg-1. Conversely, in the dry year of 1993, the maximum depth of penetration was 20 cm and persistence in the surface soil layer (0-5 cm) was greater. After the first month in 1992, residues of terbacil were distributed in the 0-20 cm layer, and after 2, 3 and 5 months the herbicide had penetrated to a depth of 40 cm. In 1993, terbacil residues were distributed in the 0-10 cm layer only. In both years, residues of flurochloridone (1.0 kg a.i. ha-1) were located mainly in the 0-5 cm layer, but there was some penetration to 10 cm. Oxy-fluorfen (1.2 kg a.i, ha-1) showed least mobility in the soil profile. It was retained in the 0-5 cm layer throughout the experimental period in both. years. 相似文献
3.
Annual applications of the herbicides atrazine, simazine, linuron and diuron at 45 kg/ha were made to the same plots for 9 consecutive years from 1963 to 1971 in a peach (Prunus persica (L.) Batsch.) orchard located on sandy loam soil near Harrow, Ontario. Soil samples from these plots were collected in late October for the last 3 years (1969–1971) and trees were cut down in December, 1969. Herbicide residues were determined by bioassays based on the fresh and dry weight of oats (Avena sativa L.) and in one year results were confirmed by chemical analysis. Significant accumulation of herbicides was not observed. The maximum residue levels measured in October over the 3 years of sampling were 7′3 kg/ha for diuron, 3–8 kg/ha for linuron, 1–6 kg/ha for simazine and 04 kg/ha for atrazine in the top 15 cm of the soil profile. Simazine and atrazine showed a rapid decrease in amount after treatment but diuron and linuron were degraded more slowly. Measurable residues of all herbicides were confined to the upper 15 cm of the soil profile and the majority of herbicide remained in the 0–5-cm soil layer. Oats were planted in the orchard plots from 1972 to 1974 to follow the disappearance of the herbicides. All herbicides caused highly significant yield decreases in 1972, atrazine causing the least (38%) and diuron the greatest (86%) reductions. Diuron reduced the yield of oats in 1973 and caused a highly significant decrease in the weight of young oat plants in 1974. 相似文献
4.
Petri dish bioassays, based on root response of corn grown in soil or in perlite, were used to study the activity, adsorption,
mobility and field persistence of sulfosulfuron in a silty clay loam and a sandy loam soil. Both bioassays indicated that
activity of sulfosulfuron increased with increasing herbicide concentration, and to a slightly greater degree in sandy loam
soil than in silty clay loam soil. More sulfosulfuron was adsorbed on the sandy loam (not biologically available) than on
the silty clay loam soil. Consequently, slightly greater amounts of sulfosulfuron were leached through the silty clay loam
than through the sandy loam soil. Biologically available sulfosulfuron was not detected at depths below 40 cm after application
in sandy loam, but this was not the case for the silty clay loam soil. In 2002, all sulfosulfuron rates showed field persistence
of less than 5 months. On the other hand, in 2003, biologically available sulfosulfuron was detected in the 0–10-cm soil depth
150 days after application.
http://www.phytoparasitica.org posting May 6, 2004. 相似文献
5.
Laboratory studies on the formation of bound residues and on the degradation of the triazole fungicide propiconazole were conducted in two different soils. Soils treated with 14C-propiconazole were incubated at 22 degrees C and extracted exhaustively with a solvent at each sampling date until no further propiconazole was extracted. The solvent-extractable residues were used to measure propiconazole remaining in the soil, and the extracted soils were used to investigate bound residues of propiconazole. Mineralization of propiconazole was investigated by measuring [14C]carbon dioxide evolved from the soil samples. Formation of bound residues of propiconazole was higher in silty clay loam soil than in sandy loam soil, giving approximately 38 and 23% of the applied 14C, respectively. In contrast, the rates of degradation and mineralization of propiconazole were lower in silty clay loam soil than in sandy loam soil. Decreased extractability of the 14C residues with incubation time was observed with increased formation of bound residues. When the propiconazole remaining in the solvent-extractable residues was quantitatively measured by high-pressure liquid chromatographic analysis, the half-life value in sandy loam soil was about 315 days, while the half-life in silty clay loam soil exceeded the duration of the 1 year experimental period. Increased formation of bound residues was observed as propiconazole degraded with incubation time, suggesting that degradation products are involved in the formation of bound residues. Our study suggests that the formation of bound residues of propiconazole contributes to the persistence of this fungicide in soil. 相似文献
6.
Imazathabenz-methyl dissipated rapidly in sandy and sandy loam field soils in Nova Scotia. Canada, seeded to wheat ( Triticum aestivam L.).The time to 50% loss of herbicide residues in the 0-10 cm soil zone was about 3-4 weeks after October applications and about 2.5 weeks after June ones. After October applications, there was further loss of >60% of the remaining parent herbicide during the winter and early spring despite periods of prolonged snow cover and freezing, or near freezing, soil temperatures. After October applications, imazamethabenz-methyl residues in May-collected samples from the 10-20 and 20-30 cm soil zones ranged from 40% to 80% and from 15% to 40%, respectively of those extracted from the 0-10 cm zone over four sites. Precipitation in the month after October applications ranged from 105 to 180 mm. which suggests leaching may play an important role in dissipation at times of the year when precipitation greatly exceeds evapotranspiration. Levels of the phytoioxic free acid ranged from 15% to 35% of the parent herbicide in selected samples. These residues had no effect on spring wheat replacement crops. The effect of the herbicide on replacement crops may also be influenced by the soil pH. A laboratory study demonstrated that as soil pH increased from 4.1 to 6.5. degradation of imazamethabenz-methyl increased with a corresponding increase in free acid formation. 相似文献
7.
The effect of irrigation time on the dispersion of 1,2-dibromo-3-chloroproparie (DBCP) in soil after a shallow injection treatment was determined for Yolo fine sandy loam. When injections equivalent to 23.5 litres of DBCP/ha at a depth of 7 to 8 cm were subsequently followed by 15 cm of irrigation water, adequate distribution of DBCP was obtained if the soil was irrigated within 5 days. However, the most rapid and deepest penetration of fumigant was obtained by irrigating 2 to 5 days after application. There was insufficient downward movement of DBCP in non-irrigated soil. 相似文献
8.
E. E. SCHWEIZER 《Weed Research》1976,16(1):37-42
Persistence of ethofumesate [(±)2-ethoxy-2.3-dihydro-3,3-dimethylbenzofuran-5-yl-methansulphonate] in soil was associated with soil temperature. Ethofumesate applied at 4.5 kg/ha in November persisted about twice as long in soil as that applied the following March. In another field study, 88–91% of the herbicide had dissipated after 24 weeks in sandy loam soil, compared to 72–77% in loam soil when it was applied at rates of 2.2, 3.4, 4.5, and 9.0 kg/ha. The rate of degradation was independent of the initial rate of chemical applied. The time required for 50% of the herbicide to dissipate in sandy loam and loam soils was 7.7 and 12.6 weeks, respectively. The movement of ethofumesate in these two soils over a 24-weeks sampling period was confined mainly to the upper 7.5 cm of the soil profile. 相似文献
9.
Although glyphosate (N‐(phosphonomethyl)glycine) is one of the most frequently used herbicides, few controlled transport experiments in undisturbed soils have been carried out to date. The aim of this work was to study the influence of the sorption coefficient, soil‐glyphosate contact time, pH, phosphorus concentration and colloid‐facilitated transport on the transport of [14C]glyphosate in undisturbed top‐soil columns (20 cm height × 20 cm diameter) of a sandy loam soil and a sandy soil. Batch sorption experiments showed strong Freundlich‐type sorption to both soil materials. The mobility of glyphosate in the soil columns was strongly governed by macropore flow. Consequently, amounts of glyphosate leached from the macroporous sandy loam soil were 50–150 times larger than from the sandy soil. Leaching rates from the sandy soil were not affected by soil‐glyphosate contact time, whereas a contact time of 96 h strongly reduced the leaching rates from the sandy loam soil. The role of pH and phosphorus concentration in solution was relatively unimportant with respect to total glyphosate leaching. The contribution of colloid‐facilitated transport was <1 to 27% for the sandy loam and <1 to 52% for the sandy soil, depending on soil treatment. The risk for glyphosate leaching from the top‐soils seems to be limited to conditions where pronounced macropore flow occurs shortly after application. © 2000 Society of Chemical Industry 相似文献
10.
A. RAHMAN 《Weed Research》1977,17(2):145-152
Soil samples were collected from forty-three field trials conducted on ten soil types to investigate the residual activity of terbacil and trifluralin at the end of the cropping season, approximately 6 months after application. The soil was bioassayed in a glasshouse using soya beans and German millet for terbacil and trifluralin respectively. At 1 kg/ha terbacil phytotoxic residues occurred in a majority of the trials, while at 2 kg/ha such a carry-over could be found in every case. Trifluralin doses of up to 1 kg/ha did not persist in toxic amounts in most soils, while application of 2 kg/ha showed residual activity in 74% of the trials and application of 4 kg/ha killed German millet in all instances. Results are also presented from the time-rate dissipation studies conducted on both herbicides by assaying soil samples collected at monthly intervals. Both organic matter and clay content of the trial sites affected the persistence of terbacil, while trifluralin residues were influenced only by the soil organic matter content. Trial sites receiving high rainfall showed considerably less residues of terbacil, but the persistence of trifluralin was not affected by rainfall to any appreciable extent. 相似文献
11.
E.D. WILLIAMS 《Weed Research》1979,19(1):25-32
Soil core samples taken from a sandy loam soil at Woburn during January 1972, following spring beans during the previous year, indicated that half the rhizome dry weight of Equisetum arvense (L.) occurred in the uppermost 25 cm of soil and 10% between 75 and 100 cm. Tubers occurred relatively more deeply with half the number and three-quarters of the weight deeper than 50 cm. However, after a 2-year fallow 80% of the rhizomes and tubers were in the uppermost 25 cm of soil. In general, the weight of individual tubers increased with increasing depth in the soil. In pots in the glasshouse, tubers that were formed in one season lost weight when new shoots emerged in the following year; those formed during summer germinated readily in warmth indoors when detached in the autumn, but not until June of the following year in the field. Burial of tubers at a range of depths down to 25 cm did not affect the number of shoots emerging but emergence was delayed. Plants made more growth in neutral than in acid or basic soil, more in silty clay loam than in sandy loam and appeared well adapted to growth in soils with little nitrogen. In general, rhizome growth was less affected by variations in pH and nitrogen level than were shoots and tubers. Plants grown from tubers were suppressed greatly by wheat sown densely and given a moderate amount of nitrogen fertilizer but had negligible effect on the wheat. With fewer wheat plants given less nitrogen, the species partitioned more of its assimilate into tubers than when it was grown alone. The significance of tubers in the biology of the species is briefly discussed and areas meriting further study are highlighted. 相似文献
12.
Sulcotrione soil persistence in spring maize ( Zea mays L.) crops grown on a sandy loam soil was greater at pH 5·5 and 6·0 (soil half-life T 1/2 ≈58 days) than at pH 7·1 ( T 1/2 = 44 days). Sulcotrione was also applied as recommended on a summer maize crop at the five- to six-leaf growth stage, grown on a sandy loam soil. Sulcotrione soil half-life was 44 days, and the herbicide remained mainly in the 0- to 5-cm surface soil layer during the cropping period, in spite of the high water solubility and the heavy rains at the end of August; lower sulcotrione concentrations (10–18% of the total during the 2-month period after sulcotrione application) were detected in the 5- to 10-cm surface soil layer. The herbicide was applied pre-emergence to winter wheat ( Triticum aestivum L.) at four sites that differed in their soil texture and composition: loamy sand, sandy loam, loam and clay loam. Persistence was greater in the soils containing more organic matter. In soils having similar organic matter contents, persistence was lower in the soil containing more sand relative to loam and clay. During the winter crops, sulcotrione moved down to the 10- to 15-cm soil layer, in spite of the fact that the rains were lower in winter than in summer. Sulcotrione most generally was not detected in the 15–20 cm soil layer of the maize and winter wheat crops. 相似文献
13.
With the scheduled phasing out of methyl bromide, there is an urgent need for alternatives. We evaluated the efficacy of propargyl bromide as a potential replacement for methyl bromide for the control of barnyardgrass (Echinochloa crus-galli) and Fusarium oxysporum in an Arlington sandy loam, a Carsitas loamy sand and a Florida muck soil. Soil was mixed with barnyardgrass seeds or F oxysporum colonized on millet seeds, and treated with propargyl bromide at a range of concentrations. The mortality of the fungi and weed seeds was determined after 24 h of exposure at 30 degrees C. The concentrations required to inhibit 50% barnyard seed germination (LC50) were 2.8, 2.4 and 48.5 micrograms g-1 in the sandy loam, loamy sand and muck soil, respectively. In contrast, the LC50 values for F oxysporum were 11.2, 10.8 and 182.1 micrograms g-1 in the sandy loam, loamy sand and muck soil, respectively. The low efficacy of propargyl bromide in the muck soil was a result of the rapid degradation and high adsorption of the compound in the soil. The degradation half-life (t1/2) was only 7 h in the muck soil at an initial concentration of 6.8 micrograms g-1, compared to 60 and 67 h in the sandy loam and loamy sand, respectively. The adsorption coefficients (Kd) were 0.96, 0.87 and 5.6 cm3 g-1 in the sandy loam, loamy sand and muck soil, respectively. These results suggest that registration agencies should consider site-specific properties in recommending application rates for propargyl bromide. 相似文献
14.
A glass-lined trough was divided into six compartments by vertical transverse partitions and filled with soil to a height of 5 cm above the top of each partition. The base of the box and the surface of the soil sloped forwards one end with a gradient of 1 in 3·7. Dieldrin was applied (22 kg active ingredient/ha) to the soil surface in the uppermost compartment and the movement of dieldrin into leachate and down the slope was followed for 17 weeks. During this time 19·5 cm of rain fell. Less than 0·02% of the dieldrin appeared in the leachate and 99% of this was collected during the first 9 weeks, mainly from the uppermost compartment. Very little dieldrin moved down the slope and it was not detected in the leachate from compartments other than the treated one during 9–17 weeks after treatment. In other experiments, 3 cylinders were filled respectively with sandy loam, heavy clay loam and peat which were transferred from the field as intact cores. Three other cylinders were filled with soils of the same types but broken up. Approximately 2% of the dieldrin leached through one column but usually it was much less than 0·1%. The largest amounts of dieldrin were leached down columns of heavy clay loam, intermediate amounts down columns of peat, and least through sandy loam. Ten times as much dieldrin leached down the columns of intact soil as through those with broken soil. The results indicate that the movement of dieldrin from treated soil into water systems by leaching is limited and is unlikely to be a major pathway for the contamination of water. 相似文献
15.
采用土柱淋溶法和气相色谱法研究了3种拟除虫菊酯类农药三氟氯氰菊酯、联苯菊酯和高效氯氰菊酯在热带地区主要土壤类型砂土和壤土中的淋溶特性。结果表明:3种拟除虫菊酯类农药在砂土和壤土中主要残留于第1段土壤 (0～5 cm) 中,且驻留量随土壤深度增大而减少。三氟氯氰菊酯、高效氯氰菊酯和联苯菊酯在砂土中的Ri值分别为52.86%、94.73%和83.19%,在壤土中的Ri值分别为54.70%、77.28%和55.33%,均大于50%。根据农药在土壤中的淋溶性等级划分标准,3种药剂均属于难淋溶农药,不易对地下水造成污染。本研究结果可为热带地区土壤和地下水中农药污染修复提供参考。 相似文献
16.
基于HYDRUS-1D的不同质地土壤入渗过程数值模拟 总被引：1，自引：0，他引：1
基于HYDRUS-1D软件,对不同土质(淤泥、粉砂壤土、砂质粘壤土)的灌溉方案进行了系统的数值实验,模拟灌溉结束时及灌溉结束24 h之后的土壤剖面含水量和土壤湿润锋的变化情况。结果表明:在不产生径流的情况下,灌溉结束24 h后土壤的含水量分布和湿润深度只与土壤种类和灌溉量有关,与灌溉速度无关;对透水性较好的土质,灌溉水分重分布明显,以粉砂壤土灌溉速率0.7 cm·h~(-1)和灌溉时间3 h为例,灌溉结束时和灌溉24 h后土壤湿润深度分别为9.2 cm和20.6 cm,有55.3%的灌溉水参加了水分重分布;土壤湿润深度与灌溉量之间存在线性关系,拟合直线的斜率介于5.15(淤泥)和5.95(砂质黏壤土)之间。 相似文献
17.
Philip公式确定吸渗率时间尺度研究 总被引：4，自引：0，他引：4
选用直径5 cm和10 cm的盘式吸渗仪,对杨凌土(粘土 )和神木砂黄土(砂壤土)两种质地的土壤在1 cm、3 cm、6 cm、9 cm和12 cm水头5种负压下进行了室内盘式吸渗仪三维吸渗实验,选取Vandervaere公式作为参考模型,对Philip 公式确定吸渗率的时间尺度选取进行了分析.结果表明,对两种质地的土壤,在相同盘径下 ,随着负压的降低,吸渗率随之减小;在相同负压下,盘径越小,吸渗率越大;质地较砂的砂黄土吸渗率明显大于质地较粘的土的吸渗率.从相对误差来看,两种质地土壤吸渗率均被高估;在同一盘径下,随着负压的减小,误差值逐渐降低;即在选取的时间范围内,负压越低,计算吸渗率的准确性越高.对土而言,5 cm盘径下-12 cm水头、10 cm盘径下-9 cm水头和-12 cm水头时确定吸渗率的适宜时间分别为30～40 s和40～50 s;其余确定吸渗率的适宜时间均应小于30 s ;对砂黄土而言,10 cm盘径下-9 cm水头和-12 cm水头时确定吸渗率的适宜时间分别为30～ 40 s和40～50 s,其余确定吸渗率的适宜时间也均应小于30 s.对于质地较砂的土壤推荐使用大盘径进行盘式吸渗仪实验. 相似文献
18.
红麻根结线虫在病田中的分布与消长动态 总被引：1，自引：0，他引：1
研究结果,红麻根结线虫二龄侵染幼虫主要分布在0-40cm土层内;砂壤土中的线虫量比黄壤土中的大,分布亦较深,前者可在80cm以下,而后者只在60cm以上土层。在冬闲季,卵和侵染幼虫主要群集在病残上;根际土中的越冬幼虫比根际外土中的多2倍以上。侵染幼虫量的波动在红麻生长季节有4个高峰,收获后还出现一个高峰。用免疫或高抗作物换茬轮作一年,病原线虫群体密度即大幅度下降。文中对该病防治理论基础作了讨论。 相似文献
19.
Appearance of Florida wax scale (FWS) crawlers in citrus groves planted in sandy soil preceded that in groves planted in loam.
The duration of crawler presence was longer on citrus in loam than in sandy soil. Mean age, as expressed by weighted developmental
stage, yielded a linear regression with time. FWS develops two generations per year, which on sandy soil appear earlier and
develop faster to the preovipositional stage than on loam. The size of ovipositing females was in direct correlation with
the duration of development. 相似文献
20.
The soil type is a key factor influencing N(nitrogen) cycling in soil; however, gross N transformations and N_2O emission sources are still poorly understood. In this study, a laboratory ~(15)N tracing experiment was carried out at 60% WHC(water holding capacity) and 25℃ to evaluate the gross N transformation rates and N_2O emission pathways in sandy loam and silt loam soils in a semi-arid region of Heilongjiang Province, China. The results showed that the gross rates of N mineralization, immobilization, and nitrification were 3.60, 1.90, and 5.63 mg N/(kg·d) in silt loam soil, respectively, which were 3.62, 4.26, and 3.13 times those in sandy loam soil, respectively. The ratios of the gross nitrification rate to the ammonium immobilization rate(n/ia) in sandy loam soil and silt loam soil were all higher than 1.00, whereas the n/ia in sandy loam soil(4.36) was significantly higher than that in silt loam soil(3.08). This result indicated that the ability of sandy loam soil to release and conserve the available N was relatively poor in comparison with silt loam soil, and the relatively strong nitrification rate compared to the immobilization rate may lead to N loss through NO_3~– leaching. Under aerobic conditions, both nitrification and denitrification made contributions to N_2O emissions. Nitrification was the dominant pathway leading to N_2O production in soils and was responsible for 82.0% of the total emitted N_2O in sandy loam soil, which was significantly higher than that in silt loam soil(71.7%). However, the average contribution of denitrification to total N_2O production in sandy loam soil was 17.9%, which was significantly lower than that in silt loam soil(28.3%). These results are valuable for developing reasonable fertilization management and proposing effective greenhouse gas mitigation strategies in different soil types in semiarid regions. 相似文献