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1.
采用酸性大红GR染料和BL-阻燃剂同步处理杨木单板,通过改变浸渍温度、BL-阻燃剂浓度、酸性大红GR染液浓度等工艺参数,分析酸性染料和阻燃剂同步处理对杨木单板性能的影响。结果表明:BL-阻燃剂的添加明显提高了单板的上染率,且BL-阻燃剂浓度为10%时上染率最大为23.97%,氧指数和色差随BL-阻燃剂浓度的增加而增大,最大值分别达到46.3%和72.346;随着酸性大红GR染液浓度的增加,单板上染率在浓度为0.1%时达到峰值,而氧指数呈减小趋势,色差逐渐增大再减小;浸渍温度对单板性能影响显著,单板上染率、氧指数和色差随温度升高均增大,80℃最大值分别是34.18%、42.7%和73.257。  相似文献   

2.
以气干椴木和BL-环保型阻燃剂为原料,采用轴向真空处理设备对椴木进行阻燃处理,研究不同的轴向真空阻燃处理工艺因素对椴木阻燃效果的影响,分析得出处理时间、前真空时间、阻燃剂溶液浓度对椴木的载药量、氧指数的影响。结果表明:阻燃材的载药量和氧指数随处理时间增长而增大,随前真空时间及阻燃剂溶液浓度的增加呈先增加再减小的趋势;沿椴木长度方向,试样的氧指数先减小再增大。  相似文献   

3.
以三层实木复合地板为对象,探讨阻燃剂对其生产工艺的影响,结果表明:芯板、背板浸渍阻燃剂时,单板的增重率随着浸渍时间的延长而增加,当浸渍时间超过30 min后,增重率增加不明显;随着阻燃剂施加量增加氧指数增大,含水率、静曲强度随着施加量增加而降低;含水率、静曲强度、甲醛释放量和氧指数随着涂胶量的增加而增大;热压温度和热压时间对含水率、静曲强度、甲醛释放量和氧指数影响不明显。最佳热压工艺条件为:阻燃剂施加量8%,涂胶量360g·m-2,热压温度120℃,热压时间12 min。  相似文献   

4.
选用3种自制阻燃剂浸渍思茅松单板,通过测试胶合板的胶合强度、氧指数和烟密度,分析阻燃剂对胶合板的胶合强度和燃烧性能的影响.研究结果表明:工业制备阻燃胶合板的胶合强度、氧指数、烟密度等级满足国家标准GB/T 17657和GB 8624-2006的要求,说明工业生产阻燃胶合板是可行的.与对照试件相比较,阻燃胶合板的氧指数提高了75.8%~149.8%、烟密度等级降低了15.4%~60.5%、胶合强度降低了43.9% ~ 56.1%;其中阻燃剂FR-B对胶合板氧指数影响最大,阻燃剂FR-A对胶合板的烟密度影响最大,阻燃剂FR-C对胶合板的胶合强度影响最小.  相似文献   

5.
采用亚麻屑为原料,利用脉酸胶和阻燃剂热压制成阻燃亚麻屑板。试验结果表明:根据亚麻屑原料的形态和特性,可采用粉状阻燃剂直接与子亚麻屑混合的添加工艺。当阻燃剂加量为15%时,阻燃板物理力学性能指标均达到国家标准。阻燃性能:氧指数达到43%。  相似文献   

6.
阻燃中密度纤维板阻燃特性的研究   总被引:2,自引:0,他引:2  
利用扫描电镜、氧指数测试仪、热重分析仪等仪器对采用了BL阻燃剂的中密度纤维板进行阻燃性能分析。结果表明:BL阻燃剂具有阻燃效果好、抑烟性、使用方便等优点,是一种优良的氮磷系膨胀型阻燃剂。压制的中密度纤维板,阻燃剂能均匀分布在纤维之间,燃烧时能促使纤维炭化,有效抑制燃烧。纤维板物理力学性能满足中密度纤维板优等品要求,阻燃效果明显,重量损失率低,燃烧失重率在7%以下,氧指数达到了难燃级48%的要求。  相似文献   

7.
阻燃剂WFRJ1改性木材的体积稳定性和涂饰性能   总被引:3,自引:0,他引:3  
用阻燃剂WFRJ1处理大青杨木材并对处理材的阻燃性能、涂饰性能和体积稳定性进行测定。结果表明:WFRJ1可用于木制品的阻燃处理。当WFRJ1浓度为10%时,氧指数可达到50%以上,与水溶性RF树脂复配,可大幅度提高处理材的抗胀缩率和阻湿率,增加体积稳定性。经WFRJ1处理后杨木单板的涂饰性能未受影响。  相似文献   

8.
阻燃亚麻屑板的研制   总被引:1,自引:0,他引:1  
林利民  米忠明 《林业科技》1997,22(4):50-52,54
以粉状无机盐类为阻燃剂,采用阻燃剂直接与亚麻屑混合拌胶施加工艺,通过阻燃剂的选择,配制,制板等工艺研究,开发出阻燃亚麻屑板。阻燃剂加量为15%,氧指数可达37%,这种阻燃剂对亚麻屑板的物理力学性能影响较小。  相似文献   

9.
主要利用碎单板压制阻燃杨木单板条层积材,研究了P-N阻燃剂与酚醛树脂胶相容性及合适的热压工艺。实验结果表明:当P-N阻燃剂pH值调至10~11,阻燃剂用量为15%时,阻燃剂与胶粘剂相容性较好,随着阻燃剂用量增大,试件氧指数不断增大,内结合强度逐渐降低。较优的热压工艺为热压温度190℃,热压时间90 s/mm。  相似文献   

10.
选用聚磷酸氢铵(APP)、磷酸二氢氨盐(MAP)及硼酸与硼砂合剂(SBX)3种阻燃剂,采用常压浸渍法处理竹片,通过氧指数、锥形量热法考察了3种阻燃剂对竹片阻燃性能的影响,并研究了阻燃竹片的涂饰性能及阻燃剂的流失行为。结果表明,3种阻燃剂均可提高竹片的极限氧指数,MAP处理竹片的极限氧指数最高;正交试验得出优选浸渍工艺为:20%阻燃剂浓度、40℃浸渍温度和0.5 h浸渍时间。锥形量热测试结果表明,3种阻燃剂均能有效降低热释放速率、热释放总量,并抑制发烟,SBX处理竹材的综合性能最佳。涂饰性测试表明,SBX阻燃剂不影响竹片表面的漆膜附着力,而APP和MAP阻燃处理使竹片表面漆膜附着力显著下降。流失性测试表明3种阻燃剂抗流失性较差,SBX处理竹片相对较好,14 d流失率为53%。  相似文献   

11.
阻燃刨花板阻燃剂的研制   总被引:4,自引:0,他引:4  
以氨基树脂为载体,磷-氮系阻燃液与固体无机耐火剂所构成的刨花板用阻燃体系,采用阻燃剂与刨花直接混合的添加工艺,不会造成阻燃剂的浪费,不污染环境。所生产的阻燃刨花板主要物理力学性能达到国家标准。阻燃性能:氧指数40%~50%.1000℃火焰穿透时间15~25分钟,发烟等级为一级。对人低毒。  相似文献   

12.
赵殊  方堃 《林业研究》1995,6(1):76-80
INTRoDUCTIoNThechemicalscommonlyusedforflameretardantstowoodincludeammoniumphosphate,phosphoricacid,boricacid,borax,hydratedalumna,am-moniasulfate,zincchlorideandmagne--siumcNoridetl'2j.Thesechemicalsareimpregnatedasaqueoussolutionsintothewoodwheretheyaredepositedwithintheporesandcapillariesofthewoodwhenthesolutionevaporates.Butthesechemicalsarenotsuitableforexteriorandunder-groundconstructionwheretheflameretardantsareleachedeasily[3:.Nowanimportantdevelopmentorientationofstudyingonflamere…  相似文献   

13.
The use of multifunctional wood for decorative purpose has grown increasingly popular in recent years. In this study, fast-growing poplar wood was treated with dye (0.5%) and flame retardant (0, 10, 20, and 30%) simultaneously to enhance its visual characteristic and safety. The dynamic wettability and surface free energy of wood samples were studied using S-D wetting model and van Oss–Chaudhury–Good (vOCG) method, respectively. Dye uptake, drug load, color difference, and combustion performance were determined. The treated wood was also characterized by infrared spectroscopy, scanning electron microscopy, and energy-dispersive X-ray spectroscopy. The results indicated that the proposed treatment yields favorable adhesive spreading and penetration ability at the wood surface. The surface free energy of treated wood was higher than that of untreated wood, and the dye uptake, drug load, color difference, and limited oxygen index all increased after the proposed combination treatment compared to dye-only treated wood. The results also indicated that the flame retardant reacted chemically with the wood as the dye and flame retardant molecules diffused into the cell cavity, wood vessel, and aperture.  相似文献   

14.
木材结构特性对氧指数的影响   总被引:2,自引:0,他引:2  
采用氧九法对4种树种木材、5种阻燃物质燃烧特性的研究发现,未阻燃木材的氧指数在纵横向上有差异性,纵向高于横向,径弦向差异很小。这主要是木材结构各向异性以及各方向上的导热系数不同所致。木材树种不同氧指数也有差异,原因之一密度不同所致。阻燃处理可使方向上的的差异逆转,即横向高于纵向。同一阻燃物质对不同树种木才的作用效果不同,即树料与阻燃物质之间存在适应性问题。树种铎氧指数有很大影响。  相似文献   

15.
王齐  唐伟  杨玲  周志芳 《林业科技》2012,37(6):28-30
在研制木质碎料与聚苯乙烯颗粒复合保温板工艺中,施加FRW阻燃剂,用以提高复合保温板的阻燃性能。试验结果表明,在施加10%~20%的范围内,阻燃剂对复合保温板的导热系统、抗压强度和氧指数影响显著,对线性收缩率影响不显著。  相似文献   

16.
To enhance dimensional stability and biological properties, low molecular weight phenolic resins of a conventional alkaline type and neutralized type were impregnated into Japanese cedar wood (Cryptomeria japonica D. Don) and heat-cured. The treatment with the neutralized type resin retained the original wood color, whereas the alkaline treatment changed the color of wood to red-brown. The concentrations of the resin solutions and the weight gains due to the resin loading of wood after treatment were highly correlated, and the target resin loading could be assessed from the solution concentration. A high dimensional stability of 60% antiswelling efficiency was attained when both types of resins were impregnated at about 30% resin loading and no significant difference was recognized between the two. To suppress decay attack from brown-rot and white-rot fungi, 15% and 10% resin loading due to treatment was required for the neutralized and alkaline types of phenolic resins, respectively. The penetration of resin into wood cell walls was investigated by means of light microscopy, Scanning Electron Microscopy (SEM), and Electron Probe X-ray Microanalysis (EPMA). A m-Bromophenol-formaldehyde resin of three levels of an average molecular weight was used to detect the presence of resin by bromine signals. The phenolic resins with low and medium molecular weights (290 and 470) were shown to penetrate into the cell walls the furthest, thereby contributing to the enhancement of dimensional stability and decay resistance in the resin-impregnated wood. Also, for phenolic resin with a high molecular weight (820), only the resin components of low molecular weight appeared to be present in the walls, making very little contribution to the dimensional stability.  相似文献   

17.
一剂多效是木材阻燃剂的主要发展方向。文中分别对常用的木材功能化阻燃剂和阻燃处理工艺的国内外研究进展进行了综述,包括磷氮硼阻燃剂、金属化合物阻燃剂、树脂阻燃剂、纳米阻燃剂和微胶囊阻燃剂及新型浸渍法、表面改性法和溶胶-凝胶法等阻燃处理工艺,讨论了木材阻燃研究的发展趋势。  相似文献   

18.
We improved the overall performance of fast-growing poplar by utilizing a low-cost, effective and simple method. The fast-growing poplar was modified by a vacuum-pressure impregnation method with three...  相似文献   

19.
考察了三乙醇胺(TEM)对3种木材阻燃剂(F1、F2、DPB)处理试件的载药率、阻燃效果、吸湿性的影响。试验结果表明:随三乙醇胺加入量的增加,阻燃试件的载药率增加,氧指数增加,阻燃效果得到改善;三乙醇胺加入量大于3.5%时,处理液的黏度增加,载药率增加不明显;加入2.5%~3.5%的三乙醇胺时,处理试件的吸湿率最小。同时实验还显示了在3种木材阻燃剂中加入三乙醇胺后,只有F2与三乙醇胺有协同效应,其它两种阻燃剂协同效应不明显。  相似文献   

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