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1.
The clay mineralogy of 22 samples of the Ap horizons of Ando soils was determined by a combination of methods. Of these samples, 15 did and 7 did not contain allophane and imogolite. Opaline silica was found in 4 samples, whereas aluminum—humus complexes, iron oxides and layer silicates were found in all samples. The presence of allophane and imogolite and the absence of opaline silica in a few Ap horizons was related to mixing of A1 horizons and subsoils by cultivation and to lower supplies of organic matter relative to the amounts of aluminum released from volcanic ash by weathering. The contents of 2:1 and 2:1:1 layer silicates and their intergrades were larger in soils in which quartz predominated in fine fractions. It was inferred that aluminum bound with humus and in allophane-like constituents, rather than aluminum in allophane and imogolite, is important in reactions with phosphate and fluoride.  相似文献   

2.
Thirty-three samples of Ando soils were extracted by sodium pyrophosphate (O.IM; pH 10) and by dithionite-citrate. The Al, Fe, and C contents of these two extracts offer a means of differentiating the status of humus in relation to Al and Fe in the different horizons. The humus that forms at first in the Al horizon has a very low complexing ability for Al and Fe and little is dissolved by pyrophosphate. The humus evolves with time or pedogenesis into forms that complex Al and Fe released from volcanic ash by weathering, and which are dissolved by pyrophosphate. In the old horizons, the humus further reacts with additional Al and Fe, some of which may be present as hydrous oxides or allophane-like constituents, allophane and imogolite. This reaction probably makes the humus less soluble in pyrophosphate.  相似文献   

3.
Eight samples of Ando soil A1 and buried A1 horizons of different ages were fractionated into clay-, silt-, and sand-size separates, and the yields and carbon contents of these separates were determined. The clay-size separates were subjected to two series of successive extractions, 1) 0.1 M Na4 P2 O7/2% Na2 CO3/0.5 M NaOH and 2) dithionite-citrate/2% Na2 CO3/0.5 M NaOH; and to difference infra-red spectroscopy for identification of the extracted constituents. The result indicated that humus evolves from forms with a very low complexing ability for Al and Fe into forms that complex Al and Fe in the A1 horizon, and that humus further interacts with allophane-like constituents, allophane and imogolite in the buried A1 horizon. These reactions between humus and inorganic constituents result in formation of silt- and sand-size aggregates which are stable to sonic wave treatment, but are broken down into finer particles upon boiling with H2 O2.  相似文献   

4.
Two field experiments in which straw has been removed or incorporated for 17 yr (loamy sand) and 10 yr (sandy clay loam) were sampled to examine the effect of straw on the C and N contents in whole soil samples, macro-aggregate fractions and primary particle-size separates. The particle size composition of the aggregate fractions was determined. Aggregates were isolated by dry sieving. Straw incorporation increased the number of 1–20 mm aggregates in the loamy sand but no effect was noted in the sandy clay loam. Straw had no effect on the particle size composition of the various aggregate fractions. After correction for loose sand that accumulated in the aggregate fractions during dry sieving, macro-aggregates appeared to be enriched in clay and silt compared with whole soil samples. Because of the possible detachment of sand particles from the exterior surface of aggregates during sieving operations, it was inferred that the particle size composition of macro-aggregates is similar to that of the bulk soil. The organic matter contents of the aggregate fractions were closely correlated with their clay + silt contents. Differences in the organic matter content of clay isolated from whole soil samples and aggregate fractions were generally small. This was also true for the silt-size separates. In both soils, straw incorporation increased the organic matter content of nearly all clay and silt separates; for silt this was generally twice that observed for clay. The amounts of soil C, derived from straw, left in the loamy sand and sandy clay loam at the time of sampling were 4.4 and 4.5 t ha?1, corresponding to 12 and 21% of the straw C added. The C/N ratios of the straw-derived soil organic matter were 11 and 12 for the loamy sand and sandy clay loam, respectively.  相似文献   

5.
FORMATION, COMPOSITION AND STRUCTURE OF HYDROXY-ALUMINOSILICATE IONS   总被引：7，自引：0，他引：7  
Formation of hydroxy-Al (HA) and hydroxy-aluminosilicate (HAS) ions was studied in solutions of A1C13, orthosilicic acid and NaOH. Evidence for incorporation of Si into HA is that HA retarded the development of silicomolybdate colour and Si was retained by a cation-exchanger. The reaction is believed to be mainly a condensation reaction between the hydroxyl groups in Al–OH–Al and Si–OH groups. The HAS with Si/Al ratio 0.3–0.6 showed infrared spectra similar to allophane-like constituents in Ando soils.  相似文献   

6.
The mineralogy of the clay fractions separated from the B horizons of two Hydrandepts (Hilo and Akaka soils), a Torrox (Molokai soil) and a Humitropept (Kolekole soil) was determined by a combination of methods.The Hydrandept B horizons were characterized by predominance of hydrous non-crystalline alumina and iron oxides associated with considerable amounts of humus and with very small amounts of silica. Allophane, allophane-like constituents and imogolite were present but in minor amounts. Gibbsite, goethite, chlorite and illite were also present as accessory minerals.The Torrox and Humitropept B horizons were characterized by predominance of kaolinite, hematite and goethite. The iron oxide minerals were present as fine particles (40–80 A diameter) often clustered to form larger aggregates. Neither imogolite nor allophane and allophane-like constituents were detected. Considerable amounts of dithionite-citrate soluble Al and humus were, however, present in the Humitropept B horizon, which may reflect the effect of an admixture of volcanic ash to the parent material.  相似文献   

7.
持久性有机污染物在土壤环境中的行为在很大程度上取决于土壤有机质对它们的吸附作用，粒径分组通常用来区分具有不同有机质组成和周转速率的有机质库。本研究利用菲（Phe）和苯并[a]芘（Bap）作为多环芳烃（PAHs）低、高环组分的代表物质，研究了它们在污染区9个农业表层土壤（0～20cm）不同粒径组分（粘粒、细粉粒、粗粉粒、细砂粒和粗砂粒）中的分配特征。结果表明，Phe在不同粒径组分中的平均含量大小顺序为粗砂粒〉细砂粒〉粘粒〉细粉粒〉粗粉粒，Bap为粗砂粒〉细砂粒〉粗粉粒〉细粉粒〉粘粒。Phe和BaP在不同粒径组分中的含量与粒径组分中有机质的含量均呈显著性正相关（P〈0．01）。不同粒径组分中的有机质对Phe富集能力的大小顺序为粗粉粒〉细粉粒〉细砂粒〉粗砂粒〉粘粒，对Bap的富集能力为粗粉粒〉粗砂粒〉细粉粒〉细砂粒〉粘粒。  相似文献   

8.
Towada Ando soils consisted of five soils—Towada-a (1,000 years old), Towada-b (2,000 years old), Chuseri (4,000 years old), Nanbu (8,600 years old), and Ninokura soils (10,000 years Amorphous clay materials of these soils taken at different localities were studied by the combined use of selective dissolution and differential infrared spectroscopy, X-ray analysis, electron microscopy, etc.

The main clay minerals of Towada-a soils, present-day soils, were montmorillonite-vermic-ulite chloritic intergrades and opaline silica, or these minerals and allophane in the humus horizons, and allophane in the non-humus ones. Towada-b soils overlain by the Towada-a soils showed the clay mineralogical constituents similar to those of Towada-a soils. However, allophane was one of the main clay minerals in all the humus horizons as well as non-humus ones. The main clay minerals of Chuseri soils were allophane and layer silicates consisting chiefly of chloritic intergrades and chlorite in the humus horizons, and allophane in the non-humus ones. Opaline silica was present in minor amounts in the humus horizons of Chuseri soils, but nearly absent in Nanbu and Ninokura soils.

There were remarkable differences in the clay mineralogical composition of Nanbu and Ninokura soils with differences of their environmental conditions. Allophane and imogolite Were dominant in the clay fractions of both humus and non-humus horizons of very shallowly buried Nanbu soil which was subjected to the strong leaching process. Allophane was the main clay mineral of deeply buried Nanbu and Ninokura soils which showed the absence of notable accumulation of bases and silica. On the contrary, halloysite with a small amount of siliceous amorphous material appeared in very deeply buried Nanbu and Ninokura soils where bases and silica were distinctly accumulated. The amounts of halloysite in the clay fractions were larger in the humus horizons than non-humus ones, and in Ninokura soil than Nanbu soil.

Soil age, soil organic matter, and depositional overburden of tephras were observed to be conspicuous among various factors relating to the weathering of amorphous clay materials in Towada Ando soils.  相似文献   

9.
Some allophanic soils in Japan, developed from deposits of volcanic ashes have aggregates, the sizes of which are mostly those of silt and sand, and which are very stable against the ordinary soil dispersion treatment such as decomposition of organic matter with hydrogen peroxide and addition of deflocculants to the suspension, but can be broken to smaller particles by mechanical forces. Oba and Kono (1, 2) reported that there were aggregates stable even against deferration treatment in the soils, especially plenty in ones developed from basic volcanic ashes, and these aggregates could be broken up into clay of allophane mainly by a sonic-wave vibration technique. Miyazawa (3) recognized that the aggregates were only found in Andosols developed under warm-temperate climates, being concentrated in B horizon, but not so much in A horizon and few in gleyey subhorizon, and assumed that they were formed under a specific weathering like seasonal wetting and drying. Yasuo et al. recognized a high correlation between the degree of aggregation and free iron oxide content of the soils in Kanto Plain and suggested that sesquioxide and structure of allophane might associate with the aggregate fonnation. On the other hand, airdrying of volcanic ash soils sometimes reduces their dispersibilities through irreversible formation of aggregates. Kishita (5) found that this effect of drying was remarkable at subsoiLs, and similar results were obtained by TAPA et al. (6). The poor dispersibility and the irreversible change by drying are known also about volcanic ash soils of New Zealand (7, 8), and Latin America (10, 11), Hawaii (9).  相似文献   

10.
The phosphate fixation capacity at pH 4.5 and an equilibrium concentration of 250 mM phosphate was measured. The soil samples were divided into five groups according to their clay mineralogical composition. The first group soils contain opaline silica and allophanelike constituents, and some unidentified minerals, the second opaline silica and crystalline layer .i1icates, the third opaline silica and crystalline layer silicates with additional allophanelike constituents or aluminarich gel-like materials, the fourth allophanelike constituents, allophane and imogolite and the fifth crystalline layer silicates, allophanelike constituents and alumina-rich gel-like materials, plus some halloysite-like minerals, respectively. The first group soils had phosphate fixation capacities of 3,000 to 8,000, the second group soils 1,000 to 3,000, the third group loib 2,000 to 13,000, the fourth group soils 8,000 to 15,000 and the fifth group soil. 5,000 to 12,000 mg P2O5/100 g oven-dry soil, respectively. The fourth group soils in which allophane and imogolite predominated showed the highest phosphate fixation capacity.

The fractions which dissolved from almost all soil samples by treatments with 6% H2O2 Na2S2O4-NaHCO2-Na citrate and 2% Na2CO3 were estimated to have very high phosphate fixation capacities (8,000 to 19,000 mg P2O5/100 g dry-matter), and there was not much difference among the soil samples examined. Iron and aluminum combined with humus, allophanelike constituents, alumina-rich gel-like materials and halloysite-like minerals in addition to allophane and imogolite contribute to the phosphate fixation of Ando soils.  相似文献   

11.
Andosols developed on basaltic material are naturally rich in metals. Organic matter and allophane, the key colloids of these soils, have a strong affinity for trace metals, but are intimately mixed so that speciation of trace metal is difficult to determine. We used three complementary approaches, namely physical fractionation, chemical extraction and potentiometric measurement, to distinguish them. Physical particle-size separations and chemical selective dissolution of allophanes and organic matter were combined to demonstrate relations between the occurrence of colloids and contents of Cu and Zn in an andic B horizon. About 22% of total soil Cu and 7% of total soil Zn were present in the < 5-μm fraction, associated with organic or amorphous mineral constituents. To support this association further, the affinity of soil colloids for Cu and Zn in a mimicked system was demonstrated. An Al-rich allophane was synthesized, and a portion of the organic matter was extracted from the clay fraction, and their reactivities towards Cu2+ or Zn2+ were studied by potentiometry. The two metallic cations displayed specific affinity towards allophane or soluble organic matter. Furthermore, the behaviour of copper and zinc in the ternary system, allophane + soluble organic matter + trace element, revealed a synergy in the surface complexation. The use of these three speciation approaches highlighted the linkage between metals and constituents, and showed how important the colloidal constituents are in the behaviour of Cu and Zn in Andosols.  相似文献   

12.
Allophane has been known to occur widely in volcanic ash soils in Japan and New Zealand. However, exact knowledge of its nature has not been well established, mainly because of extreme difficulty to separate it in pure state and of its x-amorphous nature. In the course of the studies on soil allophane, it was noticed that certain Ando soils contained two different mineral colloids together, in addition to crystalline clay minerals and free sesquioxides. X-ray examination revealed that one was x-amorphous colloid which would be called allophane, and the other an unknown colloid of low crystallinity. Imogolite*** Imogolite will be described in a subsequent paper by the present authors. was proposed as the name of the latter colloid by the present authors after imogo in which imogolite was first found. Imogo is a brownish yellow, volcanic ash soil. in the Kuma basin in the Kumamoto Prefecture3). When deferration treatment is applied to the soils, allophane disperses both in an acid and alkaline media, whereas imogolite disperses in an acid medium and flocculates in an alkaline one.  相似文献   

13.
Abstract

A method to determine the contents of imogolite and Al-rich allophane (Sil Al ? 1 : 2) in volcanic ash soils was presented. The method is based on the (1) assessment of the presence of Al-rich allophane in clays by successsive extraction with dithionite-citrate and oxalate-oxalic acid, (2) trimethylsilylation of soil clay with a mixture of hexamethyldisiloxane, HCl, and isopropyl alcohol, and determination of the content of monomeric Si based on the trimethylsilyl derivative of monomeric orthosilicate anion by gas / liquid chromatography, (3) determination of the total content of imogolite and Al-rich allophane based on the content of monomeric Si from imogolite, (4) determination of the imogolite content by Thermogravimetry (TG )-Differential Thermal Analysis (DTA) based on the weight loss due to endothermic dehydroxylation with maximum values at ca. 386°C, (5) calculation of the Al-rich allophane content by subtracting the imogolite content from the total content of these minerals, and (6) evaluation of the imogolite and Al-rich allophane content of soil by multiplying clay content of soil and the two mineral content of clay. The trimethylsilylation analysis was found to be reproducible, and the estimated total amounts of two minerals in clays by this method were adequately approximated to those evaluated from the amount of Si (= Sio) extracted with oxalate-oxalic acid after extraction with dithionite-citrate. The variation in the abmldance of two minerals in the soil horizons of volcanic ash soils from the San'in region indicated that this method is suitable for the profile-study of volcanic ash soils.  相似文献   

14.
THE INFLUENCE OF TEXTURE ON THE MOISTURE CHARACTERISTICS OF SOIL   总被引：1，自引：0，他引：1  
A quantitative assessment was made of the effect of the proportion of sand, silt, clay, and organic matter in twenty-six soils on the moisture contents at the upper and lower limits of available-water of the soils. Regression equations were obtained which enabled the moisture contents to be estimated on a weight or volume basis from mechanical analysis data using either International or American size grades. The accuracy of estimating the upper limit of available-water from the various equations ranged from ±9 to 22 per cent: for the lower limit from ±8 to 16 per cent of the measured values. Mean values of the moisture contents at the upper and lower limits of available-water for each textural class were calculated from the average particle-size composition for each class and from the regressions obtained.  相似文献   

15.
采取化学分析和Tessier连续提取法,对西宁市6个功能区城市土壤重金属Cu、Zn、Pb和Cd的含量及形态进行研究。结果表明:西宁市各功能区土壤的Cu、Zn、Pb和Cd的全量分别是全国土壤相应重金属几何平均值的1.9~5.2,1.9~6.9,0.8~4.0,7.4~11.1倍,4种重金属污染比较严重。6个功能区的重金属Cu、Zn、Pb和Cd含量进行差异显著性分析,结果是广场区Cu的含量与风景区的差异不显著(P>0.05),但与其他4个功能区差异显著(P<0.05);风景区与开发区差异显著(P<0.05),但与其他4个功能区差异不显著(P>0.05);开发区Zn的含量与商业区和居民区的差异显著(P<0.05),而其他各功能区间差异均不显著(P>0.05);各功能区Pb和Cd的含量均无显著差异(P>0.05)。研究土壤中重金属的化学形态有较大的差异,Cu以残渣态和有机结合态为主;Zn以残渣态和铁锰氧化物结合态为主;Pb和Cd以残渣态为主。Cu活性相对较高的土壤出现在风景区、矿冶区和居民区,Zn活性相对较高的土壤出现在风景区和广场区,Pb活性相对较高的土壤出现在风景区和居民区,Cd活性相对较高的土壤出现在矿冶区和开发区,研究土壤中4种重金属均具有一定的生物有效性和潜在的生态危害性。  相似文献   

16.
Particle-size distribution in soddy-podzolic and light gray forest soils of the Botanical Garden of Kazan Federal University has been studied. The cluster analysis of data on the samples from genetic soil horizons attests to the lithological heterogeneity of the profiles of all the studied soils. It is probable that they are developed from the two-layered sediments with the upper colluvial layer underlain by the alluvial layer. According to the discriminant analysis, the major contribution to the discrimination of colluvial and alluvial layers is that of the fraction >0.25 mm. The results of canonical analysis show that there is only one significant discriminant function that separates alluvial and colluvial sediments on the investigated territory. The discriminant function correlates with the contents of fractions 0.05–0.01, 0.25–0.05, and >0.25 mm. Classification functions making it possible to distinguish between alluvial and colluvial sediments have been calculated. Statistical assessment of particle-size distribution data obtained for the plow horizons on ten plowed fields within the garden indicates that this horizon is formed from colluvial sediments. We conclude that the contents of separate fractions and their ratios cannot be used as a universal criterion of the lithological heterogeneity. However, adequate combination of the cluster and discriminant analyses makes it possible to give a comprehensive assessment of the lithology of soil samples from data on the contents of sand and silt fractions, which considerably increases the information value and reliability of the results.  相似文献   

17.
Quantitative relationships between aggregation of soil particles and the content of haematite and goethite were studied by removing iron oxides, with dithionitetrate-bicarbonate (DCB) and oxalate reagents, from various sizes of soil separates which were stable to sodium hexametaphosphate, and then determining the particle-size distribution. Significant quantitative relationships were found between DCB-extractable oxides and particles obtained from the separates up to 20 pm, whereas oxalate-extractable oxides were correlated only with < 0.2-μm particles. Oxalate-extractable oxides were observed to aggregate a greater quantity of fine clay and a larger surface area of particles per gram of oxide than DCB-extractable oxides, A more efficient mechanism of aggregation was postulated for the oxalate-extractable oxides than for the DCB-extractable oxides. There were fewer aggregated particles in soils containing haematite and goethite than in soils containing only goethite. This was attributed to differences in pedoenvironment, rather than to a difference in the behaviour of the oxides. Although various clay minerals were identified in the soils studied, no preferential aggregation of any mineral was observed.  相似文献   

18.
The electric charge characteristics of four Ando soils (A1 and μA1) and a Chernozemic soil (Ap) were studied by measuring retention of NH4+ and Cl– at different pH values and NH4Cl concentrations. No positive charge appeared in the Ando soils at pH values 5 to 8.5 except for one containing allophane and imogolite. The magnitude of their negative charge (CEC; meq/l00g soil) was dependent on pH and NH4Cl concentration (C; N) as represented by a regression equation: log CEC =a pH +b log C +c, where the values of a and b were 0.113–0.342 and 0.101–0.315, respectively. Unlike the Chernozemic soil, Ando soils containing allophane, imogolite, and/or 2:1–2:1:1 layer silicate intergrades and humus showed a marked reduction of cation retention as pH decreased from 7 to 5. This was attributed to the charge characteristics of the clay minerals and to the carboxyl groups in humus being blocked by Al and Fe.  相似文献   

19.
The clay mineralogy of the Ap horizons of Ando soils in Japanese paddies was determined by a combination of methods and compared with that of Ando soils of uplands. Six of 13 paddy soil samples contained allophane and imogolite and none contained gibbsite, whereas parallel figures were 15 and 7 for 22 upland soil samples. Substantial numbers of diatoms were found in 5 paddy and 1 paddy-converted upland soil samples. The lack of gibbsite was related to the stage of soil formation rather than the paddy condition, whereas the presence of diatoms was related to both. Regarding layer silicates, there was no particular difference between the paddy and upland soil samples but one unidentified mineral with unique morphology and infrared spectrum was found in two paddy soil samples. There was no particular difference in phosphate adsorption between the paddy and upland soil samples.  相似文献   

20.
Relationships between the clay mineralogy and the primary mineral association were studied on seventeen Andosol samples (<3,000 years old) collected from Aomori, Hokkaido, and Iwate. Opaline silica, allophane, and imogolite were predominant in the soils derived from volcanic ashes which contained practically no quartz, while opaline silica, crystalline layer silicates, alumina-rich gel-like materials, and allophanelike constituents were abundant in the soils which contained abundant quartz. There was no positive indication of the presence of allophane in any quartz andesitic Andosols. High contents of finely comminuted amphibole and mica in the quartz andesitic volcanic ashes suggested that the crystalline layer silicates are inherited and are not formed pedochemically from amorphous materials.  相似文献   

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