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1.
脂肪酸甲酯生物柴油改善低硫柴油的润滑性能   总被引:1,自引:1,他引:0  
生物柴油可作为改善低硫柴油润滑性能的天然添加剂。该文将豆蔻酸甲酯(C14:0)、棕榈酸甲酯(C16:0)、硬脂酸甲酯(C18:0)、油酸甲酯(C18:1)、亚油酸甲酯(C18:2)、亚麻酸甲酯(C18:3)、蓖麻醇酸甲酯(C18:1 OH)及蓖麻油甲酯和餐饮废油甲酯按照0.5%、1.0%、1.5%和3.0%的体积分数添加到低硫柴油中,在高频往复试验机(high-frequency reciprocating rig,HFRR)上进行润滑性能测试,探究脂肪酸甲酯的碳链长度、不饱和度及含羟基等结构特征对润滑性能的影响。结果表明,长碳链脂肪酸甲酯一般比短链润滑效果好;碳链长度为十八的脂肪酸酯中,不饱和程度即碳碳双键数目越高则润滑性能越好;而在相同碳链长度和不饱和度条件下,含羟基的蓖麻醇酸甲酯的润滑改善效果优于油酸甲酯。由多种脂肪酸酯构成的混合物生物柴油的润滑性能要优于某单一的纯脂肪酸甲酯。在低硫柴油中,当某饱和脂肪酸甲酯的体积分数比例达3.0%时,或不饱和酯的体积分数达到1.5%时,或生物柴油的体积分数达1.0%时,可使低硫柴油的润滑性能指标满足相关标准。研究脂肪酸甲酯的各种结构特征对其润滑性能的影响及作用机制,有助于筛选合适的生物柴油组分及其添加浓度作为低硫柴油的润滑添加剂。  相似文献   

2.
Extreme soil water repellency can have substantial implications for soil hydrology, plant growth and erosion, including enhanced splash erosion caused by raindrop impact. Previous studies of water droplet impact behaviour on man‐made super‐hydrophobic surfaces, with which water‐repellent soil shares similar characteristics, revealed three distinct modes of splash behaviour (rebound, pinning and fragmentation) distinguished by two transition velocities: rebound‐to‐pinning (vmin) and pinning‐to‐fragmentation (v*). By using high‐speed videography of single water droplet impacts we show that splash behaviour is influenced by the hydrophobicity of immobile particles, with hydrophobic glass spheres exhibiting all three modes of splash behaviour in the hydrophobic state but hydrophilic spheres exhibiting solely pinning behaviour. We found that increasing the particle size of fixed glass spheres increases vmin. A study of droplet impact on hydrophobic sand shows that the increased roughness of the immobile particles makes impacting droplets more likely to fragment at slower impact velocities. The mobility of the particles influenced droplet impact behaviour, with loose, hydrophobic particles displaying significantly greater vmin values than their fixed analogues. The surface tension of the water droplet also lifted loose, hydrophobic particles from the surface, forming highly mobile ‘liquid marbles'. Water‐repellent soil was also shown to form ‘liquid marbles' at both the slow (approximately 0.3–2.1 m s?1) and fast (about 7 m s?1) droplet impact velocities studied. The observation of very mobile liquid marbles upon water droplet impact on water‐repellent soil is significant as this provided a mechanism that may enhance erosion rates of water‐repellent soil.  相似文献   

3.
Oxidation of oil-in-water emulsion droplets is influenced by the properties of the interfacial membrane surrounding the lipid core. Previous work has shown that an important factor in the oxidation of oil-in-water emulsions is surfactant properties that impact interactions between water-soluble prooxidants and lipids in the emulsion droplet. The purpose of this research was to study the impact of surfactant hydrophobic tail group size on lipid oxidation in oil-in-water emulsions stabilized by polyoxyethylene 10 lauryl ether (Brij-lauryl) or polyoxyethylene 10 stearyl ether (Brij-stearyl). The ability of iron to decompose cumene peroxide was similar in hexadecane emulsions stabilized by Brij-stearyl and Brij-lauryl. Oxidation of methyl linoleate in hexadecane emulsions containing cumene peroxide was greater in droplets stabilized by Brij-lauryl than in those stabilized by Brij-stearyl at pH 3 with no differences observed at pH 7.0. Oxidation of salmon oil was greater in emulsions stabilized by Brij-lauryl than in those stabilized by Brij-stearyl as determined by both lipid peroxides and headspace propanal. These results suggest that surfactant hydrophobic tail group size may play a minor role in lipid oxidation in oil-in-water emulsions.  相似文献   

4.
The incorporations of oleate (endogenous) and ricinoleate (nonendogenous) into phosphatidylcholine (PC) and acylglycerol (AG) in immature soybean microsomes were compared. [(14)C]Oleate and [(14)C]ricinoleate were incubated individually with soybean microsomal preparations for up to 4 h, and molecular species of PC and AG incorporated were identified and quantified by HPLC. The activities of acyl CoA:lysoPC acyltransferase and phospholipase A(2) are in general not affected by the fatty acid (FA) chain at the sn-1 position. However, comparison between oleate and ricinoleate revealed that different FA incorporated at sn-2 of PC showed some different selection of the molecular species of lysoPC. The incorporation of [(14)C]ricinoleate into triacylglycerols (TAG) was slightly better than that of [(14)C]oleate and indicated that soybean was capable of incorporating ricinoleate into TAG when ricinoleate can be produced endogenously in a transgenic soybean. The incorporation of FA into TAG in soybean microsomes was much slower than that in castor microsomes.  相似文献   

5.
The purpose of this research was to examine the influence of the physical state of lipids on iron-promoted oxidation of methyl linolenate in octadecane oil-in-water emulsions. Octadecane and methyl linolenate oil-in-water emulsions were prepared that contained droplets having the octadecane as either liquid or solid. The physical state of the octadecane was confirmed by a differential scanning calorimeter (DSC). The effect of the physical state of the lipid on oxidation rates was determined as a function of iron concentration (80 and 160 microM), pH (3.0 or 7.0), emulsifier type, and cooling rate. Oxidation of methyl linolenate was determined by lipid hydroperoxides and thiobarbituric acid reactive substances (TBARS). Emulsions containing solid octadecane had higher rates of lipid hydroperoxide and TBARS formation than those containing liquid octadecane. The rate at which the emulsions were cooled had no influence on oxidation rates. Oxidation rates in both emulsions increased with increasing iron concentration and decreasing pH. Oxidation rates were lowest in emulsions with cationic droplet membranes (dodecyl trimethylammonium bromide-stabilized), presumably due to the repulsion of iron from the oxidizable methyl linolenate in the emulsion droplet core. These results suggest that upon crystallization of octadecane, the liquid methyl linolenate migrated to the emulsion droplet surface, where it was more prone to oxidation because it was in closer contact with the iron ions in the aqueous phase.  相似文献   

6.
为减少农药飘移损失,保护生态环境,该研究从提高喷雾有效性和降低喷雾装置对果树枝叶的机械性损伤出发,研制了一种悬挂式柔性对靶喷雾装置。该装置以东方红MS-304拖拉机为载体,采用超声波传感器探测树冠位置,利用霍尔传感器构建测速模块。对株距4.0 m、树高1.6 m、树冠直径1.4 m的橘树进行对靶喷雾试验验证悬挂式柔性对靶喷雾装置作业性能。试验结果表明:拖拉机行驶速度为0.5 m/s时,喷雾压力0.4、0.5及0.6 MPa对应的平均药液附着率分别为84.7%、91.7%、88.9%,药液附着率较高且接近,喷雾压力对药液附着率的影响不明显;拖拉机行驶速度为1.0 m/s时,喷雾压力0.4、0.5和0.6 MPa对应的平均药液附着率分别为64.2%、70.3%、75.8%,喷雾压力越大,药液附着率越高;拖拉机行驶速度为 1.5 m/s时,平均药液附着率低于50%,且喷雾飘移较为严重,不适宜进行自动对靶喷雾;拖拉机行驶速度和喷雾压力相同时,药液附着率按树冠上、中、下层顺序呈递减规律,且速度越高,递减规律越明显。研究结果对提高果园对靶喷雾的药液附着率具有较好的实用价值。  相似文献   

7.
为提高果园轻型机动喷雾机的作业性能,设计了一种果园在线混药型静电喷雾机,进行了混药均匀性与稳定性试验和静电喷雾沉积试验。试验测得混药均匀性和混药稳定性的最大变异系数分别为4.46%和3.51%。采用风辅静电喷雾方式的无冠层采样架上采样点正面的雾滴附着率相对于无风辅无静电喷雾方式分别提高了9.3%、46.3%和53.2%,采样点反面的雾滴附着率分别提高了82.9%、164.3%和184.2%。风辅静电喷雾下在仿真柑橘树冠层内部叶片正面的雾滴附着率为48个/cm2左右,叶片反面为37个/cm2,相对于无风辅无静电方式分别提高了166.7%和428.6%。试验结果表明:所设计的在线混药系统具有良好的混药性能,风辅静电式喷雾系统可提高雾滴吸附能力和穿透能力,能够满足25个/cm2的病虫害防治附着率要求。该研究为果园喷雾机的机构设计和性能优化提供参考。  相似文献   

8.
施药喷嘴分级可行性及方法研究   总被引:1,自引:1,他引:0  
针对国产农用喷嘴的雾滴粒径分级数据及方法缺失的问题,该文依据ASAE S572.1标准,以NJS-01植保低速风洞为平台建立了雾滴粒径标准测试方法。在规范的测试条件和测量程序下,以Teejet 11001、11003、11006、8008和6510不锈钢芯扇形喷嘴为参考喷嘴,测试了Teejet F110、Lurmark F110、国产Lanao F110、YZS80、YZK80等24种待分类喷嘴在0.2、0.3、0.4 MPa下的雾滴粒径。在此基础上建立了参考喷嘴的雾滴粒径分级参考图,提出了基于该参考图的喷嘴分级方法。同时用Teejet、Lurmark标准扇形雾喷嘴的测试数据和厂家提供的分级结果,验证了喷嘴分级方法的正确性和适用性。该文运用该分级方法对国产Lanao F110、YZS80、YZK80系列喷嘴在不同压力下的雾滴粒径进行分级,可为该类型国产喷嘴的选型和应用提供参考。  相似文献   

9.
针对传统喷杆喷雾机作业时需水量大、叶片背面雾滴沉积量不足和雾滴分布不均匀等问题,该研究提出一种静电喷雾与喷杆喷雾相结合的施药技术。为探究静电喷杆喷雾机的最佳工作参数,明确不同参数对雾滴雾化效果的影响,利用Fluent软件建立了流场、离散雾场和空间电场耦合仿真模型。仿真试验结果表明,多喷头的空间电场分布均匀性优于单喷头,静电喷雾的雾滴体积中径比非静电喷雾减小12.7%。搭建静电喷雾试验平台,以喷雾水压、充电电压和喷头间距为试验因素,以雾滴的荷质比、粒径、分布均匀性和沉积量为试验指标进行雾滴的荷电特性和沉积特性试验。试验结果表明,多喷头喷雾的雾滴荷质比最大值为0.26 mC/kg,比单喷头喷雾提高52.9%,雾滴均匀性变异系数比非静电喷雾减小32.1%,体积中径减小14.8%,上、中、下层叶片正面的雾滴附着率分别提高27.1%、37.3%和45.2%;静电喷雾的最佳作业参数组合为充电电压6 kV、喷雾水压0.4 MPa和喷头间距250 mm。田间试验表明,静电喷头与常规喷头喷雾施药的病虫害防治效果基本一致,静电喷头的施药用水量减少了60%。在满足防控效果的前提下,静电喷雾能增加雾滴在植株下层和叶片背面的沉积量,有效减少田间作业的需水量,研究结果可为静电喷雾技术在大型喷杆喷雾机上的应用提供参考。  相似文献   

10.
农药喷洒雾滴粒径分布数值分析方法   总被引:3,自引:3,他引:0  
雾滴谱作为衡量喷头雾化性能的重要指标,可用激光雾滴粒径仪测定,但是此设备成本高、操作复杂,不能方便快速地测得雾滴谱。该文以ULLN模型为基础,用3种雾滴谱DV0.1、DV0.5和DV0.9提供的信息作为已知条件,设计了Newton迭代格式并反算出ULLN模型中相关系数,从而确定了模型的具体表达形式,随后利用辛普森数值积分的方法,计算出各雾滴粒径分段所占体积百分率。理论上,由于雾滴谱分布函数已经确定,所以本算法可以计算得到任何雾滴粒径分段的体积百分率。将该方法计算得到的结果和美国俄亥俄州立大学开发的 Driftsim软件计算结果进行了对比,结果表明该算法具有较高计算精度。  相似文献   

11.
为实现施药后雾滴地面沉积量的快速获取,该文提出一种基于驻波率原理的叉指型雾滴采集极板结构。为验证该极板结构的合理性,应用三维电磁仿真软件HFSS对此系统进行电磁仿真。HFSS模型求解的结果表明,叉指型极板内部出现了静电屏蔽,极板间通过雾滴能够实现电磁耦合,可用于雾滴沉积量检测,系统灵敏程度将随着极板间距的增大而减小。通过标定试验,建立了检测系统输出电压与试剂溶液沉积量关系的回归方程,测试后2种不同介电常数的胭脂红溶液和丙三醇溶液决定系数R2分别为0.982 1和0.997 6。通过对3W-ZW10型温室自走式喷雾机应用测试,结果表明:该系统在采样点上沉积量的模拟值最大相对误差率不超过7.95%,且模拟值与实测值均方根误差RMSE最大为0.076 7 mg/cm~2,雾滴沉积检测准确率高,方便实用,可用于田间雾滴沉积率的快速测量。  相似文献   

12.
为了获得GP-81A系列航空喷头的雾滴粒径分布情况,该文针对GP-81A系列航空喷头进行了风洞条件和飞行条件下的雾滴粒径及分布测试,通过高速风洞测试系统模拟飞行时产生的高速气流开展了气流大小对雾滴粒径及分布的影响研究;基于农用航空常用的Y5B飞机开展了不同型号喷嘴航空喷雾时的雾滴粒径及分布研究;同时,比较了相近喷雾压力条件下,相同喷嘴在风洞条件和飞行条件下的雾滴粒径及分布差距。试验结果表明,风洞条件测试时,当风速小于33.8 m/s时,雾滴粒径随气流的增加而增大;而当风速大于33.8 m/s时,雾滴粒径随气流的增加而减小,足够大的气流可以使雾滴进一步雾化。当气流在33.8 m/s时,7#喷嘴雾滴粒径最大,为491.1μm;当气流在84.87 m/s时,2#喷嘴雾滴粒径最小,为202.1μm。该系列喷头的6种不同喷孔的喷头的雾滴粒径均大于150μm,说明该喷头航空喷雾时的飘移损失较小。在喷雾压力基本相同的条件下,风洞条件下的雾滴粒径测试结果略高于飞行试验结果,主要原因是距离喷头出口的测试位置不同。风洞条件和飞行条件下的雾滴谱相对宽度S值均较小,表明雾滴分布较均匀,而飞行条件下的雾滴分布更均匀些。该研究为进一步优化航空喷头的作业参数,开展减少雾滴飘移研究提供参考。  相似文献   

13.
植保无人机航空喷施作业有效喷幅的评定与试验   总被引:5,自引:10,他引:5  
植保无人机有效喷幅宽度的准确评定是农业航空精准作业的前提,对其作业航线的规划及喷施作业质量的提升均有着重要意义。该文以不同参数的单旋翼植保无人机和多旋翼植保无人机为例,分别通过12架次不同飞行参数下的航空喷施试验及目前国内常用的雾滴密度判定法和50%有效沉积量判定法来评定植保无人机的有效喷幅宽度,并根据雾滴处理软件Deposit Scan对水敏纸等采集卡上的图像处理原理对不同评定方法进行了深入分析。结果表明:50%有效沉积量判定法更适于雾滴粒径相对较大的3WQF120-12型植保无人机有效喷幅宽度的评定,且评定的平均有效喷幅宽度为≥4.44 m;雾滴密度判定法更适于雾滴粒径相对较小的P-20型植保无人机有效喷幅宽度的评定,且评定的平均有效喷幅宽度为≥2.58 m;评定的有效喷幅结果与实际情况相符合。另外,由分析可知,由于当前图像处理技术的限制,不同粒径大小的雾滴斑点图像,软件Deposit Scan所产生的相对误差不同,因此,应根据植保无人机喷施雾滴粒径的范围选择合适的有效喷幅宽度评定方法。该结果为不同参数的植保无人机选择较优的有效喷幅评定方法提供了指导,降低了航空喷施作业的重喷率和漏喷率,提高了植保无人机航空喷施作业质量,可为植保无人机精准喷施作业的实施提供参考。  相似文献   

14.
植保无人机施药喷嘴的发展现状及其施药决策   总被引:8,自引:4,他引:4  
农药的低利用率是影响农业生态环境和农产品品质安全的重要原因之一,优化农药喷施技术是提高农药利用率的有效手段。无人机植保喷施作业作为航空施药领域的重要组成部分,因其应对突发灾害能力强、不受作业地点限制等优势,具有巨大的发展潜力。喷嘴作为植保无人机喷施系统中的关键部件,主要分为液力雾化喷嘴和离心雾化喷嘴两大类,良好的喷嘴性能能够大大提升航空施药喷洒的均匀性,提高农药的利用效率。该文总结了各类植保无人机常用喷嘴的原理、特点以及应用场合,提出了喷嘴性能评价指标并总结了三大类常用的雾滴粒径、沉积量、分布、速度等指标的测量手段,包括雾滴收集方法,雾滴沉积量测试方法以及仪器测量法。最后,针对目前无人机施药缺乏专业的指导,农药喷施效果有待提升的现状,该文提出合理的施药决策是结合靶标作物、喷药需求以及喷施环境三方面因素共同作用的结果,并从喷嘴喷雾角、防堵塞性、喷嘴压力与流量以及最佳作业粒径4个方面分析了喷嘴选型的思路,从专业喷嘴选型决策系统的建立以及无人机植保专用喷嘴的研发两方面对今后的研究进行展望。  相似文献   

15.
Particle‐stabilized emulsions, called Pickering emulsions, can be produced by using starch particles. In this work we studied how the properties of the starch particles affect the droplet size and creaming of such emulsions. In the study, various sizes of starch particles were generated by two different methods and used to stabilize Pickering emulsions. Sedimentation according to Stokes’ law was used to separate small and large starch granules. Acid hydrolysis was another method used to obtain smaller particles. All samples were modified with octenyl succinic anhydride (OSA) to increase their hydrophobicity with a level of OSA substitution between 1.8 and 3.1%. The size of starch particles was the main factor influencing emulsion droplet sizes. Furthermore, the droplet size decreased as the starch concentration increased. Using small starch particles with sizes <10 μm produced stable emulsions with smaller droplet size compared with larger sizes of starch particles, >10 μm. When subjected to acid hydrolysis, smaller starch particles were generally obtained, which could subsequently create smaller emulsion droplets. The emulsion index increased for the acid‐hydrolyzed starch owing to the size reduction of starch particles. The shape of the starch seemed to have a minor impact on the droplet size and the creaming of Pickering emulsions.  相似文献   

16.
Sixty-one molecular species of triacylglycerols (TAG) and diacylglycerols produced from castor microsomal incubations incorporating six different (14)C-labeled fatty acids have been identified and quantified. The preference for incorporation into TAG was in the order ricinoleate > oleate > linoleate > linolenate > stearate > palmitate. Ricinoleate was the major fatty acid incorporated, whereas stearate, linolenate, and palmitate were incorporated at low levels. Twenty-one molecular species of acylglycerols (HPLC peaks) in castor oil have also been assigned. The levels of TAG in castor oil are RRR (triricinolein) > RR-TAG > R-TAG > no R-TAG. The levels of the molecular species within the groups of RR-TAG, RL-TAG, and LL-TAG individually are ricinoleate > linoleate > oleate > linolenate, stearate, and palmitate. The results of the labeled fatty acid incorporation are consistent with ricinoleate being preferentially driven into TAG and oleate being converted to ricinoleate in castor oil biosynthesis.  相似文献   

17.
农药雾滴在喷施过程中因无法有效润湿靶标而出现反弹、飞溅、聚并滚落等现象,致使周边环境受侵害,严重威胁生态稳定及安全。由于雾滴沉积过程较为复杂,且相关机理尚不成熟,因此雾滴沉积特性研究是实现药液有效沉积,推动病虫害防治技术快速发展的关键。该文从单液滴微观动力学和雾滴群沉积飘移特性两个方面对目前研究进行总结,主要阐述了单液滴撞壁行为研究方法、影响单液滴界面行为的主要因素及单液滴撞壁理论建模研究;雾滴群分布特性研究方法、沉积量收集及检测方法以及雾滴群建模研究;并探讨了以上两种主流研究思路对最终沉积量评估的贡献及目前存在的瓶颈问题,且基于此提出了未来发展建议,以期为农药沉积特性研究及病虫害防治技术提供参考。  相似文献   

18.
气液两相流流型影响喷嘴喷雾形态及液滴粒径分布   总被引:2,自引:1,他引:1  
为了获得气泡雾化喷嘴内不同气液两相流流型对喷雾形态及液滴粒径分布的影响规律,该文建立了气泡雾化喷雾可视化试验系统,采用试验方法获得喷嘴内气液两相流流型及宏观喷雾形态;该文建立了喷嘴内和喷雾场中气液流动模型。研究结果表明,泡状流时喷孔出口含气率呈周期振荡衰减且含气率较低,搅拌流时喷孔出口截面含气率脉动幅度及其变化较小且含气率较高(较泡状流高1倍);搅拌流时喷雾形态脉动不明显,喷雾半锥角分布比较集中,而泡状流时正好相反,搅拌流时喷雾半锥角在8°~14°范围内的占比超过70%,而泡状流不到40%。搅拌流时喷孔出口附近液滴粒径分布更加集中且随轴向距离增加分布范围变化更大,液滴平均粒径比泡状流小4%左右;在喷孔出口附近,搅拌流时液滴粒径标准差明显小于泡状流时液滴粒径标准差,较泡状流小30%以上;不同气液两相流流型时液滴粒径分布的差异随轴向距离的增加而减小。研究结果可为气泡雾化喷射技术的发展以及不同领域喷嘴内流型的合理选择提供一定的理论和试验依据。  相似文献   

19.
The effect of process and formulation on sensory perception and flavor release was investigated on salad dressing models. Oil/vinegar emulsions (phi = 0.5, droplet size > 10 microm) with thickeners and a whey protein concentrate were prepared with different fat droplet sizes and different distributions of fat droplet size. The effect of the amount of emulsifier was also tested. Sensory profile analysis was performed by a trained panel and flavor release quantified by dynamic headspace analysis. When the droplet size is increased, the lemon smell and citrus aroma significantly increase, whereas the egg note, mustard, and butter aroma significantly decrease. The concentrations of alcohols and acids significantly increase when droplet size increases, whereas those of other compounds such as limonene or benzaldehyde significantly decrease. The dispersion of the droplet size has a small effect on flavor perception, and the effect of the increase of the amount of emulsifier is noticed only by instrumental analysis.  相似文献   

20.
锥形风场式防飘喷雾装置是利用辅助气流进行防飘作业的一种创新结构形式。为分析其防飘机理,改善防飘喷雾作业效果,对现有装置进行优化设计与防飘特性研究。基于质子动力学基本定律,构建了单个雾滴在运动空气介质中的受力模型,明晰了锥形风场的防飘机理。运用流体力学理论分析内流道气流损失,并利用CFD数值仿真技术结合风场测试对防飘喷雾装置进行优化设计。结果表明:当内流道弯管的曲率半径设计为4 cm时,优化后装置出口处仿真试验风速较优化前提高23.5%,测试试验风速较优化前提高28%,风机有效利用率提高21.2个百分点,优化方案合理。风洞条件下装置防飘特性试验结果表明:侧风风速、喷头高度、锥风风速与总雾滴飘移量占比具有相关性,通过多因素正交试验建立的竖直和水平方向的数学模型显著性较高(P<0.05,R2分别为0.934、0.945),表明锥形风场可以抵御绕流涡旋的产生,具有减少雾滴在纵向高度上随风飘失的特性。该研究可为综合分析雾滴飘移沉积规律提供一定参考。  相似文献   

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