共查询到18条相似文献，搜索用时 471 毫秒
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采用H2O2溶液对落叶松表面进行活化处理的研究 总被引：2，自引：0，他引：2
为提高用水性高分子异氰酸酯胶粘剂(API)胶接的落叶松木材的胶接性能,采用H2O2溶液对落叶松表面进行活化处理.试验结果表明采用H2O2溶液处理落叶松木材表面可以提高其胶接强度,用H2O2溶液处理过的落叶松表面比未处理过的落叶松素材的常态压缩剪切强度提高15%.文中还讨论了采用H2O2溶液对落叶松表面进行活化处理可以提高其胶接强度的主要机理.通过傅立叶红外吸收光谱(FTIR)证明用H2O2溶液处理落叶松木材表面可以提高其常态压缩剪切强度的机理主要是氧化作用,即用H2O2溶液处理落叶松木材表面后,其表面或获得活性基团羰基.通过对其表面接触角的测定可以看出,H2O2溶液处理过的落叶松表面润湿性增加,这对胶接有利. 相似文献
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节子对落叶松胶合木胶合性能的影响 总被引：1，自引：0，他引：1
《林业工程学报》2016,(1)
采用水性高分子-异氰酸酯(API)胶黏剂对含有木节的兴安落叶松(Larix gmelinii)层板按照工程胶合木的胶合工艺进行常温加压胶合,探讨木节及其大小对兴安落叶松工程胶合木胶合性能的影响。通过对试件进行胶缝剪切强度试验和浸渍剥离与煮沸剥离试验,发现节子对胶缝常态剪切强度、木破率、浸渍剥离率和煮沸剥离率均有显著的影响,随着木节直径的增大其胶缝剪切强度和木破率可下降40%和67%以上,浸渍二次总剥离率和煮沸二次总剥离率可增大至16%和37%以上。研究表明:两胶合面中仅一面有小木节(占板宽1/7~1/6),只能用于室内结构用集成材,不能用于室外结构用集成材;只有尺寸小于木板宽度1/10的木节与无节面胶合才能满足室外用工程胶合木的要求。 相似文献
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《林业工程学报》2021,6(3)
胶合性能径向变异的研究可为马尾松防腐集成材的原料选取提供重要依据。以35年生马尾松为试验用材,选用季铵铜防腐剂和间苯二酚-苯酚-甲醛树脂胶黏剂制备防腐材胶合试件,并检测其拉伸剪切强度及木破率,研究胶合性能的径向变异,从木材密度和胶黏剂渗透性能两方面分析胶合性能变化的原因。结果表明:沿髓心至树皮方向,马尾松防腐材剪切强度呈现出先增加(1～13 a)而后趋于稳定(≥14 a)的变化规律,不同部位对应的木破率均在90%以上,未表现出显著差异;木材密度(0.493～0.572 g/m~3)沿径向的变化趋势与剪切强度一致,且两者之间呈较强的线性正相关性(Pearson相关系数为0.659),而径向不同部位对应的胶黏剂平均渗透深度(76.65～88.01μm)之间无显著性差异。成熟材区域对应的马尾松防腐材的胶合性能明显优于幼龄材区域,因而在生产集成材时应优先选择14年生以上的成熟材为原料。木材密度是马尾松防腐材胶合剪切强度出现明显径向变异的重要影响因子,而胶黏剂在木材中的渗透性能对其影响较小。 相似文献
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采用铜氨(胺)季铵盐(ACQ-D)防腐剂处理马尾松木材,以水性高分子异氰酸酯(API)、聚氨酯(PUR)和间苯二酚-苯酚-甲醛树脂(RPF)为胶黏剂制备防腐材胶合试样,研究胶黏剂种类和防腐剂处理浓度对马尾松胶合强度的影响。结果表明:API、PUR、RPF适用于ACQ处理马尾松的胶合,平均剪切强度和木破率均达到GB/T 26899—2011《结构用集成材》要求。胶黏剂种类对防腐材胶合强度有显著影响,表现为PUR和RPF的剪切强度优于API。与未处理材相比,ACQ处理对API胶合有负面影响,对PUR胶合有增强效应,对RPF胶合没有显著影响。在ACQ浓度为0.1%～1.0%范围内,胶合强度没有显著变化。 相似文献
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为验证进口俄罗斯落叶松木材胶合性能,选用4种具代表性的结构用室温固化胶黏剂,根据GB/T 26899—2011《结构用集成材》进行胶合性能试验,对俄罗斯落叶松及胶黏剂的胶合性能进行分析研究。结果表明:对于俄罗斯落叶松,单组份聚氨酯、双组份聚氨酯和水性高分子异氰酸酯3种胶黏剂的胶层剪切强度和胶层剥离率均满足标准要求,其中双组份聚氨酯和水性高分子异氰酸酯胶黏剂胶合性能优异,单组份聚氨酯胶黏剂胶合性能良好;间苯二酚-甲醛树脂胶黏剂的胶合性能虽能达到标准要求,但不推荐作为结构用胶黏剂。 相似文献
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赵仁杰 《中南林业科技大学学报(自然科学版)》2002,22(3):47-50
径向竹篾帘复塑板是以竹材径向剖篾和径向胶合为其特征的一种新型复塑竹帘胶合板 ,对其试验的结果表明 :径向竹篾的加工与浸胶具有竹材利用率高、胶粘剂用量少的优点 ;采用竹帘卷内放置有孔棱的空心刚性轴进行束缚干燥 ,可以有效提高干燥速度和干燥质量 ;采用热 -热胶合工艺 ,每毫米厚的板材热压 1.5 min,即可获得高比强度的复塑板材 . 相似文献
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The attenuation coefficients of 100-GHz millimeter waves polarized linearly were measured for cross-cut, quarter-sawn, and
flat-sawn boards of hinoki (Chamaecyparis obtusa) that were 0.2–2.0 cm thick. This was done to examine the applicability of free-wave propagation theory for applying electromagnetic
waves to wood. It was found that the transmittance of a millimeter wave through the specimen boards was lower when the fiber
direction of a board was parallel to the direction of the electric field of the incident wave than when the fiber direction
was perpendicular to the electric field, and there was little difference in the transmittance between the tangential and radial
directions for the former case. These findings can be quantitatively explained by using propagation theory and the dielectric
properties of wood. 相似文献
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Soichi Tanaka Yuko Fujiwara Yoshihisa Fujii Shogo Okumura Hiroyoshi Togo Naoya Kukutsu Shoji Mochizuki 《Journal of Wood Science》2013,59(5):367-374
To evaluate the dielectric anisotropy caused by wood structure at a millimeter wave frequency of 100 GHz, the dielectric parameters for flat-sawn specimens of nine wood species at 0 and 11 % moisture content (MC) were measured using a free space method devised for reducing the multiple reflections under an electric field of millimeter waves parallel to longitudinal and tangential directions of wood, and those in radial direction were estimated using a conventional approximation theory. The dielectric parameters in the tangential and radial directions were almost identical and constantly smaller than those in the longitudinal direction. All the dielectric parameters increased with wood density and were larger at 11 than 0 % MC. The dielectric parameters in the longitudinal and transverse directions and the dielectric anisotropy between them were well fitted to the regression lines based on a dielectric mixture model composed of pores and dielectric isotropic wood substance, and a parallel capacitor and Lichtenecker’s exponential formulas were employed to represent the dielectric parameters of the mixture in the longitudinal and transverse directions, respectively. It was concluded that the dielectric anisotropy at 100 GHz is caused by the pore alignment and that the dielectric parameters are almost unaffected by anatomical structures, such as the rays. It was also confirmed that the free space method was effective for the measurement of the dielectric parameters for the flat-sawn specimens. 相似文献
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参照ASTM D143标准对黄山马尾松进行顺纹剪切测试，结果表明，径切面剪切强度平均值为9.59MPa、弦切面剪切强度平均值为11.38MPa、45＆#176;纹理方向剪切强度平均值为11.15MPa。弦切面剪切强度略高于45＆#176;纹理方向剪切强度，径切面剪切强度最小。弦切面和径切面的剪切强度与密度均呈线性相关，密度越大，剪切强度越大。材料满足GB50005-2003《木结构设计规范》中对剪切强度的要求，可作为结构材使用。 相似文献
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Alireza Bastani Stergios Adamopoulos Holger Militz 《Wood material science & engineering》2017,12(4):236-241
The shear strength of furfurylated, N-methylol melamine (NMM) and thermally modified wood bonded with emulsion polymer isocyanate, polyvinyl acetate (PVAc), and polyurethane (PU) adhesives was examined. Furfurylation and NMM modification of Scots pine had a significant negative effect on the bonding strength with all adhesives irrespective of the treatment intensity. The obtained low-shear strength values were related to the brittle nature of the wood after modifications rather to the failure of the bondline. PVAc showed a better bonding performance with both furfurylated and NMM modified wood while the combination of furfurylated wood and PU gave the highest reduction in bonding strength (47–51%). Shear strength also decreased significantly after thermal modification in both Scots pine (36–56%) and beech (34–48%) with all adhesives. With the exception of thermally modified beech samples bonded with PU, bondline was found to be the weakest link in thermally modified wood as it was revealed by the wood failure surfaces. Bondline thickness and effective penetration of adhesives did not relate to the shear strength of all modified wood materials. The lower shear strength of modified wood could be attributed to other factors, such as the reduced chemical bonding or mechanical interlocking of adhesives, and the reduced strength of brittle modified wood substrate. 相似文献
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Mehmet Hakan Akyildiz 《Journal of Wood Science》2014,60(3):201-206
The effects of screw type, moisture content, and grain direction on the screw and nail withdrawal strength and bonding strength were investigated for paulownia (Paulownia tomentosa Steud.) wood grown in Turkey. The withdrawal strength was carried out according to the ASTM-D 143 and ASTM-D 1761 and Turkish Standard 6094 in three directions (tangential, radial, and longitudinal) on 60 samples. The moisture content of half of the samples was 12 % and that of the other half 28 %.The experiment of bonding strength (BS EN 205) was applied to both sanded surfaces jointed by poly-vinly acetate and Desmodur-VTKA adhesives. Results of the tests indicate that, the withdrawal strength values at 12 % moisture content were higher than the 28 % for screws whereas the withdrawal strength for 28 % moisture content was higher than 12 % for nails. The maximum withdrawal strength value was found in the chipboard screw. In the case of directions, the withdrawal strength values of radial direction were found to be higher than the others for all parameters. The lowest withdrawal strength values were found in the longitudinal directions for both nails and screws. For adhesive types, the highest bonding strength of D-VTKA was found to be 5.64 N mm?2 and it was higher than the bonding strength with PVAc (5.33 N mm?2). However, there were no significant statistical differences between the two adhesive types. The results show that paulownia wood can be used for different purposes such as house construction, roof systems, and box cases as it possesses enough strength. 相似文献
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A sophisticated approach for the precise determination of both longitudinal shear moduli of wood at single test is introduced. The method is based on the combination of the torsion test inducing pure shear stresses in sample and an optical method providing the full-field strain data of such stress state. The proposed procedure of the longitudinal shear moduli determination consists of two main steps. In the first step, the apparent longitudinal shear modulus following the standardized procedure (EN 408+A1) was determined. Secondly, both longitudinal shear moduli were derived based on the apparent longitudinal shear modulus and the shear strain distribution on the radial and tangential sample surfaces. The wood of European beech (Fagus sylvatica L.) was used as material for the experiments. The exploratory analysis revealed the increasing difference between the longitudinal shear moduli determined in the longitudinal–radial plane and in the longitudinal–tangential plane as the total torsion angle increased as well as with the increase in the average torsion stiffness. Further, the longitudinal shear moduli and the torsional longitudinal shear strength did not correlate well. Therefore, they cannot be used in order to predict each other. Although such findings need more detailed studies, they should be taken into account when designing wood structures. 相似文献
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Soichi Tanaka Keiichiro Shiraga Yuichi Ogawa Yoshihisa Fujii Shogo Okumura 《Journal of Wood Science》2014,60(3):194-200
To clarify the effect of pore conformation on the dielectric anisotropy of wood, the relative permittivity along the longitudinal and tangential axes of flat-sawn oven-dry specimens of 12 different wood species was measured using terahertz time-domain transmission spectroscopy and compared with the values calculated using the eigenvalue problem for two-dimensional photonic crystals. The measured dielectric anisotropy, which is the ratio of the relative permittivity along longitudinal axis to that along the tangential axis, was well explained by the calculated value. It was concluded that the ratio of tangential to radial widths of wood pores affects the relative permittivity along the tangential axis, and that the dielectric anisotropy decreased with an increase in the ratio. This discussion can also be applied to the relative permittivity in frequencies below 0.15 THz. These findings show promise as a new method for evaluating the porous structure of wood. 相似文献