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1.
The water- and acid-insoluble fractions of a chestnut ( Castanea sativa L.) leaf litter sample and their complexes with Cu(II), Fe(III), and Mn(II) prepared in the laboratory were characterized by major elemental analysis, total Cu, Fe, and Mn content, infrared (IR), and electron spin resonance (ESR) spectroscopy. The IR spectra revealed a broad typology of functional groups (particularly carboxyls) in the solid litter, whereas the ESR spectra showed the existence of indigenous organic free radical species, inner-sphere Fe3+ complexes, and outer-sphere Mn2+ complexes. The litter exhibited a high residual binding capacity for Cu, Fe, and Mn in chemical forms of differing stability against water leaching and proton exchange. The ESR spectra of the metal complexes prepared in the laboratory indicated that Fe3+ and Cu2+ formed highly water-stable, inner-sphere complexes, whereas Mn2+ formed water-labile, outer-sphere complexes. Oxygen ligands of the litter were involved in metal complexation in all cases. The litter showed the highest affinity for Cu2+, followed by Fe3+ and Mn2+, when it was reacted with a single metal, whereas it complexed Fe3+ preferentially in the presence of both Cu2+ and Fe3+. Only a limited portion of the metal ions retained at the pH of distilled water remained bound in stable forms by the litter when the pH was lowered. Thus, variations of pH in forest soils will significantly affect micronutrient metal content and mobility in leaf litter.  相似文献   

2.
Abstract. Inputs of acidity to the ground arise through two distinct routes: wet deposition which includes all acidity deposited in rain and snow and dry deposition, the direct sorption of SO2, NO2 or HNO3 gases by vegetation or soil surfaces. The acidity from dry deposition of SO2 and NO2 is created during the oxidation of deposited SO2 and NO2 to SO24 and NO3− respectively. The areas of Britain experiencing the largest wet deposition of acidity are the high rainfall areas of the west and north, in particular the west central highlands of Scotland, Galloway and Cumbria where inputs exceed 1 kp H+ ha−1 annually. Wet deposited acidity in the east coast regions of Britain is in the range 0.3–0.6 kg H+ ha−1 a−1. Monitoring data for rainfall acidity at rural sites throughout northern Britain show a decline in deposited acidity of about 50% during the last six years. Dry deposition is largest in the industrial midlands and southeast England and in the central lowlands of Scotland, where concentrations of SO2 are largest. In these regions the dry deposition of SO2 following oxidation may lead to acid inputs approaching 3 kg H+ ha−1 a−1 and greatly exceeding wet deposition.  相似文献   

3.
The reactions of cadmium with calcium carbonate surfaces   总被引：1，自引：0，他引：1  
The reaction of cadmium with calcite was studied with 10−6–10−2M Cd2+ using 4g CaCO3 and 50 ml solution. The calcite-water suspension was equilibrated for 2 d before adding Cd(NO3)2. The CaCO3 surface has a high affinity for Cd and at < 1 μmol g−1 a linear adsorption isotherm (C-type) describes the reaction, whereas precipitation of CdCO3 on calcite predominates at higher Cd additions. In the latter case pH decreased and solutions were undersaturated with respect to CaCO3 indicating that CdCO3 prevented the CaCO3 surface from reacting with the acidity generated from CdCO3 precipitation. The data for low Cd additions suggests that an ideal surface solid solution is formed between CdCO3 and CaCO3 and the Thorstenson and Plummer equation expressing the pIAP values of surface solid solutions is valid. Equilibrium was attained for low Cd additions in several minutes, whereas precipitation was a slow process; at the changeover point distinction between the two processes is difficult. The reacting surface area calculated from the maximum adsorption of Cd is 0.5-1.0 times that measured by the BET method.
The Cd-reacting surface areas of four natural calcareous minerals were much less than those found by the BET method which includes the surfaces of other minerals present. The Thorstenson and Plummer equation may be a useful way to relate solution composition and carbonate-adsorbed Cd in contaminated soils.  相似文献   

4.
Pyrite and iron-rich carbonate and phosphate minerals are found in large quantities in an inland moor in western Jutland, Denmark. Sediments with up to 10.4% pyrite (FeS2) occur well-separated from sediments with iron-rich carbonate and phosphate minerals both reaching up to ∼6–7%. Analysis of the ground water showed that water enters the moor from different sources. Water of high alkalinity (up to 2.05 meq l−1) as well as water rich in sulphate (up to 79 mg l−1), sulphide (up to 1.75 mg l−1) and Fe2+ (up to 22.4 mg l−1) were sampled from the upper ground water flowing into the moor. On entering the moor processes within moor sediments control authigenic mineralogy, resulting in segregated mineral precipitation.  相似文献   

5.
The effect of pH on the adsorption of copper (Cu), lead (Pb) and cadmium (Cd) by a peat soil was studied, and the results compared with those corresponding to cation binding by a dissolved peat humic acid (HA), and interpreted with a NICA–Donnan model. A potentiometric titration technique was used to determine the adsorption isotherms for H+, at different ionic strengths, and for Cu2+, Pb2+ and Cd2+ at different pH values, in a peat soil. The effect of the ionic strength on proton binding was similar for the soil (solid) organic matter and for dissolved HA. The adsorption isotherms for cation–peat and the binding curves cation–dissolved HA are almost parallel, although more cation was adsorbed per kg of C in the dissolved HA. The effect of pH on cation binding is similar for dissolved organic matter and for the organic soil. At low metal concentration the amount of adsorbed metal followed the order Cu2+ > Pb2+ > Cd2+. The cation-binding parameters obtained with the NICA–Donnan model allow excellent simulation of the effect of pH on the adsorption of Cu, Pb and Cd ions in the studied peat soil. The binding constants for the peat suspension were greater than the corresponding generic parameters for dissolved HA. Speciation calculations showed that for Cu and Pb, the most abundant fraction was the metal adsorbed on peat, whereas for Cd the most abundant fraction was dissolved metal.  相似文献   

6.
The reactions of copper and zinc with calcium carbonate surfaces   总被引：2，自引：0，他引：2  
The reaction of copper and zinc were studied by adding the metal nitrate to a 4g:50ml suspension of calcite and water which had been equilibrated for two days, and then equilibrating for a further three days. Zinc behaved in a similar manner to cadmium in forming a surface-solid solution of ZnχCa1-χCO3 as a result of adsorption, and the pIAP of the equilibrium solutions were close to those expected from the Thorstenson & Plummer equation. However, the continuity from adsorption to precipitation was broken by the formation of Zn5(OH)6(CO3)2 which has a higher stability than ZnCO3. The CaCO3 surface appears to constrain the adsorbed Zn to conform to a carbonate structure despite its lower stability than the hydroxy carbonate.
The adsorption data for Cu can also be explained in terms of a surface-solid solution of CuχCa1-XCO3, but CuCO3 is not found naturally because of much greater stability of Cu(OH)2, and so there is no independent value for the solubility of a CuCO3 end-member if a surface-solid solution is formed. Secondary reactions are more likely to occur for Cu, especially close to the adsorption-precipitation boundary. Continuity from adsorption to precipitation again was not found. Theory predicts that Cu is less likely to form a surface-solid solution than Zn.
Upper Chalk (calcite with 4% other minerals, mostly quartz) behaved in a similar way but with increased adsorption due to its higher surface area.  相似文献   

7.
Abstract. The success of organic cropping systems depends on symbiotic N2 fixation by leguminous crops, and it is important to explore new management systems to improve the nitrogen input through N2 fixation. During two growing seasons the possible advantage of growing fababean ( Vicia faba L.) in ridges was studied in comparison to the traditional method on flat soil. Differences in soil physical parameters resulted in a significantly greater microbial activity and a deeper root system at the flowering stage when grown in the ridge than on the flat. Consequently, the amount of fixed N at flowering was significantly greater in ridges than in flat soil. However, during the period from flowering until harvest, when the major part of the N uptake and N2 fixation took place, the differences between the treatments disappeared. Average values for the growing season of fluorescein diacetate hydrolysis, arylamidase activity and arylsulphatase activity were significantly greater in the ridge than on the flat, and the microbial biomass-C, derived from substrate induced respiration (SIR), was on average 232 and 223 μg C g−1 soil in the ridge and on the flat, respectively. Measured total-N uptake, including root N (0–30 cm depth), ranged from 206 to 247 kg N ha−1, of which 182–201 kg N ha−1 was fixed N. From 154 to 173 kg N ha−1 was removed in grain resulting in a soil-N balance of +28 kg N ha−1 in both years. However, by including estimates of total root N and rhizodeposition-N the soil-N balance ranged from +52 to +62 kg N ha−1.  相似文献   

8.
Abstract. Studies have been made of the effects of 15 g N/m2 as urea in two dressings during April and June on annual nutrient fluxes in runoff from reseeded blanket bog also receiving annually 6 g P/m2 as granular superphosphate and 6 kg K/m2 as potassium chloride. Urea applications increased significantly ( P < 0.05) the mean annual ammonium-N flux from 17 mg/m2 for the P + K plots to 245 mg/m2 for the N + P + K plots. Annual fluxes of total P, K and Ca were also increased ( P < 0.05) by the addition of urea. This was attributed to the effects of increased acidity around grass roots following N uptake as ammonium-N. In contrast, nitrate-N was removed from rainwater throughout the year and concentrations in runoff were at the limit of detection (< 0.01 mg/1) on many occasions. Concentrations of organic-N in runoff exceeded those of ammonium-N, but were not significantly changed by fertilization.  相似文献   

9.
Iron deficiency stress causes a severe reduction in plant growth. Although Fe deficiency causes an imbalance in divalent heavy metal nutrients, the mechanisms underlying the growth reduction caused by this imbalance remain unclear. We investigated Zn uptake and accumulation in maize under Fe-deficient conditions. Under Fe-deficient conditions, Zn uptake was 15-fold higher and Zn accumulation was 16-fold higher than that under normal nutrient conditions. The Zn content of maize leaves under Fe-deficient conditions was >0.4 mg g−1 dry weight, which was higher than the content of plants grown in a nutrient solution containing 50 µM ZnCl2. Plant growth under conditions of both Fe and Zn deficiency was significantly higher than that under only Fe-deficient conditions. Moreover, Fe deficiency increased the thiol content of the plant. These results indicate that Fe deficiency causes excess uptake and accumulation of Zn, and that the stress resulting from the Zn overload accelerates growth reduction in maize.  相似文献   

10.
P-Zn interactions can affect fertilizer use and produce Zn deficiencies with certain crops. Phosphorus-Zn sorption-desorption reactions were studied in topsoil and subsoil samples from three Quebec soils. Soils were equilibrated with P solutions, then with Zn solutions, and finally with solutions containing no P or Zn. The first equilibration evaluated P sorption (Ps), the second evaluated Zn sorption (Zns) after P sorption (Ps), and the third evaluated Zn desorption (ZnD) as related to added P. Subsequently, Zn fractions were extracted sequentially with KNO3 (Zn kno 3), NaOH (ZnNaOH) solutions and concentrated HN03+ H202(ZnHNO,).
One mmole sorbed P resulted in increases of 0.5 to 1.0 meq (mean = 0.72) increases in cation exchange capacity (CEC). Increased Zns with added P was equivalent to 4 to 5% of the increase in CEC induced by Ps in the Uplands (sand) and St. Bernard (loam) soils, and 0.4 to 0.9% in the Dalhousie (clay) soils, while one meq increase in CEC resulted in 1.5-3.5% decrease in ZnD. There existed positive correlations between Ps and extractable soil Fe materials. Phosphate sorption enhanced associations between Zns, ZnD or Zn fractions and soil organic or crystalline Fe contents, confirming that P addition increased specific sorption of Zn on Fe components. Other mechanisms including precipitation, P-induced negative charge and 'bridge' effects are also discussed.  相似文献   

11.
Although iodine is harmful to plants, rice plants ( Oryza sativa L.) absorbed iodine more selectively than bromine. To explain this selective absorption, the authors proposed the following hypothesis based on the fact that the standard redox potential for (I2+ 2e = 2I−) is lower than that for (Br2+ 2e = 2Br−) and (Fe3++ e = Fe2+), and the roots of rice plants are able to oxidize ferrous ion (Fe2+) into ferric ion (Fe3+), namely rice plants oxidize iodide ion (I−) to form molecular iodine (I2) via the oxidizing power of their roots, and absorb the molecular iodine formed more selectively than iodide ion. Bromine, by contrast, is absorbed by rice plants only in the form of ion (Br−). According to this hypothesis, there should be a significant correlation between the oxidizing power of the rice roots and the amount of iodine absorbed. Therefore, the relationship between the oxidizing power of the roots and the concentration of iodine absorbed was studied in a water culture using 8 varieties of rice plants. Rice seedlings, 14 d after germination, were cultured in a solution containing 1 mg L−1 each of iodide and bromide ions for 3 d. The oxidizing power of the rice roots was evaluated based on the amount of 1-naphthylamine oxidized by the roots. A significant correlation (0.78, n = 16, 0.1% significant level) was found between the oxidizing power and the concentration of iodine absorbed by the roots. However, no relationship was found between the oxidizing power of the roots and the amount of bromine absorbed.  相似文献   

12.
Andosols developed on basaltic material are naturally rich in metals. Organic matter and allophane, the key colloids of these soils, have a strong affinity for trace metals, but are intimately mixed so that speciation of trace metal is difficult to determine. We used three complementary approaches, namely physical fractionation, chemical extraction and potentiometric measurement, to distinguish them. Physical particle-size separations and chemical selective dissolution of allophanes and organic matter were combined to demonstrate relations between the occurrence of colloids and contents of Cu and Zn in an andic B horizon. About 22% of total soil Cu and 7% of total soil Zn were present in the < 5-μm fraction, associated with organic or amorphous mineral constituents. To support this association further, the affinity of soil colloids for Cu and Zn in a mimicked system was demonstrated. An Al-rich allophane was synthesized, and a portion of the organic matter was extracted from the clay fraction, and their reactivities towards Cu2+ or Zn2+ were studied by potentiometry. The two metallic cations displayed specific affinity towards allophane or soluble organic matter. Furthermore, the behaviour of copper and zinc in the ternary system, allophane + soluble organic matter + trace element, revealed a synergy in the surface complexation. The use of these three speciation approaches highlighted the linkage between metals and constituents, and showed how important the colloidal constituents are in the behaviour of Cu and Zn in Andosols.  相似文献   

13.
Peat land has been considered as an alternative type of land for agricultural development especially in the tropics. In the present study, the N-supplying capacity, one of the most important soil properties in terms of crop production, of peat soils was examined. Ten peat soil samples were collected from Indonesia, Malaysia, and Japan. Gross N mineralization in the soil samples was estimated using a zero-order model, and kinetic parameters of mineralization were determined using a simple type model. Soil organic matter composition was investigated using 13C CPMAS NMR. Mineralization potential ( N 0), apparent activation energy ( E a), and mineralization rate constant ( k ) ranged between 571–2,445 mg kg−1, 281–8,181 J mol−1, and 0.009–0.020 d−1, respectively. Although none of the parameters showed a significant correlation with the soil C/N ratio, a negative correlation was observed between the k value and the ratio of the proportion of alkyl C in total C to that of O -alkyl C estimated by 13C CPMAS NMR. The latter suggested that the k values were higher in the peat soils relatively rich in readily decomposable organic matter including carbohydrates.  相似文献   

14.
Effects of organic matter and calcium on soil structural stability   总被引：2，自引：0，他引：2  
The cationic bridging effect of the calcium ion (Ca2+) and the flocculating ability of clay and organic matter are crucial in the formation and stability of soil aggregates. They are therefore likely to influence the soil's saturated hydraulic conductivity ( K s). We tested the individual effects of these factors on aggregate stability and related hydraulic properties, and studied the influence of clay mineralogy also. Samples from the surface (0–10 cm) of three contrasting soils in Trinidad were used. The soils were treated with three levels of Ca2+ and three levels of organic matter in a 3 × 3 × 3 factorial design and incubated for 14 days. Both aggregate stability and saturated hydraulic conductivity were influenced by all factor combinations. Interactions between soil type and Ca2+ revealed the importance of polyvalent cations in aggregate stability of soils with low activity minerals. The influence of organic matter varied with quantity; the more there was, the more stable the soil became, particularly in the soil containing little clay. Clay dispersion and slaking of expanding minerals occurred even with large additions of Ca2+ and organic matter, emphasizing the overall influence of mineralogy in determining the response of soils to stability treatments.  相似文献   

15.
The reactions of Ni, Zn and Cd with goethite were studied over a range of initial metal concentrations (10−6 to 10−4M), pH values (4 to 8), reaction times (2h to 42d) and temperatures (5 to 35°C). The adsorption of metals increased with pH, reaction time and temperature. Adsorption of Ni increased relative to Zn and Cd with increasing time and temperature. The initially rapid adsorption of metals within a few hours was followed by a much slower reaction linearly related to time1/2, interpreted as diffusion–controlled penetration of goethite. The pH–dependent relative diffusion rates (Ni > Zn > Cd) were influenced by both affinity for goethite surfaces and by ionic radius. Diffusion coefficients of the three metals ranged from about 10−19to 10−20cm2s−1. The corresponding activation energies of diffusion were also calculated (Ni 35, Cd 55, Zn 90 kJ mol−1). Our view about the reactions of heavy metals with goethite involves (i) adsorption of metals on external surfaces, (ii) solid–state diffusion of metals from external to internal binding sites, and (iii) metal binding and fixation at positions inside the goethite particles. The general parameters of these processes are related to the hydrolytic properties (p K values) and the ionic radii of the metals. The results show that goethite may be an efficient sink for trace metals.  相似文献   

16.
Radiocaesium fixation in soils is reported to occur on frayed edge sites of micaceous minerals. The weathering of mica in acid soils may therefore influence the Cs+ fixation process and thereby the mobility of the radiopollutant. We produced a laboratory weathering model biotite → trioctahedral vermiculite → oxidized vermiculite → hydroxy interlayered vermiculite (HIV) and quantified the Cs+ fixation of each mineral both in a fixed K+–Ca2+ background and in acid conditions. The transformation process was achieved through K depletion by Na-tetraphenylboron, oxidation with Br2 and Al-intercalation using NaOH and AlCl3. In a constant K+–Ca2+ background, vermiculite fixed 92–95% of the initial 137Cs+ contamination while biotite and HIV fixed only 18–33%. In acid conditions, the interlayer occupancy by either potassium (biotite) or hydroxy-Al groups (HIV) strongly limited Cs+ fixation to 1–4% of the initial 137Cs+ contamination. Cs+ fixation occurred on vermiculitic sites associated with micaceous wedge zones. Though both oxidized and trioctahedral vermiculites fixed similar Cs+ amounts in a constant K+–Ca2+ background (92–95%), the oxidized vermiculite retained much more radiocaesium in acid conditions (78–84% against 54–59%), because of its dioctahedral character.  相似文献   

17.
Sodium, potassium, magnesium and calcium chloride solutions of four concentrations (0.4, 1.0, 4.0, l0.0meq dm−3) and distilled water were equilibrated with the highly weathered, acidic subsoil of a Plinthic Paleudult from Natal at a soil:solution ratio of 2.2:1, then separated by centrifugation with an immiscible liquid and analysed for inorganic solutes. With each salt, increasing ionic strength resulted in lower solution-pH (the maximum pH was 4.95 in the distilled water equilibration) and higher aluminium concentration and activity. These effects were much less marked for sodium (maximum ΔpH of 0.47) than for the other cations (maximum ΔpH of 0.83) and both the concentration and activity of aluminium were correspondingly lower (by tenfold at the highest chloride concentration) in the sodium solutions.
Irrespective of the nature or concentration of the electrolyte added, pH and the activities of A13+ and silica in solution were consistently interrelated in a way which suggests that equilibrium with the gibbsite and poorly crystalline kaolinite in this soil had been closely approached. The results provide a basis for anticipating the effect of infiltrating solutions of fertilizer salts on subsoil acidity and suggest that a beneficial effect may accrue from the presence of sodium in the cation suite of acid soils.  相似文献   

18.
Potassium transport was investigated in the root elongation zone of Arabidopsis seedlings during the first minutes of Al3+ exposure, using the non-invasive MIFE microelectrode technique. To prevent pH changes during Al3+ application, and to separate aluminium from acidic stress, plants were pre-treated with 5 mM homoPIPES before addition of AlCl3 (pH 4.2). The 30-min treatment with 50 or 500 μM AlCl3 led to a significant increase in K+ efflux in solutions containing 100 μM CaCl2. This efflux was suppressed by high concentrations of Ca2+ (10 mM) in the bathing solution. Our results suggest that elevated external Ca2+ activities can sustain K+ influx in the root elongation zone during Al3+ exposure either by maintaining [Ca2+]cyt or by affecting Al3+ uptake across the plasma membrane.  相似文献   

19.
Counter ionic migration rates of dilute Cs+ and Sr2+ against sodium in a Na-montmorillonite gel are measured using a radially perfused diffusion cell. Enhanced or surface diffusion for caesium is observed both at ambient and elevated temperature. To quantify these surface diffusivities the ion-exchange properties of the diffusing species are required. Thus, exchange isotherms for caesium against sodium on montmorillonite at 22 and 90°C are given for 10−1, 10−2, and 10−3M background NaCl concentrations. Caesium counterion surface diffusivities at 22 and 90°C are 2.2*10−6 and 8.0 * 10−6 cm2 s−1, respectively. These values are found to be essentially independent of background ionic strength over the range 10−3 to 10−1 m NaCl. Experimental evidence of enhanced transport through Na-montmorillonite for the divalent cation Sr2+ is also confirmed with a surface diffusivity of 2 * 10−6 cm2 s−1 at 22°C and in 10−1 m NaCl.  相似文献   

20.
适量供锌明显提高平邑甜茶幼苗碳氮吸收和同化效率   总被引：1，自引：1，他引：0  
[目的]氮素利用率低严重制约我国果树产业的可持续发展.通过研究不同供锌水平对苹果砧木平邑甜茶幼苗生长、光合作用、13C同化与分配和15N吸收、利用与分配的影响,探究锌对苹果氮素吸收利用的影响机制,为苹果生产中氮肥利用率的提高提供理论参考.[方法]以苹果砧木平邑甜茶幼苗为试材进行砂培试验,试验周期为30天.设置ZnO、Z...  相似文献   

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