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1.
A combined treatment method of cutinase, keratinase, and protease was applied in the wool processing to modify the wool properties. The results demonstrated that individual protease treatment did not obviously improve the wettability and anti-felting property of wool fabrics. The combined process of cutinase and protease seemed more efficient than the keratinase-protease method, the obtained wettability and anti-felting ability of wool fabric were more encouraging. The combined use of cutinase, keratinase, and protease treatments endowed wool with more satisfactory properties compared to other methods. The contact angle of the protease-treated wool fabric reduced to 66 ° and the area shrinkage decreased to 5.2 % with an acceptable strength loss of 14 %. Reaction mechanism of the three-step enzymatic process was proposed in this paper. The data from amino acid analysis revealed the cooperative actions of cutinase, keratinase, and protease treatments during the combined enzymatic processing.  相似文献   

2.
In this study, the natural pigment from sappan was used for the dyeing of wool fabrics after treatment with the protease and transglutaminase. The influences of protease and transglutaminase on the UV/visible absorption spectrum of aqueous extract of sappan were studied. The enzymatic modified wool was compared with non-modified wool in K/S value and fastness after direct dyeing and mordant dyeing. It was shown that protease and transglutaminase made the absorbance at the λ max 540 nm in visible region increase. It suggested that there might be some interaction between the enzymes and sappan dye and the residual enzyme on wool fabric might affect the color of following dyeing. Compared to untreated wool, treatments with protease and transglutaminase enhance K/S value of wool dyed subsequently with sappan. Modification of protease led to some decrease in wet rubbing fastness, whereas transglutaminase had almost no influence on rubbing fastness. Enzymatic treatments have no influence on the washing fastness for samples dyed with sappan.  相似文献   

3.
The wool fabrics were treated by ultraviolet (UV) radiation and then dyed with Camellia sinensis (L.) O. Ktze var. waldensae (S.Y.Hu) Chang (yellow-bud tea) extract using meta-mordant dyeing method. The results indicated that the hydrophilicity of wool fabrics was improved after UV radiation treatment, which was conducive in improving color performance for the meta-mordant dyeing with yellow-bud tea extract of wool fabrics. The optimal dyeing process was that the powdered extract (5.0 % o.w.f) and the CuSO4 (2.0 % o.w.f) were added to the dyeing liquor, the pH value was adjusted to 3.5-4.0 by HCOOH, the wool fabrics treated by UV radiation for 10 min and then were dyed at a bath ratio of 1:50 under 95 °C for 70 min. By means of three-factor quadratic current rotation revolving design (TQCRRD) method, the computation results of the mathematical equations and models indicated that UV radiation was the most important factor for meta-CuSO4 dyeing with yellow-bud tea extract for wool fabrics.  相似文献   

4.
Wool fabrics, without any surface treatment, can undergo undesirable and irreversible structural changes of wool fiber during washing under heat and mechanical agitation, leading to high shrinkage of wool garments. The traditional method based on polyamide resin can prevent felting and/or shrinkage of wool textiles, but adversely affect the surface hydrophobicity. In the present study, a treatment solution was developed based on TriSilanolIsooctyl POSS® and 3- mercaptopropyl trimethoxysilane, which created wool surface with increased hydrophobicity and highly resistant to shrinkage or felting, as measured after 3×5A wash cycles (equivalent to 24 domestic washes). After the treatment, the wool fabric appeared to be superhydrophobic with a water contact angle of above 150°, compared to the untreated fabric. The treatment has marginal effect on mechanical performance as observed in tensile properties. Scanning electron microscopic images revealed a coating of POSS® on the wool surface. The dyeing of untreated and treated fabrics appeared to be uniform to the naked eye, though spectrophotometric analysis indicated a difference in the extent of dyeing performance. This research showed that POSS®-based treatment is a potentially effective approach for developing shrink-resistant wool textiles with enhanced surface hydrophobicity, in contrast to traditional chlorine/polyamide resin treatment.  相似文献   

5.
The enzymatic anti-felting of wool with proteases is a promising eco-friendly alternative to the chlorine-Hercosett process. However, protease molecules could penetrate into the interior of fibers during wool processing, easily causing unacceptable damages. In this paper, the action and mechanism of two protease treatments, i.e. Savinase and papain treatments on the properties of cutinase-pretreated wool fabrics were investigated and compared. The results showed that the anti-felting processing based on cutinase and papain treatments seemed more effective. When the percentages of weight loss for the combined treated fabrics were similar, the improvement of wettability and shrink-resistance for the cutinase-papain treated sample was more remarkable, the strength loss was also lower than that of the sample treated with cutinase and Savinase consecutively. The mechanisms of the two different combined treatments were further evaluated by Allwöden’s reaction and amino acid analysis. The comprehensive comparison proved that the hydrolytic activity of papain towards the scale exocuticle of wool was a bit higher than that of Savinase and less degradation of the interior of fibers occurred during the cutinasepapain treatment.  相似文献   

6.
Compressive shrinkage or compressive shrinkage finishing is one of the most important finishing procedures in the textile industry to improve the dimensional stability of cotton fabrics. Study of the physical and mechanical properties of compressive shrinkage finished fabrics could be useful for optimizing the treatment conditions. This research was carried out in a production line of a recognized garment company on cotton woven fabrics with two different woven patterns (twill and plain). The samples were first dyed with reactive and sulfur dyes in a jigger dyeing machine and finished with a silicone softener. The dried fabrics were then processed in a compressive shrinkage machine. Several physical and mechanical properties of the samples were evaluated including area shrinkage, crimp percentage, thickness, abrasion resistance, drapeability, mechanical and colorimetric properties. The results showed that the thickness of all treated samples increased due to compressive shrinkage. The fabrics were analyzed with a Martindale Abrasion Tester to determine the abrasion resistance. Interestingly, we noted an increase in the abrasion resistance. After the compressive shrinkage process, the strength of the plain woven fabrics decreased in the warp direction, but increased for twill woven cotton fabrics. On the contrary, the strength of all samples increased in the weft direction. Colorimetric evaluation of the samples showed that the effect of compressive shrinkage on the color of all samples was negligible.  相似文献   

7.
The effects of yarn number and liquid ammonia (L/A) treatment on the physical properties of woven fabrics prepared with pure hemp spun yarns were investigated. As a result of L/A treatment, the crystal structure of hemp fiber was changed from cellulose I to the mixtures of cellulose III and cellulose I and its crystallinity was slightly decreased by 13 %. The crease recovery of hemp fabric treated with L/A was improved upto 78 %. The washing shrinkage of hemp fabric treated with L/A decreased significantly to less than 0.4 %, while the washing shrinkage of hemp fabric prepared with the fined yarn was superior to that of hemp fabric prepared with the coarsed yarn. Especially, the wicking speed and drying ratio of hemp fabrics treated with L/A were higher than those of the untreated as yarn number increased. However, it was found that there is no significant effect on the UV protection of the L/A treated hemp fabrics.  相似文献   

8.
Dyeing of wool fabrics with natural dyes from Phytolacca berries has been studied. The effect of dye concentration, dye bath pH, dyeing time and temperature were discussed. The influence of chitosan application on the dyeing properties of wool fabrics was investigated. The SEM photographs of chitosan treated wool fabrics clearly depict the deposition of chitosan on the fibers. The effect of chitosan concentration, dye bath pH, dyeing time and temperature has been studied by orthogonal experiment. It has been proved that the dyed wool samples pretreated by chitosan have higher color fastness, faster dyeing rate, and better antibacterial properties compared with untreated ones.  相似文献   

9.
Development of water-soluble dyes for the dyeing of different textile fabrics is essential for the textile industry due to ecological and economical reasons. In this study, a series of new azoic dyes were prepared by diazotization reaction between the phenyl boronic acid and different aniline derivatives, and their dyeing capacity in aqueous solution was evaluated. The synthesized boronic azo dyes present good water solubility and can dye polyamide (nylon), wool, silk, and cellulose acetate fabrics. The effect of factors such as concentration of dye, dyeing temperature, and pH on the level of color strength (K/S) was studied. The dyeing results showed that higher color strength K/S (about 16) and fastness properties (about 4/5) with boronic acid dyes were achieved at higher temperatures avoiding the use of surface agents, mordants, and other polluting chemical additives.  相似文献   

10.
Mahonia napaulensis DC. (local name—Taming) family Berberidaceae, produces natural dye from its stem which has been used for dyeing textiles by the Apatanis (a tribe of Arunachal Pradesh) since ancient times. Sonicator dyeing with Mahonia napaulensis showed marked improvement in dye uptake. It showed that pretreatment with metal mordant (2%, w/w with respect to the fabric) improved substantially the fastness properties for dyed cotton, silk fabrics and wool yarn. Five fractions were isolated from column chromatography of the stem extract of Mahonia. Attempts have been made to identify these fractions by matching the spectral data which indicated that they were from a well-known isoquinoline alkaloid family.  相似文献   

11.
Two proteolytic enzymes were used as auxiliaries in the dyeing of wool fabrics with acid dyes. The effect of the enzymes on dye exhaustion (%E) and dye uptake (K/S) was studied at 70, 85, and 98 °C and compared to the corresponding values obtained for the control samples which were dyed without enzymes under the same conditions. Two commercially available dyeing auxiliaries commonly used for the dyeing of wool at low temperatures were also used under the same conditions and compared with the dyeings made with and without enzymes. Treatment with transglutaminase was done in order to compensate the damaging effects of protease. The study shows that the enzymes could be used as auxiliaries in the dyeing of wool at lower temperatures.  相似文献   

12.
The growing concern for the personal health and hygiene has created the necessity of acquiring wool fabric antibacterial activity. Silicon dioxide nanoparticles (SiO2 NPs) have appropriate features to enhance the functional properties of wool fabrics, especially with polymer application. In this study efficient coating using polyethylene glycol (PEG2000) and SiO2 NPs were used for imparting antibacterial properties to treated fabrics. All the treatments were carried out using both conventional and ultrasound techniques. The physical and chemical properties were evaluated using FTIR, XRD, and SEM. The result indicated that treated wool fabrics by PEG/SiO2 NPs improved the dyeability and antibacterial of the fabrics and also enhanced its mechanical properties. Furthermore, it is believed that the ultrasound radiation causes homogeneous distribution of cross-links and polymerization throughout the wool surface. This offers considerable advantages compared to conventional treatment.  相似文献   

13.
The surface morphology of the CO2 laser treated grey cotton fabrics was studied which showed a characteristics sponge-like structure on cotton fibres after treating with CO2 laser irradiation. The laser treatment parameters ranging from 100 to 150 pixel time and 40 to 70 dot per inch (dpi) were irradiated on the grey cotton fabrics directly and the degree of physical modifications, such as surface morphology, wettability and fabric strength, were changed accordingly with various laser treatment parameters. The surface morphology, wettability and tensile strength of cotton fibre treating with laser were evaluated using different instruments, such as Scanning Electron Microscope (SEM), contact angle meter and tensile strength machine. In spite of creating a sponge-like structure on fibre surface after treating with laser, the wettability of the samples was highly improved but the tensile strength was decreased.  相似文献   

14.
The effect of scouring, bleaching and dyeing on the low stress mechanical and surface properties of wool woven fabrics was studied. Fabric properties were measured by the KES-FB system. In general, mechanical properties of the treated fabrics are greatly affected by scouring, moderately by dyeing and least by bleaching.  相似文献   

15.
Three different silicone polymer systems, such as aminofunctional, epoxyfunctional, and hydrophilic epoxyfunctional silicone polymers, were applied onto plasma pretreated wool fabric to improve the dimensional properties. The results showed that the plasma pretreatment modified the cuticle surface of the wool fiber and increased the reactivity of wool fabric toward silicone polymers. Felting shrinkage of plasma and silicone treated wool fabric was decreased with different level depending on the applied polymer system. Fabric tear strength and hand were adversely affected by plasma treatment, but these properties were favorably restored on polymer application. Therefore, it has been concluded that the combination of plasma and silicone treatments can achieve the improved dimensional stability, and better performance properties of wool fabric. The surface smoothness appearances of treated fabrics were measured using a new evaluation system, which showed good correspondence with the results of KES-FB4 surface tester.  相似文献   

16.
Natural dye extracts were obtained by extraction from Punica granatum L. using water as an extractant at 90 °C for 90 min with various liquor ratios (solid Punica granatum L.(wt.): solvent water(wt.); 1:100–1:5). Dyeing was carried out using a 1:50 dyeing bath ratio at 80 °C for 60 min by exhaustion method. This study focused on the effect of liquor ratio on dyeing properties and deodorizing/antibacterial performance of various fabrics (cotton, silk and wool) dyed with Punica granatum L. extract without mordants. The optimum liquor ratio was found to be 1:10. By IR, UV-visible spectroscopies and HPLC analysis, the main component in Punica granatum L. extract and the yellow colorant component were found to be ellagic acid. By GC/MS analysis, the major volatile components of pristine Punica granatum L. powder were found to be acetic acid (area: 25.84 %), ethanol (area: 17.97 %), acetoin (area: 13.11 %), acetaldehyde (area: 8.96 %), isobutanal (area: 4.90 %). All dyed fabrics (cotton, silk and wool fabrics) displayed outstanding deodorizing performance (99 %) against ammonia gas and excellent antibacterial performance (bacteriostatic reduction rate: 99.9 %) against Staphylococcu aureus and Klebsiella pneumoniae.  相似文献   

17.
High-bulk worsted yarns with different shrinkable and non-shrinkable acrylic fibers blend ratios are produced and then single jersey weft knitted fabrics with three different structures and loop lengths are constructed. The physical properties of produced yarns and compression properties of produced fabrics at eight pressure values (50, 100, 200, 500, 1000, 1500 and 2000 g/cm2) were measured using a conventional fabric thickness tester. Then, weft-knitted fabric compression behavior was analyzed using a two parameters model. It is found that at 40% shrinkable fibre blending ratio the maximum yarn bulk, shrinkage, abrasion resistance and minimum yarn strength are obtained. It is also shown that high-bulk acrylic yarn has the highest elongation at 20% shrinkable fibre blend ratio. The statistical regression analysis revealed that the compression behavior of acrylic weft-knitted fabrics is highly closed to two parameter model proposed for woven fabrics. It is also shown that for weft-knitted structure, there is an incompressible layer (V′) which resists against high compression load. Acrylic weft-knitted fabrics with knit-tuck structure exhibit higher compression rigidity and lower softness than the plain and knitmiss structures. In addition, at 20% shrinkable fibre blend ratio, the high-bulk acrylic weft-knitted fabrics are highly compressible.  相似文献   

18.
The comfort of textiles is important and one area under evaluation is the development and application of Phase Change Materials, PCMs, in order to impart thermal adaptability. PCMs research for textiles has also focused on the use of polyethylene glycol (PEG). While there is a good adhesion between fibre and PEG polymer for cotton and polyester fibres, polymer adhesion to wool fibres appears poor and loosely bound within the yarn and had dislodged and crumbled. Therefore in this paper, the effect of changing the wool fibre surface energy and surface charge, shrinkproofing, on performance properties of thermally adaptable wool fabrics were studied. Untreated, gaseous fluorinated, as well as Chlorine-Hercosett treated 100 % wool fabrics have been evaluated to obtain highly cross-linked PEG with acceptable fastness properties. The surface interface was effectively probed by XPS & ToF-SIMS and characterised the loss of surface lipids, the nature of the fibre oxidation and deposition of Hercosett polymer on the wool fibre. The results indicate the necessity of having high surface energy in order to obtain appropriate adhesion and binding higher amount of solid polymer to wool fibres which results in superior thermal activity, better durability, and enhancement in felting performance.  相似文献   

19.
In this work, water-extraction of Vitis Vinifera L. (Black Grenache) leaves and analysis of aqueous extracts for anthocyanins were investigated. Vegetable leaves were cultivated in North of Tunisia at different dates. Anthocyanins were identified as main constituents in these natural dyeing materials using high performance liquid chromatography (HPCL). Dyeability of wool and its fastness properties using Vitis Vinifera L. leaves extract were also determined. Aqueous extract of Vitis Vinifera L. leaves has markedly yielded shades with good fastness properties. Thus, affordability is a point favorable for Vitis Vinifera L. leaves. Effects of dye bath pH and temperature on dyeability and fastness proprieties of wool fabrics by aqueous extract of Vitis Vinifera L. leaves were evaluated. Experimental results showed that fastness properties of dyed fabrics ranged from average to very good. Vitis Vinifera L. leaves extracts showed potential to dyeing wool fibers under highly acidic conditions (pH ≤2). The results obtained here revealed that natural dyes extracted from Vitis Vinifera L. leaves can be cost-effective for dyeing wool fabrics.  相似文献   

20.
Dimethylaminopropyl methacrylamide (DMAPMA) was grafted onto PET/wool blend fabrics by continuous UV irradiation. Union dyeing of the photografted fabrics was investigated using three reactive dyes of α-bromoacrylamide reactive groups. The influence of grafting yield, DMAPMA concentration, NaCl amount, pH value, and dyeing temperature on the dyeability was evaluated. The dyeability of both PET and wool components was improved significantly by the DMAPMA photografting and successive reactive dyeing. Although the dyeability of the PET component in the blend substantially was improved with higher grafting, equal dyeability between PET and wool was difficult to achieve due to more facile grafting and higher reactivity of the wool component compared with the modified PET component. However, the color fastness of the PET/wool blend fabric was excellent for all three colors. This study may offer a way to achieve union dyeing of PET/wool blend fabrics.  相似文献   

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