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1.
Potential vitiative effects of Millipore 0.45-, 0.22-, 0.05- and 0.025-pm filter elements on aqueous samples were investigated. All the filter elements evaluated exhibited a cation exchange capacity (CEC); in the case of 0.025-pm filter elements, the CEC increased with pH. Filtration of 20 μM AlCl3/1.65 mM CaCl2, solutions (I～0.005 M) to 0.45, 0.22 and 0.05 pm resulted in no significant change in solution A1 concentration. Filtration through 0.025-μm filter elements significantly reduced the total A1 present in solutions adjusted to pH 4.5 and 5.0; the A1 concentration of solution adjusted to pH 4.0 was not altered. The removal of A1 from pH 4.5 and pH 5.0 solutions was attributed to the retention of A1 hydroxide micro-particulates formed during pH adjustment of the AlCl3/CaCI2, solution. Adsorption of A1 by the filter element was not significant. Soil solutions were analysed without filtering and after filtration to 0.45,0.22,0.05 and 0.025 pm. Filtration had no effect on the concentration of the major anions (Cl?, SO24 -, NO13) or cations (Ca++, Mg++, Na+, K+). However, filtration to 0.05 and 0.025 pm resulted in significant reductions in the concentration of Al, Fe, Si and organic C in some samples. In soil solutions for which filtration resulted in the removal of large amounts of particulate material, the solution appeared less coloured after filtration and exhibited lower absorbance in the visible spectrum (4O(MOO nm). However, the absence of colour did not preclude the presence of colloidal particles.  相似文献   

2.
Abstract

Accurate determination of orthophosphate (P) in soil solutions is a prerequisite for rigorously assessing soil P availability for plants as well as the potential risk of P transfer to water bodies. Although P is usually measured on extracts filtered at 0.45 μm, little is known on the potential interfences due to the presence of colloidal particles. This work was conducted to study the influence of colloidal particles on P concentration by measuring it both by the phosphoantimonylmolybdenum blue colorimetry and ion chromatography in soil water extracts filtered at 0.45, 0.2, or 0.025 μm. Results strongly suggest that direct measurements with colorimetry might lead to an overestimation of the P concentration due to the solubilization of P‐containing particles in the acid medium prevailing in the solution during colorimetric essay. In the present study, the largest overestimations were observed in soil extracts rich in iron (Fe) and aluminum (Al) that had been filtered at 0.45 μm, on the opposite this overestimation remained lower but constant for the three levels of filtration in the studied calcareous soil. Ion chromatography constantly underestimated P concentration especially when the solutions were rich in Al and Fe. This underestimation could not be related to the presence of dissolved polyvalent cations in the solution and, therefore, might be accounted for by the sorption of P at the surfaces of colloids. In order to limit these interferences, it is proposed to measure P concentration by colorimetry after a filtration of the solution through a 0.2‐ or 0.025‐um membrane, instead of a 0.45‐μm filter. In some cases for instance for soil solutions rich in calcium phosphate particles, it might be advisable to determine P concentration with ion chromatography.  相似文献   

3.
The chemical composition of marine particulate matter from the Southern Baltic has been studied using ICP atomic emission spectrometry. The samples were collected on polycarbonate 0.4 µm, cellulose acetate and glass fiber 0.45 µm filters, and on polycarbonate filters of 0.2, 0.4, 0.6, and 1.0 µum pore size. The suspensions were analyzed for the major elements Ca, Mg, Al, Fe, and P, and for the minor and trace constituents: Mn, Mo, Zn, Cu, Co, Cd, Cr, As, Se, Sb, Ag, and S. The concentrations of metals calculated on dry weight basis were higher when polycarbonate filters were used while the values for cellulose acetate and glass fiber filter were comparable. The determination of net mass particulate matter was the main reason for these differences. A comparative study of the chemical composition of suspensions from the Southern Baltic and from other areas showed a similar range of concentrations of particulate elements in coastal waters.  相似文献   

4.
Few research studies have examined the influence of delayed filtration on sample stability or runoff nutrient loss assessments. Runoff samples from irrigation furrows were each split into four volumes: two were filtered (45 μm) in the field and two were filtered 10 days later, with or without boric acid treatment, and stored at 4 °C. Sample dissolved reactive P (DRP), nitrate nitrogen (NO3-N), and ammonium (NH4)-N concentrations were measured in all filtered samples 10 and 107 days after collection. Samples filtered in the field and those with a 10-day delayed filtration had similar dissolved DRP, NO3-N, and NH4-N concentrations, whether or not boric acid was added. Boric acid stabilized DRP and NH4-N sample concentrations, but not NO3-N, during the 107 days of storage (relative to field-filtered samples). The effect of treatments on computed furrow stream concentration and runoff mass losses was similar to that for sample concentrations, except that furrow NH4-N parameters were unaffected by treatments. The field-filtered or 10-d delayed filtration without boric acid treatments provided the best dissolved nutrient measurements for comparing agricultural management effects at the field edge; however, results suggest that an incubation-type test for field-edge runoff water may provide a more accurate estimate of field management effects on dissolved nutrient loads in downstream aquatic ecosystems.  相似文献   

5.
为增大柴油车尾气微粒捕集器滤芯的过滤面积,降低滤芯的过滤阻力,提高滤芯的过滤效率,设计了一种内部具有中空通道的齿形木纤维柴油车尾气微粒捕集器滤芯。首先根据纤维材料的过滤理论,建立齿形木纤维滤芯的过滤效率模型;然后通过理论分析和数值计算得到滤芯过滤效率与各影响因素之间的关系曲线;最后利用自行研制的滤芯性能检测试验台对理论分析结果加以验证。研究表明,试验和理论结果吻合较好,当尾气微粒捕集器过滤室壳体尺寸为直径140 mm,高150 mm时,木纤维直径为15μm、滤芯填充率为0.3、滤芯厚度为12 mm时滤芯过滤效率和过滤阻力都处于较理想的范围,使用寿命可达60 h,过滤效率为96%,排气背压为3 k Pa,完全能满足柴油车尾气排放国家标准。该研究对柴油车尾气净化机及环境保护具有十分重要的意义。  相似文献   

6.
We present results Irom an experimental study of suspended particle (4.5–36.5 μm silicon carbide powder deposition from surface water to ‘clean’ equi-granular permeable beds in a small 12.5×12.5×15cm box and a re-circulating flume. Enhanced deposition rates of up to 5 times the accepted sediment deposition model (e.g., Einstein,1968 are explained by filtration of particles in the bed. Compared to this model depotiion increases with increasing surface fluid speed, decreasing suspended particle size and increasing bed particle size. These results can be explained by an increased ability of particles to penetrate into the bed with the pore water which increases the effective filter thickness. The predominant deposition mechanism within the bed pores appears to be settling. Enhanced deposition, evident in Einstein's (1968) experimental data, was previously attributed to flocculation but may be explained better by filtration. These enhanced deposition rates drop off to close to the accepted model predicted rate after a certain volume of sediment has entered the bed, which may be due to the stumping of deposits from the top of bed elements. This reduction in deposition rate occurs long before the bed is filled with fine sediment.  相似文献   

7.
Background, Goal and Scope   The aim of this study was to check the concentration of some elements in water samples collected near Pb-Zn mining and smelting works and comparison of the obtained data with results achieved for sediment samples originated from the same reservoirs. Objective   Here, 8 water samples and 3 bottom sediments collected from water reservoirs in the vicinity of 3 big Polish Pb-Zn smelters were analysed.Methods   Water analysis was performed after filtration through a 0.45 µm filter and pH adjustment to 2. For decomposition of dried sediment samples, microwave assisted digestion with total dissolution of silicate matrix was applied. The elements studied were determined using ICP-MS and ICP-OES methods. Results and Discussion   The concentrations of most studied elements in water samples were on the 0.X µg/L level, while only the contents of Tl, As, Mn, Cd, Pb and Sb in two water reservoirs were above the limits established for drinking water. The content of studied metals in sediments was in a wide range from X mg/kg (Se and Sb) to X000 mg/kg (Pb and Zn).Conclusions  and Recommendation. The study indicates that the impact of Tl, As, Cd, Cu, Mn, Pb, Zn, Se and Sb on bottom sediments is much more extensive than on the water in ponds located in the vicinity of a post-flotation waste heap. Monitoring of surface and underground waters, if limited only to the dissolved elements, can lead to faulty conclusions about environmental pollution. The bottom sediments mainly contain easily mobilised phases, and water-sediment equilibrium could be changed easily.  相似文献   

8.
The behaviour of Co, Fe, Mn, and Ni was investigated in the mixing area of the Po river in six surveys over the period March 1992 to June 1995 during low-to-medium solid load and flow conditions. The concentrations (nM) of dissolved elements for the riverine and marine end-members respectively were in the ranges 0.09 to 0.93 and 0.24 to 0.98 for Co, 10 to 53 and 5 to 20 for Ni, 12 to 87 and 5 to 33 for Fe, and 10 to 155 and 26 to 105 for Mn. Co and Mn behave non-conservatively in the Po estuary; an addition to the dissolved phase occurred for these elements that was more marked in the summer period. The concentrations of dissolved and particulate Ni decreased almost linearly with increase in salinity, with more marked variations in dissolved Ni concentration in winter than summer. The concentrations of dissolved and particulate Fe also varied conservatively with salinity. This unusual behaviour for dissolved Fe is attributed to the analytical procedure which excluded kinetically inert colloidal species.  相似文献   

9.
Varying amounts of humic acid (Na-salt; 0 to 10 ppm) were first equilibrated with a dilute suspension of H+ -Kaolin and then with spiked (high activity radioactive 64Cu) water. After filtration, through a 0.45 µm Millipore membrane, the amount of radioactivity on the filter and the filtrate was measured separately using a Gamma ray well counter. Adsorption of Cu (expressed as distribution coefficient — K d ) was plotted against humic acid concentration. K d values decreased sharply upto 1 ppm humic acid concentration and thereafter remained constant up to 10 ppm.  相似文献   

10.
Varying amounts of H+-Kaolin were equilibrated with spiked (high activity radioactive64Cu) water and kept overnight in a constant temperature water bath shaker. After proper filtration, through 0.45 µm Millipore memberane, the amount of radioactivity on the filter paper and the filtrate was measured separately using a Gamma ray well counter. Adsorption of Cu (expressed as distribution coefficient ? Kd) was plotted against the final clay concentration. Kd values decrease initially with increasing clay concentration and then seem to reach an equilibrium condition at higher clay concentrations. At low clay concentration higher particle aggregation (nucleation) of the metal with clay in suspension is a possible explanation for this behavior.  相似文献   

11.
In the analysis of Mehlich III, deionized water (DI), Bray, and Olsen soil phosphorus (P) extractions, variations in shaking vessel, centrifugation, and filter paper result in different soil test P (STP) values. Of these factors, centrifugation and type of filtration were found to have the greatest impact on the results of water‐extractable P (WEP), that is, extraction with DI. Further spectrophotometric experiments demonstrated that centrifugation removed fine soil particles from the extract. Without the commonly used 0.45‐µm filters or centrifugation, these particles scatter the radiation of the spectrometer. During colorimetric analysis, this scattering of radiation will be perceived as absorption. This misperception results in a falsely high STP. In WEP analysis with only qualitative filtration, the scattering is very significant and appears to be due to limited aggregation of soil particles in the low ionic strength extract.  相似文献   

12.
Phosphorus (P) from soil can impair the water quality of streams and lakes. We have studied the forms and pathways of its movement from soil to water using 1-ha plot lysimeters, managed as grazed grassland for 12 months in temperate South-west England. The water flow through three pathways, namely (i) surface plus interflow to 30 cm (on undrained soil), (ii) surface plus interflow to 30 cm (on a mole and tile drained soil), and (iii) mole and tile drains (to 85 cm), were gauged. Samples of water from each path were treated with various combinations of 0.45-μm filtration and sulphuric acid-persulphate digestion and molybdate reaction, to determine the different forms of P. The total P (TP) concentration was greatest in the surface plus interflow to 30 cm paths (means 232 and 152 μg l–1), whereas the mean concentration in the drainage to 85 cm was 132 μg l–1. This reflects the substantial enrichment of the Olsen-P extracts from the surface horizons, as extracts from the 0–2 cm layer were 10-fold more than below 45 cm. In all paths, the dissolved P comprised the greatest proportion of the P transferred, with dissolved reactive P being the dominant form. Draining land reduced the transfer of TP by about 30% (≈ 1 kg–1 ha–1 year–1), because it can be sorbed as it flows through soil to drains. All these concentrations could cause eutrophication in surface waters.  相似文献   

13.
Soil phosphorus tests offer a potentially powerful tool for land managers trying to predict the areas which will contribute diffuse losses of phosphorus (P) to surface water bodies through the overland flow vector – but do they work? We address this question at a range of scales, from patch (< 1 m2), through plot (several m2) to small watershed (several hectares). Our hypothesis is that as we increase the scale, and therefore the complexity of the system, soil P tests will predict P concentrations and losses associated with overland flow less well, and that this is partly due to a shift from dissolved P losses to P losses associated with eroded soil material. At the patch scale soil P tests were used to predict the P concentration and load from 24 European soils exposed to simulated rainfall under controlled conditions in the laboratory. Results showed that soil P tests were generally good predictors of reactive P <0.45 μm, but did less well at predicting total P > 0.45 μm. By combining the soil P test with measured sediment concentrations predictions of total P concentrations improved. Outdoor rainfall simulation experiments on bare soil plots (10 m2) revealed the overwhelming influence of particle bound P losses compared with P losses in the water phase. Soil P tests, which relate primarily to the dissolved P fractions in soil, were not able to predict total P losses, but were related to reactive P < 0.45 μm losses. At the watershed scale soil P tests were able to predict reactive P < 0.45 μm losses, but with considerable uncertainty. We conclude that soil P tests, in combination with sediment concentration provide a useful means of assessing the mobilization of P in overland flow, but should not be expected to provide watershed scale predictions of the movement of P into overland flow.  相似文献   

14.
Mechanisms of Phosphorus Control in Urban Streams Receiving Sewage Effluent   总被引：1，自引：0，他引：1  
Urban streams often are a major source of phosphorus (P) to rivers, primarily due to large inputs of sewage effluent. A good example of this is Chicago (Illinois, USA) area streams, which make up most of the flow of the upper Illinois River. Even though streams in this section of the Mississippi River basin are characteristic hard-water systems and exhibit high calcium and carbonate concentrations, the precipitation of Ca–P minerals is minimal and phosphate is not removed from the water column. The objective of this study was to determine the chemical mechanisms controlling P activity in Chicago area streams. Measurement of dissolved ion activities on filtered surface water samples demonstrated that an average of 79% of P in the study streams was dissolved and the remaining was particulate (<0.05 μm and >1.0 μm in diameter, respectively). Neither a P colloidal-size fraction nor a correlation between dissolved and particulate Fe and P was observed. Thermodynamic modeling and SEM-EDS analysis of particulate matter in filter residues indicated that dissolved P may adsorb and co-precipitate on the surface of calcite rather than precipitating in a pure Ca–P mineral phase. Although SEM-EDS results also suggested that P was adsorbed to silicate minerals, organic residues likely dominated the P-containing particulate fraction. Sediment extraction results indicated that organic P was one of two major P components in the stream bottom. The Fe-associated P fraction represented the largest sediment-P fraction, and with little association between Fe and P in the overlying water, dissolved inorganic P may have aided in the authigenic formation of an Fe–P sediment phase. Overall, results suggest that pH combined with Ca and Mg activity are the dominant chemical controls on P chemistry in this P enriched system.  相似文献   

15.
基于物质平衡的对虾高位池循环水养殖系统设计与试验   总被引：1，自引：1，他引：0  
为建立一种高效、低成本的高位池循环水养殖系统构建技术,采用物质平衡相关原理,结合水净化设施构建技术,精准设计确立水处理系统物理过滤设施体积、生物过滤设施体积、循环量及供氧量等关键参数,并优化系统结构,建立融斜管沉淀设施、流化床生物过滤设施、增氧于一体的设施型高位池循环水养殖系统。应用该系统开展凡纳滨对虾运行试验,结果表明:p H值7.43~8.03,溶解氧5.32~7.82 mg/L,氨氮值0.06~0.54 mg/L,水质调控良好;系统养殖负荷2.26 kg/m3,饲料系数1.17,成活率81.3%,取得高效养殖生长结果;单茬利润3.34万元,亩均年利润2.67万元(按1年3茬计),获得良好经济效益。该研究系统主要参数设定值(预期值)与实测值吻合较好,可为高位池养殖模式可持续发展提供借鉴。  相似文献   

16.
Varying amounts of CaCl2 or MgCl2 were first equilibrated with a dilute suspension of H+-kaolin and then with spiked (high activity radioactive 64Cu) water. After filtration, through 0.45 μm Millipore membrane the amount of radioactivity on the filter and the filtrate was measured separately using a Gamma ray well counter. Adsorption of Cu (expressed as distribution coefficient ?K d ) was plotted against Ca or Mg concentration. K d values decreased sharply at Ca or Mg concentration from 0 to 10 mg l?1 and changed only slightly from 10 to 200 mg l?1. Increase in the concentration of Ca or Mg reduces the Cu binding capacity of the clay.  相似文献   

17.
Abstract

Surface‐applied manures create a potential phosphorus (P) runoff hazard, especially when unincorporated. In such cases, the concentration of water‐extractable P in the manure has been correlated to soluble P concentrations in runoff. This study evaluated the influence of holding time, sample‐handling procedure, and filtration method on measurement of the water‐extractable P content of manures in a 3×3×2 factorial arrangement of treatments. A two‐way interaction between holding time and sample‐handling procedure occurred for most samples. Six samples had water‐extractable P concentrations that were less than or equal to dried and dried/ground treatments. Only one sample had higher water‐extractable P concentrations for fresh than for dried and dried/ground treatments. When significant differences occurred as a result of the filtration method, results for Whatman No. 40 filters, with a larger pore size than 0.45 µm nitrocellulose membranes, were usually higher. There was no significant difference in the coefficient of variation across sample‐handling procedures, suggesting that efforts to dry and/or grind samples were not needed. These results support the adoption of a standardized protocol for measuring water‐extractable P in manures that represents the appropriate balance between the ease of implementation and the strength of the correlation to P runoff concentrations.  相似文献   

18.
This study conducted a two-stage experiment. The first stage attempted to establish biostable filter beds. Two parameters, total bacterial count (TBC) and non-purgeable dissolved carbon (NPDOC), measured by passing through a 0.2 μm membrane filter, were selected to compare the difference of biostability of a filtration system with recirculation with different O3-to-NPDOC ratios of filtered water. The excitation emission fluorescence matrix (EEFM) was used as an effective tool for understanding information regarding organic characteristics by comparing source filtered water before and after ozonation and the effluent during biostablizing filter. During the second stage, a biostable filter was used to compare differences in biodegradability of ozonated products sodium oxalate and sodium acetate. Experimental results demonstrate that both parameters, NPDOC removal and TBC, can be utilized to evaluate the biostabilty of a filter bed. With each parameter, a plateau was reached in roughly 20 days. The source water from Chen Ching Lake (CCL) contained a protein-like substance determined by the EEFM. This protein-like substance was also destroyed by O3/NPDOC?=?1.1. Soluble microbial products (SMPs) released from the biostablizing filter into the effluent have two peaks in the EEFM, identified as protein-like and humic-like acid. The NPDOC removal for the biostabilizing filter using O3/NPDOC?=?1.7 was less than that using O3/NPDOC?=?1.1. Bacterial counts in the effluent from the biostabilizing filter using O3/NPDOC?=?1.1 was better than that of O3/NPDOC?=?1.7. This difference can be explained by the high ratio of O3/NPDOC producing by-products of ozonation that were easily utilized by microorganisms; however, filter bed also released relatively more SMPs owing to increased proliferation of microorganisms attached to glass pellets in the filter. Regarding the differences in decomposition of the by-products of ozonation by the biostable filter, such as sodium oxalate, the NPDOC removal at O3/NPDOC?=?1.1 was better than that at O3/DOC?=?1.7. This phenomenon can be explained as previously mentioned.  相似文献   

19.
沼液一体化综合处理与循环利用工艺   总被引：2，自引：1，他引：2  
沼液过滤膜浓缩作为沼液处理的一个新方向,得到了广泛关注。该文将可堆肥处理的生物质材料秸秆作为滤料引入沼液的预处理,并对沼液过滤、膜浓缩及秸秆滤料堆肥效果进行了整体研究。研究结果表明,经过秸秆、火山岩、石英砂依次过滤后,可以去除沼液中95%以上的悬浮物,过滤后的秸秆经过简单晾晒,在含水率为75%的情况下,可以正常升温堆肥,高温期可以持续10 d,经过28 d堆置后基本达到腐熟要求,堆肥产品总养分含量接近5%,但含水率下降不明显。经过预处理的沼液进行超滤和纳滤之后,营养物质含量得到不同程度的提升,和未处理的原液相比,氮磷钾含量分别提升了2.6倍、1.9倍和4.5倍,Mg和Fe的浓缩倍数均达到10以上,氨基酸浓度提高了8.8倍,而且纳滤产生的透过液基本可以达到农田灌溉水水质标准。该研究结果为沼液的处理利用提供了参考。  相似文献   

20.
The synthetic precipitation leaching procedure (SPLP) is commonly used to measure the potential for release of constituents from soils and wastes by natural precipitation. However, experience has shown that SPLP extract pH values obtained from commercial laboratories are often elevated beyond that expected based on sample mineralogy and sometimes exceed environmental standards. This study was conducted to examine the effects of glass microfiber filters (GMFs) on pH values and metal concentrations of SPLP extracts. In a control experiment, GMF filtration increased the pH of standard SPLP extraction fluids (Eastern extraction fluid, pH 4.2, and Western extraction fluid, pH 5.0) to approximately 10.0 in the first 100 mL of filtrate. Filtration using GMFs also produced substantial pH increases in SPLP extracts from a variety of geologic materials, although dissolved metal concentrations were less affected. Laboratory analysts should be conscious of artificially elevated pH values in SPLP extracts caused by GMF filtration and consider using techniques to minimize these effects, such as (1) prerinsing GMFs with deionized H2O and pH monitoring of the resulting filtrate prior to SPLP filtration and (2) filtering the maximum volume of SPLP extract practicable.  相似文献   

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