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Cao Jin-zhen Li Li-dan Liu Zhi College of Materials Science Engineering Beijing Forestry University Beijing P. R. China 《中国林学(英文版)》2005,7(4)
In this study, the contact angles of three different reference liquids (including distilled water, diiodomethane, and formamide) and PF resin on the surfaces of Chinese fir (Cunninghamia lanceolata) samples untreated or treated with different con- centrations of ACQ-D (ammoniacal copper quat Type D) solutions were measured. Then, the surface free energy was calculated by two approaches: acid-base approach and geometric mean approach. ACQ-D treatment caused higher contact angles and lower surface free energies at a retention level corresponding to the commodity treated wood products. When wood was treated with much higher concentrations of ACQ-D, the total surface free energy of wood would be higher than the untreated control. Acid-base/polar compo- nents related with the hydrogen bonding state in wood were considered to be responsible for the observed changes according to the applied approaches. The hydrophobic properties and also higher contact angles of PF resin drop on wood surfaces after ACQ-D treatment at a reasonable retention level confirms the changes on surface free energy. 相似文献
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基于"荷叶效应"仿生原理,首先采用传统一步法和晶核辅助生长法合成ZnO纳米颗粒,再通过层层自组装法分别在竹材表面构建2种不同的微纳结构,并用低表面能物质十七氟癸基三甲氧基硅烷进行修饰,获得超疏水层,最后对其性能进行表征。扫描电子显微镜和原子力显微镜观察显示,传统一步法制备的ZnO纳米颗粒呈球形结构,粒径为200～400 nm,在竹材表面相对分散,粗糙度为18.6;而晶核辅助生长法制备的ZnO纳米颗粒呈纺锤形,粒径为100～300 nm,且具有明显的分层结构,粗糙度为28.9。水静态接触角测试结果显示,随着自组装次数增加,接触角先增加后减少,当自组装次数达到20次时,传统一步法和晶核辅助生长法制备的ZnO纳米颗粒构建的微纳层的水静态接触角达到最大值,分别为142.4°和152.4°,后者达到了超疏水的要求。酸碱试剂浸渍评价纳米颗粒的耐久性结果表明,2种方法制备的ZnO纳米颗粒在强酸强碱溶液中浸泡后,接触角均无明显变化,传统一步法制备的竹材接触角在pH 2的盐酸和pH 12的氢氧化钠溶液中分别浸渍12 h后,接触角仍保持在141.1°和141.7°;晶核辅助生长法制备的竹材在pH 2的盐酸和pH 12的氢氧化钠溶液中分别浸渍12 h后,接触角仍保持在150.2°和150.8°。耐磨性测试结果表明,2种方法制备的疏水竹材具有较好的耐磨性,在30cm的线性摩擦试验后,传统一步法制备的竹材接触角仍在142°左右,晶核辅助生长法制备的竹材接触角在150°左右。X射线衍射测试结果显示,2种方法制备的疏水涂层均具有明显的ZnO晶体的衍射特征峰。2种竹材样品在XRD曲线上均出现了32.45°,34.76°,36.82°和47.65°等一系列新衍射峰,而且这些衍射峰与标准的纤锌矿ZnO的XRD卡片(JCPDS,36-1451)一致。 相似文献
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Cao Jin-zhen Li Li-dan Liu Zhi 《中国林学(英文版)》2005,7(4):29-34
In this study, the contact angles of three different reference liquids （including distilled water, diiodomethane, and formamide） and PF resin on the surfaces of Chinese fir （Cunningharnia lanceolata） samples untreated or treated with different concentrations of ACQ-D （ammoniacal copper quat Type D） solutions were measured. Then, the surface free energy was calculated by two approaches： acid-base approach and geometric mean approach. ACQ-D treatment caused higher contact angles and lower surface free energies at a retention level corresponding to the commodity treated wood products. When wood was treated with much higher concentrations of ACQ-D, the total surface free energy of wood would be higher than the untreated control. Acid-base/polar components related with the hydrogen bonding state in wood were considered to be responsible for the observed changes according to the applied approaches. The hydrophobic properties and also higher contact angles of PF resin drop on wood surfaces after ACQ-D treatment at a reasonable retention level confirms the changes on surface free energy. 相似文献
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用润湿角测量仪测量了胶粘剂在竹材表面的润湿角,用物理方法(喷砂处理)、化学方法(NaOH,Na_2CO_3处理)处理竹青、竹黄,并测定了用这些竹片压制成的竹胶板的胶合强度。实验中,借助于红外光谱仪分析了处理前后竹青、竹黄表面化学结构的变化。实验结果表明:喷砂处理方法可明显地提高竹青、竹黄的胶合强度。 相似文献
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In this study, the contact angles of four different reference liquids (including distilled water, diiodomethane, formadide
and glycerol) formed on the surfaces of wood, treated with chromated copper arsenate (CCA) and two other emerging copper-based
water-borne systems (commercial names: NW and NS) were measured with sessile drop method. Based on the contact angle data,
the surface energy was obtained from the acid-base approach. The total surface energy consisted of Lifshiz-van der Waals parameter
and acid-base parameter. Results showed that the NW and CCA treatments made the wood surface more hydrophobic while the NS
treatment had the reverse effect on the wood surface mainly owing to the increased penetration of earlywood. By using three
liquids, diiodomethane, formamide and distilled water, the total surface energy obtained for untreated earlywood, untreated
latewood, CCA-treated earlywood, CCA-treated latewood, NW-treated earlywood, NW-treated latewood, NS-treated earlywood and
NS-treated latewood were 43.1, 44.5, 43.4, 45.1, 49.4, 40.6, 46.0 and 40.9 mJ/m2, respectively. The surface energy of CCA-treated wood was almost the same as untreated wood. After NW and NS treatments,
the surface energy of both earlywood and latewood changed a little. However, the change was not so obvious as to draw any
further conclusion concerning the influence of NW and NS treatments on the surface energy of wood.
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Translated from Journal of Beijing Forestry University, 2006, 28(4): 1–4 [译自: 北京林业大学学报] 相似文献
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通过渗透扩散系数来评价胶粘剂在试材表面的湿润性能,研究酚醛树脂胶(PF)、聚异氰酸酯胶(PM D I)、双组分聚异氰酸酯乳液型胶粘剂(EP I)和脲醛树脂胶(U F)4种胶粘剂分别在毛竹和杉木表面的接触角及渗透扩散速率变化规律.结果表明:4种胶粘剂在毛竹表面的润湿性均小于杉木,在毛竹竹青上的润湿性小于竹黄;对于同一毛竹或杉木表面,PM D I胶的润湿性最好,而EP I胶较差,PF、U F介于二者之间. 相似文献
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Effect of alkali treatment on wettability and thermal stability of individual bamboo fibers 总被引：1，自引：0，他引：1
Hong Chen Wenfu Zhang Xuehua Wang Hankun Wang Yan Wu Tuhua Zhong Benhua Fei 《Journal of Wood Science》2018,64(4):398-405
The aim of this study is to examine the wettability and thermal properties of individual bamboo fibers after alkali treatment. The individual bamboo fibers were treated by sodium hydroxide (NaOH) solution with varying concentrations (6, 8, 10, 15 and 25%) followed by freeze-drying treatment. The surface analysis of alkali-treated individual bamboo fibers was characterized by atomic force microscope. Water droplet on the individual fiber surface was observed with drop shaper analyzer and the contact angles on fiber surface were also measured. Thermal properties were further studied by thermogravimetric analysis. The results indicated that alkali treatment resulted in the increase in surface roughness of individual bamboo fibers. Alkali treatment with low NaOH concentration could enhance the wettability of treated individual bamboo fibers, and while the wettability was reduced with alkali treatment at high concentration (25%). Thermal analysis revealed that the onset of decomposition and the maximum decomposition were moved to higher temperature after alkali treatment at low NaOH concentrations (6, 8, and 10%), suggesting the improvement in the thermal stability of treated individual bamboo fibers, while the thermal stability was compromised after alkali treatment at higher concentrations (15 and 25%). 相似文献
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Fangbing Yu Wenbin Yang Jianbin Song Qiuning Wu Lihong Chen 《Wood Science and Technology》2014,48(2):289-299
To convert the hydrophilic surface of bamboo flour into a hydrophobic surface, methyl methacrylate (MMA) was grafted onto bamboo flour surface by means of atom transfer radical polymerization (ATRP) method. The grafted bamboo flour was characterized by using Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy, scanning electron microscopy (SEM), water contact angle and thermogravimetric analysis. The results from FTIR and SEM have confirmed that MMA groups have been successfully grafted onto bamboo surface by means of the ATRP method, which caused the water contact angle increase to be 128.7°, i.e., hydrophilic bamboo flour turned into hydrophobicity. However, the thermal stability of grafted bamboo flour decreased compared with pure bamboo flour. 相似文献
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Summary Thermodynamic work of adhesion, contact angle, wettability and acid-base contributions of the wetting of four North American wood species were determined using the Wilhelmy technique. The wetting angles with water varied from 60° for Sitka spruce to 74° for Douglas-fir. The wood surfaces had a strong acidic character since the greatest interactions for all the wood species occurred with formamide (basic probe) while lesser interactions were obtained with ethylene glycol (acidic probe). In addition, dispersive and polar surface free energies of wood,
d
s
and
p
s
respectively, were determined using Wu's simultaneous equations. In general, 75 to 80% of the total surface free energy of wood was due to dispersion forces. Specific wettabilities of wood and advancing contact angles in thirty various organic liquids were also evaluated. 相似文献
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INTRODUCTIONSome scientists and specialists think that agriculturalresidues are the second forest resource in China.Straw boards use the agricultural residues, such aswheat straw, rice straw and so on, as main rawmaterial, which are one-year-growth plants and veryrich in China. Producing straw boards can increasewood resource and decrease consumption of wood(Zhou Dingguo, et al, 2000).Wetting is a term to describe what happens when aliquid meets with a solid surface. The surface contact… 相似文献
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基于玫瑰花瓣褶皱微表面特性仿生构筑疏水竹材的研究 总被引：1，自引：1，他引：0
本研究利用软印刷法以不同浓度的聚乙烯醇（PVA）为弹性印章,以新鲜红玫瑰花为模板,经过二次复形将玫瑰花表面微纳褶皱结构转印到竹材表面,制备得到具有类玫瑰花表面微观结构的疏水竹材。试样表面利用扫描电子显微镜（SEM）及水接触角进行检测,结果显示类玫瑰花竹材样品具有乳突状和凹槽状微纳米结构的粗糙褶皱表面。研究发现,以10% PVA为模板复形的竹材表面水接触角接近于新鲜玫瑰花瓣表面的水接触角数值,展现出良好的疏水特性。 相似文献
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The structural performance of finger-jointed laminated bamboo was investigated for two bamboo species by considering the finger
length, profile orientation, lamination direction, culm growth height, and mechanical properties of bamboo materials. Based
on the growth height variation and bamboo species, the best finger-jointed laminated bamboo was found for the lamina processed
from the middle growth height of a moso bamboo culm with the finger profile shown on the width face of the beam. It was 38.7%
higher in bending strength than the lowest group, with the lamina from the lower ma bamboo culm showing the finger profile
on the thickness face of the beam. When considering the finger length and lamination orientation, the strongest finger-jointed
laminated bamboo joined with an 18-mm finger, showing the finger profile on the width face of a vertically laminated beam
was 50.1% higher in bending strength than the lowest group having a 12-mm finger showing the finger profile on the thickness
face of a vertically laminated beam. The laminated ma bamboo showed higher finger-joint efficiency, 11.6%, than moso bamboo,
and the members showing the finger profile on the width surface was 12.3% better in joint efficiency than that showing on
the thickness surface of the beam. 相似文献
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Kun-Tsung Lu 《Journal of Wood Science》2006,52(2):173-178
The poor adhesion of bamboo coatings is a serious issue in the bamboo industry. To develop a pretreatment method that improves
the adhesion of films and increases the economic value of bamboo products, a study of hydrogen peroxide treatment with solutions
of various pH (pH 4–9) on bamboo surfaces was conducted. Five-year-old ma bamboo (Dendrocalamus latiflorus Munro), and nitrocellulose lacquer were used in the study. Surface properties of the bamboo such as contact angle and color
were evaluated, and 180° peel strength and shear strength tests for measuring adhesion of films were conducted. The results
showed that the wettability of water droplets and the carbonyl group concentration on the bamboo surface were increased significantly
by alkaline (pH 8 and 9) hydrogen peroxide treatments. There was only minor color variation and the outer wax layer of bamboo
was etched to form additional recesses after hydrogen peroxide treatment. It was also found that all hydrogen peroxide treatments
improved the adhesion of bamboo coating; bamboo treated with hydrogen peroxide at pH 7 showed the greatest improvement. The
enhanced adhesion was attributed to the mechanical interlocking of the film on the treated bamboo rather than to surface activation. 相似文献
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The objective of this study was to determine the technical feasibility of producing a structural composite from Calcutta bamboo.
The first article on surface characteristics published in this series addressed pH, buffer capacity, wetting, and surface
energy (Ahmad and Kamke 2003). In this paper, the physical and mechanical characteristics were considered for their variability
with respect to location along the length of the bamboo culm, nodes versus internodes section, and radial versus tangential
directions. The physical and mechanical characteristics were also compared to timber species commonly used in the manufacture
of structural composites. The characteristics studied were found to have some variability at different locations, sections,
and directions. Calcutta bamboo was found to have similar physical and mechanical characteristics to commercial timber species
in Malaysia and North America. 相似文献
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为优化木竹材超高压水射流切割加工工艺参数,以红橡木和竹地板为对象,采用正交试验法,研究磨料流速、切割压力、进给速度、靶距对水射流加工试件表面粗糙度的影响,探索优化工艺参数。利用扫描探针式三维表面形貌测定法测量试件切割面的表面粗糙度值,分析三维表面形貌图。结果表明:红橡木磨料射流的试验影响因素排序为CADB;竹地板磨料射流的试验影响因素排序为BCAD。红橡木和竹地板优化工艺参数为:进给速度为250 mm/s,磨料流速为35 kg/h,靶距3 mm,切割压力为310 MPa。在此加工工艺条件下切割材料表面粗糙度相对较小,加工所得材料品质较好。 相似文献