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1.
Prabir K. Ghosal Trishit Chakraborty Buddhadeb Bhattacharya Dipak K. Bagchi 《植物养料与土壤学杂志》2003,166(6):750-755
The Relative Agronomic Effectiveness (RAE) of rock phosphates as compared to water soluble Triple Super Phosphate was measured on direct, residual, and cumulative application of the P fertilizers in a field experiment with rice on an Oxic‐Rhodustalf in the eastern plateau region of India. The fertilizers were Morocco Rock Phosphate (MORP), Mussoorie Rock Phosphate (MRP), Partially Acidulated Rock Phosphate (PARP), and Triple Super Phosphate (TSP). The RAE of the rock phosphates were lower for direct application (54–80 %) and cumulative application (70–93 %) of P but roughly equal or larger for the residual effect (92–142 %) as compared to TSP. The P adsorption characteristic of the experimental soil conformed to the linear relationship of both Freundlich and Langmuir isotherm equation. The adsorption data when plotted according to Langmuir equation deviated from a single linear relationship at higher concentration (10 μg ml–1), thereby giving two adsorption maximum values ( 68.49 μg g–1 and 256.41 μg g–1) and binding energies ( 2.86 ml μg–1 and 0.089 ml μg–1) for the soil. Two populations of P adsorption site with widely different affinity for P probably existed in the soil. 相似文献
2.
The two-surface Langmuir equation was used to study P adsorption by 24 calcareous soils (pH 7.2-7.6; 0.8-24.2 per cent CaCO3) from the Sherborne soil series, which are derived from Jurassic limestone. High-energy P adsorption capacities (x″m) ranged from 140–345 μg P/g and were most closely correlated with dithionite-soluble Fe. Hydrous oxides therefore appear to provide the principal sites, even in calcareous soils, on which P is strongly adsorbed (x″m 6–51 ml/μg P). The low-energy adsorption capacities (x″m) ranged from 400–663 μg P/g and were correlated with organic matter contents and the total surface areas of CaCO3 but not with per cent CaCO3, pH, or dithionite-soluble Fe. Total surface areas of CaCO3 in the soils ranged from 4.0 to 8.5 m2/g soil. Low-energy P adsorption capacities agree reasonably with values (100 pg P/m2) for the sorption of phosphate on Jurassic limestones but phosphate was bonded much less strongly by soil carbonates (k″= 0.08–0.45 ml/μg P) than by limestones (k～10.0 ml/μg P). Low-energy P adsorption in these soils is tentatively ascribed to adsorption on sites already occupied by organic anions (and probably also by bicarbonate and silicate ions) which lessen the bonding energy of co-adsorbed P. 相似文献
3.
D.W. Anderson 《Geoderma》1977,19(1):11-19
Strip-mining and the construction of spoil banks composed of unweathered, clay loam textured, moderately calcareous glacial till has provided a model system for studying soil formation in the semi-arid grasslands of southern Saskatchewan. Revegetation of fresh spoils probably occurred within a year or two and includes many native and introduced grasses and herbs. On spoil banks 28–40 years old soluble salts, particularly sodium salts, had leached to considerable depth. Greater soluble cation contents in the surface horizons, as compared to 2.5–5 or 5–10-cm layers, indicated a cycling of these nutrients by vegetation. Nitrogen has accumulated at a rate of , organic carbon at a rate of , suggesting that organic-matter levels characteristic of regional soils could be accumulated in 250–350 years. Cation-exchange capacities increased with the accumulation of organic matter. The fractional composition and spectral properties of humic acids indicated that the humus of soils 28 years old was similar to that of the normal, regional soils. Carbonate weathering appears to be quite slow in grassland environments. 相似文献
4.
The earthworms Allolobophora catiginosa and Lumbricus rubellus were used to study the toxicity of 2,3,7,8-TCDD (dioxin) for earthworms. The earthworms were exposed to soil containing concentrations ranging from 0.05 to 5.0 μgg?1. No worms were killed or showed any other observable toxicological effects when exposed to concentrations up to 5 μg g?1 for 85 days in soil. The lethal threshold concentration for TCDD to earthworms falls between 5 and 10 μg g?1 in this study. In soils containing 0.05 μg g?1 earthworms accumulated TCDD up to 5 times the original soil concentration within 7 days. Worms were also exposed to TCDD on filter paper to study the behaviour of earthworms and the uptake of TCDD after surface contact. The earthworms did not avoid TCDD in their environment, indicating an indifference to it. No active penetration of TCDD into the body occurred where earthworms were exposed to surface concentrations. No indication was found of possible biological breakdown of TCDD on passing through the earthworm gut, although the search for metabolites was limited to the mono-, bi- and trichlorinated dioxins. There was a steady decrease (a T-value of 80–400 days) in the amount of TCDD recovered from worm-worked soil compared to soil without worms. 相似文献
5.
F.C. Greenhalgh 《Soil biology & biochemistry》1978,10(3):257-259
Three baiting techniques and a sieving technique were evaluated for the quantitative detection zof Phytophthora cinnamomi Rands. Baiting with seedlings of Lupinus angustifolius L. (blue lupins), cotyledons of Eucalyptus sieberi F. Muell. and pear fruits cv. Packham's Triumph, detected one chlamydospore introduced into 50 g of either sand or soil. Sieving detected one chlamydospore in 50 g sand and also in 5 g soil. In naturally-infested soil, diluted with a similar non-infested soil, P. cinnamomi was detected at dilutions of and by the sieving and the baiting techniques, respectively. In general, pears were the most satisfactory bait for the detection and isolation of P. cinnamomi. The potential of baiting techniques for estimating numbers of propagules of P. cinnamomi in naturally-infested soil is discussed. 相似文献
6.
In order to characterise the term microbial ?activity”? three different microbial populations belonging to a luvisol (I), a phaeozem (II) and a rendzina (III) were used for studying kinetic parameters such as substrate affinity, growth rate, yield and turnover time and the metabolic quotient of basal respiration. Glucose was used as a carbon source. Specific growth rate values (μ) varied between 0.0037 and 0.015 h?1 depending on soil type and glucose concentration and were far below the potential μmax. The calculated turnover time was 3–11 days, respectively. The yield coefficient was in the range between 0.37 and 0.53. The maximal uptake rate of glucose–C of soil population (II) was 0.041 g C g?1 biomass-C h?1. The determined affinity constant (Km) was 57 μg C g?1 soil. The affinity to glucose was higher for the glucose-mediated CO2 evolution with Km values of 15.2 and 17.5 than for the glucose uptake system itself. The observed qCO2 values of the basal respiration at temperature increments from 0 to 45° C were almost identical for the soils (I) and (II). The calulated Q10 lay in the range between 1.4 and 2.0. 相似文献
7.
The effect of previous P additions on commonly used sorption parameters was studied using four alkaline-calcareous soils of Greece, two Vertisols and two Entisols. Solution concentration and buffering capacity indices were significantly affected while sorption curves of the quantity of P removed from the solution (x/m) against final P solution concentration (c) were shifted to the right, towards the higher c concentration values. Different buffering indices (e.g. the slope of the Freundlich equation, the slope of the semi-logarithmic sorption curve of x/m against log c, the slope of the linear portion of the high c concentration range) showed an increasing trend with increasing previous P additions to the soils, with the exception of the slope of the tangent of the Freundlich equation at c = 1 μg P/ml. However, correction for the quantity of exchangeable P already present in the soil (q), resulted in an increasing trend for this parameter as well, while obviously it did not have any effect on the slopes of the linear portions of the sorption curves. Chemical changes, as for example the slow formation of insoluble Ca–P salts, could possibly explain the increased capacity of previously fertilized alkaline-calcareous soils to remove P from the experimental equilibration solution suggested by the increasing trend in the buffering indices of the present work. At any case, this effect should be taken into account, especially in studies where sorption parameters are related to various soil-plant characteristics with respect to P. 相似文献
8.
Isotherms for the sorption of inorganic phosphate (P) by hydrous ferric oxide gel (Fe gel) were described by a three-equation Langmuir sorption model. Each equation described sorption within a distinct concentration range or region (I, II, and III) of the overall isotherm. Regions I and II involved chemisorption, whereas region III involved a more physical sorption type. With increasing sorption time between 0.7 and 28.7 days, the extent of sorption in region I increased by more than 30%. In contrast, the extent of sorption in regions II and III remained essentially constant. An equation was developed, based on the change in the sorption maximum of region I (bI) with increasing sorption time, which described the change in solution P concentration with time. The increase in bI with time, evaluated by the closeness of fit of this relationship to experimental data, was found to depend on two factors: first, the extent to which P was chemisorbed, and this was affected by pH and ionic strength; second, the batch of Fe gel used. For two different levels of P addition, the proportion of sorbed P which remained extractable in 0.1M NaOH, decreased with increasing sorption time. After 30 days only 88% of the sorbed P remained NaOH-extractable. The data obtained indicated that the increasing chemisorption of P with increasing sorption time involves the diffusion of sorbed P into the bulk of the Fe gel particles. This concept is discussed in relation to mechanisms proposed by previous workers to explain the time-dependence of P sorption. 相似文献
9.
From concurrent data of stomatal conductance of sunlit leaves (Ci; mm s?1), leaf water potential (ψ; m), and net radiation (Rn; W m?2) we derive the empirical relationship: Stomatal conductances calculated using the above equation are compared with an independent data set. Canopy resistance derived from the above equation is used in a plant water balance equation to simulate diurnal evaporation fluxes for three days, and we compare the calculated fluxes with lysimeter observations for well-watered and water-stressed wheat. Canopy temperatures are additionally obtained from an energy balance equation and compared with infrared radiometer observations. Regression analysis of simulated and observed evaporation fluxes yields a correlation coefficient of 0.98 and a standard error of estimate of about 37 W m?2; while for the canopy temperatures the correlation coefficient is 0.98 and the standard error of estimates 1.04°C. Variation of canopy net photosynthesis with insolation, and leaf area index are also simulated and compared with observations. 相似文献
10.
Two dextrans of similar molecular weight (?2 × 106) but containing different structural linkages (B-215F: 95% α-1→ 6 and 5% α-1→ 3 and Polytran: 75% β-1→ 3 and 25% β-1→ 6) were adsorbed on Na-montmorillonite. Adsorption isotherms showed strong, H-2-type (high-affinity. Langmuir mono-layer adsorption) clay-dextran interactions for both polymers. Maximum adsorption of the Polytran dextran (60 clay) was 33 per cent greater than that of the B-512F dextran (44.5 clay) for comparative equilibrium systems. Stable clay-Polytran complexes containing up to 47% dextran were prepared. Excess Na2SO4 (0.1 m) did not affect the quantity of dextran adsorption by montmorillonite at the 15% dextran concentration. Acid hydrolysis and modified Pregl method-C analyses did not quantitatively recover adsorbed dextran from complexes containing more than 13 mg of dextran adsorbed per 100 mg of clay. Loss on ignition determinations were in good agreement with the difference measurements of dextran adsorption, suggesting that part of the C was expelled as something other than CO2 in the ignition determinations. The maximum adsorption segment for Polytran was much smaller than the individual molecule. In contrast, the maximum adsorption segment for the B-512F dextran appeared to be the same magnitude as the individual polymer molecule. Adsorption segment length was regarded as a manifestation of the relative proportions of primary and secondary alcohol groups of the molecules. 相似文献
11.
Yang Ruijia Tao Jie Huang Qiaoyun Tie Boqing Lei Ming Yang Yuan Du Huihui 《Journal of Soils and Sediments》2019,19(3):1319-1327
Purpose
Heavy metal and metalloid commonly coexist in soils and sediments, and interact frequently with various minerals. The coexistence of Sb and Cd is commonly observed in Sb mine area, but their co-adsorption behaviors to soil minerals still remain poorly understood. This study aimed to elucidate the co-adsorption characteristics of Cd(II) and Sb(III) by ferrihydrite (Fh) under anoxic condition.
Materials and methodsBatch experiments were performed to determine the sorption capacity of Cd(II) and Sb(III) in both single and binary systems. The major functional groups that were responsible for Cd(II) and Sb(III) sorption were determined by X-ray photoelectron spectroscopy (XPS), while the thermodynamic sorption mechanisms were elucidated using isothermal titration calorimetry.
Results and discussionCd(II) sorption on Fh increases with increasing pH levels (4–8) whereas Sb(III) sorption shows less variation with pH level variations. The Langmuir adsorption capacity is 55.54 mg/g for Cd(II) and 188.19 mg/g for Sb(III). In Cd–Sb binary systems, Cd(II) sorption is significantly diminished whereas Sb(III) uptake is close to single Sb(III) sorption. XPS indicates the Fe–OH groups are mainly responsible for the binding of Cd and Sb, possibly through the formation of inner-sphere complexes. This hypothesis is further confirmed by the positive entropy (ΔS) after Cd and/or Sb binding. A larger ΔS in the binary Cd–Sb titration than in their single titrations implies the formation of a ternary Fh–Sb–Cd complex, which results in a higher disorder of the sorption system.
ConclusionsThe presence of Sb(III) reduces Cd(II) sorption whereas Cd(II) has a negligible effect on Sb(III) sorption to ferrihydrite; moreover, Sb(III) and Cd(II) might form surface ternary complexes in binary systems. These new findings have important implications for predicting the sequestration, migration, and fate of Cd and Sb in soils.
相似文献12.
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Laboratory studies were conducted to investigate the nature of chemical equilibria of zinc in some acid soils of Himachal Pradesh (India). The results indicated that one of the chemical reactions controlling zinc ion activity in the ambient soil solution may be represented by the equation: Sequential extraction of 65Zn-equilibrated soils provided a measure of the intensity of its different forms and their relative contribution to the pool of potentially available zinc in such soils. Adsorption-desorption parameters have been derived from a quattitative treatment of these phenomena as defined by the Langmuir equation. A supply parameter, , integrating the combined effects of quantity, intensity and buffering capacity has been derived from the adsorption studies. A linear relationship between the supply parameter and cumulative desorption of applied zind in these soils has been noted. The desorption of zinc from these soils is an exponential process. The solubility relationship of zinc is expressed in terms of the theory of simultaneous equilibria of competitive chemical reactions which obviates the necessity of assuming a single physico-chemical model in predicting and relating the activity of zinc in the ambient soil solution and its surface reactivity on solid phases in the immediate vicinity of plant roots to its ultimate transport and uptake by plants. 相似文献
15.
Field experiments were conducted at two locations in the seleniferous region of northwestern India from 2001 to 2006 to evaluate the efficiency of four cropping systems in removing Se from contaminated soil containing 2843–4345 μg Se per kg in the surface layer (0–15 cm). Rapeseed (Brassica napus) followed by arhar (Cajanus cajan), sunn hemp (Crotalaria juncea) or cotton (Gossypium arboretum) and wheat (Triticum aestivum) followed by rice (Oryza sativa) were the four cropping systems. The total biomass generated by Brassica‐based systems ranged from 16 to 21 t/ha when harvested at maturity. Corresponding values for a wheat–rice sequence were 22–26 t/ha. Among the different crops at both the experimental sites, the highest Se content was recorded in leaves (157–209 mg/kg), grains (64–201 mg/kg) and stems (42–93 mg/kg) of Brassica and the lowest in the shoots (10–27 mg/kg), grains (5–13 mg/kg) and straw (13–20 mg/kg) of the rice crop. Except for S and P, concentrations of other nutrients (Zn, Cu, Mn and Fe) were not significantly affected by variations in the Se content of plants. Significant correlation coefficients were observed between Se and S (r = 0.838, P ≤ 0.001), Se and P (r = 0.817, P ≤ 0.001) at the peak flowering stage (n = 16), and r = 0.743, P ≤ 0.001 and r = 0.498, P ≤ 0.05, respectively, at the maturity stage (n = 16). Total Se removal through harvested biomass of rapeseed‐based cropping sequences varied from 716 to 1374 g/ha/yr at peak flowering and 736–949 g/ha/yr at the maturity stage. Corresponding values for a wheat–rice system were 435–492 and 370–517 g/ha/yr, respectively. The amount of Se recycled through leaf senescence ranged from 255 to 500 g/ha/yr for Brassica‐based cropping systems. In the wheat–rice system, Se addition through irrigation varied from 170 to 243 g/ha/yr and was three to four times more than that added in Brassica‐based systems. On completion of the phytoremediation experiments at site I, Se removal through harvested biomass at maturity was 1.7–5.1% of total Se in the soil down to a depth of 120 cm and 4.8–13.2% at site II. Analysis showed that Se losses under different crop rotations were 18.5–24.5% at site I and 21–33% at site II of total soil Se. Thus, at both sites 16–20% of total Se lost from the soil was unexplained. Results show that Brassica‐based cropping systems lead to significant reductions in Se capital of contaminated soil over 2–3 years. Although a long‐term commitment is required, adoption of Brassica‐based systems as a regular agricultural practice must lead to sustainable management of seleniferous soils. 相似文献
16.
《Communications in Soil Science and Plant Analysis》2012,43(15-16):1525-1543
Abstract Overwintering soil temperature may influence crop response to phosphorus (P) and indices of P availability in the humid, temperate, transitional climate of Tennessee. The effects of P fertilization and soil incubation temperature on sorghumsudangrass (Sorghum bicolor x S. Sudanese) grown on a Typic Hapludalf was investigated in a greenhouse study. In order to determine the effect of temperature on P availability, soils were incubated prior to cropping, at a constant temperature of 6°C or an average diurnal temperature of 24 and 36°C. Reagent grade Ca(H2PO4)2.H2O was used as the fertilizer source and applied at rates of 0, 10, 20, and 30 mg P kg‐1 for the first test and 0, 20, 40, 60, and 80 mg P kg‐ 1 for the second test. Critical P concentration in the shoots for optimum yield was found to be 1.3 mg g‐1, corresponding to soil solution and labile P concentrations of 5.5 μmol L‐1 and 167 μg g‐1, respectively. Optimum yield occurred for applications of >65 mg P kg‐1 and was unaffected by soil incubation temperature. Applied P rates affected extractable P by five chemical extractants (Bray I, Bray II, Mehlich I, Mehlich III, and Mississippi), but soil incubation temperature had no affect. The extractants, however, were poorly correlated to plant P uptake and no one extractant appeared preferable to the others as an indicator of P availability. 相似文献
17.
Callyn D. Yorke 《Biological conservation》1984,29(4):345-362
A study was made to determine the impact of a plantation of rubber trees Hevea brasiliensis and an adjacent suburban environment on birds inhabiting the western lowlands of peninsular Malaysia. Results from six consecutive censuses in January 1980 showed that the plantation exceeded the suburban area in bird species richness () and diversity (). Over a three-year period a total of 84 bird species was recorded in the plantation but only 25 species were found in the suburban area. Distribution of several bird species appeared to be influenced by local variation in tree density. Rubber tree plantations, and especially suburban areas, cause a drastic reduction in bird species richness where they replace lowland rainforest. 相似文献
18.
R.C. Mondal 《Geoderma》1973,9(1):35-41
Ground waters with electrical conductivity of 4.9–7.4 mmhos/cm, a pH of 7.7–8.8 and a Mg/Ca ratio of 0.8–41.5 were equilibrated with a Na-illite in the presence and absence of CaCO3. In the presence of CaCO3, exchangeable Ca, exchangeable and the exchangeable Ca/Mg of the equilibrated clay increased but exchangeable Mg and Na decreased. The pH values of the ground waters were positively correlated with (1) exchangeable Ca, (2) exchangeable , and (3) exchangeable Ca/Mg ratio, both in the presence and absence of CaCO3. 相似文献
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Amidase was extracted from a bacterium isolated from soil, and its properties were compared with those of amidase in soil. Amidase activity of the bacterial protein was lower than that of soil amidase, respectively, in its optimal pH (7.0 vs 8.5), optimal temperature (50 vs 60°C), Km constant calculated by the Lineweaver-Burk plot (5.6 vs 17.9 mm), activation energy (18.9 vs 43.3 kJmol?) and Q10 (av. = 1.28 vs 1.75). Bacterial amidase was stable at temperatures ranging from 10 to 50°C and denatured at 55°C. Toluene inhibited both bacterial and soil amidase.When the inhibitions by 21 trace elements were compared by using 2 μmol 0.1 mg?1 protein, the most effective inhibitors of bacterial amidase (> 25% inhibition) were: Ag(I), Cd(II), Cu(II), Hg(II), Ni(II), Pb(II), Zn(II), Al(III) and Se(IV). The effect of 16 pesticides on bacterial amidase varied considerably. By using 2 μg of active ingredient of pesticide 0.1 mg?1 protein, the inhibition of bacterial amidase ranged from 7 to 49% with Dinitroamine and Butylate, respectively. The results show that soil constituents have a considerable influence on the reaction catalyzed by this enzyme. 相似文献