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1.
Unmodified and acetylated cedar wood specimens were swollen in various liquids and dried under radial compression. Two stress
relaxation processes were observed during drying, and the second process observed below the fiber saturation point was responsible
for the drying-set and the temporary fixation of compressive deformation. The fixed shape of acetylated wood was partly recovered
by soaking it in water and toluene and completely recovered in acetone. The effective shape fixation and recovery of toluene-swollen
samples implied that the intermolecular hydrogen bonding was not necessary for the drying-set of acetylated wood. The degree
of shape recovery was not explained by initial softening, while the acetylated wood always exhibited greater recoverability
than unmodified wood. Although 85% stiffness was lost after large compression set and recovery of unmodified wood, such a
stiffness loss was limited to 39% when the acetylated wood was processed with organic liquids. This indicated that the swelling
of the hydrophobic region in the acetylated wood was effective in preventing mechanical damage due to large compressive deformation. 相似文献
2.
Wood specimens were prepared in a swollen state using solvent exchange (PS) treatment. The swollen wood specimens were acetylated
using acetic anhydride by heating at 80–120°C. At the beginning of heating, the weight percent gain (WPG) of PS-treated wood
was greater than that of conventionally acetylated wood. This acceleration effect of the PS treatment was explained by the
introduction of treating reagent into the wood polymers where the intermolecular hydrogen bonds were previously broken. On
the other hand, the PS treatment had no influence on the final WPG and moisture sorption characteristics of acetylated wood.
This indicated that the intrinsic reactivity of wood constituents was unaffected by the PS treatment. The acetylation of PS-treated
wood produced greater bulking and slightly higher dimensional stability than that in the case of conventional acetylation
at the same WPG. It was speculated that the expansion of cell lumina due to the PS treatment resulted in greater bulking on
acetylation and lesser swelling of acetylated wood with moisture sorption. 相似文献
3.
To investigate the affinity of acetylated wood for organic liquids, acetylated yezo spruce wood specimens were soaked in various liquids, and their swellings were compared to those of untreated specimens. The acetylated wood was rapidly and remarkably swollen in liquids having low hydrogen bonding power such as benzene and toluene in which the untreated wood was swollen only slightly or very slowly. On the other hand, the swollen volume of wood in water, ethylene glycol, and alcohols remained unchanged or slightly decreased after the acetylation. The effect of acetylation was greater in liquids having smaller solubility parameters. The easier penetration of aprotic organic liquids into the acetylated wood was considered to be due to the reduction of polarity and the scission of hydrogen bonds in the amorphous wood constituents where the hydrophilic hydroxyl groups were substituted by hydrophobic acetyl groups. 相似文献
4.
The radial compression behaviors of acetylated cedar wood were measured in various liquids. The compressive Young’s modulus
(E) of acetylated wood was reduced by soaking in water, toluene, and acetone, but it was always greater than that of water-swollen
unmodified wood at the same swelling level. The behaviors of acetone-swollen unmodified wood were similar to those of acetylated
wood rather than those of water-swollen unmodified wood. These results indicated that the swelling of hydrophobic wood components
had a lesser influence on the E of wood than the water-swelling of unmodified hydrophilic components. After large compression (ε > 45%), a part of the strain
remained unrecovered because of irreversible mechanical deformation. Since the remaining strain was smaller in the wood specimens
indicating greater stress relaxation, it was assumed that the viscoelastic deformation of amorphous matrix components is important
for lesser irreversible deformation and effective shape recovery of wood. In contrast with water-swollen unmodified wood,
the acetylated wood and acetone-swollen unmodified wood exhibited greater shape recovery despite their relatively higher E. This suggested that the swelling of hydrophobic wood components reduced the viscosity of the matrix rather than its elasticity,
resulting in more effective shape recovery with lesser softening. 相似文献
5.
Yuka Miyoshi Ai Sakae Nao Arimura Keisuke Kojiro Yuzo Furuta 《Journal of Wood Science》2018,64(2):157-163
In this study, to summarize the changes of thermal-softening behaviors of wood and acetylated wood due to differences in the kinds of swelling liquids, the following measurements were conducted. Untreated and acetylated wood samples were swollen by various liquids and the temperature dependences of the dynamic viscoelastic properties were measured after the heating and cooling histories were unified among the samples. The results obtained are as follows. Untreated samples swollen by high-polarity liquid had lower peak temperature of tanδ, however acetylated samples had higher peak temperature of tanδ than those of untreated wood. On the other hand, untreated wood samples swollen by low-polarity liquid had higher peak temperature of tanδ, however acetylated samples had lower peak temperature of tanδ than those of untreated wood. The amount of swelling is determined by interaction between wood and liquid due to proton-accepting power and molar volumes of liquid and so on, therefore the peak temperature of tanδ and degree of reduction in dynamic elastic modulus (E´) with increasing temperature were corresponded to the amount of swelling. 相似文献
6.
《Wood material science & engineering》2013,8(3-4):126-130
Abstract Three different mechanisms to explain the partial fixation of the compressive deformation of wood are postulated: non-softening, cross-linking and stress relaxation. This study attempted to fix the compressive deformation of wood by the non-softening mechanism of the cell-wall matrix using acetylation of the cell wall making it more hydrophobic. In this method, partial recovery of compressive deformation by wetting decreased at room temperature as the acetyl content increased. However, almost complete recovery occurred by boiling the compressed wood in water or soaking in acetone. This is due to the ability of boiling water or acetone to soften the cell-wall matrix of acetylated wood enough to enable recovery from compression. It is, therefore, possible to partially fix the compressive deformation of wood, preventing the resoftening of the cell-wall matrix in water. 相似文献
7.
采取清水浸泡、药物蒸煮、干燥和ＰＣ树脂浸渍处理等措施，对易裂难干、易发生翘曲变形、使用价值较低的枫香木材进行改性处理，可以显著降低其干缩差异，减少翘曲变形，实现均匀干燥．从而大大改善其加工性能和耐腐程度，提高利用价值．实践证明，以浸泡时间为６个月，蒸煮时间为４８ｈ，药量配比为１号药液：２号药液＝０．５％：１．５％进行改性处理的效果最为理想． 相似文献
8.
Five wood species were acetylated with acetic anhydride (AA) solution of glucose pentaacetate (GPA) at 120°C for 8h, and the effect of GPA on the dimensional stability of the acetylated wood was investigated. Some GPA was introduced into the wood cell wall during acetylation. The GPA remaining in the cell lumen penetrated the cell wall effectively after heating to more than 140°C for 10min. The bulking effects of GPA resulted in a 10%–30% increase in the anti-swelling efficiency of the acetylated wood with 20% GPA/AA solution in place of AA. Hydrophobic GPA did not deliquesce under highly humid conditions and it remained in the cell wall after boiling in water.Part of this paper was presented at the 51st Annual Meeting of the Japan Wood Research Society, Tokyo, April 1988 相似文献
9.
To investigate the influence of heating and drying history on the microstructure of dry wood, in addition to the dynamic viscoelastic
properties, CO2 adsorption onto dry wood at ice.water temperature (273 K) was measured, and the micropore size distribution was obtained
using the Horvath-Kawazoe (HK) method. Micropores smaller than 0.6 nm exist in the microstructures of dry wood, and they decreased
with elevating out-gassing temperature and increased again after rewetting and drying. Dry wood subjected to higher temperatures
showed larger dynamic elastic modulus (E′) and smaller loss modulus (E″). This is interpreted as the result of the modification at higher temperature of the instability caused by drying. Drying
history influenced the number of micropores smaller than 0.6 nm in dry wood not subjected to high temperature, although the
difference in the number of micropores resulting from the drying history decreased with increasing out-gassing temperature.
A larger number of micropores smaller than 0.6 nm exist in the microstructure of dry wood in more unstable states, corresponding
to smaller E′ and larger E″ than in the stable state. Consequently, unstable states are considered to result from the existence of temporary micropores
in the microstructures of dry wood, probably in lignin.
Part of this report was presented at the 55th Annual Meeting of the Japan Wood Research Society, Kyoto, March 2005, and at
the 56th Annual Meeting of the Japan Wood Research Society, Akita, August 2006 相似文献
10.
Viscoelastic properties of wood in swelling systems 总被引：2，自引：0，他引：2
T. Sadoh 《Wood Science and Technology》1981,15(1):57-66
Summary The torsion modulus and the mechanical damping were investigated on wood swollen with formamide and a series of glycols, at frequencies of 0.5 and 0.02 Hz as a function of temperature. In wood swollen with formamide to the same extent as it would swell when saturated with water, the temperature of maximum damping was about 48° and above 100°C for wood swollen with polyethylene glycols, while that of water saturated wood was 80°C. For more highly formamide swollen wood (1.2 times the swelling in water) the temperature at which maximum damping develops decreased to 30°C. With regard to the influence of swelling and temperature on the torsion modulus of wood, three regions of viscoelastic behavior were recognized in these swelling systems. They are the glassy region in non-swollen wood, where the torsion modulus decreases gradually with increasing temperature, the transition region where the torsion modulus decreases abruptly with increasing temperature and swelling, and a plateau region appearing at high temperatures for highly swollen wood where the torsion modulus remains fairly constant with temperature with a value of about one tenth the modulus for non-swollen wood. 相似文献
11.
Influence of heating history on dynamic viscoelastic properties and dimensions of dry wood 总被引：2，自引：2，他引：0
To obtain new information about the mechanical and physical properties of dry wood in unstable states, the influence of heating
history on viscoelastic properties and dimensional changes of dry wood in the radial, tangential, and longitudinal directions
was studied between 100° and 200°C. Unstable states of dry wood still existed after heating at 105°C for 30 min and were modified
by activated molecular motion in the first heating process to temperatures above 105°C. This phenomenon is thought to be caused
by the unstable states reappearing after wetting and drying again. Dry wood components did not completely approach the stable
state in the temperature range tested, because they did not entirely surpass the glass transition temperatures in most of
the temperature range. In constant temperature processes at 135° and 165°C, E′ increased and E″ decreased with time regardless of the direction. This indicated that the unstable states of dry wood components were gradually
modified with time at constant temperatures. On the other hand, anisotropy of dimensional change existed and dimension increased
in the longitudinal direction, was unchanged in the radial direction, and decreased in the tangential direction with time
at constant temperatures.
Part of this report was presented at the 13th Annual Meeting of the Chubu Branch of the Japan Wood Research Society, Shizuoka,
August 2003 相似文献
12.
This study examined how boiling and drying treatments influenced various physical properties of the tension wood with gelatinous
fibers (G-fibers) of a 29-yearold Zelkova branch. By boiling treatment, tension wood with numerous G-fibers contracted considerably in the longitudinal direction and
the longitudinal Young’s modulus decreased in spite of the water-saturated condition. The drying treatment caused green tension
wood and boiled tension wood with numerous G-fibers to shrink longitudinally and increased their longitudinal Young’s moduli.
These specific behaviors in tension wood were highly correlated with the proportion of G-fibers in a specimen and were probably
caused by the microscopic behavior of cellulose microfibril (CMF) in the gelatinous layers (G-layers). The longitudinal shrinkage
of tension wood due to drying suggests the existence of a hygro-sensible, noncrystalline region in the CMF, which is abundant
in the G-layer. Furthermore, the noncrystalline region in the CMF softens during boiling treatment, resulting in the reduction
of the longitudinal Young’s modulus in tension wood. The longitudinal contraction of tension wood with G-fibers by boiling
might be caused by the tensile growth stress remaining in green G-layers. However, no changes were detected in the 004 d-spacing of cellulose crystal in tension wood from the boiling and drying treatments, regardless of the proportion of G-fibers. 相似文献
13.
Strain development along radial direction was continuously determined by D—200Linear Variable Differential Transformers(L.V.D.T).When a wood specimen was put into waterand begin to swell from absolute dry moisture content to the maximum.Experiment results showthat the differences of swelling with soaking time between untreated and treated wood specimens dueto uptaking water.It would also give an indication to the effectiveness of various chemicals on thedimensional stability of modified wood.ASE of modified wood samples with SA-EP,EP and SA were found to be better than MA-AGE.SA-EP had got the best effetiveness on dimensional stabili-ty in reducing the swelling. 相似文献
14.
Brauns’ lignins present in the methanol extracts of fresh birch (Betula pendula) xylem and of sawn birch board subjected to vacuum drying were characterized by 1H and 13C NMR spectroscopy (1D and 2D), IR spectroscopy, gel permeation chromatography (GPC) and colour measurements (CIELab) in order to find out whether Brauns’ lignin could contribute to the colour change of sawn timber that occurred during vacuum drying. The two Brauns’ lignin samples contained about equal amounts of syringylpropane and guaiacylpropane units linked with β-O-4 and β–β side-chain structures. Molecular weight of the Brauns’ lignin of vacuum-dried birch board (acetylated: 5,200 g mol−1) was higher than that of the Brauns’ lignin of fresh birch wood (acetylated: 4,400 g mol−1). The Brauns’ lignin of vacuum-dried wood was also clearly darker and more prominently yellow and red;
between the Brauns’ lignin samples was 23.59. The differences in the molecular weights and colours suggest that the Brauns’ lignin underwent a chemical change during vacuum drying of the wood and that this change may have affected the colour of the wood. 相似文献
15.
Dynamic viscoelastic properties of wood acetylated with acetic anhydride solution of glucose pentaacetate 总被引：1，自引：0，他引：1
Spruce wood specimens were acetylated with acetic anhydride (AA) solutions of glucose pentaacetate (GPA), and their viscoelastic
properties along the radial direction were compared to those of the untreated and the normally acetylated specimens at various
relative humidities and temperatures. Higher concentrations of the GPA/AA solution resulted in more swelling of wood when
GPA was introducted into the wood cell wall. At room temperature the dynamic Young's modulus (E′) of the acetylated wood was enhanced by 10% with the introduction of GPA, whereas its mechanical loss tangent (tan δ) remained almost unchanged. These changes were interpreted to be an antiplasticizing effect of the bulky GPA molecules in
the wood cell wall. On heating in the absence of moisture, the GPA-acetylated wood exhibited a marked drop in E′ and a clear tan δ peak above 150°C, whereas the E′ and tan δ of the untreated wood were relatively stable up to 200°C. The tan δ peak of the GPA-acetylated wood shifted to lower temperatures with increasing GPA content, and there was no tan δ peak due to the melting of GPA itself. Thus the marked thermal softening of the GPA-acetylated wood was attributed to the
softening of wood components plasticized with GPA.
Received: March 29, 2002 / Accepted: May 21, 2002
Correspondence to:E. Obataya 相似文献
16.
Summary The instantaneous profile method was used to establish the boundary desorption curve of the effective water conductivity
function of red pine (Pinus resinosa Ait.) sapwood in the radial and tangential directions from nearly saturated to dry conditions at 18, 56 and 85 °C. The results
obtained demonstrate that the effective water conductivity is a function of moisture content, temperature, and direction of
flow. The effective water conductivity increases by several orders of magnitude (104–105) as moisture content increases from dry to nearly saturated conditions at a given temperature. The effective water conductivity
also increases by a factor varying between 10 and 50 as temperature rises from 18 to 85 °C in the moisture content range considered.
The variation of the moisture content–water potential relationship with temperature can explain part of the temperature effect.
The effective water conductivity was generally higher in the radial direction than in the tangential direction in a ratio
varying from about 1/1 to 3/1 depending on moisture content and temperature. Finally, the flux–gradient relationships obtained
at given moisture contents were found to be linear, confirming the validity of using a moisture flux equation considering
the water potential gradient as the driving force for the experimental conditions considered in the present work. The knowledge
of the effective water conductivity function and of the moisture content–water potential relationship allows the utilization
of a two-dimensional model of moisture movement in wood during drying using the gradient in water potential as the driving
force for drying at temperatures up to 85 °C.
Received 27 February 1998 相似文献
17.
Sub-alpine fir is characterized by its high proportion of wet pockets making it difficult to dry. Since it takes longer to
dry, mills experience reduced kiln productivity and increased energy consumption. High temperature drying (HTD) can be an
effective approach to accelerate the drying process. In this study, three drying schedules, namely, conservative (control),
HTD, and HTD and conservative combined (HTD/Cons), were evaluated when drying green sub-alpine fir 2″ × 4″ dimension lumber.
The results indicated that: (1) the drying rates in the HTD and HTD/Cons schedules were increased by 31–150% in comparison
to the drying rates obtained for the conservative schedule; (2) although drying stresses observed for the HTD schedule were
higher than those that were measured for the conservative schedule, no significant difference in drying stresses was found
between the HTD/Cons and conservative schedules; (3) warp was reduced in both HTD and HTD/Cons schedules; (4) neither the
HTD nor HTD/Cons schedule showed any significant reduction in modulus of rupture (MOR) and modulus of elasticity (MOE) when
compared to the values obtained for the conservative schedule. Diffusion coefficients during HTD for sub-alpine fir were determined
and it was found that diffusivity increases with temperature. A mathematical model describing the processes of heating and
drying under high temperatures was developed. The results of drying tests showed that the predicted drying curves by the model
satisfactorily agree with the experimental data. 相似文献
18.
3种不同处理方法对木材渗透性影响的研究 总被引：2，自引：0，他引：2
本文通过对长白鱼鳞云杉和臭冷杉生材分别进行普通气干处理和酒精置换处理以及对其气干材进行水浸处理,研究了这３种不同处理方法对木材气渗透性的影响及其影响机理。研究结果表明,长白鱼鳞云杉边材、心材和臭冷杉心村的生材经普通气干处理后,其气体渗透性较低,分别约为０．１１４、０．０４５和０．１１１ｄａｒｃｙ;长白鱼鳞云杉边材、心材和臭冷杉心材的生材经酒精置换处理后,其气体渗透性分别约为１１．７１３、０．０７４和０．１４４ｄａｒｃｙ,比普通气干处理对照组试样的平均渗透性分别增加约１０１．５倍、６２％和３０％,ｔ检验表明,前者差异非常显著,但后两者差异不显著;已气干１８个月的长白鱼鳞云杉边材、心材和臭冷杉心材经水浸处理后,其平均气体浸透性较处理前分别增加约８５％、４９％、６５．５％,ｔ检验表明差异均显著。长白鱼鳞云杉生材边材经 相似文献
19.
The influence of curing conditions on the chemical distribution in wood modified with thermosetting resins 总被引：1，自引：0，他引：1
Scots pine (Pinus sylvestris L.) sapwood was impregnated with aqueous solutions of phenol formaldehyde and methylated melamine formaldehyde resins and subsequently cured in an oven. One set of specimens was cured in plastic bags to avoid drying (wet curing) while another set of samples was heated and water was allowed to freely evaporate (dry curing). Macroscopic resin distribution was investigated using X-ray densitometry and infrared spectroscopy (FTIR-ATR). During dry curing, the resins migrated to the wood surface resulting in a gradient. Wet curing resulted in even distribution of the resins because it was immobilized due to condensation and precipitation in the wood. Neither densitometry nor FTIR-ATR was found to be generally applicable for investigating resin distribution in modified wood. Wet curing resulted in low cell wall bulking as compared to dry curing, probably because resin precipitated before drying. Storing impregnated wood prior to curing under non-drying conditions (“diffusion phase”) also reduced cell wall penetration and bulking. 相似文献
20.
《Wood material science & engineering》2013,8(2):87-92
Abstract The aim of the present work was to examine an advanced image-processing algorithm for moisture content (mc) calculation and also to use this algorithm to analyse moisture loss data for low temperature drying. Since wood starts to shrink below the fibre saturation point during drying, the geometrical shape of the wood piece will change. The dry wood image was thoroughly transformed to the shape of the wet wood image prior to calculating the dry weight mc. The results show that the algorithm for the dry weight mc on density data from the CT-scanning during low-temperature drying in the climate chamber is a powerful tool for analysing the moisture loss inside the wood piece. This method can make it possible to get a higher quality on the product. 相似文献