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1.
There are few reliable data sets to inspire confidence in policymakers that soil organic carbon (SOC) can be measured on farms. We worked with farmers in the Tamar Valley region of southwest England to select sampling sites under similar conditions (soil type, aspect and slope) and management types. Topsoils (2–15 cm) were sampled in autumn 2015, and percentage soil organic matter (%SOM) was determined by loss on ignition and used to calculate %SOC. We also used the stability of macroaggregates in cold water (WSA) (‘soil slaking’) as a measure of ‘soil health’ and investigated its relationship with SOC in the clay‐rich soils. %SOM was significantly different between management types in the order woodland (11.1%) = permanent pasture (9.5%) > ley‐arable rotation (7.7%) = arable (7.3%). This related directly to SOC stocks that were larger in fields under permanent pasture and woodland compared with those under arable or ley‐arable rotation whether corrected for clay content (F = 8.500, p < .0001) or not (F = 8.516, p < .0001). WSA scores were strongly correlated with SOC content whether corrected for clay content (SOCadj R2 = .571, p < .0001) or not (SOCunadj R2 = 0.490, p = .002). Time since tillage controlled SOC stocks and WSA scores, accounting for 75.5% and 51.3% of the total variation, respectively. We conclude that (1) SOC can be reliably measured in farmed soils using accepted protocols and related to land management and (2) WSA scores can be rapidly measured in clay soils and related to SOC stocks and soil management.  相似文献   

2.
Past land‐use changes, intensive cropping with large proportions of root crops, and preferred use of mineral fertilizer have been made responsible for proceeding losses of soil organic C (SOC) in the plough layer. We hypothesized that in intensive agriculturally managed regions changes in SOC stocks would be detectable within a decade. To test this hypothesis, we tracked the temporal development of the concentrations and stocks of SOC in 268 arable sites, sampled by horizon down to 60 cm in the Cologne‐Bonn region, W Germany, in 2005 and in 2013. We then related these changes to soil management data and humus balances obtained from farmers' surveys. As we expected that changes in SOC concentrations might at least in part be minor, we fractionated soils from 38 representative sites according to particle size in order to obtain C pools of different stability. We found that SOC concentrations had increased significantly in the topsoil (from 9.4 g kg?1 in 2005 to 9.8 g kg?1 in 2013), but had decreased significantly in the subsoil (from 4.1 g kg?1 in 2005 to 3.5 g kg?­1 in 2013). Intriguingly, these changes were due to changes in mineral‐bound SOC rather than to changes in sand‐sized organic matter pools. As bulk density decreased, the overall SOC stocks in the upper 60 cm exhibited a SOC loss of nearly 0.6 t C (ha · y)?1 after correction by the equivalent soil mass method. This loss was most pronounced for sandy soils [?0.73 t SOC (ha · y)?1], and less pronounced for loamy soils [?0.64 t SOC (ha · y)?1]; silty soils revealed the smallest reduction in SOC [?0.3 t SOC (ha · y)?1]. Losses of SOC occurred even with the overall humus balances having increased positively from about 20 kg C (ha · y)?1 (2003–2005) to about 133 kg C (ha · y)?1 (2005–2013) due to an improved organic fertilization and intercropping. We conclude that current management may fail to raise overall SOC stocks. In our study area SOC stocks even continued to decline, despite humus conservation practice, likely because past land use conversions (before 2005) still affect SOC dynamics.  相似文献   

3.
Agricultural soil CO2 emissions and their controlling factors have recently received increased attention because of the high potential of carbon sequestration and their importance in soil fertility. Several parameters of soil structure, chemistry, and microbiology were monitored along with soil CO2 emissions in research conducted in soils derived from a glacial till. The investigation was carried out during the 2012 growing season in Northern Germany. Higher potentials of soil CO2 emissions were found in grassland (20.40 µg g?1 dry weight h?1) compared to arable land (5.59 µg g?1 dry weight h?1) within the incubating temperature from 5°C to 40°C and incubating moisture from 30% to 70% water holding capacity (WHC) of soils taken during the growing season. For agricultural soils regardless of pasture and arable management, we suggested nine key factors that influence changes in soil CO2 emissions including soil temperature, metabolic quotient, bulk density, WHC, percentage of silt, bacterial biomass, pH, soil organic carbon, and hot water soluble carbon (glucose equivalent) based on principal component analysis and hierarchical cluster analysis. Slightly different key factors were proposed concerning individual land use types, however, the most important factors for soil CO2 emissions of agricultural soils in Northern Germany were proved to be metabolic quotient and soil temperature. Our results are valuable in providing key influencing factors for soil CO2 emission changes in grassland and arable land with respect to soil respiration, physical status, nutrition supply, and microbe-related parameters.  相似文献   

4.
Landuse can alter soil organic carbon (SOC) fractions by affecting carbon inflows and outflows. This study evaluated changes in SOC fractions in response to different landuses under variable rainfalls. We compared cropland, grassland and forest soils in high rainfall (Islamabad ~1142 mm) and low rainfall (Chakwal ~667 mm) areas of Pothwar dryland, Pakistan. Forest soils in both rainfall areas had highest SOC (11.32 g kg?1), particulate organic carbon (POC, 1.70 g kg?1), mineral-associated organic carbon (MOC, 7.17 g kg?1) and aggregate-associated organic carbon (AOC, 7.86 g kg?1). However, in rangeland and cropland soils, these varied with rainfall. Under high rainfall, SOC and MOC were 12% and 17% higher in rangeland than in cropland while POC and AOC were equal. Under low rainfall, SOC and MOC were higher in rangeland than in cropland by 7.21 and 1.79 g kg?1 at 0–15 cm and equal at 15–30 cm depth. POC and AOC were higher in rangeland than in cropland, in both depths. Averagely, SOC, POC, MOC and AOC were 26%, 68%, 76% and 30% higher in high rainfall than in low rainfall soils. Sensitivity of SOC fractions to landuses observed under different rainfalls could provide useful information for soil management in subtropical drylands.  相似文献   

5.
Land use change (LUC) is known to have a large impact on soil organic carbon (SOC) stocks. However, at a regional scale, our ability to explain SOC dynamics is limited due to the variability generated by inconsistent initial conditions between sample points, poor spatial information on previous land use/land management history and scarce SOC inventories. This study combines the resampling in 2003–2006 of an extensive soil survey in 1950–1960 with exhaustive historical data on LUC (1868–2006) to explain observed changes in the SOC stocks of temperate forest soils in the Belgian Ardennes. Results from resampling showed a significant loss of SOC between the two surveys, associated with a decrease in variability. The mean carbon content decreased from 40.4 to 34.5 g C kg?1 (10.6 to 9.6 kg C m?2), with a mean rate of C change (ΔSOC) of ?0.15 g C kg?1 year?1 (?0.023 kg C m?2 year?1). Soils with high SOC content tended to loose carbon while conversely soils with low SOC tended to gain carbon. Land use change history explained a significant part of past and current SOC stocks as well as ΔSOC during the last 50 years. We show that the use of spatially explicit historical data can help to quantitatively explain changes in SOC content at the regional scale.  相似文献   

6.
Grassland management aimed at enhancing carbon (C) in soil is an important tool in mitigation of rising atmospheric CO2, yet little is known of how grassland soil C changes with livestock stocking rate (SR). We relate soil organic and inorganic C mass (t ha−1 to 60 cm depth) with cattle stocking over periods of 7–27 year for 32 paddocks distributed across nine community pastures in the mixed-grass prairie of Saskatchewan, Canada. Initial analysis comparing Akaike information criterion models showed that cattle SR explained a greater proportion of variance in soil C, particularly soil organic C, than rainfall. Soil organic C mass increased with cattle SR (R2 = .293; p = .001), even when the latter was normalized to account for differences in vegetation composition and growing conditions among pastures. Normalized SR varied from 0.49 to 2.30 times recommended levels, over which SOC increased from 24.7 to 57.4 t ha−1. Increases in soil organic C under greater stocking coincided with increased abundance of introduced vegetation, particularly the rhizomatous grass Poa pratensis. Inorganic soil C accounted for 34.6% of total soil C, being particularly large below 30 cm soil depth, but did not vary with stocking rate. These findings indicate that both organic and inorganic C are important pools of C in northern temperate grassland soils, with soil organic C positively associated with long-term cattle SR. Further studies are recommended to understand more fully the mechanisms regulating grazing impacts on soil C mass in northern temperate grasslands.  相似文献   

7.
Dynamic changes in soil organic carbon (SOC) have become a popular topic in global research on organic carbon as part of the increasing attention being paid to food security and reducing greenhouse gas emissions. In this paper, the semiarid regions of China were selected as a research focus, and SOC data from 1980 to 2015 were analysed using IBM SPSS Statistics 20.0 software. SOC in farmland varied according to cultivated land type, mulching material type and planting method in the studied regions. The SOC content is 10.3–10.8 g kg−1 in supplementally irrigated land and flat dry land, 7.1–8.7 g kg−1 in terraced dry land and river beach land, and 6.2–6.4 g kg−1 in sloping dry land. The SOC content increased to 16.1–17.4 g kg−1 when crop stalks were used as mulch. The increase was only 11.5–13.5 g kg−1 in soils mulched with film or sandstone. The SOC value in wheat, maize and potatoes sown on single or double ridges was 2.4%–3.2%, 35.7%–36.4% and 4.4%–4.8%, respectively, which are higher than the values for wheat, maize and potatoes sown using the flat planting method. The SOC sequestering potential also varied according to the previously noted factors and was improved from 224.1% to 383.8% depending on cultivated land type, from 96.5% to 182.3% depending on mulching material type and from 96.1% to 191.3% depending on planting method. The SOC sequestering potential can be improved by 453.2%–757.4% with the integration of the optimal cultivated land type, mulching material type and planting method. Thus, there is substantial soil carbon sequestration potential in China's semiarid regions.  相似文献   

8.
We evaluated the contents of organic carbon (Corg) of Ap horizons from 11 North German study areas along a Southeast to Northwest precipitation gradient with respect to their general levels and as related to C : N ratio, soil texture (clay content), bulk soil density, climate, and historical land‐use since 1780. The focus was on sandy soils, with the largest group of samples originating from 308 km2 of the Fuhrberg catchment north of Hannover/Lower Saxony. Data from loess areas were used for comparisons. Major aims were (1) to quantify current Corg stocks, (2) to provide data on site‐specific, steady‐state Corg levels in old arable soils, and (3) to identify the main controls of Corg levels in the studied sands. The mean Corg content in sandy, well‐drained, old Ap horizons (uplands, > 200 years under cultivation, near steady‐state) increased with precipitation from < 8 g kg—1 in the dry eastern parts of the study area (530 mm year—1, 8.3°C) to 25 g kg—1 in the moist Northwest (825 mm year—1, 8.4°C). The Corg levels in lowlands which have been drained for more than 40 years were approximately 3 g kg—1 higher than those of uplands under a similar climate. The factor clay content had no predictive value because low contents were associated with high Corg levels. Large proportions of refractory organic matter in sands resulting from specific features of historical land‐use and soil development (calluna heathland, heath plaggen fertilization, podzolization) appeared to be the most probable reason for such high Corg levels. However, the high Corg levels of these old arable sites were still exceeded by those of younger arable areas formerly under continuos grassland. A chrono‐sequence suggested that a period of about 100 years is necessary until a new steady‐state Corg level is established after conversion of grassland into arable land. Elevated Corg levels in current Ap horizons were also found for former woodland and heathland soils. The main conclusion is that sands can contain a lot of stable organic matter, sometimes more than finer textured soils.  相似文献   

9.
ABSTRACT

Soil fertility in many parts of the north?western Himalayan region (NWHR) has declined owing to accelerated nutrient mining under existing crop regime. Therefore, this study aimed to assess effect of the predominant horticulture?based land uses on soil fertility and health in mid and high hills of NWHR. Soil samples (0?20 cm) were collected, analyzed for different soil chemical attributes (pH, electrical conductivity, organic C, available primary-, secondary-, and micro-nutrients), and compared across five key land uses: perennial grass (PG), peach orchard (PO), apple orchard (AO), field vegetable farming (VF), and protected vegetable farming (PV). Soils of the investigated land uses were neutral to near neutral in soil reaction (6.3?6.8) except field vegetable and protected vegetable farming. Amount of soil organic C and labile organic C was significantly higher (p ≤ 0.05) in soils of apple orchards (18.6 g kg?1 and 687.3 mg kg?1, respectively) and peach orchards (20.4 g kg?1 and 731.3 mg kg?1, respectively) over others. An abrupt and significant increase in Olsen-P was recorded in soils of field vegetable farming (17.1 mg kg?1) and protected vegetable farming (13.0 mg kg?1), which shifted their nutrient index (NI) of P in to high category (≥ 2.33). The concentration of mineralizable-N in soil was statistically at par in soils under perennial grass and fruit orchards, while protected vegetable farming showed maximum soil mineralizable-N content (115.5 mg kg?1) and NI of nitrogen (1.83). The NI was in high category (≥ 2.33) for copper, iron, and manganese in majority of the land uses. In view of the results, temperate fruit?tree based land uses are benign in up?keeping soil fertility and soil health, and needs promotion on large scale. Additionally, policies to create incentives for the build-up of soil organic matter and replenishment of the depleted soil macro and micro nutrients in vegetable-farmed lands are warranted.  相似文献   

10.
基于GIS的亚热带典型地区土壤有机碳空间分布预测   总被引：19，自引：4，他引：19  
Spatial distribution of organic carbon in soils is difficult to estimate because of inherent spatial variability and insufficient data. A soil-landscape model for a region, based on 151 samples for parent material and topographic factors, was established using a GIS spatial analysis technique and a digital elevation model (DEM) to reveal spatial distribution characteristics of soil organic carbon (SOC). Correlations between organic carbon and topographic factors were analyzed and a regression model was established to predict SOC content. Results for surface soils (0-20 cm) showed that the average SOC content was 12.8 g kg-1, with the SOC content between 6 and 12 g kg-1 occupying the largest area and SOC over 24 g kg-1 the smallest. Also, soils derived from phyllite were the highest in the SOC content and area, while soils developed on purple shale the lowest. Although parent material, elevation, and slope exposure were all significant topographic variables (P < 0.01), slope exposure had the highest correlation to SOC content (r = 0.66). Using a multiple regression model (R2 = 0.611) and DEM (with a 30 m × 30 m grid), spatial distribution of SOC could be forecasted.  相似文献   

11.
The major aim of this study was to evaluate how the pool size of slowly mineralizable, ‘old’ soil organic N can be derived from more easily accessible soil and site information via pedotransfer functions (PTF). Besides modeling, this pool size might be of great importance for the identification of soils with high mineralization potential in drinking‐water catchments. From long‐term laboratory incubations (ca. 200 days) at 35 °C, the pool sizes of easily mineralizable organic N (Nfast), mainly in fresh residues, and slowly mineralizable, ‘old’ soil organic N (Nslow) as well as their first‐order rate coefficients were obtained. 90 sandy arable soils from NW Germany served to derive PTFs for Nslow that were evaluated using another 20 soils from the same region. Information on former land‐use and soil type was obtained from topographical, historical, and soil maps (partly from 1780). Pool size Nslow very strongly depends on soil type and former land‐use. Mean pool sizes of Nslow were much lower in old arable lowland (105 mg N kg–1) than upland soils (175 mg N kg–1) possibly due to lower clay contents. Within lowlands, mean pool sizes in former grassland soils (245 mg N kg–1) were 2 to 3 times larger than in old arable soils due to accumulation of mineralizable N. In contrast, mean pool sizes of Nslow were lowest in recently cleared, former heath‐ and woodland (31 mg N kg–1) as a result of the input of hardly decomposable organic matter. Neither N nor C in the light fraction (density < 1.8 g cm–3) was adequate to derive pool size Nslow in the studied soils (r2 < 0.03). Instead, Nslow can be accurately (r2 = 0.55 – 0.83) derived from one or two basic soil characteristics (e.g. organic C, total N, C : N, mineral fraction < 20 μm), provided that sites were grouped by former land‐use. Field mineralization from Nslow during winter (independent data set) can be predicted as well on the basis of Nslow‐values calculated from PTFs that were derived after grouping the soils by former land‐use (r2 = 0.51***). In contrast, using the PTF without soil grouping strongly reduced the reliability (r2 = 0.16).  相似文献   

12.
Reclamation of disturbed soils is done with the primary objective of restoring the land for agronomic or forestry land use. Reclamation followed by sustainable management can restore the depleted soil organic carbon (SOC) stock over time. This study was designed to assess SOC stocks of reclaimed and undisturbed minesoils under different cropping systems in Dover Township, Tuscarawas County, Ohio (40°32·33′ N and 81°33·86′ W). Prior to reclamation, the soil was classified as Bethesda Soil Series (loamy‐skeletal, mixed, acid, mesic Typic Udorthent). The reclaimed and unmined sites were located side by side and were under forage (fescue—Festuca arundinacea Schreb. and alfa grass—Stipa tenacissima L.), and corn (Zea mays L.)—soybean (Glycine max (L.) Merr.) rotation. All fields were chisel plowed annually except unmined forage, and fertilized only when planted to corn. The manure was mostly applied on unmined fields planted to corn, and reclaimed fields planted to forage and corn. The variability in soil properties (i.e., soil bulk density, pH and soil organic carbon stock) ranged from moderate to low across all land uses in both reclaimed and unmined fields for 0–10 and 10–20 cm depths. The soil nitrogen stock ranged from low to moderate for unmined fields and moderate to high in some reclaimed fields. Soil pH was always less than 6·7 in both reclaimed and unmined fields. The mean soil bulk density was consistently lower in unmined (1·27 mg m−3 and 1·22 mg m−3) than reclaimed fields (1·39 mg m−3 and 1·34 mg m−3) planted to forage and corn, respectively. The SOC and total nitrogen (TN) concentrations were higher for reclaimed forage (33·30 g kg−1; 3·23 g kg−1) and cornfields (21·22 g kg−1; 3·66 g kg−1) than unmined forage (17·47 g kg−1; 1·98 g kg−1) and cornfield (17·70 g kg−1; 2·76 g kg−1). The SOC stocks in unmined soils did not differ among forage, corn or soybean fields but did so in reclaimed soils for 0–10 cm depth. The SOC stock for reclaimed forage (39·6 mg ha−1 for 0–10 cm and 28·6 mg ha−1 for 10–20 cm depths) and cornfields (28·3 mg ha−1; 32·2 mg ha−1) were higher than that for the unmined forage (22·7 mg ha−1; 17·6 mg ha−1) and corn (21·5 mg ha−1; 26·8 mg ha−1) fields for both depths. These results showed that the manure application increased SOC stocks in soil. Overall this study showed that if the reclamation is done properly, there is a large potential for SOC sequestration in reclaimed soils. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

13.
Wang  Mengzi  Wang  Shanyun  Long  Xien  Zhuang  Linjie  Zhao  Xue  Jia  Zhongjun  Zhu  Guibing 《Journal of Soils and Sediments》2019,19(3):1077-1087
Purpose

Ammonia oxidation is the limiting step in soil nitrification and critical in the global nitrogen cycle. The discovery of ammonia-oxidizing archaea (AOA) has improved our knowledge of microbial mechanisms for ammonia oxidation in complex soil environments. However, the relative contributions of AOA and ammonia-oxidizing bacteria (AOB) to ammonia oxidation remain unclear.

Materials and methods

In this study, through large geographical scale sampling in China, totally nine samples representing various types of arable land soils were selected for analyzing the ammonia oxidation activity. The AOA and AOB activities were separately determined by using the dicyandiamide and 1-octyne inhibition method. High-throughput pyrosequencing and DNA stable-isotope probing (DNA-SIP) analysis were applied to investigate the distribution and activity of Candidatus Nitrosocosmicus franklandus in the arable land soils.

Results and discussion

In this study, AOA abundance (3.2?×?107–3.4?×?109 copies g?1) and activity (0.01–1.33 mg N kg?1 dry soil day?1) were evaluated for nine selected arable land soils and accounted for 4–100% of ammonia oxidation. By separately determining AOA and AOB rates, we observed that archaeal ammonia oxidation dominated the ammonia oxidation process in six soils, revealing a considerable contribution of AOA in ammonia oxidation in arable land soils. Based on high-throughput pyrosequencing analysis, the AOA species Ca. N. franklandus with relatively low abundance (0.6–13.5% in AOA) was ubiquitously distributed in all the tested samples. Moreover, according to the DNA-SIP analysis for Urumqi sample, the high activity and efficiency of Ca. N. franklandus in using CO2 suggests that this species plays an important role in archaeal ammonia oxidation in arable land soils.

Conclusions

Through determining the AOA activity and analyzing the potential predominant functional AOA species, this study greatly improves our understanding of ammonia oxidation in arable land soils.

  相似文献   

14.
Sustainable soil management requires reliable and accurate monitoring of changes in soil organic matter (SOM). However, despite the development of improved analytical techniques during the last decades, there are still limits in the detection of small changes in soil organic carbon content and SOM composition. This study focused on the detection of such changes under laboratory conditions by adding different organic amendments to soils. The model experiments consisted of artificially mixing soil samples from non‐fertilized plots of three German long‐term agricultural experiments in Bad Lauchstädt (silty loam), Grossbeeren (silty sand), and Müncheberg (loamy sand) with straw, farmyard manure, sheep faeces, and charcoal in quantities from 3 to 180 t ha?1 each. In these mixtures we determined the organic carbon contents by elemental analysis and by thermal mass losses (TML) determined by thermogravimetry. The results confirmed the higher reliability of elemental analysis compared to TML for organic carbon content determination. The sensitivity of both methods was not sufficient to detect the changes in organic carbon content caused by small quantities of organic amendments (3 t ha?1 or 0.1–0.4 g C kg?1 soil). In the case of elemental analysis, the detectability of changes in carbon content increased with quantities of added amendments, but the method could not distinguish different types of organic amendments. On the contrary, the based on analysis of degradation temperatures, the TML allowed this discrimination together with their quantitative analysis. For example, added charcoal was not visible in TML from 320 to 330°C, which is used for carbon content determination. However, increasing quantities of charcoal were reflected in a higher TML around 520°C. Furthermore, differences between measured (with TML110–550) and predicted mass loss on ignition using both organic carbon (with TML330) and clay contents (with TML140) were confirmed as a suitable indicator for detection of organic amendments in different types of soils. We conclude that thermogravimetry enables the sensitive detection of organic fertilizers and organic amendments in soils under arable land use.  相似文献   

15.
Maintaining soil organic carbon (SOC) in arid ecosystem is important for soil productivity and restoration of deserted sandy soil in western plain of India. There is a need to understand how the cropping systems changes may alter SOC pools including total organic carbon (TOC), particulate organic C (POC), water soluble carbon (WSC), very labile C (VLC), labile C (LC), less labile C (LLC) and non-labile C (NLC) in arid climate. We selected seven major agricultural systems for this study viz., barren, fallow, barley–fallow, mustard–moth bean, chickpea–groundnut, wheat–green gram and wheat–pearl millet. Result revealed that conversion of sandy barren lands to agricultural systems significantly increased available nutrients and SOC pools. Among all studied cropping systems, the highest values of TOC (6.12 g kg?1), POC (1.53 g kg?1) and WSC (0.19 g kg?1) were maintained in pearl millet–wheat system, while the lowest values of carbon pools observed in fallow and barren land. Strong relationships (P < 0.05) were exhibited between VLC and LC with available nutrients. The highest carbon management index (299) indicates that wheat–pearl millet system has greater soil quality for enhancing crop productivity, nutrient availability and carbon sequestration of arid soil.  相似文献   

16.
Pig slurries are widely used on calcareous soils in European rainfed systems. Here we assess their impact on the amount of soil organic carbon (SOC) and on the composition of humic-type substances (HTS). Seven doses of slurry (five from fattening pigs and two from sows) ranging from 1.0 to 4.8 Mg ha−1 yr−1 of organic matter were evaluated after a period of 12 years and compared with mineral fertilizer treatment. At the end of the last annual cropping season (September), SOC was quantified, and HTS were isolated by alkaline extraction followed by acid precipitation, and studied by visible spectroscopy (800–400 nm) and Fourier-transformed infrared spectroscopy (4000–400 cm−1). Following the trend in the slurry organic matter applied rates, SOC increased from 9.5 g C kg−1 (mineral treatment) to 13.8 g C kg−1. This SOC increase was equivalent to c. 25.4% of the slurry organic carbon applied. The incorporation of aliphatic structures, mainly polyalkyl, from slurries into the HTS tends to modify the composition of the soil organic matter (SOM), which is reflected in a decrease in the intensity of FT-IR peaks related to aromatic structures. Despite the trend of significant increase in SOC with fattening slurries, mainly from the organic matter rate of 1.6 Mg ha−1 yr−1 (c. 185 kg N ha−1), the composition of the HTS showed an important aliphatic enhancement. The FTIR results showed that using exclusively the relative intensities of specific peaks (alkyl, carboxyl, aromatic and amide groups) as variables for the discriminant analysis, it is possible to identify HA between different groups of soils treated with progressive levels of slurry. Although the new aliphatic components could be considered important to improve soil physical quality, after the incorporation of additional SOM, the spectroscopic characteristics of HTS in soils treated with slurries suggested a weak effect in long-term C sequestration, as the newly incorporated OC forms are not qualitatively similar to the presumably stable native SOM. These potential changes in SOC and SOM composition at field level are constrained by the maximum allowed N rates from organic origin in some agricultural systems.  相似文献   

17.
Organic carbon (OC) is generally low in Alabama (U.S.A.) soils and varies considerably with cropping systems. Information on decomposition rates of the added C is a prerequisite to designing strategies that improve C sequestration in farming systems. Different models including exponential models have been used to describe OC mineralization in soils as well as to describe its potential as CO2 to be released into the environment. We investigated the decomposition of broiler litter added to ten non-calcareous soils (Appling, Troup, Cecil, Decatur, Sucarnoochee, Linker, Hartsells, Dothan, Maytag, and Colbert soils). A non-linear regression approach for N mineralization was used to estimate the potentially mineralizable OC pools (Co) and the first-order rate constant (k) in the soil samples. Results showed that the non-amended soils have distinct differences in their ability to release their native OC as CO2 and can be divided into four groups depending on their potentially mineralizable C (Co) and their ability to protect stable organic matter. Sucarnoochee soil represents the first group and contains a moderate amount of OC (11.4 g C kg−1) but had the highest Co (7.30 g C kg−1 soil). The second distinct group of soils has Co varying between 5.50 and 5.00 g C kg−1 soil (Decatur, Hartsells, Dothan, and Maytag). The third group has Co between 5.00 and 4.00 (Appling, Cecil, and Linker). The fourth group has Co less than 4.00 g C kg−1 soil (Troup and Colbert). Half-life of C remaining in non-amended soils varied from 26 days in Maytag soil to 139 days in Cecil soil. The OC in these non-amended soils represents a very stable form of organic C and thus, not easily decomposed by soil microorganisms. In the broiler litter-amended soils, the Co varied from 3.82 g C kg−1 in Appling soil amended with broiler litter 1-7.04 g C kg−1 soil in Maytag amended with broiler litter 2. Decomposition of the added OC proceeded in two phases with less than 31% decomposed in 43 days. Potentially mineralizable organic C (Co) was related to soil organic C (r = 0.661**) and soil C/N ratio (r = 0.819*).  相似文献   

18.
The concept of soil organic C (SOC) saturation suggests that the quantity of stable SOC is limited and determined by the amount of fine particles (clay + fine silt, Clay + fSilt). The difference between the theoretical SOC saturation value and the measured SOC one for the fine fraction corresponds to the soil’s saturation deficit and may represent the potential for SOC sequestration in a stable form. We calculate the saturation deficit of French arable soils based on the national soil test database and using the saturation equation. For the whole database (n = 1 454 633), the median saturation deficit was 8.1 gC/kg and this generally increased with the Clay + fSilt content to reach a maximum of 500 g/kg. National mapping of the SOC saturation deficit allowed investigation of spatial variation and controlling factors. Saturated soils were found in localities with specific land use (grassland, meadows) or farming systems (livestock production with high manure production). Smaller deficits occurred at higher altitudes, probably due to the combined effect of cooler temperature and the presence of meadows. Some very sandy soils appeared to be almost saturated, largely due to their very small fine fraction. Soils in the highly cultivated plains in the northern half of the country had a significant saturation deficit. Soils in the southern part of the country had the highest saturation deficit because of the combined effects of climatic factors (low production, high temperature) and land use (vineyards, orchards). Analysis of communal data revealed significant correlations at the national level with Clay + fSilt (r = 0.59), pH (r = 0.44) but also with the proportion of grassland in the cultivated area (r = ?0.47). Some areas had apparent oversaturation which may be due to uncertainty associated with the theoretical C saturation equation because of overestimation of the stable soil C fraction. Mapping the C saturation deficit at the national scale demonstrates the influence of climate, soil parameters and land use on the SOC stabilization potential and indicates that a significant proportion of agricultural soils have potential for further SOC storage.  相似文献   

19.
Switchgrass (Panicum virgatum L.) is a perennial biofuel crop with a high production potential and suitable for growth on marginal land. This study investigates the long-term planting effect of switchgrass on the dynamics of soil moisture, pH, organic carbon (SOC), total nitrogen (TN), nitrate nitrogen (NO3–-N) and ammonium nitrogen (NH4+-N) for soils to a depth of 90-cm in a sandy wasteland, Inner Mongolia, China. After crop harvesting in 2015, soil samples were collected from under switchgrass stands established in 2006, 2008, and 2009, native mixture, and a control that was virgin sand. Averaged across six layers, soil moisture and pH was significantly higher under the native mixture than switchgrass or virgin sand. However, SOC and TN were significantly higher under the 2006 switchgrass stand when compared with all other vegetation treatments and the control. The SOC and TN increased from 2.37 and 0.26 g kg?1, respectively, for 2009 switchgrass stand, and to 3.21 and 0.42 g kg?1, respectively, for 2006 switchgrass stand. Meanwhile, SOC and TN contents were 2.51 and 0.27 g kg?1, respectively, under the native mixture. The soil beneath switchgrass and native mixture showed the highest NO3–-N and NH4+-N, respectively. The soil moisture increased with depth while SOC, TN, and NO3–-N decreased. An obvious trend of increasing moisture, SOC, TN, and mineral N was observed with increasing switchgrass stand age. Thus, growing switchgrass on sandy soils can enhance SOC and TN, improve the availability of mineral N, and generate more appropriate pH conditions for this energy cropping system.  相似文献   

20.
Nuclear magnetic resonance (NMR) spectra were obtained for solid samples of whole soils from three long–term field sites at Rothamsted Experimental Station, UK. In all sites, soil organic matter content was either increasing or decreasing due to contrasted long–continued treatments. Two soils were from Highfield, one from under old grassland (47 g organic C kg?1) and one from an area kept as bare fallow following ploughing of grass 21 years previously (14 g organic C kg?1). Three soils were taken from Broadbalk, two from plots within the Broadbalk Continuous Wheat Experiment which had received no fertilizer or animal manure annually for 148 years (7 and 27 g organic C kg?1, respectively) and one from Broadbalk Wilderness, wooded section (38 g organic C kg?1). Broadbalk Wilderness was arable until 1881 and has reverted to deciduous woodland in the subsequent 110 years. Two soils were from Geescroft, one from an arable field (9 g organic C kg?1) and one from Geescroft Wilderness (35 g organic C kg?1) which began reversion to deciduous woodland at the same time as Broadbalk Wilderness but is now acid (pH = 4.2) in contrast to Broadbalk which is calcareous (pH = 7.3). Solid–state 13C NMR spectra were obtained on a 300–MHz instrument using cross polarization (CP) and magic angle spinning (MAS). All samples exhibited peaks in the following spectral regions: 0–45 ppm (alkyl), 45–60 ppm (methoxyl, carbohydrate and derivatives), 60–110 ppm (carbohydrates and derivatives, C–α of peptides), 110–160 ppm (aromatics) and 160–185 ppm (carboxyl groups and derivatives). Within the spectrum of a specific sample it was not possible to determine the relative proportions of soil organic carbon in the different forms identified because a range of factors can potentially alter the relative areas of peaks in different regions of the spectrum. However, from a comparison of relative peak areas within a set of soils from a given site, differing only in organic matter content, information can be deduced regarding the forms of C that are more or less subject to change in response to land use or management. At all sites carbohydrate C appears to be the form that is most subject to change, suggesting that it is an ‘active’ fraction compared with the other forms. It was greatest where organic matter inputs were greatest (due to inputs of farmyard manure or reversion to woodland) and declined relative to other forms following ploughing of old grassland. Alkyl C increased as total C accumulated but did not decline relative to other forms following ploughing of grass. One reason for the non–quantitative nature of the soil 13C CPMAS spectra was a short (approximately 1 ms) component of the rotating–frame TI relaxation time for H nuclei (T1pH). This problem was not overcome by acquiring data at – 60°C. In principle, solid–state spectra of soils obtained by direct polarization (i.e. without CP) might produce quantitative results, but the low C content of most mineral soils (10–50 g C kg?1) precludes this, given current instrumentation.  相似文献   

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