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用FTIR法研究木材阻燃剂FRW的阻燃机理 总被引：3，自引：0，他引：3
采用FTIR显微分析技术,对FRW阻燃处理红松木材限制燃烧固相产物的结构进行分析;采用GC_FTIR联机分析方法,对经FRW阻燃剂及其主要组分处理的紫椴木材试样的热解挥发性产物进行分析和鉴定;讨论FRW阻燃处理木材的热解炭化过程、阻燃剂的作用以及热解产物的结构特点。结果表明:FRW阻燃木材受热时,随着温度的升高,在FRW及其分解产物的催化下,木材逐步发生聚糖脱水、半纤维素脱乙酸、聚糖降解、木质素降解、木材热解产物聚合、脂肪族聚合物脱氧及芳构化等反应,最终炭化;FRW阻燃剂改变了木材的热解途径,并且显著降低了挥发性有机化合物的生成量。 相似文献
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酚类阻燃剂处理杉木热解过程的热动力学研究 总被引：8，自引：0，他引：8
抗流失阻燃剂是当前阻燃剂研究开发的一个重要方向。采用TG DTA热分析技术研究了酚类阻燃剂处理杉木热解过程各阶段的木炭产量和热动力学参数。结果表明 ,酚类阻燃剂阻燃处理杉木的产炭量因苯环上取代基不同而不同 ,其阻燃作用的大小顺序为 :氨基 >溴 >硝基。同时具有氮元素和溴元素的二溴硝基苯酚和二溴氨基苯酚的产炭量都大于相应的单取代苯酚衍生物。浸泡实验后 ,磷酸氢二铵的产炭损失率是二溴硝基苯酚的 5倍。阻燃处理后产炭量的增大总是对应于炭化阶段热解反应峰温降低、反应速率常数增大 ,但产炭量的增大程度与这些热动力学参数的改变是负相关的。因此 ,氮和溴的苯酚衍生物不仅对木材具有很强的阻燃作用 ,而且具有很强的抗浸泡能力 ,氮元素的阻燃作用与其在阻燃剂中的氧化态关系极大 ,氮和溴在木材阻燃中存在协同增效作用 ,阻燃处理对木材的吸湿性也有影响。 相似文献
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用热分析法研究木材阻燃剂FRW的阻燃机理 总被引：10，自引：2，他引：10
采用热重(TG)、微商热重(DTG)和差热(DTA)分析法，对木材阻燃剂FRW及其主要组分硼酸和磷酸脒基脲(GUP)、硼酸处理紫椴木材(BZ)、GUP处理紫椴木材(GZ)、FRW处理紫椴木材(FZ)以及未处理紫椴木材(UZ)进行了系统的热解行为研究。TG和DTG分析结果表明，当FRW受热达到分解温度时，其组分的热分解是独立的：硼酸在95和160℃依次分解为偏硼酸和三氧化二硼，GUP在180、285和385℃依次分解为聚磷酸胍(GPP)、聚磷酸铵(APP)和多聚磷酸(PPA)。用阻燃剂FRW及其组分处理的木材，其热解均不同于传统的木材热解模式，其中，BZ在较低的温度下(约165℃)即发生明显的失重，说明硼酸的阻燃机理除了传统理论认为的物理覆盖作用以外尚存在化学催化作用(催化脱水)；GUP处理使紫椴木材的最大失重速率出现的温度从375℃(uz)降到314℃(GZ)，同时失重率也显著降低，而成炭率升高；FZ的失重率低于其他处理材。此外，与各种药剂TG曲线之间的相互关系不同，FZ曲线不等于BZ曲线与GZ曲线的简单加和，这3条曲线相互交叉，预示着GUP与硼酸之间存在阻燃协同作用。DTA分析支持了上述结果。此外，BZ的DTA曲线在约425℃产生一个放热峰，说明硼酸的分解产物可能在高温下催化木材热解产物的芳构化。 相似文献
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木材阻燃剂FRW的阻燃机理 总被引：10，自引：2，他引：10
在综合分析热分析法、锥形量热仪法和FTIR法获得的FRW阻燃机理研究结果并吸收木材阻燃机理研究现有成果的基础上,推导进而提出了木材阻燃剂FRW的阻燃机理。其主要内容是:1)FRW阻燃木材受热时,阻燃剂FRW分解产生不燃性气体和不挥发的酸性熔融物质,具有降低体系温度和氧气浓度及屏蔽热辐射的作用,降低了木材的热解速度;2)FRW的组分硼酸和GUP的酸性分解产物催化木材脱水、降解,以及木材热解产物的缩合、聚合、芳构化等反应,能改变木材的热解途径并使其向着有利于炭化的方向变化,FRW显著的催化成炭作用,使阻燃木材的燃烧放热量大大降低,这是FRW阻燃机理的主要方面;3)硼酸与GUP起阻燃作用的温度和方式不同,并且有相互补充的作用,因而表现出阻燃协同效应。 相似文献
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用CONE法研究木材阻燃剂FRW的阻燃性能 总被引：29，自引：4，他引：29
利用锥形量热仪 (CONE)系统地测定了新型木材阻燃剂FRW的阻燃性能 ,讨论了FRW对阻燃木材在燃烧时的热释放、质量变化及耐点燃性的影响 ,并与Dricon阻燃剂进行了对比。结果表明 ,在 5 0kW·m2 的热辐射功率下 ,FRW阻燃处理木材的热释放速率 (RHR)和总热释放量 (THR)随FRW载药率的升高而降低 ,至载药率达到 10 %左右时 ,RHR及THR降低为未处理木材的 5 0 %左右 ,并且降低的趋势明显变缓 ;FRW与Dri con阻燃木材的有效燃烧热 (EHC)曲线基本重合 ,说明二者的阻燃机理类似 ;FRW阻燃木材的质量损失速率(MLR)曲线与RHR曲线相似 ,失重和热释放主要发生在有焰燃烧阶段 ;FRW阻燃处理能显著提高木材燃烧时的成炭率 ,但对木材的点燃时间影响不大 ;FRW与Dricon的阻燃效力相当 ,属高效木材阻燃剂。 相似文献
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用CONE法研究木材阻燃剂FRW的抑烟性能 总被引：21，自引：5，他引：21
采用锥形量热仪 (CONE)法系统地测定了新型木材阻燃剂FRW的抑烟性能 ,讨论了FRW对木材燃烧时发烟及烟气毒性的影响 ,并与Dricon阻燃剂进行了对比。结果表明 ,当热辐射功率为 5 0kW·m- 2 时 ,FRW阻燃处理木材的烟化率SR、比消光面积SEA、二氧化碳浓度CO2 及二氧化碳产率YCO2 比未处理木材显著降低 ;FRW阻燃处理对木材燃烧时一氧化碳的生成元显著影响 ;FRW与Dricon均具有很强的抑烟作用 ,二者的抑烟效力相当 相似文献
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该研究采用BL-阻燃剂溶液浸渍处理杨木单板,比较分析BL-阻燃杨木与未阻燃杨木的吸湿性和尺寸稳定性的影响。结果表明:①在不同的湿度条件下,阻燃处理后试件的吸潮率递增值明显高于未处理材。②BL-阻燃剂浓度越高的试件吸潮率也越高,相同浓度的试件在不同湿度中,湿度越高,其吸潮率也越高。③阻燃后杨木单板的尺寸变化率明显高于未处理材的,BL-阻燃剂具有较高的吸湿性,其对杨木单板尺寸稳定性的影响规律为:厚度弦向径向。 相似文献
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Marco Conedera Damiano TorrianiChristophe Neff Carlo RicottaSofia Bajocco Gianni Boris Pezzatti 《Forest Ecology and Management》2011,261(12):2179-2187
A comprehensive assessment of fire ignition danger is nowadays a basic step towards the prioritization of fire management measures. In this study we propose performing a fire selectivity analysis using Monte Carlo simulations to statistically estimate the relative fire ignition danger in a low-to-intermediate fire-prone region such as Canton Ticino, Switzerland. We define fire ignition danger as the likelihood that at a given place a fire will be ignited. For each 25 m × 25 m pixel of the study area, landscape characteristics that may be related to the probability of fire ignition such as vegetation type, elevation, aspect, slope, urban-forest interface were first split into 9-12 categories. The selectivity of each category with respect to fire ignition was then statistically tested by means of Monte Carlo simulations. Finally, we proposed two different approaches for calculating the ignition danger index: cumulating the scores of the Monte Carlo simulations to a final index or producing synthetic scores by performing a principal component analysis of the Monte Carlo results. The validation of the resulting fire danger indices highlights the suitability of both proposed approaches. The PCA-option allows a slightly better discrimination between ignition and non-ignition points and may be of more general application. 相似文献
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Characterization of forest fires in Catalonia (north-east Spain) 总被引：1，自引：0，他引：1
The present study analyses the temporal variation in the distribution of the number of fires, area burned and fire sizes in
Catalonia using fire data from 1942 to 2002. The study shows variations in the distribution of fire size over recent decades,
with a significant increase in the number of very large fires. The study also analyses relationships between characteristics
of the forest (altitude, slope, aspect, living fuels and species composition) and the probability of the fire occurrence.
The analysis is based on the overlay of forest cover data and perimeters of forest fires during the period (1986–2002). Of
the analysed variables, altitude affects most the probability of fire occurrence, with higher proportions of burned forest
area at lower altitudes. Stand’s vertical structure is also relevant, with lower proportions of burned area in stands with
mature tree cover without understory. The study helps to analyse the strengths and weaknesses of forest and fire management
policies, especially those related to forest and fuel management at the landscape level. 相似文献
14.
S.Sakellariou S.Tampekis F.Samara M.Flannigan D.Jaeger O.Christopoulou A.Sfougaris 《林业研究》2019,(2):589-601
Forest fire risk estimation constitutes an essential process to prevent high-intensity fires which are associated with severe implications to the natural and cultural environment. The primary aim of this research was to determine fire risk levels based on the local features of an island,namely, the impact of fuel structures, slope, aspects, as well as the impact of the road network and inhabited regions. The contribution of all the involved factors to forest fires ignition and behavior highlight certain regions which are highly vulnerable. In addition, the influence of both natural and anthropogenic factors to forest fire phenomena is explored. In this study, natural factors play a dominant role compared to anthropogenic factors. Hence essential preventative measures must focus on specific areas and established immediately. Indicative measures may include: the optimal allocation of watchtowers as well as the spatial optimization of mobile firefighting vehicles;and, forest fuel treatments in areas characterized by extremely high fire risk. The added value of this fire prediction tool is that it is highly flexible and could be adopted elsewhere with the necessary adjustments to local characteristics. 相似文献
15.
James K.Agee 《林业研究》1993,4(2):1-10
Forest fire history can be reconstructed over past centuries across a widevariety of forest types.Fire scars on living tress,and age classes of forest stands,are thetwo sources of information for these reconstructions.Point and area frequencies are usedto reconstruct fire history.Point frequencies are useful in forest types that burn withfrequent,low intensity fire so that many fire-scarred residual trees exist.A true point isa single tree,but more often point estimates are made by combining fire scar records fromseveral adjacent trees.Area frequences are applied where fires are infrequent but ofmoderate to high intensity,so that stand ages are used across wide areas to estimate firereturn interals.Proper selection and application of fire history methods are essential toderiving useful ecological implications from fire history studies.This review evaluates the common methods of determining fire history:what thetechniques are,where they are best applied,and how to interpret them in an ecologicalcontext.E 相似文献
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Shlomit Paz Yohay CarmelFaris Jahshan Maxim Shoshany 《Forest Ecology and Management》2011,262(7):1184-1188
The recent devastating wildfire on Mt. Carmel provided a unique opportunity to evaluate a fire-risk map constructed for the region, published two years ago in this journal. This largest forest fire in the history of Israel, occurred during December 2010, covering 2180 ha, burning more than half-million trees and causing the loss of life of 45 people.A study of fire risk in this area was conducted between 2007 and 2009 utilizing a combination of Monte Carlo simulation of spatial spread of fire ignition with fire behavior model (FARSITE). The fire risk map produced in 2009 is assessed here with reference to the area burnt during December 2010. The results showed that most of burnt areas corresponded to high risk levels in the risk map. According to a null model, the five lower risk levels taken together would have corresponded to 50% of the burnt area, while in fact they were presented in only 5.6% of the area. In contrast, the three highest risk levels, for which the null model expectation would be a representation of 30%, were represented in 87% of the area. Comparing the fire risk map against the map of the real recent fire provided support to the general approach, and strengthened the confidence of our fire risk model. 相似文献
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SHU Lifu TIAN XiaoruiResearch Institute of Forest Ecology Environment Protection. Chinese Academy of Forestry. Beijing China 《中国林业科技(英文版)》2002,(3)
China is not rich in natural forest sources. Owing to natural and historical factors, forest fires have long been frequenting China. Forest fire prevention is the most important of all. Forest fire prevention and controlling have long been held as a very important factor in our ecological plans. Taking china 's special geographical location, topography, climate and the distribution of forest sources into consideration, we have every reason to believe that forest fires in China have their own special environment and occurrence. China suffers forest fire hazards heavily. Forest fires arise occasionally from thunderstruck or self-burning of peat. However, most fires are due to man's fault while inappropriately using fires in production and daily life. Since China is located in the Northern Hemisphere with a vast territory, there is a striking difference in the climate between South China and North China. 相似文献
18.
防火林带树种筛选研究 总被引：5，自引：0，他引：5
防火林带树种筛选的研究是生物防火工作的重点内容之一。该文对浙江省绍兴地区木荷等18个常绿阔叶树种树叶的7个抗火性能相关指标(包括含水率、发热量、粗脂肪含量、苯-乙醇抽提物含量、燃点、粗灰分含量、叶燃烧速度)进行了测定和模糊聚类分析,认为木荷、杜英、红楠、金叶含笑和女贞等5个树种的抗火能力较强,可在浙江省绍兴地区适宜作为生物防火林带的首选树种加以推广。 相似文献
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Understanding the spatial pattern of fire is essential for Mediterranean vegetation management. Fire-risk maps are typically constructed at coarse resolutions using vegetation maps with limited capacity for prescribing prevention activities. This paper describes and evaluates a novel approach for fire risk assessment that may produce a decision support system for actual fire management at fine scales. FARSITE, a two-dimensional fire growth and behavior model was activated, using ArcView VBA code, to generate Monte Carlo simulations of fire spread. The study area was 300 km2 of Mt. Carmel, Israel. FARSITE fuel models were adjusted for Mediterranean conditions. The simulation session consisted of 500 runs. For each simulation run, a calendar date, fire length, ignition location, climatic data and other parameters were selected randomly from known distributions of these parameters. Distance from road served as a proxy for the probability of ignition. The resulting 500 maps of fire distribution (the entire area burnt in a specific fire) were overlaid to produce a map of ‘hotspots’ and ‘cold spots’ of fire frequency. The results revealed a clear pattern of fires, with high frequency areas concentrated in the northwestern part. The spatial pattern of the fire frequency map bears partial resemblance to the fuel map, but seems to be affected by several other factors as well, including the location of urban areas, microclimate, topography and the distribution of ignition locations (which is affected by road pattern). These results demonstrate the complexities of fire behavior, showing a very clear pattern of risk level even at fine scales, where neighboring areas have different risk levels due to combinations of vegetation cover, topography, microclimate and other factors. 相似文献