共查询到20条相似文献，搜索用时 15 毫秒
1.
Leveiller F Jacquemain D Lahav M Leiserowitz L Deutsch M Kjaer K Als-Nielsen J 《Science (New York, N.Y.)》1991,252(5012):1532-1536
A crystalline counterionic layer at the interface between an electrolyte solution and a charged layer of insoluble amphiphilic molecules was observed with grazing incidence synchrotron x-ray diffraction. Uncompressed arachidic films spread over 10(-3) molar cadmium chloride solution (pH 8.8) spontaneously form crystalline clusters with coherence lengths of approximately 1000 angstroms at 9 degrees C. Ten distinct diffraction peaks were observed, seven of which were attributed to scattering only from a crystalline Cd(2+) layer and the other three to scattering primarily from the arachidate layer. The reflections from the Cd(2+) layer were indexed according to a 2 x 3 supercell of the arachidate lattice with three Cd(2+) ions per cadmium unit cell. 相似文献
2.
Small-angle x-ray scattering curves from four different species of transfer RNA in solution indicate that the molecules are of very similar size and shape. A model which has regions of the molecule folded tightly around a long helical core gives good agreement with the observed scattering curves. 相似文献
3.
A simple system was developed for obtaining x-ray diffraction patterns from magnetically oriented solutions of macromolecular assemblies. A small permanent magnet was designed that produces a magnetic field of 16 kilogauss in a volume of 1 cubic millimeter and is mountable on most x-ray cameras. Many subcellular structures have sufficient diamagnetic anisotropy that they exhibit orientation in dilute solution when placed between the poles of the magnet. Diffraction from solutions oriented in this magnet can provide substantially more structural information than small-angle scattering from isotropic solutions. In favorable cases, such as dilute solutions of filamentous bacteriophages, it is possible to produce oriented fiber diffraction patterns from which intensities along layer lines can be measured to 7-angstrom resolution. The magnetically induced birefringence observed in solutions of other macromolecular assemblies suggests that this technique may have broad applicability to subcellular structures. 相似文献
4.
Cirtain JW Golub L Lundquist L van Ballegooijen A Savcheva A Shimojo M Deluca E Tsuneta S Sakao T Reeves K Weber M Kano R Narukage N Shibasaki K 《Science (New York, N.Y.)》2007,318(5856):1580-1582
Coronal magnetic fields are dynamic, and field lines may misalign, reassemble, and release energy by means of magnetic reconnection. Giant releases may generate solar flares and coronal mass ejections and, on a smaller scale, produce x-ray jets. Hinode observations of polar coronal holes reveal that x-ray jets have two distinct velocities: one near the Alfvén speed ( approximately 800 kilometers per second) and another near the sound speed (200 kilometers per second). Many more jets were seen than have been reported previously; we detected an average of 10 events per hour up to these speeds, whereas previous observations documented only a handful per day with lower average speeds of 200 kilometers per second. The x-ray jets are about 2 x 10(3) to 2 x 10(4) kilometers wide and 1 x 10(5) kilometers long and last from 100 to 2500 seconds. The large number of events, coupled with the high velocities of the apparent outflows, indicates that the jets may contribute to the high-speed solar wind. 相似文献
5.
The dispersion of longitudinal acoustic phonons was measured by inelastic x-ray scattering in the hexagonal closed-packed (hcp) structure of iron from 19 to 110 gigapascals. Phonon dispersion curves were recorded on polycrystalline iron compressed in a diamond anvil cell, revealing an increase of the longitudinal wave velocity (VP) from 7000 to 8800 meters per second. We show that hcp iron follows a Birch law for VP, which is used to extrapolate velocities to inner core conditions. Extrapolated longitudinal acoustic wave velocities compared with seismic data suggest an inner core that is 4 to 5% lighter than hcp iron. 相似文献
6.
The x-ray source GX 5-1 in the galactic bulge has been observed with the position-sensitive proportional counter onboard the R?ntgen satellite (ROSAT) during and after a lunar occultation. Extended emission around the source was unambiguously discovered while the central source was behind the lunar rim. This emission is interpreted as a dust-scattering halo around GX 5-1 that has a fractional intensity of 28 percent, implying a grain column density between GX 5-1 and Earth of approximately 3 x 10(10) per square centimeter. The halo derived from imaging during the ROSAT all-sky survey is identical to that obtained from the lunar occultation, thus demonstrating that the ROSAT x-ray mirror scattering has not changed as compared with the mirror properties as measured in preflight calibrations. 相似文献
7.
Diffraction of monochromatized synchrotron radiation by crystals of cesium hydrogen tartrate has been used to measure the magnitude and phase of x-ray scattering for cesium near the LIII absorption edge. In this wavelength region the scattering amplitude of cesium is reduced by as much as 25 electrons per atom, compared to scattering of copper Kalpha x-rays. This change, which varies as a function of wavelength, affects the diffraction intensities in a manner similar to isomorphous substitution, and it is large enough to have promise for phase determination in the study of macromolecular structures. This experiment also demonstrates that accurate diffractometer measurements are possible with synchrotron radiation produced by an electron storage ring. 相似文献
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9.
Synchrotron surface x-ray scattering (SXS) studies have been carried out at the Au(lll)/electrolyte interface to determine the influence of surface charge on the microscopic arrangement of gold surface atoms. At the electrochemical interface, the surface charge density can be continuously varied by controlling the applied potential. The top layer of gold atoms undergoes a reversible phase transition between the (1 x 1) bulk termination and a (23 x radical3) reconstructed phase on changing the electrode potential. In order to differentiate the respective roles of surface charge and adsorbates, studies were carried out in 0.1 M NaF, NaCl, and NaBr solutions. The phase transition occurs at an induced surface charge density of 0.07 +/- 0.02 electron per atom in all three solutions. 相似文献
10.
Walker HC Fabrizi F Paolasini L de Bergevin F Herrero-Martin J Boothroyd AT Prabhakaran D McMorrow DF 《Science (New York, N.Y.)》2011,333(6047):1273-1276
Magneto-electric multiferroics exemplified by TbMnO(3) possess both magnetic and ferroelectric long-range order. The magnetic order is mostly understood, whereas the nature of the ferroelectricity has remained more elusive. Competing models proposed to explain the ferroelectricity are associated respectively with charge transfer and ionic displacements. Exploiting the magneto-electric coupling, we used an electric field to produce a single magnetic domain state, and a magnetic field to induce ionic displacements. Under these conditions, interference between charge and magnetic x-ray scattering arose, encoding the amplitude and phase of the displacements. When combined with a theoretical analysis, our data allow us to resolve the ionic displacements at the femtoscale, and show that such displacements make a substantial contribution to the zero-field ferroelectric moment. 相似文献
11.
Small-angle x-ray scattering analyses of sodium humate solutions indicate either that particles of two or more different sizes exist in solution or that all of the particles are the same size but consist of a dense core and a less dense outer shell. Fractionation on a molecular sieve chromatographic column suggests that the first possibility is the more likely of the two. The radius of gyration and molecular weight of the larger particles are respectively 110 A and 1 x 10(6) and those of the smaller particles 38 A and 2.1 x 10(5). These particles are ellipsoidal. 相似文献
12.
A high-temperature plasma is created when an intense laser pulse is focused onto the surface of a solid. An ultrafast pulse of x-ray radiation is emitted from such a plasma when the laser pulse length is less than a picosecond. A high-speed streak camera detector was used to determine the duration of these x-ray pulses, and computer simulations of the plasmas agree with the experimental results. Scaling laws predict that brighter and more efficient x-ray sources will be obtained by the use of more intense laser pulses. These sources can be used for time-resolved x-ray scattering studies and for the development of x-ray lasers. 相似文献
13.
G Ghiringhelli M Le Tacon M Minola S Blanco-Canosa C Mazzoli NB Brookes GM De Luca A Frano DG Hawthorn F He T Loew M Moretti Sala DC Peets M Salluzzo E Schierle R Sutarto GA Sawatzky E Weschke B Keimer L Braicovich 《Science (New York, N.Y.)》2012,337(6096):821-825
The concept that superconductivity competes with other orders in cuprate superconductors has become increasingly apparent, but obtaining direct evidence with bulk-sensitive probes is challenging. We have used resonant soft x-ray scattering to identify two-dimensional charge fluctuations with an incommensurate periodicity of ~3.2 lattice units in the copper-oxide planes of the superconductors (Y,Nd)Ba(2)Cu(3)O(6+)(x), with hole concentrations of 0.09 to 0.13 per planar Cu ion. The intensity and correlation length of the fluctuation signal increase strongly upon cooling down to the superconducting transition temperature (T(c)); further cooling below T(c) abruptly reverses the divergence of the charge correlations. In combination with earlier observations of a large gap in the spin excitation spectrum, these data indicate an incipient charge density wave instability that competes with superconductivity. 相似文献
14.
Greaves GN Wilding MC Fearn S Langstaff D Kargl F Cox S Van QV Majérus O Benmore CJ Weber R Martin CM Hennet L 《Science (New York, N.Y.)》2008,322(5901):566-570
We combine small-angle x-ray scattering (SAXS) and wide-angle x-ray scattering (WAXS) with aerodynamic levitation techniques to study in situ phase transitions in the liquid state under contactless conditions. At very high temperatures, yttria-alumina melts show a first-order transition, previously inferred from phase separation in quenched glasses. We show how the transition coincides with a narrow and reversible maximum in SAXS indicative of liquid unmixing on the nanoscale, combined with an abrupt realignment in WAXS features related to reversible shifts in polyhedral packing on the atomic scale. We also observed a rotary action in the suspended supercooled drop driven by repetitive transitions (a polyamorphic rotor) from which the reversible changes in molar volume (1.2 +/- 0.2 cubic centimeters) and entropy (19 +/- 4 joules mole(-1) kelvin(-1)) can be estimated. 相似文献
15.
An x-ray survey of the Virgo region revealed signals from the directions of 3C 273 and M 87. Three other x-ray sources appear in the region scanned, but do not fit any known radio sources. The x-ray flux (1 to 10 angstroms) from the direction of 3C 273 is about 1000 times weaker than from the strongest x-ray source, Sco XR-1. If the source is located at the cosmological distance of 500 megaparsecs, the x-ray luminosity is 7.3 x 10(45) ergs per second. The x-ray luminosity of M87 is 1.5 x 10(43) ergs per second. 相似文献
16.
Clays K Hendrickx E Triest M Verbiest T Persoons A Dehu C Brédas JL 《Science (New York, N.Y.)》1993,262(5138):1419-1422
Hyper-Rayleigh scattering has been used to determine the nonlinear optical properties of a chromophore-containing protein in solution. Because the technique of hyper-Rayleigh scattering allows the measurement of hyperpolarizabilities in an isotropic solution without the application of an electric field, this method is ideally suited for the study of proteins that carry a net charge. The observed orientational correlation between the nonlinear optical chromophores in incompletely solubilized protein molecules suggests that guidelines from protein structures can be used for the engineering of supramolecular structures with high optical nonlinearity. 相似文献
17.
Magnetic x-ray diffraction combined with x-ray focusing optics was used to image individual antiferromagnetic spin density wave domains in a chromium single crystal at the micron scale. The cross section for nonresonant magnetic x-ray scattering depends on the antiferromagnetic modulation vector and spin polarization direction and allows these quantities to be extracted independently. The technique was used to show that the broadening of the nominally first-order "spin-flip" transition at 123 kelvin, at which the spins rotate by 90 degrees C, originates at the walls between domains with orthogonal modulation vectors. During cooling, the transition begins at these walls and progresses inward. The modulation vector domains are themselves unchanged. 相似文献
18.
Mao WL Mao HK Meng Y Eng PJ Hu MY Chow P Cai YQ Shu J Hemley RJ 《Science (New York, N.Y.)》2006,314(5799):636-638
When subjected to high pressure and extensive x-radiation, water (H2O) molecules cleaved, forming O-O and H-H bonds. The oxygen (O) and hydrogen (H) framework in ice VII was converted into a molecular alloy of O2 and H2. X-ray diffraction, x-ray Raman scattering, and optical Raman spectroscopy demonstrated that this crystalline solid differs from previously known phases. It remained stable with respect to variations in pressure, temperature, and further x-ray and laser exposure, thus opening new possibilities for studying molecular interactions in the hydrogen-oxygen binary system. 相似文献
19.
Small-angle neutron diffraction (wavelength 4.05 angstroms) of human and rabbit sciatic nerve has been carried out by means of the Brookhaven high flux beam reactor with an automated slit camera. Most of the free water of the nerves was substituted in order to minimize incoherent scatter of hydrogen atoms. The differences in amplitude and phase shifts between neutrons and x-rays resulted in a neutron diffraction pattern that was completely different from the x-ray pattern. The neutron pattern consisted of a single peak of about 89-angstrom spacing in the region examined (up to 6-angstrom spacing). The strong third, fourth, and fifth order reflections (about 60, 45, and 36 angstroms) seen in the x-ray pattern were suppressed. The neutron data indicated a strong scattering from one portion of the membrane. 相似文献
20.
Gorenstein P Harris B Gursky H Giacconi R Novick R Bout PV 《Science (New York, N.Y.)》1971,172(3981):369-372
X-ray emission from the Cygnus Loop was observed in the energy region around 0.2 to 1 kiloelectronvolt with a collector that focused x-rays along one dimension while scanning across the nebula. The total integrated intensity is 1.3x 10(-8) erg per square centimeter per second. The one-dimensional x-ray structure has the same angular size-about 3 degrees-as the outermost boundaries of the optical filaments. There is no increase in x-ray emission at the center of the nebula nor at the strong feature that is seen in certain radio maps. The x-ray spectrum is consistent with thermal radiation from a hot plasma at a temperature of about 4 x 10(6) degrees K with evidence for a line at 19 angstroms corresponding to the 2p-->1s transition of O VIII. 相似文献