共查询到19条相似文献，搜索用时 187 毫秒
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水热处理对废弃刨花板的刨花形态及其再循环利用性能的影响 总被引：5，自引：2，他引：3
刨花形态和刨花板的再循环利用在再生刨花板的制造过程中具有重要作用。本文讨论了在备料前对废弃刨花板进行热处理的新工艺,分析了水热处理工艺对再生刨花的形态、吸水性及再胶合性能的影响。研究结果表明,采用水热处理工艺制备的再生刨花所压制的刨花板性能接近于原生刨花板;再生刨花有良好的再胶合性能。 相似文献
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提高再生刨花板性能的若干途径探讨 总被引：3，自引：0，他引：3
对提高再生刨花板物理力学性能的若干途径进行的研究结果表明：提高再生刨花板密度有助于其物理力学性能的改善;增加施胶量对再生刨花按常规工艺所制刨花板的静曲强度和内结合强度均有改善,但静曲强度仍未达到国标要求;如果将超过５０％的原生刨花加入到再生刨花中去,所制刨花板可以达到国标ＧＢ／Ｔ４８９７－９２一级品的要求。 相似文献
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利用废旧人造板及其制品生产刨花板技术的研究 总被引：4，自引：0，他引：4
探讨了利用废旧人造板及其制品制备再生刨花以及利用再生刨花与普通刨花混合生产再生刨花板的制备工艺。并对影响再生刨花板物理力学的主要因素原料配比、刨花含水率和热压工艺进行了深入研究。结果表明最佳工艺条件为:再生刨花:普通刨花=15:85;刨花含水率为4%;热压压力.3MPa;热压温度180℃;热压时间20s/mm。 相似文献
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刨花板的物理力学性能在很大程度上取决于胶粘剂在刨花板表面的分布状况，胶的分布越均匀，胶合面积越大，胶合强度和尺寸稳定性就越好。在目前刨花板生产中，胶液大多以液流形式施加，再通过刨花之间及刨花与拌胶机简体之间的强烈摩擦，使胶液分散到刨花板表面上。采用这种施波方式，胶液的分散度受到了一定限制。发泡树脂胶，由于发泡，其体积一般为未发泡时的2～6倍。施加发泡胶，将大大增加刨花的胶合面积，有利于减少用胶量和降低产品成本；同时还可以以骨架形式填充刨花之间的空隙，制造出低密度刨花板。发泡树脂胶从发泡方式讲一般可… 相似文献
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除了刨花板,定向刨花板(OSB)在装饰和结构应用方面变得日益重要.用作结构材料时,板材的机械性能至关重要.在这方面,木材刨花之间的胶合质量是一个关键因素.在人造板生产中,脲醛树脂、三聚氰胺改性脲醛树脂(MUF)胶粘剂的使用是普遍的.这些胶粘剂适合工业应用.然而,UF和MUF的机械性能是有限的. 相似文献
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刨花板热压过程中热传导的几个问题 总被引：5，自引：0，他引：5
一.前言在刨花板生产过程中,刨花极内部各点的温度与加压时间和胶的固化关系十分密切,加压时间的长短直接影响到刨花板的质量以及生产过程中的能耗。本文用非线性回归的方法得出温度与时间的变化关系。利用这一关系,可以对刨花生产进行热压控制。用热电偶测试刨花板热压过程 相似文献
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沙柳刨花板及低毒脲醛树脂胶研究 总被引：3，自引：2，他引：3
《林产工业》1997,(5)
研究了沙柳材的地造，胶接特性和适用于沙柳刨花板的低毒脲醛树脂。通过试验分析了脲醛树脂胶中尿素与甲醛的摩尔比与树脂性能的关系；浓缩处理与树脂中游离甲醛含量的关系。最后研究了抄柳刨花扳的制板工艺、特点和技术改进措施、分析了施胶量与板材性能的关系。 相似文献
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采用脲醛树脂(UF)/聚合异氰酸酯(PDMI)组合胶黏剂,以不同的组合配比在较低热压温度(160℃)条件下用高含水率(9.0%)杂木刨花制备刨花板,检测其静曲强度、内结合强度以及2h和24h吸水厚度膨胀率。结果表明:聚合异氰酸酯(PDMI)的引入,可以显著提高刨花板的物理力学性能和耐水性能;将刨花终含水率提高至9.0%可节约刨花干燥能耗达13.0%以上;与脲醛树脂胶黏剂(UF)相比,使用PDMI/UF配比为1∶9的(10.0wt%PDMI)组合胶黏剂可以提高刨花板静曲强度80%,提高内结合强度150%;在不添加防水剂的条件下,可以将板材的2h吸水厚度膨胀率由31.0%提高至21.0%。该研究可为刨花板节能环保生产提供新思路。 相似文献
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For manufacturing low-formaldehyde emission particleboard from wheat straw and urea-formaldehyde (UF) resins using urea treatment for indoor environments, we investigated the influence of urea treatment on the formaldehyde emission, physical and mechanical properties of the manufactured particleboard. Wheat straws were treated at three levels of urea concentration (5%, 10%, 15%) and 95℃as holding temperature. Wheat straw particleboards were manufactured using hotpress at 180℃and 3 MPa with two types of UF adhesive (UF-45,UF-91). Then the formaldehyde emission values, physical properties and mechanical properties were considered. The results show that the formaldehyde emission value was decreased by increasing urea concentration. Furthermore, the results indicate that the specimens under urea treatment have better mechanical and physical properties compared with control specimens. Also specimens under urea treatment at 10% concentration and UF-91 type adhesive have the most optimum physical and mechanical strength. 相似文献
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Influence of the melamine content in melamine-urea-formaldehyde resins on formaldehyde emission and cured resin structure 总被引：6，自引：0，他引：6
The effect of melamine content in melamine-urea-formaldehyde (MUF) resins on the formaldehyde emission and resin structure was investigated using six MUF resins synthesized with different F/(M + U) and M/U molar ratios. The formaldehyde emission from the plywood decreased as the F/(M + U) molar ratio decreased and the M/ U molar ratio increased. In addition, the bond performance was enhanced as the M/U molar ratio increased in the MUF resins with a fixed F/(M + U) molar ratio. Quantitative solution13C-NMR spectra of MUF resins revealed that the MUF resins with a high melamine content consisted of more highly branched crosslinkage structure and free melamine compared to the resins with low melamine contents. Furthermore, solid-state13C CP-MAS NMR spectra of cured MUF resins proved that more methylol groups, dimethylene ether, and branched methylene structures were present in the MUF resins with a higher F/(M + U) molar ratio, leading to increased bond strength and formaldehyde emission. There is no significant difference in the linkage structure of the cured resins with the same F/(M + U) and different M/U molar ratios except the ratios of carbonyl carbon of urea and triazine carbon of melamine. Therefore, the lower formaldehyde emission from cured MUF resins with a higher M/U molar ratio might be ascribed to the stronger linkages between triazine carbons of melamine than those of urea carbons. Consequently, the melamine contributed to strong crosslinking linkages in the cured resin structures, leading to lower formaldehyde emission and better bond performance.Part of this work was presented at the 48th Annual Meeting of the Japan Wood Research Society, Shizuoka, April 1998 相似文献
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一种脲醛树脂胶粘剂的设计 总被引：7，自引：2，他引：7
鉴于对文献的分析和实验验证,本文提出一种脲醛树脂胶粘剂的设计原则。即:1)脲醛树脂最终摩尔比应取1.40～1.20:1,这样可以使制成的板材具有足够的胶接强度;2)为了使人造板的甲醛释放量达到10mg/100g(穿孔法)以下,树脂中的游离尿素应在10%以上;3)在脲醛树脂的分子中引入尿素的环状衍生物,如三嗪环或Uron。环状化合物含量最好在10%左右。按此原则合成了三种树脂,在试验室按标准刨花板和中密度纤维板工艺制成板材,其甲醛释放量在10mg/100g左右,板材物理力学性能均超过国家标准和企业标准。 相似文献
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Upgrading of urea formaldehyde-bonded reed and wheat straw particleboards using silane coupling agents 总被引：3，自引：0，他引：3
Guangping Han Changwu Zhang Dongmei Zhang Kenji Umemura Shuichi Kawai 《Journal of Wood Science》1998,44(4):282-286
Reed and wheat straw particleboards bonded with urea formaldehyde (UF) resin were manufactured from two different material configurations (i.e., fine and coarse particles). The board densities were in the range of 0.550–.90g/cm3. The effects of particle size and board density on the board properties were examined. The properties of particleboard produced from fine particles were better than those made from coarse particles. An increase in board density resulted in a corresponding improvement in the board properties. The properties of OF bonded reed and wheat straw particleboards were relatively lower than those of commercial particleboards. Three silane coupling agents were used to improve the bondability between the reed and wheat particles and OF resin. Results of this study indicate that all the board properties were improved by the addition of silane coupling agent. The degree of improvement achieved from each coupling agent was different; epoxide silane was found to be more effective for reed straw particleboard, and amino silane was better for wheat straw particleboard. 相似文献
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在实验室制备得到树脂型甲醛捕捉剂,考察了甲醛捕捉剂与不同F/U摩尔比脲醛树脂混合使用后制备得到的刨花板力学性能及甲醛释放量。研究结果表明,甲醛捕捉剂的添加能有效降低刨花板的甲醛释放量,但对混合树脂的最终力学强度性能不利。混合树脂的摩尔比F/U是决定相关刨花板力学性能及甲醛释放量的主要因素。当与摩尔比F/U=1的脲醛树脂混合使用时,添加占总施胶量5%甲醛捕捉剂的刨花板甲醛释放量可达到E1级,同时,内结合强度值满足室内级国家标准要求。与摩尔比F/U=1.2的脲醛树脂混合使用,当甲醛捕捉剂的添加量为20%时,刨花板性能达标。 相似文献
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To improve the understanding of strawboard manufacturing processes, mat pressing behaviour of wood particleboard and strawboard bonded with urea formaldehyde resins were experimentally investigated and compared in terms of mat compressibility, transverse permeability, mat pressure, core temperature, core gas pressure and vertical density profile. The results have shown that straw particles are much more compressible and therefore require less platen pressure for pressing. Compared to wood particle and refined straw particle mats, hammer milled straw mats have low permeability and subsequently show high core gas pressure and high maximum core temperature during hot pressing, in addition to large differential densities between surface and core layers in the final pressed boards. It is recommended that a slower press closing rate and longer press opening time be used to develop the strawboard pressing schedule. 相似文献
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Formaldehyde emission and high-temperature stability of cured urea-formaldehyde resins 总被引：5，自引：0，他引：5
A test method for measuring formaldehyde from urea-formaldehyde (UF) resins at high temperature was developed and used to assess the influence of the reaction pH on the formaldehyde emission and heat stability of the cured resins. Additionally, solid-state13C CP/MAS nuclear magnetic resonance (NMR) techniques were used to investigate the structure of cured UF resins before and after high temperature heating. Formaldehyde emissions during the cure were related to the UF resins' methylol group content. The heat stability of cured UF resins synthesized under strongly acidic conditions was much higher than that of the other resins, which were prepared in weakly acidic and alkaline media. Solid-state13C CP/MAS NMR spectra showed that formaldehyde emission from cured UF resins after heating is mainly ascribable to decreased methylol groups and dimethylene ether linkages. Significantly, it was revealed that uron structures characteristically found in the cured UF resin synthesized under strongly acidic medium indicated high heat stability.Parts of this paper were presented at the 44th annual meeting of the Japan Wood Research Society, Nara, April 1994; and at the 52nd annual meeting of the Forest Products Society, Merida, Mexico, June 1998 相似文献
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本文通过~(13)C NMR研究了脲醛树脂合成新工艺中不同反应阶段时的脲醛树脂的化学结构。研究结果表明脲醛树脂的化学结构主要受甲醛/尿素的摩尔比,pH值、反应温度和反应时间的影响。对脲醛树脂中主要的官能团:游离甲醛、亚甲基、亚甲基醚、Uron等相互关系也进行了研究。指出了生产低甲醛释放量,高力学性能刨花板用脲醛树脂中主要官能团的最佳含量。 相似文献