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1.
Increases in N deposition (wet and dry) have been associated with a decline in semi-natural plant communities, adapted for growth on nutrient poor soils in the UK and Europe. The impacts of N deposition applied as either wet NH4 + or gaseous NH3 on vegetation (7 species) from acid moorland in SE Scotland were compared in a dose-response study. Wet N deposition at 0, 8, 16, 32, 64, 128 kg N ha?1 y?1 was applied as NH4Cl, and dry deposition as gaseous NH3 (2, 6, 20, 50, 90 µg NH3 m?3) under controlled conditions in open-top chambers. A strong linear dose-response relationship (p<0.05) was found between foliar N content in all seven plant species and applied NH4?N. However, in the NH3 treatment, only C. vulgaris and P. commune showed a significant response to increasing N additions. NH3 was found to increase the rate of water loss in Calluna in both autumn and winter by comparison with wet deposition. For Eriophorum vaginatum, the NH3 and NH4 + treatments showed significant N dose response relationships for biomass. A significant increase in above ground biomass, proportional to the added N, was found for Narthecium ossifragum when N was applied as NH3 compared to NH4 +.  相似文献   

2.
山西省太原市旱作农区大气活性氮干湿沉降年度变化特征   总被引：6，自引：0，他引：6  
鉴于大气氮素沉降对整个生态系统的重要影响,我国近年来陆续开展了不同尺度的大气氮素干、湿沉降的研究,但少有农业区多年连续监测的资料。本研究利用DELTA系统、被动采样器和雨量器在山西省太原市郊区阳曲县河村旱作农业区进行了4年的监测试验,观测大气氮素干、湿沉降的时间变异。结果表明:2011年4月—2015年3月,河村4年大气活性氮NH_3、HNO_3、NO_2、颗粒态NO_3~-(pNO_3~-)、颗粒态NH_4~+(pNH_4~+)平均沉降量分别为4.50 kg(N)·hm~(-2)·a~(-1)、3.54 kg(N)·hm~(-2)·a~(-1)、2.56 kg(N)·hm~(-2)·a~(-1)、1.62 kg(N)·hm~(-2)·a~(-1)、2.75 kg(N)·hm~(-2)·a~(-1),大气氮素干沉降总量为12.38~18.95 kg(N)·hm~(-2)·a~(-1),以2011年的氮干沉降量最高,2014年的最低。2011年4月—2015年3月各月氮干沉降量与氨气沉降量之间存在显著正相关,相关系数在0.809 8~0.937 1,由此可知,该地区活性氮沉降主要受农业氨气排放的影响。河村4年雨水中NO_3~-、NH_4~+平均浓度分别为3.20 mg(N)·L~(-1)和2.43 mg(N)·L~(-1),大气氮素湿沉降11.67~41.31 kg(N)·hm~(-2)·a~(-1)。年度间氮素湿沉降存在很大差异,以2012年氮素年湿沉降量最高,2014年最低,每年大气氮素湿沉降占氮总沉降量的份额超过50%。此外,4年湿沉降中不仅NO_3~--N和NH_4~+-N之间、且二者与降雨量也呈显著线性或二次相关关系,说明降雨量对NO_3~--N和NH_4~+-N的湿沉降影响较大。本研究表明太原市旱作农区不同年份间氮素湿沉降比干沉降差异更大,且总沉降数量较高。虽然是旱作区,该地区氮素干沉降略低于湿沉降。研究结果为该地区农田氮肥施用和氮素循环监测提供了理论依据。  相似文献   

3.
In this paper estimates of dry and wet deposition of acidifying substances in the Netherlands are presented. The deposition was estimated from measured concentrations in the atmosphere and in precipitation or if these were not available, from modelled concentrations. The method was applied for the Netherlands on a 5×5 km scale. The most important components are sulphur oxides and ammonia and their reaction products. It was estimated that the annual average deposition of SO x in the Netherlands decreased from 1570 to 670 mol ha?1 a?1 between 1980 and 1989. In 1989, the annual average NO y deposition was estimated to be 1220 mol ha?1 a?1 in 1980 and 1160 mol ha?1 a?1 in 1989. The annual average NH x deposition in the Netherlands was estimated to be 2330 and 2190 mol ha?1 a?1 in 1980 and 1989 respectively. HCI deposition was about 100 mol ha?1 a?1 in all years. Dry deposition contributes most to the total deposition for each component. The spatial distribution of the total deposition shows a gradient over the Netherlands with highest values in the South and lowest in the North of the country. Meteorological conditions are also of influence on the deposition fluxes for all components. During 1988 and 1989 meteorological conditions favoured low deposition. The estimated uncertainty in the average fluxes of SO x , NO y , and NH x for the Netherlands is 15, 25, and 30% respectively. The wet deposition fluxes can be estimated more accurately than the dry deposition.  相似文献   

4.
For elucidating the atmospheric deposition contribution of dissolved organic nitrogen (DON) to the total dissolved nitrogen (TDN) deposition rate, dissolved inorganic nitrogen (DIN: NH4 + + NO3 –) and DON deposition rates were annually and monthly estimated during 4 and half-yr monitoring period in an experimental multi-farm under intensive agricultural activities of N fertilizer use and animal husbandry in Central Japan. Annual NH4 +, DON and NO3 – deposition rates in bulk and wet deposition data accounted for 48%, 32% and 20% of TDN deposition, respectively, which indicated that this area is strongly affected by the intensive agricultural activities. The DIN and DON deposition rates were respectively estimated at 21.6 and 10.1 kg N ha?1 yr?1, which ranked high in a worldwide regional data set. Consequently, this area has been exposed to a large amount of N deposition including DON with N fertilizer input. The difference between bulk and wet deposition rates (NH4 + and DON) is one of important factors controlling the N deposition in this area. Monthly DON deposition showed positive correlations with DIN and NH4 + deposition rates, respectively, with a significant linear regression curve. The linear regression curve of our monthly data (n = 127) indicates the same trend as the worldwide annual data set (n = 31).  相似文献   

5.
We estimated the total inorganic fluxes of nitrogen (N), sulfur (S), chloride (Cl?, sodium (Na+, calcium (Ca2+, magnesium (Mg2+, potassium (K+ and hydronium (H+. The resistance deposition algorithm that is programmed as part of the CALMET/CALPUFF modeling system was used to generate spatially-distributed deposition velocities, which were then combined with measurements of urban and rural concentrations of gas and particle species to obtain dry deposition rates. Wet deposition rates for each species were determined from rainfall concentrations and amounts available from the National Acid Deposition Program (NADP) monitoring network databases. The estimated total inorganic nitrogen deposition to the Tampa Bay watershed (excluding Tampa Bay) was 17 kg-N ha?1 yr?1 or 9,700 metric tons yr?1, and the ratio of dry to wet deposition rates was ～2.3 for inorganic nitrogen. The largest contributors to the total N flux were ammonia (NH3 and nitrogen oxides (NO x at 4.6 kg-N ha?1 yr?1 and 5.1 kg-N ha?1 yr?1, respectively. Averaged wet deposition rates were 2.3 and 2.7 kg-N ha?1 yr?1 for NH4 + and NO3 ?, respectively.  相似文献   

6.
上海地区氮素湿沉降及其对农业生态系统的影响   总被引：6，自引：0，他引：6       下载免费PDF全文
试验研究上海地区N素湿沉降及其对农业生态系统的影响结果表明,上海地区湿沉降中N营养盐含量较高,其中NO3-为2.587mg/L,NH4 达2.155mg/L,TIN的含量均在4.000mg/L以上。湿沉降输入到上海地区农业生态系统N营养盐的年通量较高,其中NH4 平均为26.580kg/hm2,1999年达到38.930kg/hm2;NO3-平均为31.545kg/hm2;TIN平均为58.123kg/hm2,相当于124.549kg/hm2尿素或327.980kg/hm2碳酸氢铵,1999年TIN输入量为77.750kg/hm2,相当于166.607kg/hm2尿素或438.732kg/hm2碳酸氢铵,占1998年全国化肥(N)平均施用量的35%。湿沉降中N的输入对农业生产有重要影响。  相似文献   

7.
Atmospheric nitrogen species (NH4-N and (NO3+NO2)-N) were determined in weekly samples of atmospheric bulk deposition (dry plus wet), collected in France at seven sites over the course of a year. Rural, semi-rural and industrialised-urban sites were chosen in the Seine river watershed from the Seine estuary to upstream from Paris. Mean NH4-N concentrations varied from 0.7 to 1.7 mg L-1. Mean (NO3+NO2)-N concentrations were approximately 0.5 mg L-1 for all sites except Paris (0.7 mg L-1), which has a local impact on the fallout contamination from urban emissions. The relation between concentration and rainfall amount obeys a power law, in the form of y = ax b. When the nitrogen sources are very local, this relationship turns into a dilution law. Annual atmospheric nitrogen deposition (NH4-N+(NO3+NO2)-N) was calculated and varied from 7.8 kg ha-1 yr-1 in the neighbourhood of a rural town to 17.3 kg ha-1 yr-1 in a very industrialised harbour. 58% of the atmospheric nitrogen deposition occurred during ‘spring + summer’ period. The total nitrogen atmospheric input to the Seine estuary, via direct deposition + indirect input via the watershed, was estimated to about 5% of the total nitrogen load within the Seine river basin.  相似文献   

8.
The present study aimed to elucidate the atmosphere–forest exchange of ammoniacal nitrogen (NHX-N) at a young larch ecosystem. NHX-N exchanges were measured at a remote site in northernmost Japan where 4-year-old larches were growing after a pristine forest had been clear-cut and subsequent dense dwarf bamboo (Sasa) had been strip-cut. The site was a clean area for atmospheric ammonia with mean concentrations of 0.38 and 0.11 μg N m?3 in snowless and snow seasons, respectively. However, there was a general net emission of NHX-N. The annual estimated emission of NHX-N of 4.8 kg N ha?1 year?1 exceeded the annual wet deposition of 2.4 kg N ha?1 year?1, but the weekly exchange fluxes may have been underestimated by 28–60%. The main cause of the ammonia loss from the young larch ecosystem was probably enhanced nitrogen supply stimulated by the cutting of the pristine forest and Sasa, in particular, the Sasa.  相似文献   

9.
Information on atmospheric inputs, water chemistry and hydrology were combined to evaluate elemental mass balances and assess temporal changes in elemental transport from 1983 through 1992 for the Arbutus Lake watershed. This watershed is located within a northern hardwood ecosystem at the Huntington Forest within the central Adirondack Mountains of New York (USA). Changes in water chemistry, including increasing NO3 ? concentrations (1.1 μmol c , L?1 yr-1), have been detected during this study period. Starting in 1991 hydrological flow has been measured from Arbutus Lake and these measurements were compared with predicted flow using the BROOK2 hydrological simulation model. The model adequately (r2=0.79) simulated flow from this catchment and was used to estimate drainage for earlier periods when direct hydrological measurements were not available. Modeled drainage water losses coupled with estimates of wet and dry atmospheric deposition were used to calculate solute budgets. Export of SO4 2? (831 mol c ha?1 yr?1) from the greater Arbutus Lake watershed exceeded estimates of atmospheric deposition in an adjacent hardwood stand suggesting an additional source of S. These large drainage losses of SO4 2? also contributed to the drainage fluxes of basic cations (Ca2+, Mg2+, K+ and Na+). Most of the atmospheric inputs of inorganic N were retained (average of 74% of wet precipitation and 85% total deposition) in the watershed. There were differences among years (56 to 228 mol ha?1 yr?1) in drainage water losses of N with greatest losses occurring during a warm, wet period (1989–1991).  相似文献   

10.
David  M.B.  Cupples  A.M.  Lawrence  G.B.  Shi  G.  Vogt  K.  Wargo  P.M. 《Water, air, and soil pollution》1998,105(1-2):183-192
The responses of temperate and boreal forest ecosystems to increased nitrogen (N) inputs have been varied, and the responses of soil N pools have been difficult to measure. In this study, fractions and pool sizes of N were determined in the forest floor of red spruce stands at four sites in the northeastern U.S. to evaluate the effect of increased N inputs on forest floor N. Two of the stands received 100 kg N ha-1 yr-1 for three years, one stand received 34 kg N ha-1 yr-1 for six years, and the remaining stand received only ambient N inputs. No differences in total N content or N fractions were measured in samples of the Oie and Oa horizons between treated and control plots in the three sites that received N amendments. The predominant N fraction in these samples was amino acid N (31-45% of total N), followed by hydrolyzable unidentified N (16-31% of total N), acid-soluble N (18-22% of total N), and NH4 + (9-13% of total N). Rates of atmospheric deposition varied greatly among the four stands. Ammonium N and amino acid N concentrations in the Oie horizon were positively related to wet N deposition, with respective r2 values of 0.92 and 0.94 (n = 4, p < 0.05). These relationships were somewhat stronger than that observed between atmospheric wet N deposition and total N content of the forest floor, suggesting that these pools retain atmospherically deposited N. The NH4 + pool may represent atmospherically deposited N that is incorporated into organic matter, whereas the amino acid N pool could result from microbial immobilization of atmospheric N inputs. The response of forest floor N pools to applications of N may be masked, possibly by the large soil N pool, which has been increased by the long-term input of N from atmospheric deposition, thereby overwhelming the short-term treatments.  相似文献   

11.
Many ecosystems in Switzerland suffer from eutrophication due to increased atmospheric nitrogen (N) input. In order to get an overview of the problem, critical loads for nutrient N were mapped with a resolution of 1×1 km applying two methods recommended by the UN/ECE: the steady state mass balance method for productive forests, and the empirical method for semi-natural vegetation, such as natural forests, (sub-)alpine or species-rich grassland and raised bogs. The national forest inventory and a detailed atlas of vegetation types were used to identify the areas sensitive to N input. The total N input was calculated as the sum of NO3 ?, NH4 +, NH3, NO2 and HNO3 wet and dry deposition. Wet deposition was determined on the basis of a precipitation map and concentration measurements. Dry deposition was calculated with inferential methods including land-use specific deposition velocities. The concentration fields for NH3 and NO2 were obtained from emission inventories combined with dispersion models. Reduced N compounds account for 63% of total deposition in Switzerland. As indicated by exceeded critical loads, the highest risk for harmful effects of N deposition (decrease of ecosystem stability, species shift and losses) is expected on forests and raised bogs in the lowlands, where local emissions are intense. At high altitudes and in dry inner-alpine valleys, deposition rates are significantly lower.  相似文献   

12.
The field measurement of dry deposition still represents a difficult task. In our approach, a 1 to 2 cm thick layer of water in a petri dish with a diameter of 22 cm, serves as a surrogate surface. The atmospheric constituents taken up by the water can be analyzed chemically by the same procedure as for the wet deposition samples. In contrast to solid surrogate surfaces, water exhibits the following advantageous properties: low and constant surface resistance, high sticking coefficient for aerosols, and predictable Sorption behavior for gases. Consequently, the deposition rates measured to the wet surface are generally higher, by up to a factor of 4 for NH4 +, Cl?, NO3 ? and SO4 2?, than those to a dry surface, but still smaller than the concurrent wet deposition rates. We observed the following average dry deposition rates in μmol m?2 d?1∶ NH4 + 48.3, Ca2+ 40.7, Na+ 15.8, Mg2+ 8.4, K+ 4.2, H-Aci 36.4; SO4 2? 57.2, Cl? 39.2, NO3 ? 34.5, HSO3 ? 5.7, formate 4.0; acid soluble metals: Fe 2.8, Zn 0.60, Cu 0.11, Pb 0.073, Cd 0.0022. The soluble fraction of Zn, Cd, Cu, Pb and Fe in the dry deposition varied with the pH of the water phase corresponding to the adsorption tendency of these metals to oxide surfaces. The sampling method also allows tracing of regionally and locally emitted atmospheric pollutants. In our study the local pollution sources included road salting, construction work and a refuse incinerator. Finally, chemical reactions occurring in the atmosphere, such as the conversion of Cl? to HCl by HNO3 or the oxidation of SO2, can be identified by evaluating the data. The method proposed is relevant to measure reproducibly the dry deposition of a variety of compounds to water bodies and moist vegetation.  相似文献   

13.
In this study the dry input of atmospheric particles into a forest stand is quantified. A wash-off-method using the natural leaf surfaces as collectors of the dry deposition was chosen. The direct on-site-measurement on living branches were achieved in a spruce stand (Picea abies (L.) Karst) at Solling, Germany. The ion exchange processes occurring on natural branches can reliably be quantified through immediate sequential washings. In order to calculate also the gas dry deposition of those trace elements which occur in both particle and gas phases, a resistance model was used. From these results the deposition velocity of particulate aerosol components into the forest stand was calculated. Dry particle deposition constitutes an important part of the total matter input into the forest ecosystem. Just the nitrogen input into Solling only by dry deposition (from particle-, mist-, and gas-deposition) with about 30 kg N ha?1 a?1 already exceeds the critical load of 20 kg N ha?1 a?1 by far, and this is without even considering the additional load by wet deposition which amounts to 15 kg ha?1 a?1. These findings are of greatest ecological importance, as the damage to the stability of the forest ecosystem caused by increased nitrogen input is considerable. Only a quick and drastic reduction of sulphur and nitrogen emissions could stop the further increase of the nutritient imbalance and the progressing acidification of this ecosystem.  相似文献   

14.
Aerodynamically designed surrogate surfaces were used to determine the relative importance of gaseous (SO2, HNO3, NH3) and particulate species (SO4 2?, NO3 ?, NH4 +, Ca2+) in the dry deposition flux. For 11 sampling periods, we measured the deposition fluxes, ambient gaseous concentrations, size distributions of atmospheric aerosols and some meteorological parameters in Uji. The dry deposition of the gas to a nearly perfect sink was calculated by subtracting the greased surface flux from the total deposition flux to both the greased and reagent impregnated (or water) surface. It was found that the gas phase deposition contributed significantly more (60–93%) than the particulate phase to overall deposition of sulfur and nitrogen compounds. The dry deposition velocities of the species were also calculated using the deposition fluxes and the measured ambient concentrations. Comparisons were made between the measured and modeled particulate deposition flux.  相似文献   

15.
The distribution of acidic andalkaline constituents (SO4 2-,NO3 -, Cl-, NH4 +, Na+,K+, Ca2+) between the fine and coarseparticle range has been examined in an urban locationin Thessaloniki, N. Greece over an 8-month period. The chemistry of wet and dry deposition collected overthe same period was also examined. Statisticalassociations between species within each environmentalphase were investigated using correlation analysis.Use of principal component analysis was made toinvestigate compositional similarities betweenaerosol, deposited dust and rain. It was found thatSO4 followed by NO3, NH4 and Caprevailed in fine aerosol. Sulphates and Ca were alsothe prevailing ions in the coarse particle fraction.Wet deposition was found to be the dominant depositionmechanism for all species. The high dry depositionrates observed for Ca and SO4 suggest that mostof the dry deposited sulphate is in the form ofCaSO4. Scavenging ratios of ionic speciesassociated with coarse aerosol were higher than thecorresponding ratios for fine particles. Principalcomponent analysis suggested that variations in ioniccomposition of fine aerosol could be interpretedprimarily by gas-to-particle neutralization reactionsinvolving atmospheric ammonia. In contrast, theinteraction between SO2 and HNO3 with Cacompounds seems to be the most likely factor that canexplain variations in wet and dry deposition ioniccontents.  相似文献   

16.
Nitrogen (N) deposition to the ocean is thought to be increasing worldwide, but the amount of coastal and open ocean measurements is very limited. In this paper, we assess N deposition in the coastal zone of Cayo Coco, in central Cuba, during a multi-annual period (2005–2007). Wet and dry N depositions were estimated based on the NH4+ and NOx– concentrations in the rain. Cold fronts and troughs, coming from the west, contributed most to rain (41%) and to N deposition, followed by tropical waves and storms coming from the east, which caused 31% of the rain. Average concentrations of NH4+ and NOx– in the rain were 8.8 and 8.3 μM. NOx– presented a clearly decreasing trend (0.26 μM per month), decreasing by half during 2005–2007. Total N deposition averaged 3.23 kg N ha−1 year−1, similar to that found in Virgin Islands and Puerto Rico, but lower than previously measured in Cuba and in nearby areas of the USA and than model predictions for the oceanic region around Cuba. These low values and the decreasing trend found are attributed to drastic reduction of fossil fuel and fertilizer use in Cuba since 1990. Because land input has decreased even more drastically, deposition seems to be nowadays the most important N source to the coastal zone of Cayo Coco. The δ15N range of seagrass (Thalassia testudinum) and macroalgae (Penicillus dumetosus) in the area (−1.83‰ to 3.02‰ and +1.02‰ to +4.17‰, respectively) sustain that atmospheric sources (deposition and N2 fixation) comprise 70–90% of the N budget.  相似文献   

17.
Atmospheric deposition and above-ground cycling of sulfur (S) were evaluated in adjacent deciduous and coniferous forests at the Panola Mountain Research Watershed (PMRW), Georgia, U.S.A. Total atmospheric S deposition (wet plus dry) was 12.9 and 12.7 kg ha-1 yr-1 for the deciduous and coniferous forests, respectively, from October 1987 through November 1989. Dry deposition contributes more than 40% to the total atmospheric S deposition, and SO2 is the major source (～55%) of total dry S deposition. Dry deposition to these canopies is similar to regional estimates suggesting that 60-km proximity to emission sources does not noticeably impact dry deposition at PMRW. Below-canopy S fluxes (throughfall plus stemflow) in each forest are 37% higher annually in the deciduous forest than in the coniferous forest. An excess in below-canopy S flux in the deciduous forest is attributed to leaching and higher dry deposition than in the coniferous forest. Total S deposition to the forest floor by throughfall, stemflow and litterfall was 2.4 and 2.8 times higher in the deciduous and coniferous forests, respectively, than annual S growth requirement for foliage and wood. Although S deposition exceeds growth requirement, more than 95% of the total atmospheric S deposition was retained by the watershed in 1988 and 1989. The S retention at PMRW is primarily due to SO4 2- adsorption by iron oxides and hydroxides in watershed soils. The S content in white oak and loblolly pine boles have increased more than 200% in the last 20 yr, possibly reflecting increases in emissions.  相似文献   

18.
Montane heaths dominated by the moss Racomitrium lanuginosum are in decline, for which increased atmospheric nitrogen (N) deposition may be partially responsible. To test this, field plots in northeast Scotland were treated with either low or high (10 or 40 kg N ha−1year−1) doses of nitrogen (as NO3− or NH4+) for 2 years. Although Racomitrium tissue N increased after treatment, with greater response for low than high N application, activity of the enzyme nitrate reductase and Racomitrium growth were severely inhibited by increasing N addition. Racomitrium cover declined following N addition and graminoid cover increased, also with greatest effect at high doses. Of all measurements, only nitrate reductase showed a distinction between NO3− and NH4+ application. The results demonstrate the detrimental effects of even low increases in nitrogen deposition on the moss heath, suggesting that loss of Racomitrium and its replacement by graminoids is strongly linked to increased levels of anthropogenic N pollution.  相似文献   

19.
Three oak stands (Quercus petraea and Quercus robur) in the Weinviertel, Lower Austria, located along a distance gradient from a lime quarry, were studied to determine the effects of basic aerosols on the deposition of ammonium, nitrate and sulfate. Higher concentrations of limestone aerosols in the vicinity of the quarry are suggested by higher Ca2+ fluxes and pH in throughfall and precipitation. The ammonium/nitrate ratio in throughfall decreases with distance from the quarry, though monitoring of NH3 and NO2 concentrations in the air with passive samplers shows the opposite trend. These findings support the theory of discrimination against NH3 in dry deposition due to the presence of Ca 2+ particles on leaf surfaces resulting from limestone aerosols. Higher sulfate deposition near the quarry is consistent with higher atmospheric SO2 concentrations and co-deposition between calcium and sulfate.  相似文献   

20.
Ambient particle and gas concentrations, wet deposition and dry deposition were measured in Warren, MI between December 18, 1983 and April 6, 1984. Dry deposition was measured to various surfaces in a cutoff bucket, including a snow surface, a snow/water surface during melting and a deionized water surface. Dry deposition velocities were calculated for various species from the ratio of the dry flux to the ambient concentrations. The dry deposition velocities measured to a snow surface were 0.082 cm s?1 SO2 2.0 for HNO3, 0.083 for NH4 +, 2.0 for Ca++ and 4.3 for Cl?. The values were not significantly different for a snow/water surface during melting compared to a snow surface. However, higher values of 0.69 cm s?1 for SO2, 6.2 for HNO3, 0.33 for NH4 +, and 4.2 for Ca++ were found to a deionized water surface in the spring. These higher values could be due to the higher air temperature, the pH of the liquid or to increased atmospheric mixing during this period.  相似文献   

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