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1.
Stability of Perovskite (MgSiO3) in the Earth's Mantle 总被引：1，自引：0，他引：1
SK Saxena LS Dubrovinsky P Lazor Y Cerenius P Haggkvist M Hanfland J Hu 《Science (New York, N.Y.)》1996,274(5291):1357-1359
Available thermodynamic data and seismic models favor perovskite (MgSiO3) as the stable phase in the mantle. MgSiO3 was heated at temperatures from 1900 to 3200 kelvin with a Nd-YAG laser in diamond-anvil cells to study the phase relations at pressures from 45 to 100 gigapascals. The quenched products were studied with synchrotron x-ray radiation. The results show that MgSiO3 broke down to a mixture of MgO (periclase) and SiO2 (stishovite or an unquenchable polymorph) at pressures from 58 to 85 gigapascals. These results imply that perovskite may not be stable in the lower mantle and that it might be necessary to reconsider the compositional and density models of the mantle. 相似文献
2.
Miyagi L Kanitpanyacharoen W Kaercher P Lee KK Wenk HR 《Science (New York, N.Y.)》2010,329(5999):1639-1641
Understanding deformation of mineral phases in the lowermost mantle is important for interpreting seismic anisotropy in Earth's interior. Recently, there has been considerable controversy regarding deformation-induced slip in MgSiO(3) post-perovskite. Here, we observe that (001) lattice planes are oriented at high angles to the compression direction immediately after transformation and before deformation. Upon compression from 148 gigapascals (GPa) to 185 GPa, this preferred orientation more than doubles in strength, implying slip on (001) lattice planes. This contrasts with a previous experiment that recorded preferred orientation likely generated during the phase transformation rather than deformation. If we use our results to model deformation and anisotropy development in the D' region of the lower mantle, shear-wave splitting (characterized by fast horizontally polarized shear waves) is consistent with seismic observations. 相似文献
3.
The single-crystal elastic moduli of MgSiO(3) in the perovskite structure, the high-pressure polymorph of MgSiO(3) pyroxene, have been determined. The data indicate that a mantle with either pyrolite or pyroxene stoichiometry is compatible with the seismic models appropriate to the earth's lower mantle, provided that the shear modulus of MgSiO(3) perovskite exhibits a strong negative temperature derivative. Such a temperature derivative falls outside of the range expected for a well-behaved refractory ceramic and could result if the pressure-temperature regime of the earth's lower mantle is near that required for a ferroelastic phase transformation of the perovskite phase. 相似文献
4.
The individual elastic constants of magnesium oxide (MgO) have been determined throughout Earth's lower mantle (LM) pressure-temperature regime with density functional perturbation theory. It is shown that temperature effects on seismic observables (density, velocities, and anisotropy) are monotonically suppressed with increasing pressure. Therefore, at realistic LM conditions, the isotropic wave velocities of MgO remain comparable to seismic velocities, as previously noticed in athermal high-pressure calculations. Also, the predicted strong pressure-induced anisotropy is preserved toward the bottom of the LM, so lattice-preferred orientations in MgO may contribute substantially to the observed seismic anisotropy in the D" layer. 相似文献
5.
Laboratory experiments document that liquid iron reacts chemically with silicates at high pressures (>/=2.4 x 10(10) Pascals) and temperatures. In particular, (Mg,Fe)SiO(3) perovskite, the most abundant mineral of Earth's lower mantle, is expected to react with liquid iron to produce metallic alloys (FeO and FeSi) and nonmetallic silicates (SiO(2) stishovite and MgSiO(3) perovskite) at the pressures of the core-mantle boundary, 14 x 10(10) Pascals. The experimental observations, in conjunction with seismological data, suggest that the lowermost 200 to 300 kilometers of Earth's mantle, the D" layer, may be an extremely heterogeneous region as a result of chemical reactions between the silicate mantle and the liquid iron alloy of Earth's core. The combined thermal-chemical-electrical boundary layer resulting from such reactions offers a plausible explanation for the complex behavior of seismic waves near the core-mantle boundary and could influence Earth's magnetic field observed at the surface. 相似文献
6.
Crystals of MgSiO(3) perovskite synthesized at high pressures and temperatures have orthorhombic symmetry under ambient conditions. Examination by transmission electron microscopy shows that the microstructure of crystals synthesized at 26 gigapascals and 1600 degrees C is dominated by a large number of twin domains that are related by reflection operations with respect to {112} and {110} planes. These twins may be associated with the transformations of MgSiO(3) perovskite from the cubic to tetragonal and tetragonal to orthorhombic phases, respectively, upon decreasing pressure and temperature. These observations suggest that under the experimental synthesis conditions, and perhaps in the earth's lower mantle, the stable phase of MgSiO(3) might have the cubic perovskite structure. 相似文献
7.
A new and sensitive differential drop solution calorimetric technique was developed for very small samples. A single experiment using one 5.18-milligram sample of perovskite, synthesized at 25 gigapascals and 1873 Kelvin, gave 110.1 +/- 4.1 kilojoules per mole for the enthalpy of the ilmenite-pervoskite transition in MgSiO(3). The thermodynamics of the reaction of MgSiO(3) (ilmenite) to MgSiO(3) (perovskite) and of Mg(2)SiO(4) (spinel) to MgSiO(3) (pervoskite) and MgO (periclase) were assessed. Despite uncertainties in heat capacity and molar volume at high pressure and temperature, both reactions clearly have negative pressure-temperature slopes, -0.005 +/- 0.002 and -0.004 +/- 0.002 gigapascals per Kelvin, respectively. The latter may be insufficiently negative to preclude whole-mantle convection. 相似文献
8.
The transition zone of Earth's mantle is delineated by globally observed discontinuities in seismic properties at depths of about 410 and 660 kilometers. Here, we investigate the detailed structure between 410 and 660 kilometers depth, by making use of regional stacks of precursors to the SS phase. The previously observed discontinuity at about 520 kilometers depth is confirmed in many regions, but is found to be absent in others. There are a number of regions in which we find two discontinuities at about 500 and 560 kilometers depth, an effect which can be interpreted as a "splitting" of the 520 kilometer discontinuity. These observations provide seismic constraints on the sharpness and observability of mineralogical phase transitions in the mantle transition zone. 相似文献
9.
Inferences of the chemical homogeneity of Earth's mantle depend on comparing laboratory-derived equations of state of mantle phases with seismically determined properties of the material in situ. A uniform chemical composition of the entire mantle has been found to be consistent with measurements, to date, of these properties for the end-member MgSiO3 perovskite phase. New pressure-volume-temperature data for silicate perovskite containing 5 mole percent Al2O3 has yielded different values of the equation of state parameters, with the bulk modulus being significantly smaller at lower mantle conditions than for aluminum-free perovskite, thus requiring adjustments in other components to match seismic observations. 相似文献
10.
A sharp discontinuity at the base of Earth's mantle has been suggested from seismic waveform studies; the observed travel time and amplitude variations have been interpreted as changes in the depth of a spatially intermittent discontinuity. Most of the observed variations in travel times and the spatial intermittance of the seismic triplication can be reproduced by a ubiquitous first-order discontinuity superimposed on global seismic velocity structure derived from tomography. The observations can be modeled by a solid-solid phase transition that has a 200-kilometer elevation above the core-mantle boundary under adiabatic temperatures and a Clapeyron slope of about 6 megapascal per kelvin. 相似文献
11.
Transmission electron microscopic observation of forsterite (Mg(2)SiO(4)) shocked to peak pressures of 78 to 92 gigapascals revealed that forsterite breaks down to an assemblage of MgO plus MgSiO(3) glass. This strongly supports the interpretation that the high-pressure phase of forsterite under shock compression is due to the assemblage of MgSiO(3) perovskite plus MgO. 相似文献
12.
Dynamical processes in the Earth's mantle, such as cold downwelling at subduction zones, cause deformations of the solid-state phase change that produces a seismic discontinuity near a depth of 660 kilometers. Observations of short-period, shear-to-compressional wave conversions produced at the discontinuity yield a detailed map of deformation beneath the Izu-Bonin subduction zone. The discontinuity is depressed by about 60 kilometers beneath the coldest part of the subducted slab, with a deformation profile consistent with the expected thermal signature of the slab, the experimentally determined Clapeyron slope of the phase transition, and the regional tectonic history. 相似文献
13.
Seismic studies indicate that beneath some regions the 520-kilometer seismic discontinuity in Earth's mantle splits into two separate discontinuities (at approximately 500 kilometers and approximately 560 kilometers). The discontinuity near 500 kilometers is most likely caused by the (Mg,Fe)2SiO4 beta-to-gamma phase transformation. We show that the formation of CaSiO3 perovskite from garnet can cause the deeper discontinuity, and by determining the temperature dependence for this reaction we demonstrate that regional variations in splitting of the discontinuity arise from variability in the calcium concentration of the mantle rather than from temperature changes. This discontinuity therefore is sensitive to large-scale chemical heterogeneity. Its occurrence and variability yield regional information on the fertility of the mantle or the proportion of recycled oceanic crust. 相似文献
14.
Experiments on melting and phase transformations on iron in a laser-heated, diamond-anvil cell to a pressure of 150 gigapascals (approximately 1.5 million atmospheres) show that iron melts at the central core pressure of 363.85 gigapascals at 6350 +/- 350 kelvin. The central core temperature corresponding to the upper temperature of iron melting is 6150 kelvin. The pressure dependence of iron melting temperature is such that a simple model can be used to explain the inner solid core and the outer liquid core. The inner core is nearly isothermal (6150 kelvin at the center to 6130 kelvin at the inner core-outer core boundary), is made of hexagonal closest-packed iron, and is about 1 percent solid (MgSiO(3) + MgO). By the inclusion of less than 2 percent of solid impurities with iron, the outer core densities along a thermal gradient (6130 kelvin at the base of the outer core and 4000 kelvin at the top) can be matched with the average seismic densities of the core. 相似文献
15.
The Nature of the 660-Kilometer Upper-Mantle Seismic Discontinuity from Precursors to the PP Phase 总被引：2，自引：0，他引：2
Global Seismic Network data were used to image upper-mantle seismic discontinuities. Stacks of phases that precede the PP phase, thought to be underside reflections from the upper-mantle discontinuities at depths of 410 and 660 kilometers, show that the reflection from 410 kilometers is present, but the reflection from 660 kilometers is not observed. A continuous Lame's constant lambda and seismic parameter at the 660-kilometer discontinuity explain the missing underside P reflections and lead to a P-wave velocity jump of only 2 percent, whereas the S-wave velocity and density remain unchanged with respect to previous global models. The model deemphasizes the role of Lame's constant lambda with regard to the shear modulus and constrains the mineralogical composition across the discontinuity. 相似文献
16.
T Irifune N Nishiyama K Kuroda T Inoue M Isshiki W Utsumi K Funakoshi S Urakawa T Uchida T Katsura O Ohtaka 《Science (New York, N.Y.)》1998,279(5357):1698-1700
The phase boundary between spinel (gamma phase) and MgSiO3 perovskite + MgO periclase in Mg2SiO4 was determined by in situ x-ray measurements by a combination of the synchrotron radiation source (SPring-8) and a large multianvil high-pressure apparatus. The boundary was determined at temperatures between 1400 degrees to 1800 degreesC, demonstrating that the postspinel phase boundary has a negative Clapeyron slope as estimated by quench experiments and thermodynamic analyses. The boundary was located at 21.1 (+/-0.2) gigapascals, at 1600 degreesC, which is approximately 2 gigapascals lower than earlier estimates based on other high-pressure studies. 相似文献
17.
The tetragonal garnet (Mg,Fe)SiO(3) is a high-pressure phase of pyroxene that is thought to be a major constituent of the earth's upper mantle. Its crystal structure is similar to that of cubic garnet, but it is slightly distorted to tetragonal symmetry so that its x-ray powder diffraction pattern shows a very small line splitting. A suite of tetragonal garnets with different compositions in the MgSiO(3)-rich portion of the MgSiO(3)-FeSiO(3) system was synthesized at about 20 gigapascals and 2000 degrees C. The lattice parameters a and c of quenched samples were determined by whole-powder-pattern decomposition analysis of Fe Kalpha x-ray powder diffraction data, which has the capacity to resolve to a high degree heavily overlapping reflections. It was found that the lattice parameters can be obtained from the following equations; a (in angstroms) = 11.516 + 0.088x and c (in angstroms) = 11.428 + 0.157x, where x, teh mole fraction of FeSiO(3), is 0.0 相似文献
18.
The single-crystal elastic moduli of the modified spinel structure (beta phase) of magnesium orthosilicate (Mg(2)SiO(4)) have been measured by Brillouin spectroscopy under ambient conditions. Single crystals with dimensions up to 500 micrometers were grown at 22 gigapascals and 2000 degrees C over a period of 1 hour. Growth of crystals larger than 100 micrometers was achieved only when the pressure was within 5 percent of the pressure of the phase boundary separating the beta- and gamma-phase stability fields. A comparison of the elastic properties of the modified spinel phase with those of the olivine phase suggests that the 400-kilometer seismic discontinuity in the earth's mantle can be described by a mantle with 40 percent olivine. These results confirm that the 400-kilometer discontinuity can be due to the transition from olivine to modified spinel. The amount of olivine that must be present is less than that in a pyrolite model, although the results do not exclude pyrolite as a possible mantle model. 相似文献
19.
In the solid state, NaMgF(3) transforms smoothly with temperature into a solid electrolyte phase; the conductivity is 130 siemens per meter just below the melting point. The isostructural compound MgSiO(3) should behave similarly under conditions obtaining in the earth's lower mantle, and so it is expected that the electrical conductivity in that region is ionic rather than electronic. 相似文献
20.
Strong, scattered reflections beyond 8 degrees (8degrees) offset are characteristic features of all high-resolution seismic sections from the continents. The reflections identify a low-velocity zone below approximately 100 kilometers depth beneath generally stratified mantle. This zone may be caused by partial melting, globally initiated at equal depth in the continental mantle. Solid state is again attained at the Lehmann discontinuity in cold, stable areas, whereas the zone extends to near the 400-kilometer discontinuity in hot, tectonically active areas. Thus, the depth to the Lehmann discontinuity may be an indicator of the thermal state of the continental mantle. 相似文献