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1.
K-Ca-exchange isothermes of soils from loess and the potassium supply of plants From 80 Ap-horizons of Luvisols and Phaeozems on loess from south of Hannover K-Ca-exchange isotherms and cation concentrations in saturation extracts were investigated. Though not K deficient these soils show a very wide range of available K. From the very high K-concentrations in the saturation extracts (up to 3 meq/1) of part of the soils it was concluded, that mass flow should be sufficient for plant needs of K. The only soil property varying the exchange isotherms seems to be the clay content (Fig. 4). In order to calculate available K from the exchange isotherms in the same way as available water from pF characteristics the isotherms were extended down to activity ratios, according to literature, marginal for plant uptake of K (Fig. 6). The estimated soil K content, sufficient for plant in loess soils, amounts to about half that considered marginal by the regional extension service. With the assumption that so called non exchangeable, but plant available K is essentially very slowly exchangeable, an experiment was performed at 80°C to accelerate the exchange and to establish a true equilibrium. The comparison between the new exchange curve and the 25°C curve (Fig. 8) seems to reveal additional 180–450 kg/ha · 30 cm bound with equal free energy of exchange as easily exchangeable K. 相似文献
2.
Field determination of water withdrawal from soil by plant roots as a function of depth and time . The water flow through roots as a function of depth and time can be determined in homogeneously rooted, level soils with closed plant canopies, provided the total vertical water flow and the capillary water flow are known for the soil profile. Theory, measuring methods and some results on water withdrawal of wheat (fig. 2–4) and sugar-beet (fig. 5) roots on a loess grey-brown podsolic soil profile underlain by gravelly sand (fig. 1) are described. The time averaged rates (2–7 day periods) for water extraction by roots are up till about 12 × 10?3 \documentclass{article}\pagestyle{empty}\begin{document}$ \frac{{{\rm cm}^3 {\rm water}}}{{{\rm cm}^3 {\rm soil} \cdot {\rm day}}} $\end{document} During the growth period variations of the depth of the effective root zone and of the extraction rate in distinct layers were found (fig. 6 + 7). A capillary rise from the subsoil into the effective root zone exists for some time (fig. 3); seepage water within the lower root zone causes a strong increase of extraction rates in these depths (fig. 4). The relative water extraction rate at the depths of 15 and 25 cm decreases with increasing soil water suction in the range between 150 and 104 cm (fig. 8). 相似文献
3.
The K-potential of soils in Lower Bavaria as influenced by long-term K fertilization In a fertilizer trial with P and K established in 1974 on 4 representative soils of the Hallertau (Lower Bavaria) the potential K-supplying power was investigated. To this purpose K-uptake of the crop, K-balance, CAL-soluble K and K-Ca-exchange isothermes were determined once yearly. As K addition increased K uptake by crops increased and this the more the lower the clay content of the soil (3–28%). Labile K was significantly correlateted with K-balance but change in labile K was only one third of change in K-balance. The remaining two thirds of K must have come from interlayer-K. Labile K and CAL-K are sufficiently identical and can be calculated from each other. The K-buffering capacity as taken from exchange isothermes at AR0 proved to be soil-specific within a wide range of K-balance (positive to negative). AR0 was closely related to the K-balance and varied the less the higher the K-buffer capacity. 相似文献
4.
E. A. Niederbudde 《植物养料与土壤学杂志》1976,139(1):57-71
Transformation of three-layer silicates through K-release and K-uptake (A review). In soils formed from unconsilidated sediments with illite-vermiculite-smectite mixtures in their clay fractions the clay mineral transformation from illite to vermiculite and smectite between pH 5 and 7 cannot be considered so far as proven on the grounds of available analytical data. Studies of soil profiles showed that the formation of illite from expandable three layer silicates predominates over the formation of smectite from illite. Practically all samples of loess and calcareous tills of the areas discussed contain smectites. K loesses between pH 5 and 7 are probably very small, because K released during the formation of vermiculites from micas is immediately fixed by smectitic layers which are converted to illite. In those soils potential K fixation of the clay fraction (« 2 μ) is lower than in the corresponding parent sediments despite of vermiculite formation in the soils. Further analytical data (X-ray, interlattice-K, K-selectivity, specific surface) support the hypothesis of illitization of smectites during soil formation. 相似文献
5.
Potassium fixation capacity and mineralogical analysis of 24 representative soils, collected from southern Iran, were studied. Potassium fixation analysis was performed by adding six rates of K from 0 to 1000 mg kg?1 soil in a plastic beaker and shaking for 24 h. Mineralogical analysis showed that the clay fractions were dominated by smectite, chlorite, mica, palygorskite, vermiculite and quartz. In general, the studied soils fixed 8.5–55% of the added K. The potassium fixation capacity of the studied soils was significantly correlated with smectite content (r 2 = 0.87), clay content (r 2 = 0.60), cation-exchange capacity (r 2 = 0.79) and NH4OAc-K. Wetting and drying treatment and incubation time had significant effects on K fixation. The average percentage increase in K fixation following the wetting and drying treatment was 24 and 30% for surface and subsurface soils, respectively. The average percentage increase in K fixation with increasing residence time was 79 and 56% for surface and subsurface soils, respectively. Because K fixation is a diffusion process, time and increased concentration of soluble K (because of soil drying) are factors affecting the rate of K diffusion from a soil solution to the interlayer positions of the expansible 2:1 clay minerals. 相似文献
6.
Mineral-selective K release from soils by octodecylammonium- ions (nc = 18) nc18-releasable potassium was determined on soils of five different areas. nc18-releasable K is the potassium which is displaced by octodecylammonium ions (ODA). Because the main sources of this potassium are trioctahedral micas, it is called briefly biotite-K. The investigated soils are from different areas in Bavaria (loess and clay stone derived soils, alluvial soils); partly the locations are K fertilizer trials. Soils of known age are locations from the Niederrhein terraces (Holocene soils). In the 0.2–2 μm (coarse clay) and 2–6 μm (fine silt) fractions the biotite-K content lies between 12 and 40% of total K. At given fractionation the highest amounts of K were released from the coarse clay of the soils. In the loess soils rich in silt the biotite-K pool in the medium and coarse silt fractions was also considerable. Clay soils showing poor K supplying power (K fertilizer trials) in the field are characterized by very low biotite-K quantities in all silt fractions. In the Holocene soils the age of which varies between 4 000 and 8 000 years the ODA releaseable values are greater than in the loess soils. In all fractions of the young Holocene soils the released K is greater than in the same fractions of the old Holocene soils. Calculated to a soil depth of 60 cm the K release in kg/ha reaches from 25 000 (young soil form) to 17 000 (old soil form). 相似文献
7.
辽宁省西部是低山丘陵区,年平均温度7.1℃,年平均降雨量400—500毫米,降雨集中在夏季,具有明显的大陆性气候特征,干燥度小于1,属半干旱类型.植被为油松柞木和草原灌木丛林.土壤属棕色森林土向栗钙土过渡的褐土地带.母质主要为花岗片麻岩风化物.山麓缓坡和河谷两岸为黄土丘陵.在黄土沉积物覆盖层下,常见红色风化壳露头,即红色粘土层.此外,并有松软易风化岩层,如砂岩、页岩和变质岩等.本区近百年来,由于自然植被受到严重破坏,大量水土流失,土壤侵蚀严重,土壤有机质含量低,成为辽宁省的低产区.因此,鉴定本区不同母质的土壤矿物胶体组成及其特征,不仅可以研究这一特定自然条件下土壤矿物的转化和形成,并且有助于了解土壤特性和肥力特征. 相似文献
8.
Clay mineralogy and K-Ca-exchange properties of surface soils from the nutrient potential trial Hallertau (Bavaria) In soils of four locations of the Hallertau nutrient potential trial, with a soil texture consisting of sand, silty sand, silty loam and sandy clayey loam, clay mineral properties were measured with the standardized glycerol expansion method and with n-alkylammonium (Rnc-NH3+-clay). The expandable minerals of the sandy soils consist exclusively of smectites s.s., (s.s. = sensu stricto) with 0.42 to 0.28 charge equivalents per formula unit (p.f.u.). The expandable minerals of the loams are an assemblage of smectites s.s. and vermiculites. The total layer charge of the smectites s.s. extend from 0.54 to 0.28 charge eq. p.f.u. The fine clay fractions (< 0.1 μm) do not contain vermiculites. The layer charge density of vermiculites with homogeneous charge in the coarse fractions varies between 0.60 and 0.95 charge eq. p.f.u. The immediate K-Ca-exchange was extended with the values of the continued K exchange versus Ca at low K intensity. The Q/I isotherms of sandy soils have a more pronounced curvature than the isotherms of the loams; in all cases, however, the exchange curves have a continuous form. This phenomen is discussed in terms of the clay mineralogy of the soils. After 8 years without K fertilizing, samples gave values between 168 and 497 kg smectite-K/ha for the surface soils. The constant rates of K-desorption vary between 12.8 and 28.7 kg K/ha (surface soil). The rates are better differentiated between unfertilized and fertilized soils for the loams than for the sandy soils. The constant rates of K release were found to be controlled at an AR-level between 1.6 · 10?4 M1/2 (unfertilized sandy soil) and 5.2 · 10?4 M1/2 (fertilized sandy clayey loam soil). 相似文献
9.
Dynamics and fixation of potassium in soils of North-West-Iran The following results were obtained from experiments conducted on two calcareous soils (A-horizon) and on two soil samples from fertilizer experimental plots (K0 = control plot, K5 = 1000 kg K2O/ha) to study the dynamics and fixation of potassium in these soils: The K-exchange curve of K5 sample when compared with K0 sample showed that, as a consequence of high fertilizer dose, most of the specific adsorption sites for cations (particularly on illites and weathering products of illites) were occupied by K which, thus, resulted into lower K-adsorption as well as fixation. The shape of K-exchange curves of other three samples (Alluvial soil, 16, Brown soil 26 and K0 sample, Fig. 5 and 6) indicates a typical bend at definite activity ratios. This bend in the exchange curves exists apparently in soils containing high content of illitic clay mineral fraction. This behaviour has been interpreted as a consequence of contraction of layers of illitic minerals which were formerly expanded due to loss of potassium. The K-desorption experiment, which then followed, showed that a major part of sorbed amounts of potassium could not be desorbed and remained fixed in the soil. Similar type bend as in the exchange curve was also observed in the potassium fixation curves (Fig. 6 and 7). Illite is the dominant clay mineral in all these soils which in Brown soil and K0-sample is expanded at edges; the expansion goes back to 10 A on treatment with K which then does not expand again on saturation with Mg. 相似文献
10.
Cesium-137 (137Cs) is strongly adsorbed on clay minerals, especially on illite. The adsorption of Cs+ on reference clay minerals, however, has not been fully investigated in relation to the presence of illite. The objective of this study was to clarify the effect of impurities (i.e., illite and vermiculite), present in reference smectite group minerals and kaolin minerals, on the retention of Cs+. The clay mineralogy of the reference minerals was characterized by X-ray diffraction (XRD). The radiocesium interception potential (RIP) was measured as an index of the Cs+ retention ability of clays. The content of illite in clay was represented by the total potassium (K) content given that illite is a major source of K in the clay fraction. The content of vermiculite in clay was represented by the Cs fixation capacity induced by Cs saturation followed by heating of samples at 110°C. Metabentonite and beidellite gave extremely high RIP values compared with other smectite group minerals, although a peak for illite (at 1.0 nm) was not observed in XRD analysis. The reference smectite and kaolin minerals showed a range of RIP values, even though their RIP values are theoretically zero. The RIP values had a significant positive correlation with the total K content of all the reference clay minerals (rs = 0.621*). This indicated that the retention ability for 137Cs depended more on the content of illite, as impurity, rather than the type of bulk mineral. Hence, the contribution of illite to the magnitude of the RIP was elucidated by the combination of measurement of total K content and XRD analysis. 相似文献
11.
This paper deals with the effects of soil erosion on the horizontal and vertical distribution of nutrients in loess soil topo-sequences in southern Lower Saxony and Frankonia (W. Germany). Each topo-sequence consists of three parts: an upper plateau (or edge of a piedmont plain) with little soil erosion up to now, a slope which as a whole has been eroded very much, and a slope foot which is covered with colluvial sediments. Compared to the pure loess the soils contain more K, Na, and P, and less Ca. The distribution of the nutrients within the investigated topo-sequences is caracterized by high contents of potassium on the slopes, provided that the A1-horizon is eroded, so that the B1-horizon has come to the surface. Finally it is considered whether the erosion-made differentiation of nutrients has negative or positive consequences on the productiveness of the arable soils. 相似文献
12.
The mineralogies of ‘Tirs’ (Typic Pelloxererts), and ‘Debs’ (Typic Haploxerolls and Typic Xerochrepts) soils of the Gharb plain in north-western Morocco are investigated, with special attention given to the determination of the nature of the smectitic phase using the lithium test (Li test) and the alkylammonium method. The sand and silt mineralogy of Tirs soils is dominated by quartz with small amounts of feldspars and kaolinite. The sand and silt fractions of Dehs soils also contain significant amounts of mica, chlorite, and interstratified phyllosilicates. The clay minerals of Tirs soils are predominantly a high-charge smectite. The estimated interlayer charge for this phase is 0.61 mol(c)/O10(OH)2 and the fraction of tetrahedral charge varies from 38 to 44%. Although the percentage tetrahedral charge is less than 50%, the smectitic phase behaves as beidellite with the Li test. Dehs clays are more heterogeneous, consisting of smectite, vermiculite, illite, kaolinite, chlorite, and interstratified illite/smectite and illite/vermiculite. The Li test and the alkylammonium method demonstrate that a high-charge smectite or vermiculite is interstratified with illite. A low-charge montmorillonite is also present both in Tirs and in Dehs soils. The high-charge beidellitic phase is believed to be a transformation product of mica, whilst the low charge montmorillonite is thought to be inherited from the parent material. 相似文献
13.
Balances of alteration and migration of clay fractions and clay minerals in Gray Brown Podzolic Soils from Loess Balances of alteration and migration of clay fractions, clay minerals, K, Mg and Fe bound in clay silicates were calculated for Gray Brown Podzolic Soils (Parabraunerden) derived from Young Pleistocene Loess below arable and forest land in the district south of Würzburg. The extent of clay formation lies between 63 and 98 kg/m2, of which 60–80 % belong to the fraction <0.1 μm. The clay migration varies between 35 and 51 kg/m2, the fractions < 0.2 μm (especially the fraction <0.1 μm) predominating, the coarse clay being involved only to a smaller extent. During Holocene soil formation 121 kg illite, 16 kg vermiculite and 11 kg kaolinite per m2 are formed in the clay fraction (< 2 pm). The loss of smectite amounts to 68 kg/m2. The biggest alterations of the clay mineral quantities occur in the fraction <0.1 pm; they indicate a smectite-illite transformation. Illite, at 23 kg/m2, accounts for half of the clay migration, followed by smectite and vermiculite each at 9 kg/m2 and kaolinite at 5 kg/m2. When comparing the migrated with the present amounts no preference of certain clay minerals during clay migration can be determined. In the clay fractions the gained Fe (3.07?4.32 kg/m2) and K (2.75?3.84 kg/m2) predominate over Mg (0.57?1.15 kg/m2). The three elements accumulate to the greatest extent in the fine clay fraction. The element migration parallels the gain. The balances of the elements are discussed in connection with pedogenic illite formation as well as biotite and vermiculite disintegration. 相似文献
14.
I. Ya. Papish N. P. Chizhikova S. P. Poznyak E. B. Varlamov 《Eurasian Soil Science》2016,49(10):1161-1173
The mineralogy of clay fractions separated from deep low-humus deep-gleyic loamy typical agrochernozems on loess-like loams of the Upper Bug and Dniester uplands in the Central Russian loess province of Ukraine consists of complex disordered interstratifications with the segregation of mica- and smectite-type layers (hereafter, smectite phase), tri- and dioctahedral hydromicas, kaolinite, and chlorite. The distribution of the clay fraction is uniform. The proportions of the layered silicates vary significantly within the profile: a decrease in the content of the smectite phase and a relative increase in the content of hydromicas up the soil profile are recorded. In the upper horizons, the contents of kaolinite and chlorite increase, and some amounts of fine quartz, potassium feldspars, and plagioclases are observed. This tendency is observed in agrochernozems developed on the both Upper Bug and Dniester uplands. The differences include the larger amounts of quartz, potassium feldspars, and plagioclases in the clay material of the Upper Bug Upland, while the contents of the smectite phase in the soil profiles of the areas considered are similar. An analogous mineral association is noted in podzolized agrochernozems on loess-like deposits in the Cis-Carpathian region of the Southern Russian loess province developed on the Prut–Dniester and Syan–Dniester uplands. The distribution of particle-size fractions and the mineralogy of the clay fraction indicate the lithogenic heterogeneity of the soil-forming substrate. When the drifts change, the mineral association of the soils developed within the loess-like deposits gives place to minerals dominated by individual smectite with some mica–smectite inter stratifications, hydromicas, and chlorite. 相似文献
15.
Fate of fertilizer ammonium in soils with different composition of clay minerals in an incubation experiment In an incubation experiment with three different soils (gray brown podsolic soil from loess, alluvial gley, and brown earth, derived from basalt) the specific adsorption (fixation) and release of fertilizer NH4+ was investigated. In one treatment 120 mg NH4–N/kg soil was added, while the other treatment (control) received no nitrogen. Soils samples were taken every ten days and analyzed for nonexchangeable and exchangeable NH4+ and NO3?. The experimental results are showing that the specific adsorption of applied NH4+ was related to the type of clay minerals. While the loess soil, rich in illite, and the alluvial soil, rich in expansible clay minerals, bound about 40% of the added NH4+ specifically, the soil derived from basalt with mainly kaolinite bound only about 10 %. From the recently “fixed” fertilizer NH4+ about a half was nitrified during the incubation period of about 9 weeks. In the control there was no significant release of specifically bound NH4+. Obviously this NH4+ is located more deeply in the interlayers of the clay minerals and not available to microorganisms. 相似文献
16.
The determination of preferentially releasable potassium in hapludalf from loess and chromudert from gipskeuper clay marl Octadecylammonium-chloride (ODA)-extractable potassium and interlayer potassium (KZW), exchanged after thermal dissociation of adsorbed NH4, were determined on particle size fractions of soils from gipskeuper clay marl (typic chromudert) and loess sediments (shallow hapludalf). The extraction by ODA is a diffusion controlled K-exchange process. This is shown by the increase of K-release at small sample quantity and K-concentration in the extraction solution. The ODA-potassium supplies (= Biotit-K) of the two typic chromudert were significantly higher than that of the shallow hapludalf (34000 and 30000 kg/ha vs. 22000 kg/ha, to a depth of 55 cm). Biotit-K was highest in the 2-6μm-fraction for both soils. The smaller the particle size, the larger were the amounts of KZW In the clay fractions of all samples they reached between 70 and 80% of total K (Kt). XRD-data give evidence of different mineral genesis processes between the two types of sediments. This is supported by the KZW-values of the particle-size fractions. The selectively releaseable interlayer potassium is associated with wedge shaped layers of illite. It can be differentiated from the bulk interlayer potassium by its preferential extractability in the first 3 to 5 heating treatments. This potassium quantity is, on an average, 22% of total clay interlayer potassium. 相似文献
17.
Effect of potassium fertilization on K-availability in potassium fixing soils over the vegetative period The effect of potassium fertilization on the K-availability over the course of the vegetative period was tested on nine potassium fixing soils over two years. The availability of potassium fertilized at the beginning of vegetative period falls (on a soil with 50% clay) to half of the original amount within one month. The availability decreases especially during the time without vegetation. Only after fertilization with 1200 kg K2O/ha are substantial amounts of potassium available for the plants until the end of the vegetative period (determined by electroultrafiltration). An annual application of 300 kg K2O/ha only slightly increased the CAL-K and exchangeable K in comparison with the unfertilized plots, although the plants showed marked yield responses. A significant improvement in potassium supply was not obtained with less than 600 kg K2O/ha. The potassium wet fixation values are relatively constant on the plots without or with low K-fertilization: after high potassium application they show considerable fluctuation. The fixation potential is considerably reduced with an annual application of 1800 kg K2O/ha, but is not completely removed. Potassium can be removed by repeated extraction with a dilute CaCl2-solution but the rate at which it is released into the soil solution is too slow compared to the needs of rapidly growing crop plants. The rise in the level of available potassium by fertilization is reverse to the clay content. There was considerable variation between the different available potassium forms over the vegetative period on the highly fertilized plots; consequently a soil test made annually can only give a rough idea of the K-level in potassium fixing soils. 相似文献
18.
Timtong Darunsontaya Anchalee Suddhiprakarn Irb Kheoruenromne Nattaporn Prakongkep Robert J. Gilkes 《Geoderma》2012
Potassium (K) deficiency is widespread in crops on highly weathered upland soils under a tropical monsoonal climate. Critical assessment of the forms of K in soils and of the ability of soils to release K for plant uptake is important for the proper management of K in crop production. The relationships between different pools of K were investigated as a function of silt and clay mineralogy for 14 upland Oxisols and 26 upland Ultisols soils from Thailand. Most soils contained no K-minerals in the silt fraction. XRD showed that kaolinite is the dominant clay mineral with variously minor or moderate amounts of illite, hydroxy-Al interlayered vermiculite and smectite present in some soils. For some soils, both conventional and synchrotron XRD were unable to detect illite. Analytical TEM including EFTEM of individual clay crystals showed that clay in the apparently illite-free samples contained very small amounts of illite. Many kaolinite particles appear to contain K which may be present in illite interleaved with kaolinite crystals. A glasshouse K-depletion experiment was conducted to assess the K supply capacity and changes in chemical forms of K and K-minerals using exhaustive K depletion by Guinea grass (Panicum maximum). Potassium deficiency symptoms and mortality of plants occurred on light textured soils, whereas plants survived for six harvests for Oxisols with clay texture, relatively high CEC and higher NH4OAc-K (exchangeable K plus water-soluble K). There is a strong linear relationship of unit slope between NH4OAc-K and cumulative K uptake by plants indicating that NH4OAc-K is a major form of K available to plants. Thus K-bearing minerals contributed little K to plants over the time scale of the experiment and XRD patterns of whole soil samples, silt and clay from soils after cropping mostly showed no change from those for the initial soil. An exception was for a single surface soil clay where a minor amount of smectite was formed from illite by K release to plants. 相似文献
19.
M. Karbachsch 《植物养料与土壤学杂志》1978,141(5):513-522
Potassium nutrition of tobacco on a potassium fixing alluvial soil A field experiment was conducted to study the effects of K-fertilization on potassium uptake by tobacco and the K-dynamics in an alluvial soil rich in clay and carbonate content. It was observed that the amount of exchangeable potassium and the concentration of K in the soil solution increased on fertilization. There were only small changes in exchangeable potassium and significant reduction in the concentration of K in the soil solution during the growth period. Uptake of potassium by plants increased during first month due to its high concentration in soil solution. Decrease in the concentration of potassium after one month caused a rapid reduction in the uptake of potassium by plants (Figure 1). K Fertilization decreases the K-Ca and K-Mg potentials especially during the first month (Table 2) which increase again during the experimental period (because of the slow release of K from the solid phase and its rapid uptake by plants). Where as the concentration of potassium in the soil solution is closely related with K-Ca and K-Mg potentials on the one hand and with K-uptake by plants on the other, no relationship was observed between exchangeable potassium content and K-uptake (Figure 2). The potassium exchange curves of soils from K0 and K5 treatments show that the extent of K-adsorption is greater in K0 soil. A major part of K adsorbed during the shaking experiment can be easily removed by CaCl2 solution in K5soil, where as in K0 soil a part of adsorbed potassium exists in nonexchangeable form. Illite is the dominant clay mineral in this soil which show wedge type structures (expansible at edges). 相似文献
20.
The magnitude of radiocaesium fixation by micaceous clay minerals is affected by their transformation, which depends on weathering in soil. The net retention of radiocaesium traces was quantified by sorption–desorption experiments in the various horizons of four sandy soils forming an acid brown earth–podzol weathering sequence derived from sandy sediments and characterized by marked changes in mineral composition. The features of the 2:1 minerals of the four soils, resulting from an aluminization process in depth and a desaluminization process towards the surface, had a strong influence on Cs+ fixation. Beneath the desaluminization front, which deepens from the acid brown earth to the podzol, hydroxy interlayered vermiculite was dominant and the 137 Cs+ fixation was the weakest. At the desaluminization front depth, vermiculite was responsible for the strongest 137 Cs+ fixation. In the upper layers, smectite appeared in the podzolized soils and the 137 Cs+ fixation decreased. The magnitude in Cs+ fixation therefore appeared as a tracer of the transformation process affecting the 2:1 clay minerals in the acid brown earth–podzol weathering sequence. This magnitude was positively correlated with the vermiculite content of the studied soil materials estimated by the rubidium saturation method. 相似文献