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1.
Denitrification losses measured by direct method (measuring the evolution of (N2 N2O)-^15N) were compared with the apparent denitrification losses (calculated from the difference between the total N loss and ammonia loss), for fertilizers applied to flooded soils.The direct measured denitrification losses from potassium nitrate were 23.0%,40.0%,and 63.1-79.7% of applied N in rice field,and in incubations of 7 cm deep layer of soil and 2 cm deep layer of soil,respectively;while the corresponding apparent denitrification losses were 96.0%,98.4%,and 97.7-97.9%,respectively.In field experiments with urea,the direct measured denitrification losses ranged from 0.1-1.8%,which were much less than the apparent denitrification losses (41.3-45.7%).Such discrepancies were primarily due to the entrapment of the gaseous products of denitrification in the soil as revealed by the facts:(1) stirring the floodwater and the surface soil markedly increased the fluxes of (N2_N2O)-^15N from urea or potassium nitrate applied to the flooded rice field,and (2) reducing the pressure in the headspace of the incubation bottle with the 7 cm soil layer during gas sampling decreased the discrepance between the direct measured and apparent denitrifecation losses from 58.4% to 21.2%.The advantage of reducing the pressure in the headspace is that there is minimal disturbance of the soil.Further testing of this technique in rice field is needed to determine its effectiveness in releasing the entrapped gaseous products of denitrification so that denitrification losses can be quantified directly.  相似文献   

2.
Total nitrogen(N) loss and ammonia volatilization from urea applied to flooded rice grown on a paddy soil in Zhejiang Province were measured by ^15N balance and micro-meteorological methods,respectively.Floodwater properties and ammonia loss from the circular plot were compared with those from the microplots.And the effectiveness of urease inhibitor,NBPT [N-(n-butyl) thiophosphoric triamide],was also tested Results showed that the total losses from urea broadcast and incorporated at transplanting (basal dressing) were similar with those from urea broadcast 12 days after transplanting (top-dressing)(51.5% and 48%,respectively,of applied N),and ammonia losses were low,the corresponding figures were 10.8% and 7.0% of applied N,respectively.Thus,denitrification was a much more important pathway of nitrogen loss than ammonia volatilization under the particular conditions.Addition of NBPT retarded urea hydrolysis,reduced pHs and ammoniacal nitrogen concentrations of floodwater for either the application of urea as basal or as top-dressing,but these effects were not translated into the reduction of total nitrogen loss.Floodwater pHs and ammonia loss in the microplots were apparently lower than those in the circular plot from urea applied as basal dressing;however,such differences were not found when urea was top-dressed.The frequently raining days occurred after top-dressing may be responsible for the insignificant effect of plot size on floodwater pHs and ammonia volatilization.It seems that the effects of phot size on ploodwater properties and ammonia loss mainly depend on weather conditions,in addition to the height and leaf area index of the crop.  相似文献   

3.
Nitrification-denitrification losses of 15N-labelled nitrate and ammonium applied to the rhizos phere and nonrhizosphere of flooded rice were evaluated in 2 greenhouse rhizobox experiments.The loss of added N via denitrification was estimated directly by measuring the total fluxes of (N2O N2)12N,It was found that 67% and 51%-56% of 15N-nitrate added to rice rhizosphere were lost as (N2O N2)-15N in the 2 experiments,respectively,which were comparable to that added to norhizosphere soil(70%and 47%,respectively),implying that the denitrifying activity in rice rhizosphere was as high as that in nonrhizosphere soil.However,only trace amounts (0-0\3% of added N)were recovered as (N2O N2)-15N when 15N-ammonium was applied to either rhizosphere or nonrhizosphere,which seems to indicate that the nitrifying activity in the either rhizosphere of nonrhizosphere soils was quite low.The apparent denitrification calculated from 15N balance studies was 10%-47% higher than the total flux of (N2O N2)-15N.Reasons for the large differences can not be explained satisfactorily.Though the denitrifying activity in rhizosphere was high and comparable to that in nonrhizosphere soil.presumably due to the low nitrifying activity and /or the strong competition of N uptake against denitrification.the nitrification-denitrification taking place in rhizosphere could not be an important mechanism of loss of ammonium N in flooded rice-soil system.  相似文献   

4.
Results showed that ammonia loss from urea broadcast into floodwater and incorporated into soil at transplanting was as high as 40% of applied N,and the corresponding total nitrogen (N) loss was 56%.Ammonia loss was measured with simplified micrometeorological method (ammonia sampler),and total N loss was concurrently measured using ^15N balance technique.The experiment was conducted under strong sunshine conditions on acid paddy soil derived from Quaternary red clay.The ammonia loss in this particular condition was much greater than those obtained from previous studies when urea was also applied to acid paddy soil but under cloudy conditions.It is concluded that the strong sunshine conditions with high temperature and shallow floodwater during the period of present experiment favoured ammonia volatilization.Application of stearyl alcohol on the surface of the floodwater reduced ammonia loss to 23% of applied N.However,the effect of stearyl alcohol was short-lived,probably due to the microbiological decomposition.  相似文献   

5.
华北平原水浇玉米-小麦轮作农田氨挥发与反硝化损失   总被引：9，自引：6，他引：9  
Ammonia (NH3) volatilization, denitriflcation loss, and nitrous oxide (N2O) emission were investigated from an irrigated wheat-maize rotation field on the North China Plain, and the magnitude of gaseous N loss from denitrification and NH3 volatilization was assessed. The micrometeorological gradient diffusion method in conjunction with a Bowen Ratio system was utilized to measure actual NH3 fluxes over a large area, while the acetylene inhibition technique (intact soil cores) was employed for measurement of denitrification losses and N2O emissions. Ammonia volatilization loss was 26.62% of the applied fertilizer nitrogen (N) under maize, while 0.90% and 15.55% were lost from the wheat field at sowing and topdressing, respectively. The differences in NH3 volatilization between different measurement events may be due to differences between the fertilization methods, and to differences in climatic conditions such as soil temperature. Denitrification losses in the fertilized plots were 0.67%-2.87% and 0.31%-0.49% of the applied fertilizer N under maize and wheat after subtracting those of the controls, respectively. Nitrous oxide emissions in the fertilized plots were approximately 0.08%-0.41% and 0.26%-0.34% of the applied fertilizer N over the maize and wheat seasons after subtracting those of the controls, correspondingly. The fertilizer N losses due to NH3 volatilization were markedly higher than those through denitriflcation and nitrous oxide emissions. These results indicated that NH3 volatilization was an important N transformation in the crop-soil system and was likely to be the major cause of low efficiencies with N fertilizer in the study area. Denitriflcation was not a very important pathway of N fertilizer loss, but did result in important evolution of the greenhouse gas N2O and the effect of N2O emitted from agricultural fields on environment should not be overlooked.  相似文献   

6.
氮肥用量对太湖水稻田间氨挥发和氮素利用率的影响   总被引：28，自引：0，他引：28  
Ammonia volatilization losses, nitrogen utilization efficiency, and rice yields in response to urea application to a rice field were investigated in Wangzhuang Town, Changshu City, Jiangsu Province, China. The N fertilizer treatments, applied in triplicate, were 0 （control）, 100, 200, 300, or 350 kg N ha^-1. After urea was applied to the surface water, a continuous airflow enclosure method was used to measure ammonia volatilization in the paddy field. Total N losses through ammonia volatilization generally increased with the N application rate, and the two higher N application rates （300 and 350 kg N ha^-1） showed a higher ratio of N lost through ammonia volatilization to applied N. Total ammonia loss by ammonia volatilization during the entire rice growth stage ranged from 9.0% to 16.7% of the applied N. Increasing the application rate generally decreased the ratio of N in the seed to N in the plant. For all N treatments, the nitrogen fertilizer utilization efficiency ranged from 30.9% to 45.9%. Surplus N with the highest N rate resulted in lodging of rice plants, a decreased rate of nitrogen fertilizer utilization, and reduced rice yields. Calculated from this experiment, the most economical N fertilizer application rate was 227 kg ha^-1 for the type of paddy soil in the Taihu Lake region. However, recommending an appropriate N fertilizer application rate such that the plant growth is enhanced and ammonia loss is reduced could improve the N utilization efficiency of rice.  相似文献   

7.
The fate of urea-and ammonium bicarbonate(ABC)-nitrogen (N) applied by prevailing traditional techniques to winter wheat (Triticum aestivum L.)or maize (Zea mays L.)grown in the fields of Fluvo-aquic soil was investigated using ^15N tracer-micro-plot technique.Results show that:(1) at maturity of wheat,N recovery in plants and N losses of urea and ABC applied at seeding in autumn were 31-39%,and 34-46%,respextively,while the corresponding figures for side-banding at 10 cm depth in early spring were 51-57%,and 5-12%;surface-broadcast of urea followed by irrigation at early spring was as efficient as the side-banding in improving N recovery in plants and reducing N loss,however,such techuique was found less satisfactory with ABC.(2)At the maturity of maize,N recovery in the plants and N loss of urea and ABC sidebanded at seedling stage or prior to tasseling ranged from 23% to 57%,and 9% to 26%,respectively.(3) Either in Wheat or in maize experiment,the majority of residual fertilizer N in soil profile (0-60cm) was in the form of biologically immobilized organic N,however,the contribution of ammonium fixation by clay minerals increased markedly nwith depth in soil profile.(4) Though the proportion of residual fertilizer N was generally highest in the top 20 cm soil layer,considerable reaidual N (nostly 6-11% of the N applied)was found in 60-100 cm soil layers.  相似文献   

8.
Field experiments were conducted in a maize (Zea mays L.)field of a calcareous fluvo-aquic soil in North China Plain for studying the fate and ammonia loss of urea-N applied at seedling stage,as well as the effectiveness of coated calcium carbide(CCC) in reducing N loss and in improving the yield efficiency of urea.Results show that:(1) For the surface-broadcast treatment ammonia volatilization (measured with micro-meteorological technique)took place quickly,reached the peak 20-26hr after application,and then declined gradually;the cumulative ammonia loss approached the maximum 188hr after application (30% of the N applied),and increased only to 32% 284 hr after application;the latter accounted for 71% of the total loss (45% of applied N).(2) In the case of point placement at a depth of 5-10 cm,ammonia loss 188hr after application was only 12% of the N applied,accounting for 40% of the total loss.(3) There was no difference in total loss between the application depths of 6cm and 10 cm,the loss of them was 30% and 29%,respectively.(4) Total loss of N applied at lower rate (40kg N/ha)with point deep placement at 6cm depth was found only 4% of the N applied,it rose up to 30% when the rate of application increased to 80kg N/ ha.(5) The nitrification inhibitor,CCC,seemed to enhance N loss of urea rather than reduce it,and did not show any benefit effect in improving the yield efficiency of urea,which is presumably due to the high potential of ammonia volatilization in the soil and climatic conditions under investigation.  相似文献   

9.
The effectiveness of polyolefin-coated urea (Meister-5 and Meister-10; CU) in a wheat (Triticum aestivum L.)-maize (Zea mays L.) rotation system was studied in lysimeter plots located in the North China Plain for three consecutive maize- wheat-maize cropping seasons. An isotopic method was used to compare the fate of CU to that of non-coated urea (NCU), and N application rates of 0, 100, 150 and 225 kg N ha-1 were evaluated. The results showed that the nitrogen use effciency (15NUE) of CU was 13.3%–21.4% greater than that of NCU for the first crop. Alternatively, when the difference method was applied (apparent NUE), no significant variations were observed among treatments in all three seasons. Although inorganic N leached from the 1.3 m layer was less than 1% of the total applied N, unidentified losses of 15N (losses of 15N = 15N applied as fertilizer – 15N absorbed by crops – 15N remaining in the 0–0.2 m layer – 15N leached from the 1.3 m layer) in CU-treated plots were 24.2%–26.5% lower than those of NCU-treated plots. The nitrate concentration in the 0–1.3 m layer of CU plots at the end of the experiment was 53% lower than that of NCU-treated plots. Thus, CU increased crop N uptake from fertilizer and reduced unidentified losses of applied N, which can reduce the risk of groundwater pollution.  相似文献   

10.
A soil column method was used to compare the effect of drip fertigation （the application of fertilizer through drip irrigation systems, DFI） on the leaching loss and transformation of urea-N in soil with that of surface fertilization combined with flood irrigation （SFI）, and to study the leaching loss and transformation of three kinds of nitrogen fertilizers （nitrate fertilizer, ammonium fertilizer, and urea fertilizer） in two contrasting soils after the fertigation. In comparison to SFI, DFI decreased leaching loss of urea-N from the soil and increased the mineral N （NH4^＋-N ＋ NO3^--N） in the soil. The N leached from a clay loam soil ranged from 5.7% to 9.6% of the total N added as fertilizer, whereas for a sandy loam soil they ranged between 16.2% and 30.4%. Leaching losses of mineral N were higher when nitrate fertilizer was used compared to urea or ammonium fertilizer. Compared to the control （without urea addition）, on the first day when soils were fertigated with urea, there were increases in NH4^＋-N in the soils. This confirmed the rapid hydrolysis of urea in soil during fertigation. NH4^＋-N in soils reached a peak about 5 days after fertigation, and due to nitrification it began to decrease at day 10. After applying NH4^＋-N fertilizer and urea and during the incubation period, the mineral nitrogen in the soil decreased. This may be related to the occurrence of NH4^＋-N fixation or volatilization in the soil during the fertigation process.  相似文献   

11.
露地种植大白菜的氮肥效应与氮素损失研究   总被引：7，自引：0，他引：7  
采用田间小区和微区试验,研究了施用化学氮肥在露地大白菜上的氮肥效应和氮素损失。氮素总损失用15N示踪法测定,氨挥发用通气密闭室法测定,反硝化损失用乙炔抑制原状土柱培养法测定,不加乙炔测定N2O排放。结果表明,施用化学氮肥增产显著,用差值法计算得到的氮肥利用率在25.3%4～7.2%之间,相应的示踪法氮肥利用率为18.1%2～4.6%。化学氮肥显著增加了氨挥发、反硝化和N2O排放等气态氮损失;其中氨挥发占施氮量的0.97%1～7.1%,反硝化占4.33%8～.55%,N2O排放在1.09%1～.63%之间变化。大白菜收获时9.2%～10.9%的标记尿素被淋洗到40.cm以下土层。试验期间尿素的氮素总损失达41.1%4～8.1%,以表观淋洗损失最为严重,其次是氨挥发,而反硝化损失最低。与普通尿素相比,包衣尿素明显降低了氨挥发。  相似文献   

12.
在特制密闭盆钵甲,研究了15N标记氮肥作水稻基肥混施时,氨的挥发及其在氮素损失中的重要性,随着通气速率的增高,氨的挥发及其在氮素损失中的重要性也增大,至换气频率达15-20次/分时即接近或达到最大值.在酸性水稻土上,硫铵的氮素损失的主要途径是反硝化作用,特别是气温较低的月份;尿素的氮素损失途径,在气温较低的月份中以反硝化作用为主,在温度较高的月份中,则氨的挥发与反硝化作用都是重要的;对碳铵来说,氨的挥发和反硝化作用都是氮素损失的重要途径.在石灰性土壤上,碳铵的氮素损失的主要途径是氨的挥发,而在硫铵和尿素的氮素损失中,氨的挥发和反硝化作用则都是重要的.  相似文献   

13.
石灰性稻田土壤上化肥氮损失的研究*   总被引：6，自引：2，他引：6  
  相似文献   

14.
Summary The relative importance of ammonia volatilization and denitrification as loss processes following the application of urea to flooded rice by the traditional method was assessed at four sites with different characteristics in the Philippines. The effect of reducing ammonia loss on denitrification and total N loss was also studied. The total N loss was determined by a 15N-balance method and ammonia volatilization was assessed by a bulk aerodynamic method following the application of urea to small plots (4.8×5.2 m). As run-off was prevented and leaching losses were negligible, the denitrification loss was assessed as the difference between total N loss and ammonia loss. When urea was broadcast into the floodwater at transplanting, the ammonia loss varied from 10% to 56% of the applied N. Loss was smallest at Aguilar where wind speeds were low and the greatest at Mabitac where floodwater pH values and temperatures were high and the winds were strong. The ammonia loss was reduced at all sites by incorporating the urea into the soil by harrowing. However, the reduction achieved varied markedly between sites, with the largest reduction (from 56% to 7% loss of the applied N) being observed at Mabitac. The total N lost from the basal application into the floodwater ranged from 59% to 71% of the applied N. Incorporating the urea by harrowing reduced the total N loss at two sites, increased the total N loss at the third site, and had no effect at the fourth site. The denitrification losses ranged widely (from 3% to 50% of the applied N) when urea was broadcast into the floodwater at the four sites. The denitrification loss was low when the ammonia loss was high (Mabitac) and high when the ammonia loss was low (Aguilar). Reducing ammonia losses by incorporating the urea into the flooded soil resulted in increased denitrification losses at three of the sites and appeared to have no effect on denitrification at the fourth site. The results show that reducing the ammonia loss by incorporating urea into the soil does not necessarily result in reduced total N loss, and suggest that the efficiency of fertilizer N will be improved only when both N-loss processes are controlled simultaneously.  相似文献   

15.
Denitrification losses from puddled rice soils in the tropics   总被引：4，自引：0，他引：4  
Summary Although denitrification has long been considered a major loss mechanism for N fertilizer applied to lowland rice (Oryza sativa L.) soils, direct field measurements of denitrification losses from puddled rice soils in the tropics have only been made recently. This paper summarizes the results of direct measurement and indirect estimation of denitrification losses from puddled rice fields and reviews the status of research methodology for measurement of denitrification in rice fields. The direct recovery of (N2+N2O)-15N from 15N-enriched urea has recently been measured at sites in the Philippines, Thailand, and Indonesia. In all 12 studies, recoveries of (N2+N2O)-15N ranged from less than 0.1 to 2.2% of the applied N. Total gaseous N losses, estimated by the 15N-balance technique, were much greater, ranging from 10 to 56% of the applied urea-N. Denitrification was limited by the nitrate supply rather than by available C, as indicated by the values for water-soluble soil organic C, floodwater (nitrate+nitrite)-N, and evolved (N2+N2O)-15N from added nitrate. In the absence of runoff and leaching losses, the amount of (N2+N2O)-15N evolved from 15N-labeled nitrate was consistently less than the unrecovered 15N in 15N balances with labeled nitrate, which presumably represented total denitrification losses. This finding indicates that the measured recoveries of (N2+N2O)-15N had underestimated the denitrification losses from urea. Even with a probable two-or threefold underestimation, direct measurements of (N2+N2O)-15N failed to confirm the appreciable denitrification losses often estimated by the indirect difference method. This method, which determines denitrification losses by the difference between total 15N loss and determined ammonia loss, is prone to high variability. Measurements of nitrate disappearance and 15N-balance studies suggest that nitrification-denitrification occurs under alternate soil drying and wetting conditions both during the rice cropping period and between rice crops. Research is needed to determine the magnitude of denitrification losses when soils are flooded and puddled for production of rice.  相似文献   

16.
南京郊区番茄地中氮肥的气态氮损失   总被引：13，自引：0，他引：13       下载免费PDF全文
采用田间试验研究了番茄地施用化学氮肥后的氨挥发、反硝化损失和N2O排放及其影响因素。氨挥发采用通气密闭室法测定，反硝化损失（N2＋N2O）采用乙炔抑制-土柱培养法测定，不加乙炔测定N2O排放。结果表明，番茄生长期间全部处理均未检测到氨挥发，其原因是土表氨分压低于检测灵敏度，较低的氨分压是由于表层土壤的铵态氮浓度和pH都不高所致。在番茄生长期间，对照区即来自有机肥和土壤本身的反硝化损失和N2O℃排放量相当高，反硝化损失总量高达N29．6kghm^-2，N2O排放量为N7．76kghm^-2。施用化学氮肥显著增加了反硝化损失和N2O排放，3个施用化学氮肥处理的反硝化损失变化在N40．8～46．1kghm^-2之间，占施入化肥氮量的5．50％～6．01％；N2O排放量为N13．6～17．6kghm^-2，占施入化肥氮量的2．62％～4．92％；与尿素相比，包衣尿素未能显著减低反硝化损失和N2O排放。施用尿素的处理在每次追肥后，耕层土壤均会出现NO3^--N高峰，继之的反硝化和N2O排放高峰。反硝化速率与土壤含水量呈极显著正相关。总的看来，番茄生长期间没有氨挥发，而硝化反硝化是氮素损失的重要途径之一。  相似文献   

17.
冀北高原草甸栗钙土春小麦中化肥氮去向的研究   总被引：7，自引：2，他引：7       下载免费PDF全文
在冀北高原张北县的草甸栗钙土上，采用＾１５Ｎ质量平衡法和微气象学技术，对春小麦中氮肥的去向，以及氨挥发进行了田间原位观测。试验中的氮肥用量为Ｎ４．８３ｋｇ／亩，１／３作基肥、２／３作追肥。基肥随播种施入，追肥于拔节期撤施，随即灌水。结果表明，小麦回收、土壤残留和损失的肥料氮各占施入氮量的３７．８％－４８．３％、３３．８％－４０．４％和１４．３％－２５．４％。其中，尿素作基肥与作追肥的处理之间，其氮  相似文献   

18.
低量施氮对小青菜生长和氮素损失的影响   总被引：1，自引：5，他引：1  
采用田间试验和微区试验相结合,研究了低量施氮对小青菜(Brassica.chinensis)产量、氮肥利用率和氮素损失的影响,其中氮素总损失用15N示踪法测定,氨挥发用通气密闭室法测定,反硝化损失用乙炔抑制-原状土柱培养法测定,不加乙炔测定N2O排放。结果表明,施用氮肥显著增加了小青菜的产量和吸氮量,在75和150kg/hm2氮肥水平下,氮肥利用率分别为46.8%和39.4%。由于试验地土壤pH低(5.38),各处理的氨挥发均很低且差异不大,施用氮肥没有增加氨挥发。试验地土壤反硝化损失和N2O排放量较高,分别为N4.34kg/hm2/sup和N2.65kg/hm2,施用氮肥没有增加反硝化损失和N2O排放,表明氮源不是反硝化作用的限制因子。在N75和150kg/hm2两个施氮水平下,氮素回收率分别为103%和91.3%,并且土壤残留氮主要累积在020cm土层,表明肥料氮损失很少,这与氨挥发、反硝化损失较低的结果相吻合。  相似文献   

19.
不同氮肥形态的氨挥发损失比较   总被引：11，自引：0，他引：11  
利用从德国引进的农田土壤氨挥发风洞法测定系统,对不同N肥形态的肥料进行对比实验。结果表明,在相同施N量条件下,硝酸铵、硝酸铵钙、硫硝酸铵的氨挥发损失分别比尿素减少22.5%、3.2%和8.3%,不同N肥的氨挥发损失差异很大。相同条件下,尿素的氨挥发损失为25.7%,添加DMPP后氨挥发损失为27.6%;硫硝酸铵的氨挥发损失为18.6%,添加DMPP后为20.6%;添加DMPP对尿素和硫硝酸铵的氨挥发影响不显著。  相似文献   

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