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1.
土壤中氮磷钾肥转化中的交互作用: Ⅰ.土壤pH的动态变化   总被引:10,自引:0,他引:10  
Dynamic changes of soil pH as influenced by ammonium sulfate (AS), monocalcium phosphate (MCP),potassium chloride (KCl) and their interaction in soils were evaluated in incubation experiments. Applyingthese fertilizers significantly reduced soil pH values in all cases and followed sequences of AS > MCP >KCl, MCP > KCl > AS and KCl > AS > MCP for the paddy, calcareous and red soils, respectively. TheAS-induced reduction of pH in the three soils followed the sequence of red soil > paddy soil > calcareous soil,while in MCP and KCl systems the reduction of pH followed the sequences of calcareous soil > paddy soil >red soil and red soil > calcareous soil > paddy soil, respectively. The interactions of the NPK fertilizers on pHwere significant. MCP plus KCl or MCP plus AS reduced pH values more than the fertilizers applied solelyin the paddy soil, but AS partly counteracted the effect of MCP on pH in the 1 d sample of the calcareoussoil. The effect of MCP on pH was trivial when MCP was applied in combination with KCl or AS in the redsoil. When applied in combination with AS, KCl did not affect soil pH initially, but suppressed the reductionof pH at the later incubation stage, which was related to inhibition of nitrification by KCl in the soils.  相似文献   

2.
共施磷酸二氢钙和硫酸铵对土壤中钾形态转化的影响   总被引:4,自引:0,他引:4  
Soil potassium (K) deficiency has been increasing over recent decades as a result of higher inputs of N and P fertilizers concomitant with lower inputs of K fertilizers in China; however, the effects of interactions between N, P, and K of fertilizers on K status in soils have not been thoroughly investigated for optimizing N, P, and K fertilizer use effciency. The influence of ammonium sulfate (AS), monocalcium phosphate (MCP), and potassium chloride application on K fractions in three typical soils of China was evaluated during 90-d laboratory soil incubation. The presence of AS significantly altered the distribution of native and added K in soils, while addition of MCP did not significantly affected K equilibrium in most cases. Addition of AS significantly increased water-soluble K (WSK), decreased exchangeable K (EK) in almost all the soils except the paddy soil that contained considerable amounts of 2:1 type clay minerals with K added, retarded the formation of fixed K in the soils with K added, and suppressed the release of fixed K in the three soils without K added. These interactions might be expected to influence the K availability to plants when the soil was fertilized with AS. To improve K fertilizer use effciency, whether combined application of AS and K was to be recommended or avoided should depend on K status of the soil, soil properties, and cropping systems.  相似文献   

3.
The study on the behaviour of potassium,phosphate and trace elements,Fe,Mn,Cu and Zn,in the rhizosphere of different varieties of flue-cured tobacco (Nicotiana tabacum L.)with high and low potassium application rate with rhizobag technique showed that soil available K,soil available P,and slow available K was in depletion status,whereas DTPA extractable Fe,Mn,Zn and Cu accumulated obviously in rhizosphere.The depletion and accumulation rates of mineral nutrients differed in degree with K application rate,soil type,and tobacco variety.The content of available K in both rhizosphere and bulk soil and K concentration in tobacco leaf increased significantly,and the available P in rhizosphere dropped with more K application.The DTPA-Fe content of red soil much lower in pH was higher than that of calcareous soil in bulk soil.But the DTPA-Fe content of calcareous soil was much higher than that of red soil in rhizosphere,which was considered perhaps to be mainly related to releasing of Fe phytosiderophore.Nitrate coule increase depletion of a vailable K in rhizosphere and also soil pH in comparision with ammonium.  相似文献   

4.
The present article deals with the natural nitrogen-15 abundance of ammonium nitrogen and fixed ammonium in different soils.Variations in the natural ^15N abundance of ammonium nitrogen mineralized in soils under anaerobic incubation condition were related to soil pH.The δ ^15N of mineralizable N in acid soils was lower but that in neutral and calcareous soils was higher compared with the δ ^15N of total N in the soils.A variation tendence was also found in the δ ^15N of amino-acid N in the hydrolysates of soils.The natural ^15N abundance of fixed ammonium was higher than that of total N in most surface soils and other soil horizons,indicating that the increase of δ ^15N in the soil borizons beneath subsurface horizon of some forest soils and acid paddy soils was related to the higher δ ^15N value of fixed ammonium in the soil.  相似文献   

5.
The clay minerals of more than 200 soil samples collected from various sites of Fujian Province were studied by the X-ray diffraction method and transmission electron microscopy to study their distribution and evolution.Montmorillonite was found in coastal solonchak,paddy soils derived from marine deposit,lacustrine deposit and river deposit,and some lateritic red soil,red soil and yellow soil with a low weathering degree.Chlorite existed mainly in coastal solonchak and paddy soil developed from marine deposit.1.4nm intergradient mineral appeared frequently in yellow soil,red soil and lateritic red soil.The content of 1.4nm intergradient mineral increased with the decrease of weathering degree from lateritic red soil to red soil to yellow soil.Hydrous micas were more in coastal solonchak,paddy soils derived from marine deposit,lacustrine deposit and river deposit.and puple soil from purple shale than in other soils.Kaolinte was the most important clay mineral in the soils iun this province.The higher the soil weathering degree,the more the kaolinite existed.From yellow soil to red soil to lateritic red soil,kaolinite increased gradually,Kaolinite was the predominant clay mineral accompanied by few other minerals in typical lateritic red soil. Tubular halloysite was a widespread clay mineral in soils of Fujian Province with varying quantities.The soil derived from the paent rocks rich in feldspar contained more tubular halloysite.Spheroidal halloysite was found in a red soil and a paddy soil developed from olivine basalt gibbsite in the soils in this district was largely“primary gibbsite” which formed in the early weathering stage.Gibbsite decreased with the increase of weathering degree from yellow soil to red soil to lateritic red soil.Goethite also decreased in the same sequence while hematite increased.  相似文献   

6.
Being divided into three groups-strong,moderate and weak-according to the different kinetic parameters (Fmax,km,Cmin) of potassium uptake by crops,21 cultivars of rice have been studied to find out the relationships between their potassium nutrition and the oxidation-reduction status in the rhizosphere soils. Results show that,with no application of K fertilizer,there were higher contents of active reducing substances and ferrous iron in rhizosphere soils planted with cultivars,such as Zhongguo 91,week in absorbing potassium than in soils cropped with cultivars,Shanyou 64,stronger in absorbing potassium.As a result of K application,however,these toxic substances were decreased appreciably in the soil,particularly in the root zone where weakly K-absorbing sultivars were growing,and the parameter of soil redox (pH pE) was increased,the most striking example of this being found in the rhizosphere soil where the more strongly K-absorbing sultivars were growing.On and close to the root surface in soils where rice plants were supplied with potassium fertilizer,rather more iron oxide had been accumulated compared with rice receiving no potash,and even greater amounts of red iron oxide precipitated on the rice root in neutral paddy soils.As shown by the concentration distribution of active reducing substances and ferrous iron in a microzone of the profile,the redox range of rice roots supplied with potassium may extend as far as several centimeters from the root surface.It can thus be seen that potassium nutrition exerts its effect first on the morphological properties of rice roots and their exudation of oxygen,then on the content of soluble oxygen and the count and species of oxygen-consuming microbes in the rhizosphere soil,and finally on the redox status of the soil.  相似文献   

7.
中国湖南省主要水稻土类型的氨固定   总被引:8,自引:3,他引:8  
The contents, affecting factors, seasonal changes and availability of fixed ammonium in major types ofpaddy soils derived from different parent materials in Hunan Province, China, were studied using the Silva-Bremner method by laboratory and pot experiments. Results showed that the content of fixed ammoniumin the plough horizons ranged from 88.3 mg kg-1 to 388.1 mg kg-1, with 273.2 ± 77.7 mg kg-1 on average,accounting for 11.2% of total soil N on average. Content of fixed ammonium decreased in the order of newlylacustrine clayey paddy soil > alluvial sandy paddy soil > purple clayey paddy soil > newly alluvial sandypaddy soil > yellow clayey paddy soil > reddish-yellow clayey paddy soil > granitic sandy paddy soil. Therewere four distribution patterns of fixed ammonium in the profiles to 1-m depth, i.e., increase with the depth,decrease with increasing depth, no distinct change with the depth, and abrupt increase or decrease in somehorizon. Percentage of fixed ammonium in total N increased with the depth in most of the soils. Fixationof NH4+ by soil was higher at 30 ℃ than at 20 ℃ and 40 ℃, and continuous submergence benefited thefixation of NH4+ in newly alluvial sandy paddy soil, purple clayey paddy soil and alluvial sandy paddy soil,while alternating wetting and drying contributed to the fixation of NH4+ in yellow clayey paddy soil mostly.Fixed ammonium content in the test paddy soils was significantly correlated with < 0.01 mm clay content(P < 0.05), but not with < 0.001 mm clay content, total N, organic N and organic matter. Fixed ammoniumcontent varied with rice growth stages. Application of N fertilizer promoted fixation of NH4+ by soil, and Nuptake by rice plant promoted release of fixed ammonium from the soil. Recently fixed ammonium in paddysoil after N fertilizer application was nearly 100% available to rice plant, while native fixed ammonium wasonly partly available, varying with the soil type and rice type.  相似文献   

8.
红壤中La的生物富集及其对玉米幼苗生长影响研究   总被引:1,自引:0,他引:1  
Through a pot culture lanthanum nitrate was applied to maize seedlings grown in a red loamy soil to investigate the physiological and toxic effects of added La on the growth of crop seedlings and La bioaccumulation to help understand the environmental chemistry behaviors of rare earth element as fertilizers in soils. Compared to the control, La concentrations in shoots and especially in roots of maize seedlings increased with an increase of La in the soil. Also, with added concentrations of La 〉 0.75 g La kg-1 soil and ≥ 0.05 g La kg^-1 soil, the dry weight of shoots and roots of maize seedlings was significantly reduced (P ≤ 0.05), respectively, compared with the control. Additionally, La ≥0.5 g kg^-1 in the soil significantly inhibited (P ≤ 0.05) primary root elongation. Roots were more sensitive to La stress than shoots and thus could be used as a biomarker to La stress. Overall, in the red loamy soil studied, La had no significant beneficial effects on the growth of maize at the added La levels above 0.1 g kg^-1 soil.  相似文献   

9.
中国洞庭湖区稻田土壤氮素淋溶损失的系统研究   总被引:5,自引:0,他引:5  
A two-year lysimeter study was conducted to study the effects of different fertilizers and soils on nitrogen leaching loss in a double rice cropping system by considering three major types of paddy soils from the Dongting Lake area. The results showed that N concentration in the leachate did not differ significantly among the treatments of urea, controlled release N fertilizer and pig manure and that all these fertilizers produced higher total nitrogen (TN) concentrations in the leachate compared to the case where no fertilizer was applied. The TN leaching loss following urea treatment accounted for 2.28%, 0.66%, and 1.50% of the amount of N applied in the alluvial sandy loamy paddy soil (ASL), purple calcareous clayey paddy soil (PCC), and reddish-yellow loamy paddy soil (RYL), respectively. Higher TN loss was found to be correlated with the increased leachate volume in ASL compared with RYL, and the lowest TN loss was observed in the PCC, in which the lowest leachate volume and TN concentration were observed. Organic N and NH4+ -N were the major forms of N depleted through leachate, accounting for 56.8% and 39.7% of TN losses, respectively. Accordingly, soil-specific fertilization regimens are recommended; in particular, the maximum amount of fertilizer should be optimized for sandy soils with a high infiltration rate. To avoid a high N leaching loss from rice fields, organic N fertilizers such as urea or coated urea should primarily be used for surface topdressing or shallow-layer application and not for deep-layer application.  相似文献   

10.
A filed experiment with an early rice-late rice rotation was carried out on a paddy soil derived from red soil in the southern part of Zhejing Province to elucidate the effect of excess P application on some important characteristics of soil properies and its relation to nutrient status and grain yields of rice crops.The experimental results indicated that adequate fertilizer P(15 kg P hm^-2)could increase the content of soil available P at the tillering stage of early rice,the contents of N,P and K in the shoots of early rice at primary growth stages,and the grain yield of early rice by increasing valid ears per hectare and weight per thousand grains,which,was mainly related to the higher contents of reduced,non-reduced and total sugar in the shoot at the heading stage, And early rice supplied with excessive P could not yield more than that applied with adequate, P de to the reduction in the valid grain percentage and weight per thousead grains. In addition,one-time excess P supply at a rate as high as 90 kg P hm^-2 could not improve the soil P fertility in case the soil available P content was lower than the initial(3.74mg kg^-1 soil) after an early rice-late rice rotaion,and made a decline in the grain yield increased by per kilogram fertilzer P.Thus,one-time excess P supply should not be adopted for soils with a large P fixation capacity like the paddy soils derived from red soils.  相似文献   

11.
A 60-day pot experiment was carried out using di-(2-ethylhexyl) phthalate (DEHP) as a typical organic pollutant phthalic ester and cowpea (Vigna sinensis) as the host plant to determine the effect of arbuscular mycorrhizal inoculation on plant growth and degradation of DEHP in two contaminated soils, a yellow-brown soil and a red soil. The air-dried soils were uniformly sprayed with different concentrations of DEHP, inoculated or left uninoculated with an arbuscular mycorrhizal (AM) fungus, and planted with cowpea seeds. After 60 days the positive impact of AM inoculation on the growth of cowpea was more pronounced in the red soil than in the yellow-brown soil, with significantly higher (P < 0.01) mycorrhizal colonization rate, shoot dry weight and total P content in shoot tissues for the red soil. Both in the yellow-brown and red soils, AM inoculation significantly (P < 0.01) reduced shoot DEHP content, implying that AM inoculation could inhibit the uptake and translocation of DEHP from roots to the aboveground parts. However, with AM inoculation no positive contribution to the degradation of DEHP was found.  相似文献   

12.
Soil organic carbon(SOC) and iron(Fe)-oxides are important contributors of aggregate stability in highly weathered soils, and they are influenced by groundwater management and straw application. A 30-year plot experiment with early rice(Oryza sativa L.)-late rice-winter fallow rotations was conducted using a upland clay soil in cement pools under shallow groundwater table at a depth of 20 cm(SGT) and deep groundwater table at a depth of 80 cm(DGT) to simulate the groundwater tables of two types of important paddy soils, gleyed paddy soils and hydromorphic paddy soils, respectively, in subtropical China. Soil redox potential(Eh) was measured in situ, and 0–20 cm soil samples were collected for the analyses of soil Fe-oxides, SOC, and aggregates under SGT or DGT with different straw application treatments, in order to evaluate the interaction of groundwater management and straw application on paddy soil aggregation and the relative importance of SOC or Fe-oxides on soil aggregation. The results showed that soil Eh was restricted by irrigation, and its variation was more significant under DGT than under SGT. The decreased soil Eh or reduced drying and wetting cycles under SGT resulted in more SOC accumulation with the straw application, had no effect on soil free Fe-oxides(Fed), significantly increased the amorphous Fe-oxide(Feo) and complex Fe-oxide contents, but decreased the crystalline Fe-oxide content(Fed–Feo). The soils under DGT had more macroaggregates than those under SGT, but the difference decreased with the straw application. It could be concluded that soil Fe-oxides were the principal contributing factor to the aggregation of paddy soils in subtropical China and SOC was also an important contributing factor.  相似文献   

13.
A field experiment was conducted from 1999 to 2002 to compare and evaluate the effects of nutrient and water regimes on paddy soil quality by investigating soil chemical and microbiological parameters. Four nutrient regimes, a control, chemical fertilizers only (CF), chemical fertilizers with swine manure (SM), and chemical fertilizers with wheat straw (WS), and two soil moisture regimes, continuous waterlogging (CWL) and alternate wetting and drying (AWD), were investigated. With SM and WS total organic carbon and total nitrogen in the paddy soil were significantly higher (P < 0.05) than those with CF. A similar effect for organic amendments was observed in the soil light fraction organic C (LFOC), water-soluble carbohydrates (WSC), and water-soluble organic C (WSOC). CWL, in particular when swine manure was incorporated into the paddy soil, markedly decreased soil redox potential (Eh) and increased total active reducing substances (ARS). Meanwhile, as compared to CF, SM and WS significantly (P < 0.05) increased soil microbial biomass C (MBC) and mineralizable carbon, with differences in AWD being higher than CWL. In addition, SM and WS treatments significantly (P < 0.05) improved rice above-ground biomass and grain yield, with AWD being greater than CWL. Thus, for ecologically sustainable agricultural management of paddy soils, long-term waterlogging should be avoided when organic manure was incorporated into paddy soil.  相似文献   

14.
Soil organic nitrogen (ON) accounts for more than 90%of the total nitrogen (TN) in paddy soils. Inadequate understanding of the different ON fractions in paddy soils and their corresponding bioavailability under different climatic conditions has constrained the development of appropriate nutrient management strategies for rice production. In this study, we applied a modified Bremner method coupled with high-performance liquid chromatography to characterize how soil ON fractions and amino acid ch...  相似文献   

15.
Adsorption of Potassium and Calcium Ions by Variable Charge Soils   总被引:1,自引:1,他引:1  
Interactions of potassium and calcium ions with four typical variable charge soils in South China were examined by measuring pK-0.5pCa value with a potassium ion-selective electrode and a calcium ion-selective electrode,and pK value with a potassium ion-selective electrode.The results showed that adsorption of potassium and calcium ions increased with soil suspension pH,and the tendency of the pK-0.5pCa value changing with pH differed with respect to pH range and potassium to calcium ratio.Adsorption of equal amount of calcium and potassium ions led to release of an identical number of protons,suggesting similar adsorption characteristics of these two ions when adsorbed by variable charge soils.Compared with red soil,latosol and lateritic red soil had higher adsorption selectivities for calcium ion.The red soil had a greater affinity for potassium ion than that for calcium ion at low concentration,which seems to result from its possession of 2:1 type minerals,such as vermiculite and mica with a high affinity for potassium ion.The results indicated that adsorption of potassium and calcium ions by the variable charge soils was chiefly caused by the electrostatic attraction between the cations and the soil surfaces.Moreover,it was found that sulfate could affect the adsorption by changing soil surface properties and by forming ion-pair.  相似文献   

16.
The stability of aggregates in the surface soil is crucial to soil erosion and runoff generation. Thus, to understand the stability and the breakdown mechanisms of soil aggregates as well as the relationship between aggregate stability and selected soil chemical properties, such as different forms of Fe and A1 oxides, organic matter, CEC and clay content, the aggregates of slightly and severely eroded red soils derived from Quaternary red clay in subtropical China were analyzed using the routine wet sieving and the Le Bissonnais methods. The results indicated that the aggregates of the severely eroded soils were more stable than those of the slightly eroded soils. Different aggregate breakdown mechanisms resulted in different particle size distribution. The slaking from entrapped air in aggregates severely destroyed the soil aggregates,especially in the slightly eroded soils. Meanwhile, mechanical breakdown and microcracking had little effect on the aggregates compared to slaking. The fragments resulting from slaking were mainly microaggregates that increased in size with increasing clay content. The main fragment size of the slightly eroded soils was 1.0-0.2 mm, while for the severely eroded soils it was 5.0-2.0 mm and 1.0-0.5 mm. Overall, more than 20% of the fragments were smaller than 0.2 mm.In addition, aggregate stability was positively and often significantly correlated with Fed, Ald, Feo and clay content, but significantly and negatively correlated to SOC.  相似文献   

17.
液体培养研究不同土壤中硝化活性   总被引:2,自引:0,他引:2  
YUAN Fei  RAN Wei  SHEN Qi-Rong 《土壤圈》2005,15(3):379-385
A red soil, a fluvo-aquic soil and a permeable paddy soil were used in a long-term investigation to study changes in nitrification with treatments: 1) soil incubation, 2) liquid incubation inoculated with soil samples, and 3) liquid incubation inoculated with ammonia-oxidizing bacteria (AOB) from the soils. There were significant differences (P < 0.001) in nitrification rates among the three soils when measured for 28 days by adding (NH4)2SO4 at the rate of 154 mg N kg-1 dry soil to fresh soil. However, the amounts of nitrifying bacteria in the three soils were not related to soil nitrification capacity. When the soil samples or the isolates of AOB enriched from the corresponding soil were incubated in liquid with pH 5.8, 7.0 and 8.0 buffers and 10 mmol L-1 ammonium nitrogen, there were no significant nitrification differences in the same soil type at each pH. The ability to oxidize ammonia through AOB from different types of soils in a homogeneous culture medium was similar, and the soil nitrification capacity could reflect the inherent properties of a soil. Altering the culture medium pH of individual soil type also showed that acidification of an alkaline fluvo-aquic soil decreased nitrification capacity, whereas alkalinization of the acidic red soil and permeable paddy soil increased their nitrification. For a better insight into factors influencing soil nitrification processes, soil properties including texture and clay composition should be considered.  相似文献   

18.
Isotopic exchangeability of phosphorus in four Chinese soils with and without P application was studied by ^32P and ^33P double-labeling technique in relation to routine chemical extractions.The results showed that Bray-I and Bray-Ⅱ reagents could extract most of the fast exchangeable P.Not all of the Olsen-P belonged to fast exchangeable P,but it was about the same quantity of fast exchangeable P in a calcareous soil and a neutral soil without P application.Sequential fractionation of the soil phosphorus showed that most of the added radioisotopes in high P fixation red soils were tightly held by iron and aluminium oxides,which could be totally extracted only by 0.1M NaOH solution.In the neutral and calcareous soils most of the radioisotopes added were loosely held on the surface of soil particles and could be extracted by anion exchange resin.Phosphate application increased the resin-P fraction significantly for all the soils studied.  相似文献   

19.
一种新的提高树苗盐容量的移植方法   总被引:2,自引:0,他引:2  
The influence of quinclorac (3,7-dichloroquinoline-8-carboxylic acid) on enzyme activities in flooded paddy soils was assessed under laboratory conditions. The enzymes differed markedly in their response to quinclorac. Quinclorac inhibited proteinase, hydrogen peroxidase, phosphorylase, and urease activities. The higher the concentration of quinclorac applied, the more significant the inhibition to these observed activities with a longer time required to recover to the level of the control. However, soils supplemented with quinclorac were nonpersistent for proteinase~ phosphorylase and urease as opposed to soils without quinclorac. Dehydrogenase activity was also sensitive to quinclorac. Three soil samples with concentrations of quinclorac higher than 1 μg g^-1 soil declined to less than 20% of that in the control. However, the highest dehydrogenase activity (up to 3.28-fold) was detected in soils with 2 μg g^-1 soil quinclorac on the 25th day after treatment. Quinclorac had a relatively mild effect on saccharase activity at the concentrations used in this experiment and a stimulatory one on soil respiration when added to soil at normal field concentrations. Nonetheless it was inhibited at higher concentrations in paddy soils. Quinclorac is still relatively safe to the soil ecosystem when applied at a normal concentration (0.67 μg g^-1 dried soil) but may have some effects on soil enzymes at higher concentrations.  相似文献   

20.
利用方式和土壤肥力对土壤团聚体和养分的影响   总被引:6,自引:0,他引:6  
The size distribution of water-stable aggregates and the variability of organic C, N and P contents over aggregate size fractions were studied for orchard, upland, paddy, and grassland soils with high, medium, and low fertility levels. The results showed that > 5 mm aggregates in the cultivated upland and paddy soils were 44.0% and 32.0%, respectively, less than those in the un-tilled orchard soil. Organic C and soil N in different size aggregate fractions in orchard soil with high fertility were significantly higher than those of other land uses. However, the contents of soil P in different size aggregates were significantly greater in the paddy soil as compared to the other land uses. Soil organic C, N and P contents were higher in larger aggregates than those in smaller ones. The amount of water-stable aggregates was positively correlated to their contribution to soil organic C, N and P. For orchard and grassland soils, the > 5 mm aggregates made the greatest contribution to soil nutrients, while for upland soil, the 0.25-0.053 mm aggregates contributed the most to soil nutrients. Therefore, the land use with minimum disturbance was beneficial for the formation of a better soil structure. The dominant soil aggregates in different land use types determined the distribution of soil nutrients. Utilization efficiency of soil P could be improved by converting other land uses to the paddy soil.  相似文献   

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