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1.
Design of wood/montmorillonite (MMT) intercalation nanocomposite 总被引：4，自引：0，他引：4
Studying new wood composites through nano science and technology (NSC) will develop new compounding theory of wood, and accelerate the combination of new technology, wood science, material science and other disciplines. The compounding of wood and inorganic MMT on nanoscale molecular level has high potential to greatly improve the mechanical properties, fire retardance, abrasion resistance, decay resistance, dimensional stability and other properties of wood. Based on the great achievements of polymer/montmorillonite (MMT) nanocomposites, this paper reviewed nano intercalation compounding methods (i.e. in-situ intercalative polymerization and direct polymer intercalation), and discussed the structure, properties and modification of montmorillonite (MMT). According to the main chemical components and particular structure of wood, the authors discussed the liquefaction and plasticization of wood, compared the dissolvability and meltability between wood and polymer, and then systematically put forward the basic idea, technological processes and schematic diagram to prepare wood/MMT nanocomposites (WMNC). The key technology to prepare WMNC is either to introduce delaminated MMT nanolayers into wood with the help of some intermediate polymers, or to obtain liquefied wood or plasticized wood from the complicated natural composite. It is applicable and effective to realize wood/MMT nanoscale compounding with the help of proper intercalation agent and medium polymer through the proposed “one-step” or “two-step” impregnating processes. 相似文献
2.
FEI BenhuaResearch Institute of Wood Industry Chinese Academv of Forestry Beijing P R China 《中国林业科技(英文版)》2002,(2)
An experiment on wood drying at different temperatures was conducted to show the fractal nature of the pore space within wood. Cubic blocks made from ginkgo (Ginkgo biloba) and Chinese chestnut (Castanea mollissima) wood were used. Samples were dried in oven at the temperature of 20, 40, 60 and 100 ℃, respectively. All the drying procedures lasted four hours. The mass was weighed and the dimensions were measured immediately for each sample when every procedure of drying ended. The fractal dimensions of the samples were obtained from the measurement. Results showed that the fractal dimensions increased with the drying temperature from 20℃ to 60℃ and the fractal dimensions keep a constant in the main. Results from different species and for different temperatures suggested thefractal dimension was a new parameter to characterize the porosity of wood. 相似文献
3.
With montmorillonite (MMT) organically modified as organophilic MMT (OMMT) and water-soluble phenol formaldehyde resin (PF) as intermediate, Chinese fir (Cunninghamia lanceolata) wood/MMT nanocomposites (WMNC) were prepared via nano intercalation compounding and characterized by XRD, SEM and FTIR. Results show that: 1) the preparation of OMMT is very successful; 2) the self-made PF can effectively intercalate into MMT to increase markably its gallery distance and even exfoliate its nano silicate laminae; 3) the XRD analysis indicates that some exfoliated MMT enters the non-crystallized region of microfibrils in wood cell walls and the crystallinity degree of wood in WMNC decreases; 4) the SEM graphs show that multiform MMT exists in WMNC. Some grains block in wood cell lumen, some layers adhere to the wood surface of the inner cell wall and some exfoliated nanolaminae even insert into wood cell walls; and 5) the FTIR analysis suggests that MMT and wood in WMNC perhaps interact via certain chemical bonding. 相似文献
4.
Lü Ning 《中国林学(英文版)》2003,5(1):39-43
Internal wood surfaces can be treated as fractals, which are between Euclidean geometry and complete randomness. The fractal dimension Dfs is very informative in investigating the roughness of the internal surfaces of wood. In this study, the water sorption isotherms, including adsorption and desorption isotherm, of untreated, benzene-alcohol extracted and delignified (after benzene-alcohol extracted) spruce (Cuninghamia lanceolata) were measured at 30℃. On the basis of these isotherms, the Dfs values were calculated by FHH equation, which is based on multimolecular sorption. The results showed that both groups of Dfs values (respectively calculated from adsorption and desorption isotherms) of untreated, benzene-alcohol extracted and delignified wood have same order, that is, untreated > benzene-alcohol extracted - delignified. Therefore, the conclusion can be made that the benzene-alcohol extractives have significant contribution to the fractal geometry of internal wood surfaces. Lignin also has influ 相似文献
5.
HUANG Luohua QIN Tefu ZHOU Qin LU Xixian Research Institute of Wood Industry Chinese Academy of Forestry Beijing P.R.China 《中国林业科技(英文版)》2005,4(4):92-94
Lauraceae plants are ordinary economic species in Southern China. Some components of essential oil can be extracted from their trunk root, bark, leaf and seedcase. Camphor tree (Cinnamomum camphora) is a rare economic species with fine grain, stable wood properties, and good resistance to fungi and ants. Some of components of the oil with bioactive are good materials for cosmetic and medication industry. Camphor is not only used for the manufacture of cellulose nitrate film as a plasticizer,… 相似文献
6.
IKEDA Atsushi 《中国林业科技(英文版)》2003,(2)
By means of gel permeation chromatography analysis, the molecular weight of liquefied wood under different reaction conditions was investigated to trace the change in the structural characteristics of the liquefied wood. The insoluble residues were analyzed by Fourier transform infrared to investigate the liquefaction order of three main wood components. The results indicate that both reaction temperature and reaction time could affect the molecular characteristics of the liquefied wood obtained. The molecular weight of liquefied Chinese Fir wood is higher than that of liquefied Poplar wood under most of reaction conditions. During wood liquefaction, lignin is liquefied firstly. Hemicellulose is liquefied in the middle stage and cellulose is the most difficult to be liquefied. 相似文献
7.
ZHOU Gao ZHAO GuangjieCollege of Material Science Technology Beijing Forestry University Beijing P.R.China 《中国林业科技(英文版)》2004,3(4):76-80
The use of more and more electron products requires interior wood products to have the performance of electromagnetic shielding. One of the ways to realize it is to introduce the chemical plating which has already been developed in electron industry into wood processing. The paper clarifies the mechanism of electroless copper and gold plating and its application to wood. It emphasizes the development and technology of electroless copper and gold plating on wood. Meanwhile, it points out that it is highly feasible to take this technology into effect. 相似文献
8.
The nano intercalation compounding of wood and MMT has important implications for the modification of wood and for the development of new materials. With water-soluble phenol formaldehyde resin as an intermediary, the nanocomposites of Chinese fir (Cunninghamia lanceolata) wood and montmorillonite (MMT) were prepared via three impregnation methods, i.e. normal pres-sure, once and twice vacuum methods. Based on the weight percent gain (WPG) of impregnated wood, the effects of compounding wood and MMT in term... 相似文献
9.
GIS-based decision support system for wood logistics 总被引：1，自引：0，他引：1
QiuRongzu EskoMikkonen 《中国林学(英文版)》2004,6(4):29-33
A wood logistics system was combined with a linear programming (LP) method utilizing GIS-based techniques on the platform of GIS soflware-ARC/INFO. The combined costs of road and off-road transport were taken as the objective function to find the least cost route and the optimal landing locations of wood transportation. Then transport costs and allowable wood volume of stands were calculated. An LP model was developed to allocate timber resources among mills in order to minimize the wood logistics costs from harvesting sites to mills. The parameters of the LP model, including the transport costs, allowable wood volume and wood orders, were written into a text file in MPS format which were then accessed by LINDO to solve the LP problem. The system is an effective tool to manage logistics, information and funds together in order to increase the speed of wood logistics and reduce the cost.The benefits and efficiency of mill cluster can be improved. The focal firm in the cluster can be competitive. 相似文献
10.
CHEN Peng ZHAO Guangjie College of Material Science Technology Beijing Forestry University Beijing P.R.China 《中国林业科技(英文版)》2007,(2)
There are many advantages of bended wood,such as good-looking shape,simple process and low cost.The product,however,is easy to get recovery,which is urgent to be dealt with.This paper concludes the features of deformation and recovery of bended wood and wood-based composites and summarizes four treating methods to keep dimensional stability.Compared to bended solid wood,some elementary perspectives on the research of bended wood-based composites are presented.The purpose of this paper is to suggest:1)to investigate the optimum heating time and temperature that bended wood and wood-based composites need from the formation of deformation to the recovery and to the permanent fixation,according to its changes of dimensional stability such as curvature radius;2)to measure the composites comprised of wood and adhesives on the changes of stress relaxation,dynamic viscoelasticity and crystal1ization field;3)to quantitatively analyze changes of the major components in wood cell wall polymers as well as the composites under heat/steam treatment and untreated conditions.It will be helpful for subsequent research to clarify on the mechanisms of permanent fixation of bended wood and also contribute to that of wood-based composites. 相似文献
11.
Studying new wood composites through nano science and technology (NSC) will develop new compounding theory of wood, and accelerate the combination of new technology, wood science, material science and other disciplines. The compounding of wood and inorganic MMT on nanoscale molecular level has high potential to greatly improve the mechanical properties, fire retardance, abrasion resistance, decay resistance, dimensional stability and other properties of wood. Based on the great achievements of polymer/montmorillonite (MMT) nanocomposites, this paper reviewed nano intercalation compounding methods (i.e. in-situ intercalative polymerization and direct polymer intercalation), and discussed the structure, properties and modification of montmorillonite (MMT). According to the main chemical components and particular structure of wood, the authors discussed the liquefaction and plasticization of wood, compared the dissolvability and meltability between wood and polymer, and then systematically put forward the basic idea, technological processes and schematic diagram to prepare wood/MMT nanocomposites (WMNC). The key technology to prepare WMNC is either to introduce delaminated MMT nanolayers into wood with the help of some intermediate polymers, or to obtain liquefied wood or plasticized wood from the complicated natural composite. It is applicable and effective to realize wood/MMT nanoscale compounding with the help of proper intercalation agent and medium polymer through the proposed "one-step" or "two-step" impregnating processes. 相似文献
12.
木材/蒙脱土(MMT)纳米插层复合材料的制备构想 总被引：11，自引：0，他引：11
基于聚合物 蒙脱土纳米插层复合材料的研究成果 ,综述了插层复合方法的原理、工艺过程和产品性能 ,分析比较了单体插层原位聚合和聚合物直接插层等方法。从木材与蒙脱土的结构和组成特性出发 ,分析比较了木材与聚合物溶解、熔融性的不同 ,讨论了利用插层复合原理制备木材 蒙脱土纳米复合材料的基本构想 ,并进一步提出了相应的技术路线和工艺流程概念图。 相似文献
13.
柠檬桉木材中二氧化硅的分布和含量的测定 总被引：5，自引：0，他引：5
生物矿化所形成的木材-无机质复合材是当前木材科学研究的热点之一，要实现木材一无机质复合材的人工模拟，其关键还在于研究和探讨木材生物矿化的机理，因此要对木材中无机物的分布及其含量进行研究，从而获取生物矿化所形成的木材一无机质复合材料的形成机理，以此来指导木材的生物改性或木材一无机复合材的仿生合成。本研究采用光学显微镜对柠檬桉木材中二氧化硅的分布进行观察，得出柠檬桉木材中二氧化硅主要分布在射线细胞中，同时大量的晶体存在于轴向薄壁细胞中，早材中的硅石多于晚材中的硅石。采用重量法对木材轴向分布、径向分布中灰分和二氧化硅的含量进行的分析表明：柠檬桉木材中灰分和二氧化硅的含量随着高度的增加而降低，柠檬桉木材灰分和二氧化硅的含量从边材部位向心材部位逐渐减少。 相似文献
14.
Summary A study of the wood-inorganic composites prepared by the sol-gel process with a metal alkoxide indicated that an inorganic modification of wood with TiO2 gels from tetraisopropoxytitanium (TPT) can not improve its properties due to the formation of the gels in the cell lumina by high hydrolysis rate of TPT. In this study, therefore, titanium alkoxides or titanium chelates which have the lower rate of hydrolysis and subsequent polycondensation than TPT were used for preparing TiO2 wood-inorganic composites to study the topochemical effects of the TiO2 gels for the property enhancement of wood. As a result, it was found by SEM-EDXA analysis that the TiO2 gels deposited within the cell walls could improve the properties of wood in dimensional stability and fire-resistance, whereas for the gels in the cell lumina, property enhancement could not be achieved, as observed in SiO2 wood-inorganic composites.This research has been performed in Dept. of Wood Sci. & Technol., Kyoto UniversityThis research was supported by a Grant-in-Aid for Scientific Research (B) (No. 06453176, 1994.4–1996.3) from the Ministry of Education, Science, and Culture, Japan. The authors were grateful to Nippon Soda Co., Ltd. for providing titanic reagents. 相似文献
15.
微纳米和微米木纤维理论研究的现状与工业化前景 总被引：6，自引：0，他引：6
微纳米和微米木纤维技术是近代高科技技术与木材工业结合的集中体现。本文综合介绍了国产外微纳米和微米木纤维理论研究现状，阐述了微纳米和微米木纤维理论的应用在我国的工业化前景。 相似文献
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17.
分别将木粉、纤维素和木质素在乙二醇中进行热化学液化。研究结果表明木粉中纤维素的非结晶区、木质素和半纤维素首先被液化,而纤维素的结晶区较慢被液化,到液化反应中期基本降解完全,液化产率高于97%。利用在线红外光谱仪跟踪检测了整个液化反应过程,结合GC-MS结果发现:乙二醇在反应过程中脱水生成了二甘醇和三甘醇。在液化反应中,纤维素的糖苷键断裂后生成葡萄糖苷结构,随后葡萄糖苷中的吡喃环也被打开,生成的活性中间体相互反应或与乙二醇反应生成了如3-(2-甲基-[1,3]-二氧戊环-2-基)-丙酸乙酯、乙酰丙酸丁酯等酯类;木质素的苯丙烷结构主要降解为苯酚、2,6-甲氧基苯酚等芳香族衍生物,因此木粉液化产物是聚醚/酯混合多元醇。 相似文献
18.
LV Wenhua ZHAO Guangjie College of Material Science Technology Beijing Forestry UniversityBeijing P.R. China 《中国林业科技(英文版)》2004,3(1):46-52
1INTRODUCTIONAsbiologicmaterialformedbycells,Woodhasparticularstructureandprominentproperties.Woodisgreenenvironmentalmaterial.Inthisaspect,otherengineeringmaterialscannotcomparewithwood.Woodhasmanyspecialvirtues,buthasalsomanyinherentdefectsthatcantbeovercomebyconventionalprocessingmethods.Woodcompositesaremoreadvantageousthancommonwoodandotherconventionalmaterialsincomposition,structure,propertiesandsoon.WiththegreatachievementsinWoodcompositematerials,manynewhigh-levelwoodcompositesha… 相似文献
19.
LI Beimei ZHAO Guangjie College of Material Science Technology Beijing Forestry University Beijing P.R.China 《中国林业科技(英文版)》2006,5(4):9-15
INTRODUCTION During the middle and late 20th century, the concept of fractal was first proposed and developed by a mathematician Benoit B. Mandelbrot in his two treatises (Mandelbrot 1977, 1982). Fractal theory makes such a great breakthrough that it can be used to quantitatively describe non-integeral or non-linear objects, which can not be expressed by the classical Euclid geometry, and further reveal the intrinsic laws of complex phenomena being characteristics of disorder, uncertaint… 相似文献