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1.
Poor compatibility was found between exploded wood fiber strand (WFS) and cement due to the excessive presence of water-soluble degraded polysaccharides in extractives of exploded WFS obtained from weathered wood waste treated by the water-vapor explosion process (WVEP). This study presents some comparative results from a continuing investigation on the compressive strengths of exploded WFS–cement mixtures. Based on results previously obtained with the hydration test, the relation between hydration behavior and compressive strength of the mixture was explored. In addition, the effect of the curing age on compressive strength development of the mixture with selected additive chemicals was examined. The results supported the results of early studies with hydration tests indicating that adding MgCl2 to the mixtures of exploded WFS mixed with quick-curing cement or ordinary Portland cement and a composite of MgCl2 + CaO added to the mixture of exploded WFS and furnace-slag cement effectively improved the hydration behaviors; it greatly enhanced the compressive strengths of mixtures as well. Compressive strengths were strongly correlated to maximum hydration temperatures (Tmax) of wood–cement mixtures influenced by the cement type, wood wastes (treated or not with WVEP), additive chemicals, and their content levels. The results also indicated that adding selected chemicals had no significant effect on compressive strength among the mixtures of exploded WFS mixed, respectively, with three types of cement at a curing age of 180 days. X-ray diffraction, scanning electron microscopy, and energy dispersive X-ray spectroscopy were used to identify the hydration products and to probe the element distribution of the mixture in the wood–cement interface zone from a fractured surface.Part of this report was presented at the 52nd Annual Meeting of the Japan Wood Research Society, Gifu, April 2002  相似文献   

2.
This study dealt with the effects of a curing method that uses gaseous and supercritical CO2. Its effects on the properties of oil palm fronds cement-bonded board manufactured by the conventional cold-press setting method were recorded. The effect of MgCl2 as an accelerator of cement setting was also investigated. The hydration of cement was examined using X-ray diffractometry, thermal gravimetry, and scanning electron microscopy. The results are as follows. (1) High-performance cement-bonded boards made from oil palm fronds were successfully manufactured using the CO2 curing method. (2) The curing method using either gaseous or supercritical CO2 resulted in accelerated curing of cement (within several minutes). Accelerated formation of the hydration products (e.g., calcium carbonate and calcium silicate) is the main reason for the high strength of CO2-cured boards. (3) The CO2 curing technology does not require setting accelerators, which cause a decrease in the dimensional stability of cement-bonded board.  相似文献   

3.
As an essential preliminary evaluation for understanding the hydration behavior of wood-cement-water mixtures, an isothermal calorimetry and experimental method were used to measure the hydration heat of woodcement-water mixtures. The compatibility of 38 wood species with ordinary portland cement was studied using this procedure. Based on the results, all the wood species tested were classified into two groups. The 24 species included in the first group showed a moderating influence on the hydration reaction of cement, and a maximum temperature (T max) peak during the exothermic reaction while the cement set appeared within 24h for each species. The other 14 species inhibited cement hydration completely. According to the maximum hydration temperature (T max) and the time (T max) required to reach the maximum temperature of the mixture, the suitability of each species in the first group was estimated when used as a raw material during production of cement-bonded particleboard. By testing mechanical properties [modulus of rupture (MOR) and internal bonding strength (IB)] during the board-making experiment using the same composition of wood-cement-water, a positive correlation was found betweenT max andt max and MOR and IB. The results imply that the method can be used as a predictor of the general inhibitory properties and feasibility of using wood species as raw materials prior to manufacture of cement-bonded particleboard.Part of this report was presented at the 49th annual meeting of the Japan Wood Research Society, Tokyo, April 1999  相似文献   

4.
To provide information on the feasibility of using exploded wood fiber strand (WFS) obtained by the water-vapor explosion process in wood-cement mixtures, the compatibility between cement and exploded WFS and its improvement with various additive chemicals were investigated by observation and analysis on hydration behaviors in terms of hydration characteristics: maximum hydration temperature (T max) and required time (t max). The three types of cement, six additive chemicals, and exploded WFS (sugi, air-dried and water-soaked) were employed as raw materials in this study. The hydration behaviors of mixtures demonstrated that exploded WFS had strong retarding effects on cement hydration and completely prevented mixtures from setting. The analysis of sugar revealed that the sugar contents of exploded WFS were much higher than those in unexploded wood and increased to about 20-fold (air-dried) and 10-fold (water-soaked), respectively. The degraded polysaccharides became a major factor and played an important role in inhibiting the setting of cement. Moreover, high-performance liquid chromatography analysis proved that the main peaks representing the molecular weight of polysaccharides in extractives of exploded WFS shifted markedly to a lower range of polymerization. MgCl2 was determined to be an effective additive chemical for restraining the inhibitory influences. Addition contents of 2%–3% and 4%–5% were available and acceptable for quick-curing cement and ordinary Portland cement, respectively. As for the furnace-slag cement, the composite additive chemicals of MgCl2 (4%) and CaO (2%) were found to have an obvious accelerating effect.Part of this report was presented at the 51th Annual Meeting of the Japan Wood Research Society, Tokyo, April 2001  相似文献   

5.
The influence of the 30 chemical additives on the hydration characteristics of birch wood-cement-water mixture was determined by measuring the maximum hydration temperature (T max) and the time (t max) required to reach the temperature. The chemical additives were tested and divided into two types depending on the pattern of exothermic reaction peak within the 24-h observation period. The wood-cement-water mixtures with additions of each of the 11 type I chemical additives showed a two-peak temperature-time curve similar to that for neat cement. CaCl2, FeCl3, and SnCl2 reached the highestT max above 50°C. When the 19 type II chemical additives were included, the mixtures offered only one peak hydration temperature-time curve. Among them, the 10 chemical additives caused an obvious temperature increase at the beginning of the hydration reaction. The most significant effect was with the addition of diethanolamine, where the mixture produced aT max above 50°C. The strength values (modulus of rupture, internal bond strength) of word-cement board were tested with separate additions of the 10 chemical additives arranged by the highestT max. There was a good positive correlation betweenT max and the strength values. In addition, the composite chemical additives were preliminarily examined to determine if they accelerated the hydration reaction of blast-furnace slag cement. The results revealed that composite chemical additives evidently accelerated the hydration reaction and the setting of blast-furnace slag cement mixed with wood. Blast-furnace slag cement can thus be considered for use as an acceptable inorganic bonding material for wood-cement panel manufacture.Part of this report was presented at the 49th Annual Meeting of the Japan Wood Research Society, Tokyo, April 1999  相似文献   

6.
Abstract

The present work was conducted to study the effects of wood species, particle size and residue particle size obtained from trimming of wood–cement composites on physical and mechanical properties of cement-bonded particleboard (CBPB). Particleboard was manufactured with a wood/cement ratio of 1:3 and specific gravity 1200 kg m?3. After manufacturing, the boards were tested. The second order plan was used to test the significant difference between factors and levels. It was shown that slenderness and compaction ratio increased and bulk density and specific surface decreased with the increase of particle size. With the increase in slenderness ratio and compaction ratio and decrease in bulk density and specific surface, thickness swelling and mechanical properties improved, but water absorption by the board increased. The addition of 6% of 5/3 fraction size of particle obtained from trimming of boards improved significantly the properties of the boards. The optimized panel properties, obtained using poplar particles with a fraction size of 7pass/on5, exceeded the BISON type HZ and EN Standard for Wood Particleboard. CBPB made of alder or poplar particles with 5/3 fraction size of residue exceeded the BISON type HZ. All CBPB with 5/3 fraction size of residue showed lower mean values of thickness swelling, well below the maximum requirements of both standards. In addition, wood species, fraction size of particles and residue size are believed to have been the main cause of change in the properties of the boards.  相似文献   

7.
Summary Tangential shrinkage was measured on longitudinal-tangential slices of separate earlywood and latewood from one board of Eucalyptus regnans F.Muell. at various temperatures. Large amounts of collapse shrinkage were measured in the latewood slices, and lesser amounts in the earlywood slices. Collapse shrinkage in the earlywood was found only when the slices were dried at temperatures above a minimum temperature (the collapse threshold temperature). End-coated board sections approximately 200 mm long were rapidly dried at dry-bulb temperatures below the collapse threshold temperature for earlywood. Incipient internal checks were found in the latewood of these boards. Board sections dried at higher temperatures showed internal checks starting in both early and latewood. A non-linear drying simulation model was modified to take the heterogeneous nature of wood into account. This model predicted that internal checks would form in this wood even if it were dried sufficiently slowly to avoid surface checking.Symbols D Diffusion coefficient - ec Creep strain - ei Instantaneous strain - em Mechano-sorptive strain - en Net strain - eu Unconfined shrinkage strain - EW Earlywood - FSP Fibre saturation point - LW Latewood - L-T Longitudinal-tangential slice - MC Moisture content (kg water/kg dry wood) - q Moisture concentration - R-T Radial-tangential slice - t Time - y Depth in board The author is pleased to acknowledge the assistance of Emeritus Professor A. R. Oliver, Associate Professor P. E. Doe, University of Tasmania, and the Australian Furniture Research and Development Institute  相似文献   

8.
Previous papers have quantitatively indicated that the total movement of cement bonded particleboard (CBPB) is equal to the sum of the movement of its components. This paper examined the efficacy of the law of mixtures when applied to the movement of a wood-cement composite under internal swelling or shrinkage stresses. Abundant data generated in companion papers were first manipulated to develop the universal formulae for predicting the movement of components. In conjunction with previous numerical results from image analysis of the structure of CBPB, and the orientated elasticity and stress algorithms, the models for theoretically predicting mass and dimensional changes of CBPB were derived. Validation studies were conducted and these demonstrated an excellent agreement of the theoretical predictions with experimental data for both mass and dimensional changes of CBPB due to internal swelling or shrinkage stresses during adsorption and desorption. The success also implied that CBPB can be treated as a composite and its properties can be well derived by the law of mixtures even though CBPB is an unusual type of composite having a very high volume fraction of wood chips, but a very high mass fraction of cement paste.Notation ERT Mean transverse modulus of elasticity of wood - EL Longitudinal modulus of elasticity of wood - Ep Modulus of elasticity of cement paste - Ewa Modulus of elasticity of embedded wood chips at angle - E Modulus of elasticity of wood chips at direction - E Modulus of elasticity of wood chips at direction - GLRT Mean transverse shear modulus of wood - L(T)cp Length/width (thickness) change of CBPB at angle - L(T)p Length (thickness) change of cement paste - mpf Mass fraction of cement paste in unit mass of CBPB - mwf Mass fraction of wood chips in unit mass of CBPB - Mcpj Mass change of CBPB at the various conditions tested - Mpj Mass change of cement paste at corresponding conditions - Mwj Mass change of wood chips at corresponding conditions - M(L; T)w/P Mass, length or thickness changes of wood chips or cement paste at various conditions - t Duration of exposure - LRT Mean transverse Poissons ratio of wood - Vpf Volume fraction of cement paste in unit mass of CBPB - Vwf Volume fraction of wood chip in unit mass of CBPB - cp Density of CBPB - k Density of wood chip or cement paste - cp Overall stresses of CBPB at angle - L Stress in the longitudinal direction of wood - RT Mean stress in the transverse direction of wood - p Stress of cement paste - w Stress of the wood chips at angle - Stress of the wood chips at direction - Stress of the chip at direction - cp Strain in CBPB - p Strain of cement paste - WL Strain in the length of wood chips - WT Strain in the thickness of wood chips - w Strain in wood chips - Angle between the longitudinal direction of wood chips and surfaces or edges of CBPB - Angle between wood chips and edges (length direction) of CBPB - Angle between wood chip and vertical coordinate - A, B, C Coefficients related to the feature of materials and exposure conditions The senior author wishes to thank Professor W.B. Banks of University of Wales, Bangor for his constructive discussions and assistance and the British Council for partly financial support.  相似文献   

9.
Binderless boards were prepared from finely ground powders of kenaf (Hibiscus cannabinus L.) core under varying manufacturing conditions. This research was designed to investigate their mechanical properties and evaluate the various manufacturing conditions: pressing temperature and time, pressing pressure, board density, board thickness, grain size of raw materials, and addition of furfural. The mechanical properties (i.e., modulus of rupture and elasticity, internal bonding strength) of boards increased with increasing board density and met the requirement for 15 type medium-density fiberboard (MDF) by JIS A 5905-1994. Thickness swelling and water absorption of boards exceeded the maximum permitted levels for 15 type MDF and S20 grade hardboard by JIS A 5905-1994, which indicates the low water-resistant property of binderless boards. In contrast to that in usual wood-based materials, internal bonding strength showed significant correlations with other board properties: modulus of rupture and elasticity, thickness swelling, and water absorption. We confirmed experimentally that the best manufacturing conditions proved to be as follows: pressing temperature 180°C, time 10min; pressing pressure 5.3MPa; board thickness 5mm; board density 1.0g/cm3; average grain size 53µm; and powder with no furfural content.Part of this paper was presented at the 52nd Annual Meeting of the Japan Wood Research Society, Gifu, April 2002  相似文献   

10.
热压水泥刨花板工艺的研究   总被引：8，自引：0，他引：8  
本文主要论述了热压法制造水泥刨花板的工艺。试验选取热压温度、热压时间、水灰比、灰木比、添加剂和板子密度等工艺变量建立多元回归方程,并对刨花形态等问题进行了讨论。试验结果表明:热压温度和刨花形态对板子性能影响极为显著;热压法水泥刨花板不仅具有与冷压法相同的物理力学性能,而且还具有水泥水化速度快、板坯脱模强度较高等特点,因而缩短了水泥刨花板的生产过。  相似文献   

11.
The purpose of the study was to investigate the relation between the skin temperature of the palm and sensory cold-warmth after contact with some materials. Ten men and ten women were selected and introduced to 21 kinds of material for a contact test of 30 min without seeing the specimens in a climate-controlled room at 25±1C and 65% relative heemidity. The palm-contacted test materials and skin temperature of the palm, central fingertip, and back of the palm were measured during the experiment. A sensory evaluation test was applied to evaluate the contacted sensory cold-warmth. Results showed that the maximum temperature decrease of the fingertip (T d) was positively related to the natural logarithm of the material's specific gravity (ln u) and to the natural logarithm of the material's thermal conductivity (ln). There were also negative linear relations between the contacted sensory cold-warmth (S) with ln u and ln; and there was a negative linear relation betweenS withT d and betweenS with the value ofT d by . The thermal osmotic coefficient (b) of wood and wood-based materials ranged from 3.63 to 3.97, and the materials were qualified as good thermal insulation materials. Furthermore, there was a negative linear relation betweenS andb. Accordingly, it is possible to evaluate the contacted sensory cold-warmth relying on the basic thermal properties of material.Part of this report was presented at the 49th Annual Meeting of the Japan Wood Research Society, Tokyo, April 2–4, 1999  相似文献   

12.
Binderless boards were prepared from steam-exploded fiber of oil palm(Elaeis guineensis Jacq.) frond at six levels of explosion conditions. Their properties were investigated and evaluated. The mechanical properties (i.e., modulus of rupture, modulus of elasticity, and internal bonding strength) of the boards increased linearly with increasing board density as the usual hardboard. The boards made from fibers treated under a steam explosion condition of 25 kgf/cm2 (steam pressure) and 5 min (digestion period) exhibited the maximum strength. These boards at a density of 1.2 g/cm3 met the requirement of S-20 grade of JIS A 5905 — 1994 (fiberboard). Thickness swelling of the boards ranged from 6% to 14% under the JIS A 5908 — 1994 (particleboard) test condition and showed no significant changes with increasing board density. The main bonding strength of the board is believed to be due to a ligninfurfural linkage. Considering the chemical components of oil palm frond, which is rich in hemicellulose, there seems to be a good possibility for producing binderless boards using steam-exploded fibers of oil palm frond.This study was presented in part at the 2nd International Wood Science Seminar, Serpong, Indonesia, November 1998  相似文献   

13.
几种树种木材制造石膏刨花板的适应性   总被引：1，自引：0，他引：1  
张奕 《木材工业》1990,4(4):3-7,18
本文论述了挪威云杉、山杨、白桦和柞木及山杨、白桦、柞木的混合刨花制造石膏刨花板的适应性。结果表明,在工艺参数相同的情况下,木材密度越大的树种制成的板材强度越低,挪威云杉板强度最大,山杨板次之,柞木板极低。挪威云杉和山杨是制造石膏刨花板的优质树种。改变木膏比、刨花体积和对刨花进行水抽提均没有使白桦和柞木制成合格的石膏刨花板。混合刨花干扰石膏刨花板的凝固时间,致使板子强度低劣,在生产中应予避免。  相似文献   

14.
In breeding Norway spruce, selection for improved growth and survival is performed at age 10–15 years in order to optimize genetic gain per year. We investigated whether a selection based on wood traits such as density and grain angle, measured under bark in the field at the same age would be informative enough with respect to structural quality traits of sawn boards. To achieve this objective, a sawing study was conducted on the butt logs of 401 trees from a 34-year-old Norway spruce progeny trial situated in southern Sweden. Stem discs were excised from the top of the logs and radial profile data of grain angle, and wood density was recorded for specific annual rings. The sawn and dried boards were assessed for structural traits such as twist, board density, bending stiffness (static modulus of elasticity, sMoE) and bending strength (modulus of rupture, MoR). Additive genetic correlations (ra) between single annual ring density measurements and board density, sMoE and MoR were consistently strong (ra>?0.7) for annual rings 5–13. Genetic correlations of similar magnitude between grain angle and board twist were estimated for all investigated annual rings (from 2 to around 26 under bark). Consequently, it was found that indirect selection for wood density and grain angle at the tree age 10–16 years would result in more genetic gain per year than selection at later ages. This makes it feasible to perform simultaneous selection of progeny in the field for both growth and wood traits at similar ages.  相似文献   

15.
Binderless boards are composite boards that rely on self-bonding mechanisms for inter-fibre bonding. Quercus acutissima and Quercus serrata logs degraded by Lentinula edodes (shiitake fungi) were used in this study to investigate whether physical and chemical changes induced by shiitake fungi can enhance board mechanical properties. Binderless boards were manufactured with 0.8 g/cm3 target density, 220 °C pressing temperature, 5 MPa pressure, and pressing duration of 10 min. Boards made from logs degraded for ≥?26 months were stronger than control boards and met modulus of rupture (MOR) and internal bonding (IB) requirements for fibreboards. Chemical composition and particle size distribution of the wood powder used to make the boards were determined to elucidate the drivers of board mechanical properties. The proportion of small particles (<?150 µm) showed a strong positive correlation with MOR for both species and hot water extractives showed a strong positive correlation with IB for Q. acutissima boards. Introduction of shiitake fungi pre-treatment to the production process may enhance the mechanical strength of binderless boards.  相似文献   

16.
柠檬桉水泥刨花板若干工艺因子的研究   总被引：2，自引：1，他引：2  
通过对柠檬桉制造水泥刨花板的可能性、水泥/刨花的比率、水泥种类与板材性能关系等因素的研究,结果表明:使用添加剂或对木材进行热水处理可以使柠檬桉成为适宜制造水泥刨花板的树种。  相似文献   

17.
Summary Oligoesterification reaction of wood with phthalic anhydride and glycidyl methacrylate (GMA) was investigated. The reaction proceeded smoothly at 90°C. The products obtained consisted of acetone-insoluble and soluble parts. The insoluble parts were novel oligoesterified woods with oligoester chains having methacrylate double bonds. The soluble parts were viscous liquids consisting mainly of free oligoesters not linked with the wood matrix, and contained small amounts of GMA and oligoesterified wood components which were dissolved out. The products (the oligoesterified wood-containing mixtures), when subjected to hotpressing, gave plasticized crosslinked wood boards whose surfaces are smooth, glossy, and plasticlike. In this case, plasticization of wood components and thermal polymerization of the methacrylate double bonds in the oligoester chains occurred simultaneously even in the absence of radical initiator. The soluble parts worked as a plasticizer for the wood components. The crosslinked wood boards exhibited outstanding properties in tensile strength (ca. 700 kg/cm2), flexural strength (ca. 900–1030 kg/cm2), and Rockwell hardness (ca. 120).  相似文献   

18.
To control reliably the suitable use of curved laminated veneer lumber (LVL) as a structural member of furniture, stress distributions and failure types of curved LVL made from massion pine (Pinus massoniana Lamb.) and fast-growing poplar (Populus euramericana CV. I.) were investigated under end-pull, end-thrust, and transverse loading. The results are summarized as follows: In curved LVL of two wood species, absolute values of the maximum axial stress ( A) occurring at the convex surface are smaller than those ( B) that occurred at the concave surface. The differences between these values decrease with an increase in the radius of curvature. With end-pull loading, there were mainly splitting failures at glue lines near the centroidal axis. With end-thrust loading, there were more fibrous fractures on the tensile side and crushing failures on the compression side. With transverse loading, curved specimens of massion pine exhibited mainly splitting failures. In contrast, for curved LVL of fast-growing poplar, fibrous fractures occurred mainly on the tensile side. Absolute values of A and B significantly increased with an increase in the radius of curvature. In contrast, absolute values of the maximum radial stress ( R,) decreased with an increase in the radius of curvature. Absolute values of A, B, and R of curved LVL of massion pine were larger under end-thrust loading than under end-pull and transverse loading. Conversely, absolute values of A and B of curved LVL of fast-growing poplar were small under end-thrust loading. However, absolute values of A and B of curved LVL of two wood species under end-pull loading were almost similar to those under transverse loading.Part of this study was presented at the 10th annual meeting of Chugoku Shikoku branch of the Japan Wood Research Society, Miki, Kagawa, September 25, 1998 and the 4th Pacific Rim Bio-Based Composites Symposium, Bogor, Indonesia, November 2–5, 1998  相似文献   

19.
Summary Various chemicals are used for protecting wood samples against fungi, and some of them are released in water, leading to pollution of the water. The kinetics of pentachlorophenol release in water has here been studied by considering the diffusion through the wood along the three principal axes of diffusion. The experiments and the modelling of the process is successfully coupled. The numerical model takes into account the three principal diffusivities, the partition factor, the volumes of wood and water. The effect of wood sample length along the longitudinal axis of diffusion is studied especially, as longitudinal diffusivity is much higher than the other two principal diffusivities. The effects of the relative volumes of wood and water are also of considerable interest not only for the concentration of the chemical in water but also for the rate of release.Symbols C concentration of liquid (g/cm3)_ - C c ,C eq concentration of liquid on the surface, at equilibrium with the surrounding, respectively - C i,j,k concentration of liquid in the wood at positioni, j, k - D diffusivity (cm2/s) - h coefficient of mass transfer on the surface (cm/s) - K partition factor - i, j, k integers characterizing the position in the wood - M L ,M R ,M T dimensionless numbers - M t ,M amount of chemical released after time t, after infinite time, respectively - t increment of time - L, R, T thickness of the slices taken in the wood for calculation - N L ,N R ,N T number of slices taken in the wood - x, y, z coordinates - V water volume of the surrounding water  相似文献   

20.
Ozonation as a quantitative tool to analyze the stereo structures of arylglycerol--aryl ether linkages was examined using wood meal, milled wood lignin, and a lignin model compound, 1-(3,4-dimethoxyphenyl)-2-(2-methoxyphenoxy)-1,3-propanediol (veratrylglycerol--guaiacyl ether, VG). The procedure was improved. When mild postreduction was conducted for ozonation products, the total yield of erythronic and threonic acids from this model compound was 74%, which is 15% higher than the yield without postreduction. A decrease in the recovery of these two acids under prolonged ozonation treatment was successfully suppressed by postreduction. Theerythro/threo ratio of VG determined by the ozonation method with postreduction is in good agreement with the ratio determined by1H-nuclear magnetic resonance. Excellent reproducibility of the yield was obtained by adopting a procedure that included trimethylsilylation of ammonium salts of ozonation products using a dimethylsulfoxide-hexamethyldisilazane-trimethylchlorosilane mixture and subjecting it to gas chromatography analysis. It was concluded that arylglycerol--aryl ether structures comprise at least 35% of the C3-C6 structure in birch wood meal, with anerythro/threo ratio of 2.8.This paper was presented at the 43rd Lignin Symposium, Fuchu, Japan, October 1998; and at the 10th ISWPC, Yokohama, Japan, June 1999  相似文献   

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