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1.
Temporarily solubilized azo disperse dyes based on 1,2-substituted indoles were synthesized and characterized. Dispersant-free
dyeing of polyester by using the synthesized dyes has been investigated. The colour yields of the dyes on the polyester fabric
were found to be highly dependent on the dyeing pH, optimum results being obtained at pH 5. The dyes exhibited good to excellent
fastness properties on polyester while lightfastness was moderate. 相似文献
2.
In this work, the effects of corona discharge (CD) and chitosan treatment on the dyeability of polyester/cotton blends with direct and reactive dyes were studied. The surface chemical changes of polyester and cotton were analyzed using X-ray Photoelectron Spectroscopy (XPS). The correlation between chemical changes, wettability, and dyeability after CD and/or chitosan treatment has been established. Color intensity of both single components and PES/cotton blend increased proportionally with increasing chitosan concentration. The results obtained open the possibility for a new method for dyeing of polyester/cotton blends in a single bath using one dye-class that is commonly used for dyeing of textile material of cellulosic origin. 相似文献
3.
黄麻/棉织物服用性能探讨 总被引:3,自引:1,他引:3
本文通过试验测定了黄麻/棉织物的服用性能,并与苎麻/棉,涤/棉,纯棉等织物的服用性能进行比较,结论表明黄麻/棉织物作为服用织物是可行的。 相似文献
4.
Three unreported cationic reactive dyes based on azobenzene were synthesized using a novel synthetic route. Synthesized dyestuffs containing three primary color dyes were characterized by FTIR, H-NMR, LC-MS, Element Analysis and UV-vis spectroscopic techniques. The absorption spectra of dyes were measured in three solvents with different polarities. The dyeing and color fastness properties of three cationic reactive dyes on wool, acrylic and wool/acrylic blend fabrics were determined. The optimum pH for wool and acrylic fabrics were 6 and 5, respectively. Effect of temperature, time on dyeing properties and color fastness properties on wool fabric showed the same tendency with acrylic fabric. The K/S value of wool fabric dyed with three dyes was similar to that of acrylic fabric when both fabrics were dyed simultaneously in the same dyebath using low dye concentration. Wool/acrylic blend fabric dyed with three cationic reactive dyes using onebath one-step method achieved good union dyeing property and excellent color fastness. 相似文献
5.
Six nano disperse dyes were prepared using corresponding O/W nanoemulsions which were obtained with sodium laurylsulphate
and caprylic triglyceride. The average particle size of the dyes prepared were in the range of 110–130 nm. Exhaust dyeing
using nano dyes resulted in low exhaustion yields of 17–26 % on regular polyester fiber and 28–38 % on ultramicrofiber polyester.
The observed low exhaustion yields of nano disperse dye can be explained by the solubilization of dye particles into surfactant
micelles as well as the high stability of the nanoemulsions, these might reduce the capacity of dye uptake onto the fibers.
However, higher K/S values of dyeings with nano dyes on ultramicrofiber sites compared to those on regular polyester sites
suggested their potential to be more efficient dyes for finer denier microfiber polyesters. 相似文献
6.
Mikyung Kim Seokhan Yoon Taekyeong Kim Jin-seok Bae Namsik Yoon 《Fibers and Polymers》2006,7(4):352-357
The cotton fabrics were pretreated by sodium 2-(2,3-dibromopropionylamino)-5-(4,6-dichloro-1,3,5-triazinylamino)-benzenesulfonate
(DBDCBS) at alkaline condition of room temperature and then dyed with four disperse dyes having amino groups (C.I. Disperse Yellow
9, C.I. Disperse Red 11, C.I. Disperse Blue 56 and C.I. Disperse Violet 1) at acidic condition of high temperature. A novel
hetero-bifunctional bridge compound,DBDCBS, has two reactive groups such as dichloro-s-triazinyl group andα, β-dibromopropionylamido group. The first has reactivity towards hydroxy group of cellulosic fiber and the second shows reactivity
towards amino groups of disperse dye containing amino groups. The results indicate that it is possible to dye polyester/cotton
blend at one-bath dyeing using one kind of disperse dye containing amino groups. Therefore, two kinds of dyeing methods such
as two-bath process one-bath dyeing and one-bath process one-bath dyeing were investigated and their dyeabilities were compared.
The differences between these two methods were negligibly small so that perfect one-bath one-step dyeing of polyester/cotton
blend by one kind of disperse dye was achieved. 相似文献
7.
The nonionic surfactant properties of ethoxylated azo dyes, such as cloud point and surface tension have been investigated.
The synthesized ethoxylated azo dyes could dye polyester fabric without any special pre-treatment. When the average number
of ethylene oxide (EO) in the ethoxylated azo dye reached 6, its fixation could exceed 90% from the thermosol dyeing process.
The average degree of condensation of ethylene glycol in the chain was interrelated with the dyeing results and did not affect
on the maximum absorption wavelength (λmax) of the polyoxyethylene dye. When the average length of polyoxyethylene chain decreased,
the molecular weight of dyes became smaller and the fixation of dyes was improved. 相似文献
8.
Kim Sam Soo Leem Su Gyung Ghim Han Do Kim Joon Ho Lyoo Won Seok 《Fibers and Polymers》2003,4(4):204-209
The effect of padding solution on the microwave heat dyeing of polyester fabric was studied extensively. Polyester fabrics
were impregnated in aqueous urea solution and aqueous sodium chloride solution for 10 min and then dyed for 7 min by microwave
apparatus (2 450 MHz, 700 W) under optimum conditions which provide good exhaustion. Aqueous solutions of urea and sodium
chloride showed more effective than water as a padding solution for microwave heat dyeing. The type of solvent added in padding
media and its concentration significantly affects the K/S values of dyed polyester fabric. Added solvents such as n-hexane,
acetone, and dimethyl formamide were also more effective than 100% water as padding media for the microwave heat dyeing. It
is supposed that the effect of used solvents on dyeing property of polyester fabrics depends on the solubility parameter difference
between solvent and polyester fabric. 相似文献
9.
In this study 3-chloro-2-hydroxypropyltrimethylammonium chloride was used as a cationic agent to cationize cotton fabric by
a pad-batch process. The cationized cotton samples were dyed with different reactive dyes containing various reactive groups.
The dyeability of the cationized cotton samples with reactive dyes without salt was significantly improved due to an increase
in the ionic attraction between the dye and cationized cotton. The results showed that the wash and dry rubbing fastness of
the cationized cotton dyed with different reactive dyes are similar to those of the untreated cotton. However, the light fastness
of some of the cationized fabric samples was improved. 相似文献
10.
The purpose of this study is to objectively evaluate the seam pucker as a fabric formability and to analyze the effects of
the fabric structural and sewing parameters to the seam pucker properties of the worsted and wool/polyester blend fabrics.
The seam pucker of the worsted and wool/polyester blend fabrics according to the different types of fibre composition were
surveyed by measuring fabric mechanical property using KES-FB and FAST systems and also seam puckering test was conducted
by objective and subjective methods. In addition, the effects of fabric structural and sewing parameters to the seam pucker
were investigated using statistical analysis. It was revealed that the effects of fabric structural parameters to the seam
pucker were dominant than those of sewing machine conditions. It was shown that low pressor foot pressure and shuttle tension
make good seam pucker, and high sewing speed and shuttle tension make bad seam pucker. And it was also shown that the precision
on estimating of the seam pucker by KES-FB system was much higher than that of FAST system. And seam pucker values between
objective and subjective methods showed good correlation. 相似文献
11.
The dyeing and color fastness properties of three reactive-disperse dyes containing a sulphatoethylsulphone group on Nylon,
cotton and N/C mixture fabrics were examined. Reduction-clearing was more effective in removing the unfixed dyes than soaping
since the reactive-disperse dye became hydrophobic during dyeing process. Nylon was dyed well with three reactive-disperse
dyes at pH 5∼8 and difference in chemical structure between dyes did not affect the final color strength of the dyed Nylon
fiber, but their build-up properties on Nylon were not so good. The color strength of the dyed cotton was not as high as that
of Nylon. The color strength of cotton increased by lowering dyeing temperature when the reactive-disperse dyes having hydroxy
group were used. Nylon absorbed more dye molecules than cotton in simultaneous dyeing, the color difference between Nylon
and cotton could be reduced as the dyeing temperature decreased. N/C mixture fabric was dyed well at 60 °C with the reactive-disperse
dyes having hydroxyl group when applied at pH 7 and 60 °C, and their build-up properties were good. It was also found that
washing fastness and rubbing fastness of dyed Nylon, cotton and N/C fabrics with the reactive-disperse dyes were excellent,
while light fastness was moderate. 相似文献
12.
An amino-terminated hyperbranched polymer (HBP-NH2), synthesized from methyl acrylate and diethylene tri-amine by polycondensation, was applied to treat cotton samples by a
pad-dry-cure method. Physical properties, salt-free dye-ability, antimicrobial activity, and antiultraviolet property of the
treated cotton samples were tested. The crystallinity and mechanical properties, including breaking strength, breaking elongation,
and Young’s modulus of the treated cotton fibers, increased slightly in comparison with those of the untreated cotton fibers.
The thermal stability and the moisture regain were also improved slightly. Dyed with direct dyes and reactive dyes in the
absence of the electrolytes, the treated cotton fabric showed similar or higher color strength compared with the untreated
cotton fabric in conventional dyeing. The treated cotton fabric can also be dyed with acid dyes effectively. In addition,
the treated cotton fabric showed good antimicrobial activities against Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli). The study of the antiultraviolet properties of the treated cotton fabric indicated that the HBP-NH2 contributed to the reduction of UV transmission and the increase of UPF. 相似文献
13.
Azohydroxypyridone disperse dyes containing a fluorosulfonyl group were dyed on PET/cotton blends and their dyeing and fastness
properties were investigated. Specially, the azohydroxypyridone dyes containing a nitro group in place of the fluorosulfonyl
group in the para position to azo group were synthesized in order to compare their dyeing and fastness properties on PET/cotton blends with
those of fluorosulfonyl-substituted analogues. As these dyes can be alkali cleared in the same bath, a one-bath dyeing method
was used and the results were compared with that of a conventional two-bath dyeing method. In particular, the cross-staining
of cotton was studied in order to assess their suitability for the one-bath dyeing of PET/cotton blends. 相似文献
14.
Yu Guan Ya-Hong Mao Qing-Kang Zheng Guang-Hong Zheng Tian Tian 《Fibers and Polymers》2009,10(4):488-495
Transfer printing with disperse dyes on cotton fabric modified with an aqueous tolylene diisocyanate derivative (TDD) was
discussed in this paper. The effect of the degree of substitution (DS) on color strength (K/S value) of the modified and transfer printed fabric was investigated. The DS of the cotton fabric increased with increases in TDD concentration and curing temperature and time, while the sample whiteness
decreased with the increasing curing temperature and time. And the change of structure of the modified cotton fabric was characterized
by FT-IR spectra, DSC curves, and SEM images. All of the factors, such as the concentration and molecular weight of poly(ethylene
glycol), the DS of the modified fabric, the transfer printing temperature and time would affect the K/S value of the sample. After transfer printing with disperse dye, the K/S value and printing fastness of TDD-modified cotton fabric were higher than those of cotton control fabric, the change of
chromatic difference was not obvious, but the tensile strength of the modified fabric was lower than that of original cotton. 相似文献
15.
In this study, the tensile strength and elongation of polyester/viscose blended needle-punched nonwovens were analyzed. For this purpose, five different blend ratios of polyester/viscose webs were produced, cross-lapped and needled in four different mass per unit areas and three different needling/punching densities. The tensile properties of the nonwovens were determined by performing the standard test methods and the data obtained from tests were statistically analyzed in Design Expert software. In addition, a mixture process crossed regression model with two mixture components (polyester and viscose blend ratios) and two process variables (fabric mass per unit area and needling density) was developed to analyze the tensile strength and elongation of polyester/viscose blended needled nonwovens. In conclusion, the regression model indicated that the tensile strength of the needle-punched nonwovens decreases with the increase of polyester proportion in the mixture and increases with the increase in mass per unit area and punching density. 相似文献
16.
Dispersant-free PTT dyeing of temporarily solubilized azo disperse dyes based on pyridone moiety which contain β-sulfatoethylsulfonyl
group was investigated. The dyes were successfully applied to PTT without the use of dispersants. The color yields of the
dyes on PTT fabric were dependent on dyeing pH as well as dyeing temperature. The optimum results were obtained at pH 5–6
and 110 °C. The dyes showed alkali-clearing property and exhibited good to excellent fastness on the PTT fabric. The COD levels
of the dyeing effluent from the temporarily solubilized disperse dyes were much smaller than those from commercial disperse
dye. 相似文献
17.
Jae-hong Choi Mi-hyeon Kim Joon-soo Park Jeong-min Jeon Dae-ok Kim A. D. Towns 《Fibers and Polymers》2007,8(1):37-42
In Part 1 of this study, the dyeability, color shade, wash, light fastness and compatibility of homogeneous disperse dyes
on PLA fabric and PET fabric were reported. The present paper (Part 2) focuses on the application of commercial disperse dyes
to PLA fabric. Specific areas of investigation are the coloration properties of dyes originally intended for the production
of high lightfastness polyester fabrics or for application to cellulose diacetate. The compatibility of the eight members
of the dye set was investigated. In terms of lightfastness, the ratings were higher than that of conventional disperse dyes.
In addition, the use of dye combinations to achieve synergistic uptake on PLA was explored leading to the pronounced synergism
with a mixture of CI Disperse Blue 374 and 284. 相似文献
18.
Formulations of acrylamido dyes containing comonomers can be photografted onto cotton fabric upon UV irradiation at room temperature without neutral salts, which makes it a novel coloration process of excellent environmental friendliness. The photografting of the dyes can be assisted by the copolymerization of the acrylamide comonomer which may reduce the steric hindrance of the bulky dyes. About 90 % of the dyes and 94 % of the acrylamide are photopolymerized in the solution and the degree of polymerization is estimated to be 13.2 according to 1H-NMR and MALDI-TOF mass analyses. The optimal K/S values of the grafted cotton fabrics showed 13.3 and 12.3 for red and yellow dyes, respectively. The optimal UV-grafting coloration can be achieved when a UV energy of 25 J/cm2 was irradiated on the padded fabrics with a formulation of 0.65 mole ratio of acrylamide to the dyes, 7 wt% acetophenone photoinitiator (Irgacure 2959) based on the dye weight under pH 6. Furthermore, the color fastness properties of the grafted fabric were superior to those of conventional reactive dyeing of the dyes due to higher molecular weight of the polymerized dyes. 相似文献
19.
Azo disperse dyes (D1-D13) were prepared by various diazotized aryl amines coupled with N-(phenyl)-2-[(4-phenyl-1,3-thiazol-2-yl)amino] acetamide. All the azo disperse dyes have been characterized by their percentage yield, UV-VIS spectroscopy, elemental analysis, IR spectroscopy, 1H-NMR spectroscopy, and dyeing performance on polyester fiber. These dyes were applied to polyester fabric by HTHP method and their fastness properties were evaluated. All the dyes gave moderate to excellent fastness properties on polyester fiber. The main focus was to synthesize azo disperse dyes that give good dyeing property along with pharmacological activity. Therefore, the synthesized compounds were examined for their antimicrobial activity at various concentrations using well-known Kirby-Bauer disk diffusion method. 相似文献
20.
M. A. El-Borai H. F. Rizk G. B. El-Hefnawy H. F. El-Sayed S. A. Ibrahim 《Fibers and Polymers》2013,14(12):2061-2068
Three series of mono and disazo disperse dyes were synthesized from 2-amino-4-(pyridin-3-yl) thiazole. The structure of the synthesized dyes was confirmed by elemental analysis, ultraviolet-visible, infrared, proton and carbon nuclear magnetic resonance and mass spectroscopy. The dyeing parameters, perspiration, wash and light fastness of eighteen azo disperse dyes on polyester have been investigated. Application of these dyes on polyester fabric gave yellow to reddish hues for mono azo derivatives and reddish to dark brown hues for disazo derivatives with fair to moderate light fastness and moderate to good wash and perspiration fastness grade. In addition, the synthesized dyes were screened for their antimicrobial activities against some gram positive, gram negative bacteria and fungi. Some of the prepared dyes gave excellent results against most of the tested organisms. 相似文献