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1.
José Manuel Mirás-Avalos Ildegardis Bertol Cleide A. de Abreu Eva Vidal Vázquez Antonio Paz González 《Communications in Soil Science and Plant Analysis》2015,46(4):272-282
Runoff may cause losses of micronutrients from soils. This can result in environmental problems such as contaminant transfers to water or a decrease in soil fertility. Appropriate soil management may reduce these micronutrient losses. This study examined the effect of applying crop residues to the soil surface on iron (Fe), manganese (Mn), copper (Cu), and zinc (Zn) losses by runoff. Runoff and sediment yield were measured on 1-m2 plots using a rainfall simulator with constant 65 mm h?1 intensity. Eight successive rainfall applications were performed at 65 mm each. Corn (Zea mays L.) straw was applied to plots at rates ranging from 0 to 8 t ha?1. Both total and dissolved concentrations of the micronutrients studied were decreased by corn straw applications. After 520 mm cumulative rainfall, total soil losses ranged from 150 to 15354 kg ha?1 depending on the amount of corn straw applied. Total micronutrient concentrations in runoff were as follows: Fe from 14.98 to 611.12 mg L?1, Mn from 0.03 to 0.61 mg L?1, Cu from 0.10 to 1.43 mg L?1, and Zn from 0.21 to 5.45 mg L?1. The relative contribution of the dissolved fraction to the total micronutrient content loss was low, but varied depending on the nutrient, being less than 1 percent for Fe and Mn and almost 10 percent for Zn. Total and dissolved concentrations in runoff of the studied elements decreased exponentially as the rate of applied corn straw increased. In conclusion, the addition of corn straw to soil reduced micronutrient losses. 相似文献
2.
B.Y. Li D.M. Zhou L. Cang H.L. Zhang X.H. Fan S.W. Qin 《Soil & Tillage Research》2007,96(1-2):166-173
Micronutrient status in soils and crops can be affected by different fertilization practices during a long-term field experiment. This paper investigated the effects of different fertilization treatments on total and DTPA-extractable micronutrients in soils and micronutrients in crops after 16 year fertilization experiments in Fengqiu County, Henan Province, China. The treatments of the long-term experiment included combinations of various rates of N, P and K in addition to two rates of organic fertilizer (OF) treatments. Winter wheat and summer maize were planted annually. Soil macro- and micronutrients along with pH and organic matter (OM) were analyzed. Grains and above ground parts of both crops in the final year were harvested and analyzed for Cu, Zn, Fe and Mn. The results showed that soil Cu, Zn, Fe and Mn concentrations did not change among the different treatments to a significant level, except for a slight decrease of soil Zn in the CK (no fertilizer application) compared to the OF treatment. The DTPA-extractable soil Zn, Fe and Mn concentrations increased from 0.41 to 1.08 mg kg−1, from 10.3 to 17.7 mg kg−1, and from 9.7 to 11.8 mg kg−1, respectively, with increasing soil OM content, thus showing the importance of soil OM in micronutrient availability for crops. The NPK treatment also had higher DTPA-extractable micronutrient concentrations in soil. Deficiency of N or P resulted in a low yield but high micronutrient concentrations in crops except Cu in maize stalks. Higher available soil P significantly decreased crop micronutrients, possibly because of their precipitation as metal phosphates. Maize stalks contained higher concentrations of micronutrients than those of wheat straw, whereas wheat grain had higher micronutrients than those of corn grain. The transfer coefficients (TCs) of micronutrients from straw to grain were significantly different between winter wheat (1.63–2.52 for Cu; 2.31–3.82 for Zn; no change for Fe; 0.55–0.84 for Mn) and summer maize (0.24–0.50 for Cu; 0.50–1.21 for Zn; 0.02–0.04 for Fe; 0.07–0.10 for Mn). In conclusion, application of organic matter significantly increased the DTPA-extractable concentrations of Zn, Fe and Mn compared to the CK, grain and vegetative tissue in the CK and NK had higher micronutrient concentrations than those in other treatments. 相似文献
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4.
Furrows are widely used in rainfed areas of semi-arid India for soil and water conservation. The orientation of furrows, either down or across slope, and their spacing influence the effectiveness of furrows as soil and water conservation measures. We evaluated treatments with furrows aligned down and across 3% sloping land at spacings of 90, 60 and 30 cm under simulated rainfall intensities of 80 and 100 mm/h on a shallow Alfisol. A bare plot without any furrows was considered as a control. A large (24 m × 3 m) rainfall simulator developed at the Central Research Institute for Dryland Agriculture (CRIDA), Hyderabad, was used for this controlled study. Run-off was measured by a calibrated tipping bucket run-off recorder. The effects of the treatments on peak flow rate (L/s), sediment loss with run-off water (kg/ha/mm), peak sediment concentration (g/L), run-off (per cent rainfall) and time to peak (min) were investigated. When compared with the control (no furrows), across slope furrowing with 60- and 30-cm spacing reduced sediment yields by 19.9 and 21.3 kg/ha/mm of run-off, respectively, under a rainfall intensity of 80 mm/h and 24 and 25.3 kg/ha/mm of run-off, respectively, under a rainfall intensity of 100 mm/h. For the control, sediment loss was 50.72 kg/ha/mm run-off and 56.68 kg/ha/mm run-off for rainfall intensities of 80 and 100 mm/h, respectively. Similar trends were recorded from observations of peak flow, time to peak and peak sediment concentration. Run-off hydrographs demonstrated the conservation value of across slope furrowing by delaying run-off initiation, reducing run-off and slowly releasing the run-off after the cessation of rainfall. The results show that furrow orientation has major effects on reducing run-off, whereas furrow spacing has insignificant effects. 相似文献
5.
长期肥料试验对土壤和水稻微量元素及重金属含量的影响 总被引：23，自引：0，他引：23
长期肥料试验会影响土壤中微量元素和重金属状况以及作物对微量元素和重金属的吸收。本文研究了长期的不同施肥处理对土壤、糙米中微量元素Cu、Zn、Fe、Mn和重金属Pb、Cd含量的影响,结果表明:经17a连续施用猪粪及秸秆还田显著增加了土壤Cu、Zn和Cd全量,而土壤Fe、Mn和Pb全量在不同施肥处理间没有显著差异;施肥增加了土壤有效态Cu、Zn和Fe含量,其中施用猪粪及秸秆还田的3个处理显著增加了土壤有效态Cu、Zn和Cd含量,而土壤有效态Pb含量在不同施肥处理间没有显著差异。不同处理糙米Cu、Zn、Fe、Mn和Pb含量变化较小或没有显著性差异,而在3个施猪粪和秸秆还田处理中,糙米Cd含量均超过国家食品卫生标准(>0.2 mg kg-1)。水稻地上部吸收积累Cu、Zn、Fe、Mn、Pb和Cd总量与其地上部生物量呈正相关,土壤Cu、Zn、Cd有效态与全量含量呈极显著相关关系,而糙米中的镉含量与土壤镉含量有较好的相关关系。长期施用畜粪导致土壤Cd污染问题应引起高度重视。 相似文献
6.
稻草与生石灰对设施土壤微量元素含量和番茄产量的影响 总被引：3，自引：0，他引：3
为了探究设施内添加稻草与生石灰对土壤微量元素含量和番茄产量的影响,以长期施肥定位试验为依托,比较了施用鸡粪(M)的基础上,添加稻草(MR)、生石灰(MCa)、稻草与生石灰同时添加(MRCa)各处理全土及各粒级团聚体中有效态Fe、Mn、Cu、Zn含量和番茄产量的变化。结果表明:(1)添加稻草可增加土壤中有效态Fe、Mn、Zn含量,MR处理较M处理分别增加3.2%,80.9%,15.1%,对有效态Cu含量无显著影响;添加生石灰也可增加土壤中微量元素含量,其中Mn含量增加显著。土壤中有效态Fe、Mn、Cn、Zn含量与pH呈极显著负相关(P<0.01),与有机质含量呈极显著正相关(P<0.01)。(2)随着土壤团聚体粒级的减小,有效态微量元素含量呈下降趋势。添加稻草和生石灰可增加1~0.25mm粒级中有效态Mn含量,MRCa处理较其他处理增加6.6%~46.6%;添加稻草可增加<0.25mm粒级中有效态Zn含量。土壤中有效态Fe含量与<1mm粒级中含量呈显著正相关(P<0.01);土壤中有效态Mn、Zn含量分别与各粒级中含量呈显著正相关(P<0.01);土壤中有效态Cu含量与1~0.25mm粒级中含量呈显著正相关(P<0.01)。(3)施入稻草或生石灰可增加番茄产量,且稻草和生石灰同时施入产量最高,MRCa处理较MCa、MR处理分别增加12.6%,33.8%。土壤有效态Fe、Cu含量与产量正相关,其中有效态Fe含量对产量具有直接作用,决策系数最高,土壤有效态Cu含量对产量具有间接作用。因此,可以通过长期添加稻草和适量生石灰缓解设施土壤微量元素短缺的现状,且可获得最高作物产量,为设施内土壤可持续利用和设施农业可持续发展提供保障。 相似文献
7.
土壤可见光-近红外反射光谱与重金属含量之间的相关性 总被引：13，自引：0，他引：13
发展基于反射光谱技术的快速、简便、低成本的土壤重金属信息提取方法是区域土壤重金属污染治理所需要的。选择江西贵溪铜冶炼厂污染区,分析了9种重金属元素(Cu、Pb、Zn、Cd、Co、Ni、Fe、Mn及Cr)与土壤可见光-近红外反射光谱之间的相关性及其相关的原因。研究表明,研究区土壤中存在Cu(含量介于66.71~387 mg kg-1之间)和Cd(含量介于0.36~6.019 mg kg-1之间)的强烈富集。土壤重金属含量与反射光谱之间存在显著相关,污染元素Cu的最高相关系数为-0.87,Pb、Zn、Co、Ni、Fe的最高相关系数达到高度相关(|r|>0.80),Cr、Cd、Mn的最高相关系数达到显著相关(|r|>0.70)。微分光谱适于获取土壤中的重金属元素信息,利用组合波段能显著提高相关性。Cu与反射光谱之间的相关性主要受有机质的影响;Pb、Zn、Co、Ni主要受黏土矿物和铁锰氧化物的影响;Cr与反射光谱之间的相关性同时受有机质和黏土矿物的影响。 相似文献
8.
Total content of Fe, Mn, Zn, Cu, Pb, Cd, Ni and Co in soils irrigated with sewage effluent increased with increasing years of using sewage effluent in irrigation. Iron and Co applied to the soil from sewage effluent were immobilized mainly in unavailable form; Pb, Cd, and Ni in moderately available form; and Mn, Zn, and Cu in highly available form. The concentrations of Fe, Mn, Zn and Cu in tops of alfalfa and leaves of corn grown on these soils increased substantially with increased levels of available metal content of the soil, while those of other metals were little affected. As for orange, continuous increase in leaves metal content with time was found for Fe, Mn, Zn, Co and Cd. The concentrations of Cd, Co, Ni and Pb in corn grains and orange fruits were several times higher than normal, and this reduces their suitability for human consumption. 相似文献
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10.
本文对甘肃省主要农业土壤中Ｃｕ、Ｚｎ、Ｍｎ、Ｆｅ的形态及其有效性进行了研究。结果表明，供试土壤的全Ｃｕ含量范围为２２－２４ｍｇ／ｋｇ，全Ｍｎ为５４２－７７２ｍｇ／ｋｇ，全Ｆｅ为３５６８５－３８３５５ｍｇ／ｋｇ。四种元素均以灌漠土的含量最低，褐土最高。土壤中Ｃｕ、Ｚｎ、Ｍｎ、Ｆｅ的大部分以残留矿物态和氧化铁结合态存在。生物试验和统计分析表明，Ｃｕ、Ｚｎ、Ｍｎ、Ｆｅ的交换态和松结有机态对植物最为有效， 相似文献
11.
The objective of this study was to test the suitability of a simple approach to identify the direction from where airborne heavy metals reach the study area as indication of their sources. We examined the distribution of heavy metals in soil profiles and along differently exposed transects. Samples were taken from 10 soils derived from the same parent material along N-, S-, and SE-exposed transects at 0—10, 10—20, and 20—40 cm depth and analyzed for total Al, Cd, Cr, Cu, Fe, Mn, Ni, Pb, and Zn concentrations. The heavy metal concentrations at 0—10 cm were larger than background concentrations in German arable soils except for Cr (Cd: 0.6—1.8 mg kg—1; Cr: 39—67; Cu: 40—77; Ni: 87—156; Pb: 48—94; Zn: 71—129; Fe: 26—34 g kg—1; Mn: 1.1—2.4). Decreasing Cd, Cu, Mn, and Pb concentrations with increasing soil depth pointed at atmospheric inputs. Aluminum and Ni concentrations increased with soil depth. Those of Fe, Cr, and Zn did not change with depth indicating that inputs at most equalled leaching losses. The Pb accumulation in the surface layer (i.e. the ratio between the Pb concentrations at 0—10 to those at 20—40 cm depth) was most pronounced at N-exposed sites; Pb obviously reached Mount Križna mainly by long-range transport from N where several industrial agglomerations are located. Substantial Cd, Cu, and Mn accumulations at the S- and SE-exposed sites indicated local sources such as mining near to the study area which probably are also the reason for slight Cr and Zn accumulations in the SE-exposed soils. Based on a principal component analysis of the total concentrations in the topsoils four metal groups may be distinguished: 1. Cr, Ni, Zn; 2. Mn, Cd; 3. Pb (positive loading), Cu (negative loading); 4. Al, Fe, indicating common sources and distribution patterns. The results demonstrate that the spatial distribution of soil heavy metal concentrations can be used as indication of the location of pollution sources. 相似文献
12.
Bonemeal, coir, compost, green waste compost, peat and wood bark all potentially could be used as amendments to remediate heavy metal contamination in soils. Their ability to sorb Pb, Cu and Zn was evaluated in the laboratory, using metal solutions ranging from 0 to 5 mmol/L as contaminants. The effects on sorption of metal concentration, background salt concentration and metal competition were evaluated. Single metal sorption by the six amendments was significantly different at metal concentrations of 1.5–5 mmol/L, with green waste compost, coir, compost and wood bark having the highest capacities to adsorb Pb, Cu and Zn. Langmuir sorption maxima were approximately 87 mg Pb/g (coir and green waste compost), 30 mg Cu/g (compost and green waste compost) and 13 mg Zn/g (compost and green waste compost) (equivalent to approx. 0.5 mmol/g of Pb and Cu, and 0.2 mmol/g Zn), all in a background solution of 0.001 M Ca(NO3 )2 . A higher background salt concentration and a combination of all three metals led to significant reduction in the amounts of Pb, Cu and Zn sorbed by all the amendments tested. Competing heavy metal cations in solution decreased Pb sorption to about 50–60% of that from a solution containing Pb alone; Cu sorption was reduced to about 30–40%; the effect of competition on Zn sorption was variable. Overall, in both single metal and competitive sorption, the order of strength of binding was Pb>Cu>>Zn. 相似文献
13.
《Communications in Soil Science and Plant Analysis》2012,43(4):421-438
Abstract Heavy metals are often added indiscriminantly to soils in pesticides, fertilizers, manures, sewage sludges, and mine wastes, causing an imbalance in nutrient elements in soils. Heavy‐metal toxicity causes plant stress in various degrees dependent on the tolerance of the plant to a specific heavy metal. The objectives of this study were (i) to show that plant species and soils respond differently to heavy metals and (ii) to show the necessity for proper quantity and balance of heavy metals in soils for plant growth. Three Fe‐inefficient and three Fe‐efficient selections of soybean, corn, and tomato were grown on two alkaline soils with Cu and Zn ranging from 14 to 340 and Mn from 20 to 480 kg/ha. Heavy‐metal toxicity caused Fe deficiency to develop in these plants. The Fe‐inefficient T3238fer tomato and ys1/ys1 corn developed Fe deficiency on all treatments and both soils. T3238FER tomato (Fe‐efficient) did not develop heavy metal toxicity symptoms on any treatment or soil. The soybean varieties and WF9 corn were intermediate in their response. The unpredictable response of both the soil and the plant to heavy metals make general recommendations difficult. In order to maintain highly productive soils, we need to know what we are adding to soils and the consequences. Without some control, the continued addition of heavy metals to soils is a crisis in embryo. 相似文献
14.
对山东省海阳地区150个不同种植年限的番茄大棚土壤重金属元素的分布特征进行了调查研究.结果表明,该地区番茄大棚土壤Fe、Zn、Cu、Mn含量平均值为18 874、80.1、27.7、467.5 mg/kg,变异系数26.7％ ～ 39.2％,具有一定的空间变异性.该地区番茄大棚土壤Cu和Zn元素含量在种植年限为1～ 10年间逐年增加,而在种植年限11 ～ 17年间呈降低的趋势,番茄大棚土壤Cu和Zn元素含量随种植年限变化的规律与大棚土壤施肥量以及土壤pH的变化有关;随着蔬菜温室使用年限的增加,土壤Mn含量有逐年降低的趋势,Fe元素含量变化趋势不明显. 相似文献
15.
Alan L. Wright Frank M. Hons Robert G. Lemon Mark L. McFarland Robert L. Nichols 《Soil & Tillage Research》2007,96(1-2):19-27
Crop management practices, especially tillage and rotation, can impact soil nutrient stratification, crop growth, and yield. The objectives of this study were to determine the soil-profile distribution of plant-available nutrients in four depth intervals from 0 to 90 cm for different cotton (Gossypium hirsutum L.) cropping systems, tillage regimes, and N fertilization rates in a south-central Texas silty clay loam soil after 5 years of treatment imposition. Distribution of nutrients in the soil profile varied between cropping systems (continuous cotton monoculture and cotton–corn (Zea mays L.) rotation), conventional (CT) and reduced tillage (RT), and N fertilization rates (0, 80, and 160 kg N ha−1). Plant-available P showed the greatest stratification and was 426% higher at 0–15 cm than at 60–90 cm, while SO4 had the greatest increase (42%) with depth. The percentage decrease from 0–15 to 60–90 cm was 47% and 147% for NO3 and K, and 76%, 12%, 43%, and 232% for Mn, Fe, Cu, and Zn, respectively. In contrast, Ca and Mg concentrations increased 22% and 15%, respectively, from 0–15 to 60–90 cm. Increasing the N fertilization rate increased plant-available NO3 and SO4 but decreased K, Fe, Cu, and Zn concentrations. Inclusion of corn in rotation with cotton decreased plant-available Mn, Fe, and Cu from 15 to 90 cm relative to continuous cotton at 160 kg N ha−1. For unfertilized soil, rotation increased micronutrient concentrations at 15–60 cm compared to continuous cotton. On average, CT cotton–corn had significantly lower K, Ca, Mg, Na, and SO4 concentrations than CT continuous cotton. Reduced tillage and diversified cropping systems altered the distribution of plant-available nutrients in soil relative to CT and continuous cotton. In fact, RT increased plant-available P and NO3 in surface soil, which may have contributed to higher lint yields than CT continuous cotton. 相似文献
16.
长期化肥配施不同有机肥对土壤和玉米中重金属累积的影响 总被引：1，自引：1，他引：0
17.
Electron microprobe studies on soil samples with varying heavy metal contamination. 2. Contents of heavy metals and other elements in aggregations of humic substances, litter residues and charcoal particles EMA point analysis show that the organic matter constituents of heavy metal contaminated soils are highly enriched with heavy metals. The maximal trace element accumulation were for Cu up to 13,000 mg/kg, for Zn up to 48,000 mg/kg, for Cd up to 2,100 mg/kg and for Pb up to 193,000 mg/kg. The affinity for the accumulation of the different heavy metals in aggregations of humic substances can be described by the sequence Cu > Pb ? Cd > Zn ? Ni > Co. In very strongly acidified humic top soil horizons the Pb and Cd accumulation in the organic matter constituents is in competition with the accumulation in Fe and Mn oxides. The heavy metal contents (especially of Cu) of the organic matter are often correlated with the content of organically bound calcium. The EMA results also show that high heavy metal amounts occur in combination with Ca-accumulations in the epidermis and the outer bark parenchym of decayed roots. EMA point analysis of the interior of fungus sclerotias show that sclerotias can contain high amounts of heavy metals, in particular lead (up to 49,700 mg Pb/kg). From statistical results of EMA point analysis follows that lead and other heavy metals attached to humic substances are not only bound as metal organic complexes but also as organic metal phosphate complexes. Also charcoal particles of polluted soils contain high amounts of heay metals. The accumulation affinity is quite similar to that of humic substances. 相似文献
18.
This study has investigated how to simultaneously remove both heavy metals (Cu, Mn, and Zn) and natural organic matters (NOM; humic acid and fulvic acid) from river water using potassium ferrate (K2FeO4), a multipurpose chemical acting as oxidant, disinfectant, and coagulant. In water sample including each 0.1 mM heavy metal, its removal efficiency ranged 28–99% for Cu, 22–73% for Mn, and 18–100% for Zn at the ferrate(VI) doses of 0.03–0.7 mM (as Fe). The removal efficiency of each heavy metal increased with increasing pH, whereas an overall temperature did not make any special effect on the reaction between the heavy metal and ferrate(VI). A high efficiency was achieved on the simultaneous treatment of heavy metals (0.1 mM) and NOM (10 mg/l) at the ferrate(VI) doses of 0.03–0.7 mM (as Fe): 87–100% (Cu), 31–81% (Mn), 11–100% (Zn), and 33–86% (NOM). In the single heavy metal solution, the optimum ferrate dose for treating 0.1 mM Cu or Mn was 0.1 mM (as Fe), while that for treating 0.1 mM Zn was 0.3 mM (as Fe). In the mixture of three heavy metals and NOM, on the other hand, 0.5 mM (as Fe) ferrate(VI) was determined as an optimum dose for removing both 0.1 mM heavy metals (Cu, Mn, and Zn) and 10 mg/l NOM. Prior to the addition of ferrate(VI) into the solution of heavy metals and NOM (HA or FA), complexes were formed by the reaction between divalent cations of heavy metals and negatively charged functional groups of NOM, enhancing the removal of both heavy metals and NOM by ferrate(VI). 相似文献
19.
《Communications in Soil Science and Plant Analysis》2012,43(15-20):2745-2750
Abstract Long‐term agricultural sustainability and water quality are impacted by different chemicals, including heavy metals. Heavy‐metal losses at the catchment scale depend largely on land‐management practices. Water‐quality indicators are required near soil‐quality indicators for different regions and farming systems. The purpose of this work is to analyze the heavy‐metal losses from a mixed agroforestry catchment. Iron (Fe), Magnesium (Mn), Zinc (Zn), and Copper (Cu) were measured in the drainage water of a 36.3 km2 catchment located at the Valiñas River (Coruña, northwest Spain), and a total of 193 samples were collected during the course of 2003. The sampling strategy was a stratified point sampling involving more frequent sampling when flow was high. Water metal content was analyzed by inductively coupled plasma (ICP‐AES). The content ranges of dissolved heavy metals were as follows: Fe between 10 and 267 µg/L, Mn 0.2 and 77 µg/L, Zn 0.62 and 53.7 µg/L, and Cu 0.20 and 9.26 µg/L. Heavy metal content strongly varied along the study time, depending on storm flow but also on timing of animal‐waste applications. 相似文献
20.
在野外采样、室内分析与统计的基础上,对陕北靖边县北部风沙区土壤有效态微量元素的含量及分布进行了研究.结果表明,该地区土壤中B,Cu,Zn,Fe和Mn等微量元素有效态含量的平均值分别为:0.421mg/kg,0.505mg/kg,0.582mg/kg,7.092mg/kg和7.251mg/kg,它们的变幅分别在2.582～0.022mg/kg,1.194～0.158mg/kg,3.944～0.096mg/kg,26.08～2.4mg/kg和13.39～2.082mg/kg之间;在水平方向上,B,Cu,Zn和Mn的含量呈由南向北增高的趋势,Fe则表现出由西向东有所增加;土壤垂直剖面中,0~20cm的耕层B,Cu,Zn,Fe和Mn明显高于20~40cm和40~60cm土层的含量. 相似文献