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1.
The mineralogical composition of agrogray, dark gray, and agro-dark gray soils (Luvic Greyzemic Retic Phaeozems); agro-dark gray residual-calcareous soils (Calcaric Cambic Phaeozems); clay-illuvial agrochernozems (Luvic Chernic Phaeozems); and agrochernozems with migrational–mycelial carbonates (Haplic Chernozems) developed in the forest-steppe of Central Siberia within the Irkutsk Depression has been studied. The clay (<1 μm) fraction separated from these soils consists of mixed-layer minerals with alternating layers of hydromica, smectite, vermiculite, and chlorite; the proportions between them change within the soil profiles. The clay fraction also contains hydromicas, kaolinite, chlorite, and some admixture of the fine-dispersed quartz. Each type of the soils is characterized by its own distribution pattern of clay material with specific alternation of layers in the mixed-layer formations. Mixed-layer minerals of the chlorite–vermiculite type predominate in the upper horizons of texture-differentiated soils. Down the soil profile, the content of mixed-layer mica–smectitic minerals increases. In the clay fraction of arable dark gray-humus soils with residual carbonates, the distribution of the clay fraction and major mineral phases in the soil profile is relatively even. An increased content of well-crystallized kaolinite is typical of these soils. The parent material of agrochernozems has a layered character: the upper horizons are generally depleted of clay, and the middle-profile and lower horizons are characterized by the considerable kaolinite content. In general, the clay material of soils of the Tulun–Irkutsk forest-steppe differs considerably from the clay material of foreststeppe soils developed from loesslike and mantle loams in the European part of Russia. In particular, this difference is seen in the proportions between major mineral phases and between biotitic and muscovitic components, as well as in the degree of crystallinity and behavior of kaolinite and chlorite. 相似文献
2.
Data are presented on the physicochemical composition and specific macro-, meso- and micro-morphological features of automorphic
soils formed on silty loams in the northern and middle taiga subzones of the Timan Ridge. These soils have a texture-differentiated
profile and are well aggregated, which is manifested at all levels of structural organization of the soil mass. The morphological
structure of the middle soil horizons is characterized by the presence of specific nongleyed cryometamorphic horizon CRM.
Its formation is due to the development of long-term seasonal cryogenic processes in relatively deep (up to 40 cm) light and
medium loam deposits under conditions of the northern and middle taiga subzones. The processes of cryometamorphism, combined
with Al-Fe-humus and textural differentiation, result in the formation of podzolic, iron-illuvial, cryometamorphic, and textural
horizons (O-E-BF-CRM-BT). The textural horizons have a set of micromorphological features indicating that recent clay illuviation
is a weak process. 相似文献
3.
A contrasting occurrence of clay minerals was found within a soil profile which was derived from volcanic materials in the suburbs of Fukuoka-city, Northern Kyushu. The soil profile is located on an isolated terrace, and the morphological characteristics of the soil correspond exactly to Andosols, so-called Kuroboku soils or Humic Allophane soils. The clay fraction of upper horizons of the soil consists largely of alumina-rich gel-like materials, gibbsite, and layer silicates such as chlorite and chloritevermiculite intergrades, while that of lower horizons is composed of allophane and gibbsite or halloysite. There was no positive indication of allophane in the upper horizons. Corresponding with the clay mineralogical composition, quartz is abundant in the fine sand fraction of the upper horizons, while the mineral is very scarce or none in the lower horizons, suggesting a close relation between the petrological nature of parent volcanic materials and the mineralogical composition of weathering products. The dominant clay mineral in the volcanic 1.10il might be dependent on the petrological nature of parent materials, and allophane is mostly formed from andesitic materials, and alumina-rich gel-like materials and layer silicates have come from quartz andesitic materials. Allophane would transform to gibbsite or halloysite according to weathering conditions, and aluminarich gel-like materials change to gibbsite under a well-drained condition. The soil materials have been so greatly weathered that some horizons contain gibbsite of even more than 40 per cent or halloysite over 70 per cent. The morphology and mineralogy are quite similar to so-cailed “non-volcanic Kuroboku soils.” 相似文献
4.
Automorphic loamy soils of the northern taiga and forest-tundra zones in the northeastern part of European Russia are characterized.
These soils are diagnosed by the presence of a paragenetic system of the podzolic (often, with gley features) and iron-illuvial
horizons combined with a specific cryometamorphic CRM horizon. The podzolic horizon is considerably impoverished in the total
and oxalate-extractable iron and slightly impoverished in aluminum and clay in comparison with the iron-illuvial horizon.
A distinctive feature of the cryometamorphic horizon is its fine angular blocky, ooidal, or granulated structure in the dry
state and curdled cryogenic structure in the wet state. The soil profile is relatively weakly differentiated with respect
to the contents of clay and sesquioxides. The genesis of these soils is related to a combination of the gley-Al-Fe-humus mobilization,
migration, and illuvial accumulation of substances and the cryogenic structuring. According to the new Classification and Diagnostic System of Russian Soils, these soils fit the criteria of iron-illuvial svetlozems in the order of cryometamorphic soils. In the studied area, these
soils are found together with texture-differentiated gley-podzolic soils having the Bt horizon and belonging to the order
of texture-differentiated soils. 相似文献
5.
Changes in the mineralogical composition of the clay fraction (<0.001 mm) sampled from soils of the model lysimetric experiment of Moscow State University have been studied. The mineralogical composition of clay is represented by the paragenetic association of minerals typical of noncalcareous mantle loams in the center of the Russian Plain. The predominant smectitic phase consists of complex mixed-layered minerals (mica-smectite with high and low contents of the smectitic layers, chlorite-smectite with different ratios between the chloritic and smectitic layers) and individual smectites. Tri-and dioctahedral hydromica, kaolinite, chlorite, and clay-sized quartz are present in lower amounts. At the early stages of the experiment, the distribution of the smectitic phase in the soil profile is more contrasting than the distribution of the clay fraction. Under the impact of artificially planted meadows, forests, and agrocenoses, soil profiles with different distribution patterns of the clay fraction are formed. The weakly pronounced eluvial distribution pattern of the clay fraction has been registered. Under spruce and mixed stands, the loss of the clay fraction from the upper horizons is due to the hydrolysis of smectitic minerals in the acidified medium. Under broad-leaved stands, perennial herbs, agroecenoses, and fallow, the depletion of smectites from the upper horizons is due to lessivage. The relative accumulation of hydromica and kaolinite is observed in the uppermost soil layer. 相似文献
6.
Five variants of the distribution of clay (<0.001 mm) and physical clay (<0.01 mm) fractions along the vertical profiles of Vertisols (slitozems) and vertic soils (slitic subtypes of different soil types) from the European part of Russia are distinguished: (1) accumulative, (2) even, (3) regressive, (4) with a maximum in the middle-profile horizon and with their approximately equal contents in the upper and the lower horizons, and (5) eluvial–illuvial. These distribution patterns are related to the lithological specificity of sedimentation and formation of parent materials composed of swelling clays of different geneses and ages. Solonetzic, eluvial- gley, and solodic processes contribute to the development of the eluvial–illuvial and, partly, regressive variants of clay distribution. All the five variants with a predominance of the even distribution pattern can be found in Vertisols. Most of Vertisols in the European part of Russia have a medium clayey or a heavy clayey texture in the entire profile. The regressive distribution pattern is typical of the group of vertic soils. In the upper horizons of Vertisols, where slickensides do not form, the texture is usually heavier than that in the analogous horizons of vertic soils. The middle-profile and lower horizons with slickensides have similar statistical distributions of particle-size fractions in Vertisols proper and in vertic soils. However, in Vertisols, a tendency for a more frequent occurrence of the soils with a higher content of the clay fraction and with a higher portion of this fraction in the physical clay fraction is observed (as compared with the vertic soils). 相似文献
7.
N. A. Karavaeva 《Eurasian Soil Science》2013,46(5):468-483
The vertical soil-geographic zonality of the Chukotka Upland in the area of the Amguema River valley can be considered a model vertical zonality in the Low Arctic regions at the interface between the continental and oceanic climates. The plain bottom of the valley has a continental climate. The surrounding mountains are under the influence of an oceanic climate, which is more pronounced in the low mountains and less pronounced in the medium-high mountains. Three altitudinal soil zones are distinguished: (1) the plain Subarctic zone with the absolute heights below 200–400 m a.s.l., where cryoturbated humus-impregnated peat-mucky gleyzems are developed from loamy substrates, and gleyed soddy podburs are developed from loamy sandy substrates; (2) the low-mountain zone of a creeping alder forest (the forest-tundra zone?) of the Low Arctic at the heights of 400–700 m a.s.l., where mucky-gray-humus humus-impregnated podzolized gleyzems are developed under tundra patches, cryoturbated peat-mucky high-humus-impregnated podzolized gleyzems are developed under creeping alder thickets, and pedoliths are exposed in the zones of landslides; and (3) the mountain Middle Arctic zone at elevations above 700 m a.s.l., where very thin soil films predominate; gray-humus cryometamorphic lithozems are developed from the eluvium of magmatic rocks, and humus-impregnated cryometamorphic soils with quicksand suprapermafrost horizons are developed from the eluvium of hard sedimentary rocks. 相似文献
8.
The OAh and Ah horizons of acid brown and podzolic forest soils are reported to fix more radiocaesium than the mineral B horizons beneath them. We determined the respective influence of organic matter and clay minerals on the magnitude of Cs+ retention in a strongly acid brown forest soil in Belgium. The soil contained mica throughout the profile. Vermiculite was identified in the OAh and Ah horizons, and hydroxy interlayered vermiculite (HIV) in the Bw horizon. The OAh and Ah clay fraction retained much more Cs+ than the Bw horizon. The extraction of Al interlayers by Na-citrate resulted in a marked increase in Cs+ fixation in the Bw clays as well as the collapse of the vermiculitic layers after K+ saturation. Organic matter had a strong but indirect effect on Cs+ fixation. In the Bw horizon, acid weathering of layer silicates releases free Al and produces HIV minerals in which Al polymers block the access of radiocaesium onto Cs+-specific sites. In OAh and Ah horizons, free Al is complexed by organic acids. Consequently, the interlayer specific sites remain accessible for Cs+ fixation. 相似文献
9.
S. N. Lesovaya M. P. Lebedeva-Verba N. P. Chizhikova O. V. Romanov 《Eurasian Soil Science》2008,41(11):1137-1147
Soils developed from the red-brown Neogene clay and the Quaternary loesslike loams have been studied in the south of the forest-steppe zone on the Central Russian Upland. A polygenetic nature of the soil profile on the loesslike loams is shown. The modern pedogenetic processes in this soil ensure its eluvial-illuvial differentiation with the development of multilayered coatings in the illuvial horizon. The soil developed from the Neogene clay has a lower degree of differentiation despite the more acid reaction. The micromorphological study of the coatings and the mineralogical analysis of the clay fraction separated from the coatings and from the intraped mass disclose differences in the geneses of B horizons of the two soils. In the soil developed from the loesslike loam, hydromica predominates among clay minerals of the coatings; in the soil developed from the red-brown clay, smectitic minerals predominate in the clay fraction. Differences in the properties of these two parent materials predetermined differences in the major directions of soil formation: the metamorphic pedogenesis predominates on the red-brown clay, whereas the textural differentiation develops in the soil on the loesslike loam. The middle horizons in the studied soil profiles are referred to as the structural-metamorphic and textural (clay-illuvial) horizons, respectively. 相似文献
10.
Soil pastes at the water content corresponding to the maximum swelling of samples from different genetic horizons of cryometamorphic soils―surface-gleyic iron-illuvial svetlozem (Folic Albic Stagnosol) and peaty and peat humus-impregnated gleyic svetlozems (Histic Gleyic Stagnosols)―have been studied with an MCR-302 modular rheometer (Anton Paar, Austria). It has been found that the strongest interparticle bonds are formed in the horizons of cryometamorphic soils characterized by high contents of humic substances and organomineral Al–Fe–humus compounds. These are horizons of podzol microprofile (Eg and BHF) in iron-illuvial svetlozem and a humus-impregnated horizon (ELhi,g) in peaty and peat svetlozems. Organomineral Al–Fe–humus compounds, as well as the seasonal freezing of soils, determine the elastic-brittle character of interparticle interactions. The contents of clay fractions, exchangeable bases, and organic and organomineral substances impart viscoelastic properties to these contacts. An enhancement of elastic-brittle properties of soil is observed under the impact of gleying and freezing. The threefold decrease of the structural interaction parameter (∫Z) when going from automorphic to semihydromorphic conditions indicates a decrease in the resistance of peaty and peat svetlozems to mechanical loads under increasing hydromorphism compared to iron-illuvial svetlozems. 相似文献
11.
Soils of the nearly level “Landes du Médoc” in southwestern France have a pattern of alternating bodies of hydromorphic podzols (Haplaquods) and low humic hydromorphic soils (Psammaquents). The soils are formed in a sedimentary mantle of coarse, quartzose sands with a slight microrelief consisting of low, elongated ridges and shallow, intervening troughs. The water table is at shallow depths throughout the plain, even at the surface in places. The podzols on the crests of the low ridges have distinct A2 and cemented B2 h horizons. Podzols persist down the sides of ridges but going downslope first lose the A2 horizon and then the cementation of the Bh horizon. Soils in the shallow troughs have A1 and Cg horizons without B horizons.The fine silt (2–20 μm) and clay (0–2 μm) fractions of the parent sand contain primary trioctahedral chlorite, mica, feldspars, and quartz, with the last mineral predominant. During soil development, the first three minerals undergo weathering at different rates and to different extents. Chlorite is most strongly weathered, followed in order by plagioclases and K-minerals. In the fine silt fraction, weathering seems to occur mostly by fragmentation of particles. In the clay fraction, the phyllosilicates successively form irregularly interstratified minerals with contractible but not expandable vermiculitic layers, interstratified minerals with contractible and expandable smectitic layers, and finally smectites.The extent to which the silicate minerals are weathered becomes progressively greater from the low humic hydromorphic soils to the podzols with friable Bh horizons to the podzols with cemented Bh horizons. Smectite is present only in the A2 horizons of these last podzols.The aluminum release by weathering of silicate minerals is translocated in part in the form of organo-metal complexes into the Bh horizons of the podzols. Greatest concentrations of Al are associated with coatings of monomorphic organic matter on mineral grains in the cemented Bh horizons, in which some Al has also crystallized into gibbsite. That mineral was not detected in friable B horizons of podzols nor in the low humic hydromorphic soil. Contrary to expectations, the mobile Al did not enter interlayer spaces of expanding 2:1 clay minerals. 相似文献
12.
西藏高原突起于我国西南,绝大部分地面的海拔高度在4000米以上,为世界上最高的大高原。它大致在第三纪开始形成,后来曾受第四纪冰川的深刻作用,高山顶部至今仍是冰川的活动场所[1,2]。高原为昆仑山、唐古拉山、喜马拉雅山和横断山等大山脉所盘踞。 相似文献
13.
Gravelly clay loamy and clayey soils developed from the derivatives of ultramafic rocks of the dunite-harzburgite complex
of the Rai-Iz massif in the Polar Urals have been studied. They are represented by raw-humus pelozems (weakly developed clayey
soils) under conditions of perfect drainage on steep slopes and by the gleyzems (Gleysols) with vivid gley color patterns
in the eluvial positions on leveled elements of the relief. The magnesium released from the silicates with the high content
of this element (mainly from olivine) specifies the neutral-alkaline reaction in these soils. Cryoturbation, the accumulation
of raw humus, the impregnation of the soil mass with humic substances, gleyzation, and the ferrugination of the gleyed horizons
are also clearly pronounced in the studied soils. Despite the high pH values, the destruction of supergene smectites in the
upper horizons and ferrugination (the accumulation of iron hydroxides) in the microfissures dissecting the grains of olivine,
pyroxene, and serpentine, and in decomposing plant tissues take place. The development of these processes may be related to
the local acidification (neutralization) of the soil medium under the impact of biota and carbonic acids. The specificity
of gleyzation in the soils developing from ultramafic rocks is shown in the absence of iron depletion from the fine earth
material against the background of the greenish blue gley color pattern. 相似文献
14.
T. A. Sokolova E. Yu. Pakhomova F. R. Zaidelman 《Moscow University Soil Science Bulletin》2012,67(4):143-151
The composition and the regularities of the profile distribution of the clay minerals in the solods of the Baraba Steppe (ground moistening) and the Priobskoe Plateau (atmospheric moistening) were studied. The two profiles have the distinct eluvial-illuvial distribution of the clay fraction. The composition of the clay fraction in the eluvial layer is dominated by illite. The content of chlorite and labile minerals of the montmorillonite group increases downwards in the profile. The revealed regularities in the profile distribution of the clay fraction and some groups of clay minerals are explained by the joint influence of the mineral dissolution under the influence of the gleying and alkaline hydrolysis, as well as the processes of illitization and lessivage. The major differences in the content and distribution of the clay minerals between the solods and the podzolic soils are the following. The solods have a clear illuvial layer in the clay, while the majority of podzolic soil profiles have the eluvial distribution of the silty fraction. The solods in the eluvial part of the profile and sometimes in even the bottom layers have an unusually high content of the illite minerals in the clay fraction due to illitization. The podzolic layers of the solods do not contain soil chlorites common for the eluvial layers of the podzolic soils, which is due here to a less acidic medium that can not provide the proper conditions of aluminum mobilization and migration needed for the development of chloritization. 相似文献
15.
Structural characterization of soil clay minerals often remains limited despite their key influence on soil properties. In soils, complex clay parageneses result from the coexistence of clay species with contrasting particle sizes and crystal chemistry and from the profusion of mixed layers with variable compositions. The present study aimed to characterize the mineralogy and crystal chemistry of the <2 μm fraction along a profile typical of soils from Western Europe and North America (Neo Luvisol). X‐ray diffraction (XRD) patterns were interpreted using: (i) the combination of XRD pattern decomposition and indirect identification from peak positions commonly applied in soil science; and (ii) the multi‐specimen method. This latter approach implies direct XRD profile fitting and has recently led to significant improvements in the structural characterization of clay minerals in diagenetic and hydrothermal environments. In contrast to the usual approach, the multi‐specimen method allowed the complete structural characterization of complex clay parageneses encountered in soils together with the quantitative analysis of their mineralogy. Throughout the profile, the clay paragenesis of the studied Neo Luvisol systematically includes discrete smectite, illite and kaolinite in addition to randomly interstratified illite‐smectite and chlorite‐smectite. Structural characteristics of the different clay minerals, including the composition of mixed layers, did not vary significantly with depth and are thus indicative of the parent material. The relative proportion of the <2 μm fraction increased with increasing depth simultaneously with smectite relative proportion. These results are consistent with the leaching process described for Luvisols in the literature. 相似文献
16.
T. A. Sokolova I. I. Tolpeshta M. L. Sizemskaya M. K. Sapanov A. V. Kolesnikov 《Eurasian Soil Science》2013,46(8):811-820
Initial soils that developed at the bottom of an artificial hollow 30 × 40 m in size and 3 m in depth have been studied. The hollow was dug on a plot with a predominance of solonetzic complexes in the soil cover on the territory of the Dzhanybek Research Station in 1979. A soil with a shallow but clearly differentiated profile composed of a litter, a humus-accumulative W horizon leached from carbonates, and an underlying C1ca horizon with a high content of dispersed carbonates formed in the hollow over 30 years. The total thickness of these horizons is 7–10 cm. The morphology of the profile corresponds to the slightly alkaline humus-accumulative calcareous soil type of the order of immature soils in the current classification of Russian soils. The soil-sediment layer to a depth of >80 cm contains little soluble salts, predominantly sulfates; the content of exchangeable Na does not exceed 1 meq/100 g. Groundwater of calcium sulfate composition occurs at a depth of ～3.8 m. These features, together with additional moistening by low-saline melt water, ensure favorable conditions for the spontaneous propagation and development of herbaceous, shrubby, and woody plants in the bottoms of artificial hollows. The development of a soil profile is accompanied by the depletion of the clay fraction from the upper W horizon, presumably due to the predominant removal of smectite minerals. In the upper W horizon, transformations of layered aluminosilicates takes place: it involves the formation of illites from smectites and from smectitic layers in illite-smectite mixed-layered minerals and partial vermiculitization of chlorites. The technology used upon the excavation of the hollow can be recommended for growing woody-shrubby plants on soils of the solonetzic complex in the clay semidesert during a relatively short time period. 相似文献
17.
Along with Fe and Al, many heavy metals (Mn, Cr, Zn, Cu, and Ni) show a markedly pronounced eluvial-illuvial redistribution
in the profiles of soils of the podzolic group. The intensity of the redistribution of the bulk forms of these metals is comparable
with that of Fe and exceeds that of Al. Although the podzolic soils are depleted of rare-earth metals, the latter respond
readily to soil podzolization. The inactive participation of Al is explained by an insignificant portion of the active reaction-capable
fraction. Podzolization does not influence the profile distribution of Sr and Ba. The leaching degree of heavy metals such
as Mn, Cr, Zn, Ni, and Zr is noticeably higher in the sandy podzols than in the loamy podzolic soils. Leaching of heavy metals
from the podzolic horizons is of geochemical importance, whereas the depletion of metals participating in plant nutrition
and biota development is of ecological importance. The leaching of heavy metals is related to the destruction of clay particles
in the heavy-textured podzolic soils; the effect of the soil acidity on the leaching of heavy metals is less significant. 相似文献
18.
Soil minerals are known to influence the biological stability of soil organic matter (SOM). Our study aimed to relate properties of the mineral matrix to its ability to protect organic C against decomposition in acid soils. We used the amount of hydroxyl ions released after exposure to NaF solution to establish a reactivity gradient spanning 12 subsoil horizons collected from 10 different locations. The subsoil horizons represent six soil orders and diverse geological parent materials. Phyllosilicates were characterized by X-ray diffraction and pedogenic oxides by selective dissolution procedures. The organic carbon (C) remaining after chemical removal of an oxidizable fraction of SOM with NaOCl solution was taken to represent a stable organic carbon pool. Stable organic carbon was confirmed as older than bulk organic carbon by a smaller radiocarbon (14C) content after oxidation in all 12 soils. The amount of stable organic C did not depend on clay content or the content of dithionite–citrate-extractable Fe. The combination of oxalate-extractable Fe and Al explained the greatest amount of variation in stable organic C (R2 = 0.78). Our results suggest that in acid soils, organic matter is preferentially protected by interaction with poorly crystalline minerals represented by the oxalate-soluble Fe and Al fraction. This evidence suggests that ligand exchange between mineral surface hydroxyl groups and negatively charged organic functional groups is a quantitatively important mechanism in the stabilization of SOM in acid soils. The results imply a finite stabilization capacity of soil minerals for organic matter, limited by the area density of reactive surface sites. 相似文献
19.
G. V. Matyshak L. G. Bogatyrev O. Yu. Goncharova A. A. Bobrik 《Eurasian Soil Science》2017,50(10):1115-1124
Differently directed and heterochronous cryogenic processes have contributed to the contrasting soil cover patterns and spatial heterogeneity of the properties of soils in hydromorphic ecosystems of the discontinuous permafrost zone of the northern taiga in Western Siberia. Frost heave and permafrost thawing within ecosystems of highmoor bogs have led to the development of specific cryogenic landforms, such as flat-topped and large peat mounds. A set of cryogenic soils is developed in these ecosystems; it includes different variants of cryozems, gleyzems (Cryosols), and peat soils (Histosols). The distribution of these soil types is controlled by the local topography and thawing depth, other factors being insignificant. Alternation of peat horizons of different types and ages, whirl-like patterns of horizon boundaries, considerable variations in the thickness of soil horizons, and inversions of soil horizons under the impact of frost cracking, frost heave, and cryoturbation are typical of the considered soils. Thawing depth is the most significant factor affecting the thickness of organic horizons, the soil pH, and the degree of decomposition of peat. As a result of the upward movement of bog ecosystems under the impact of frost heave, peat soils are subjected to considerable transformation: peat horizons undergo mineralization, and the thickness of organic horizons decreases; in some cases, eluvial–illuvial differentiation of the mineral horizons takes place, and peat podzols are developed. However, the opposite process of the return of the soils to the bog stage of pedogenesis with peat accumulation may take place in any time in the case of activation of thermokarst processes. 相似文献
20.
Specific features of soil formation in the taiga zone of Western Siberia are considered. The polygenetic nature of podzolic and gley-podzolic soils in the middle taiga zone, soddy-podzolic and soddy gley soils in the southern taiga zone, and meadow soils in the subtaiga zone is related to the pre-Holocene transformation of the lithogenic matrix upon activation of denudation and accumulation processes and the complicated Holocene evolution of these soils. A soil profile can be subdivided into separate layers according to the geomorphic features of the cryogenesis, the indices of interruption of soil formation, and the differences in the composition of the organic matter in the relict and modern humus horizons. 相似文献