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1.
Abstract

Speciation study of microelements in soils is useful to assess their retention and release by the soil to the plant. Laboratory and greenhouse investigations were conducted for five soils of different agro‐ecological zones (viz., Bhuna, Delhi, Cooch‐Behar, Gurgaon, and Pabra) with diverse physicochemical properties to study the distribution of zinc (Zn) among the soil fractions with respect to the availability of Zn species for uptake by rice plant. A sequential extraction procedure was used that fractionated total soil Zn into water‐soluble (WS), exchangeable (EX), specifically adsorbed (SA), acid‐soluble (AS), manganese (Mn)‐oxide‐occluded (Mn‐OX), organic‐matter‐occluded (OM), amorphous iron (Fe)‐oxide‐bound (AFe‐OX), crystalline Fe‐oxide‐bound (CFe‐OX), and residual (RES) forms. There was a wide variation in the magnitude of these fractions among the soils. The studies revealed that more than 90% of the total Zn content occurred in the relatively inactive clay lattice and other mineral‐bound form (RES) and that only a small fraction occurred in the forms of WS, EX, OM, AFe‐OX, and CFe‐OX. Rice (Oryza sativa L.) cultivars differ widely in their sensitivity to Zn deficiency. Results suggested that Zn in water‐soluble, organic complexes, exchange positions, and amorphous sesquioxides were the fractions (pools) that played a key role in the uptake of Zn by the rice varieties (viz., Pusa‐933‐87‐1‐11‐88‐1‐2‐1, Pusa‐44, Pusa‐834, Jaya, and Pusa‐677). Isotopic ally exchangeable Zn (labile Zn) was recorded higher in Typic Ustrochrept of Pabra soil, and uptake of Zn by rice cultivars was also higher in this soil. The kinetic parameters such as maximum influx at high concentrations (Imax) and nutrient concentration in solution where influx is one half of Imax (Km) behaved differentially with respect to varieties. The highest Imax value recorded was 9.2×10?7 µmol cm?2 s?1 at the 5 mg kg?1 Zn rate for Pusa‐933‐87‐1‐11‐88‐1‐2‐1, and the same was lowest for Pusa‐44, being 4.6×10?7 µmol cm?2 s?1 at the 5 mg kg?1 Zn rate. The Km value was highest for Pusa‐44 (2.1×10?4µmol cm?2 s?1) and lowest for Pusa‐933‐87‐1‐11‐88‐1‐2‐1 (1.20×10?4µmol cm?2 s?1). The availability of Zn to rice cultivars in Typic Ustrochrepts of Bhuna and Delhi soils, which are characterized by higher activation energy and entropy factor, was accompanied by breakage of bonds or by significant structural changes.  相似文献   

2.
ABSTRACT

Humic (HA) and fulvic (FA) acids improve the nutrient availability and uptake by plants but some aspects of their agronomic use still need to be clarified. The effects of HA soil application and FA foliar application on the growth, Zn and B uptake by coffee seedlings were evaluated. HA was added to an Oxisol at concentrations 0, 10, 25, 50, 75 and 100 mg kg?1 (C-HA), in both limed (pH 6.2) and overlimed (pH 7.2) conditions. FA (0, 0.2, 0.5 and 1 g L?1 C-FA) was applied to coffee leaves in three different application modes (M): with 0.3% Zn and 0.6% B supplied via foliar (M1), 0.6% B and 1.2% Zn supplied via foliar (M2) and 1.2 mg kg?1 B and 6 mg kg?1 Zn supplied via soil (M3). HA addition in soil significantly (p < 0.05) reduced leaf B and Zn accumulation and coffee growth in both pH conditions. In the M1 and M2, FA application significantly (p < 0.05) increased the shoot growth at 0.59 and 0.45 g L?1 and B accumulation at 0.96 and 0.45 g L?1 C-FA. Foliar application of C-FA, instead soil application of C-HA, is a suitable practice to improve coffee seedlings growth and nutrition on Oxisol.  相似文献   

3.
This experiment was conducted at Zahak Agricultural Research Station in the Sistan region in southeast Iran. A factorial design with three replications was used to determine the effects of zinc (Zn), iron (Fe), and manganese (Mn) applications on wheat yield, Zn, Fe, and Mn uptakes and concentrations in grains. Four levels of Zn [soil applications of 0, 40, and 80 kg ha?1 and foliar application of 0.5% zinc sulfate (ZnSO4) solution], two levels of iron sulfate (FeSO4; 0 and 1%) as foliar application, and two levels of Mn (0 and 0.5%) also as foliar application were used in this study. Results showed that the interactive effects of Zn and Mn were significant on the number of grains in each spike. The highest number of grains resulted from the application of 80 kg ZnSO4 ha?1 and foliar Mn. The interactive effects of Zn and Fe were significant on weight of 1000 grains. The highest weight of 1000 grains resulted from application of 80 kg Zn and foliar Fe. Application of 80 kg ZnSO4 ha?1 alone and 80 kg ZnSO4 ha?1 with foliar application of Mn significantly increased grain yield in 2003. The 2‐year results showed that foliar application of Zn increased Zn concentration and Fe concentration in grains 99% and 8%, respectively. Foliar application of Fe resulted in a 21% increase in Fe concentration and a 13% increase in Zn concentration in grains. The foliar application of Mn resulted in a 7% increased in Mn concentration in grains.  相似文献   

4.
This paper describes the effect of plant growth-promoting bacteria on sunflower growth and its phytoremediation efficiency under Cd-contaminated soils. Four levels of bacteria inoculation (non-inoculation, inoculation by Bacillus safensis, Kocuria rosea and co-inoculation by Bacillus safensis+Kocuria rosea) and four Cd concentrations (0, 50, 100 and 150 mg Cd per kg soil) were arranged as factorial experiment based on a completely randomized design (CRD). Results showed that Cd significantly decreased growth by decreasing the shoot and root length and biomass (p < 0.01). In addition, Cd dramatically decreases photosynthetic pigments, Fe transport to shoot and Zn uptake (p < 0.01). Bacterial inoculation increased Fe and Zn uptake by plants, Cd concentration in the aboveground part of plants and Cd uptake by the enhancement of Cd concentration in plant tissue and biomass production. Results showed that the highest shoot Cd uptake was ?observed in ?inoculated plants by Bacillus safensis at Cd100 (20.35 mg pot?1). However, in average of Cd treatments, the performance of co-inoculation in Cd uptake (13.04 mg pot?1) was better than singular inoculation (10.68 and 12.58 mg pot?1 for Bacillus safensis and Kocuria rosea, respectively). Results revealed that bacterial inoculation increased the Cd uptake performance in shoot and total biomass by 30% and 25%, respectively.  相似文献   

5.
《Journal of plant nutrition》2013,36(10-11):2031-2041
Abstract

In this study we have tested the hypothesis that lime‐induced Fe deficiency chlorosis of kiwifruit may be prevented by the application of a synthetic iron(II)‐phosphate analogous to the mineral vivianite [(Fe3(PO4)2·8H2O)]. Two experiments, under greenhouse and field conditions, were performed. In the greenhouse, 1‐year old micropropagated plants (Actinidia deliciosa, cv. Hayward), grown in 3‐L pots on a calcareous soil, were treated in early autumn with soil‐applied: (1) synthetic vivianite (1.35 g plant?1) and (2) Fe‐EDDHA (24 mg Fe plant?1). The synthetic vivianite suspension, prepared by dissolving ferrous sulfate and mono‐ammonium phosphate, was injected into the soil as a sole application whereas the Fe‐EDDHA solution was applied four times at weekly intervals. The field experiment was conducted in a mature drip‐irrigated kiwifruit orchard located on a calcareous soil in the Eastern Po Valley (Italy). Treatments were performed in early autumn by injecting synthetic vivianite (1.8 kg tree?1) and Fe‐EDDHA (600 mg Fe tree?1) into four holes in the soil around each tree, at a depth of 25–30 cm. The Fe‐chelate application was repeated at the same rate in the following spring. Untreated (control) plants were used in both experiments. Autumn‐applied Fe fertilisers significantly prevented development of Fe chlorosis under greenhouse conditions whereas in the field only vivianite was effective. In conclusion, these 1‐year results show that vivianite represents an effective alternative to soil‐applied Fe chelates for preventing Fe chlorosis in kiwifruit orchards.  相似文献   

6.
Chinese cabbage and surface soil samples (0–20 cm) from a periurban market garden in Yunnan Province (P.R. China) were collected to determine variations of cadmium (Cd) and zinc (Zn) contents in Chinese cabbage and the influence of soil factors. Mean Cd content was 0.49 mg kg?1 dry materials (DM) in Chinese cabbage, ranging between 0.23 and 1.34 mg kg?1 DM (n = 21 samples). Mean Zn content was 51.2 mg kg?1 DM, ranging from 34.9 to 157.5 mg kg?1 DM (n = 21 samples). The soil factors best predicting Chinese cabbage Cd and Zn contents were total and available Cd and Zn contents and cation exchange capacity (CEC). Soil samples and corresponding Chinese cabbage samples were divided into two groups: soils with low pH (<6.5, n = 10) and soils with high pH (>6.5, n = 11). Positive correlation between CEC with pH > 6.5 and Cd and Zn contents in Chinese cabbage were observed. Available trace element contents and CEC explained 77% and 69% of variation of Cd and Zn contents in Chinese cabbage, respectively. AEC (enrichment coefficient related to trace element availability) and BCF (bioaccumulation factors) could be used to understand Cd and Zn accumulation in Chinese cabbage.  相似文献   

7.
The effect of continuous cropping with maize and wheat on soil characteristics and various forms of micronutrient cations in an Incetisol over the years was studied in an ongoing long‐term experiment in New Delhi, India. The soil samples collected in the years of 1993, 1995, 1997, 1999, 2001, 2003, and 2004 were analyzed for different fractions of iron (Fe), manganese (Mn), copper (Cu), and zinc (Zn) by following a sequential extraction procedure. The pH, electrical conductivity (EC), and calcium carbonate (CaCO3) content of the soil varied from 8.28 to 8.53, 0.40 to 0.43 dSm?1, and 0.92 to 1.05%, respectively. Organic carbon content ranged from 0.38 in the control to 0.67% in 100% NPK + farmyard manure (FYM). Diethylenetriaminepentaacetic acid (DTPA)–extractable Fe and Mn (but not Zn and Cu) in soil declined from their respective initial (1971) values as a result of intensive cropping for more than three decades. It also resulted in a decrease in the concentrations of all the four metallic cations bound to organic matter, in addition to Fe and Zn, associated with carbonates in all the treatments in surface soil.  相似文献   

8.
ABSTRACT

Indian mustard (Brassica juncea Czern) is a promising species for the phytoextraction of zinc (Zn), but the effectiveness of this plant can be limited by iron (Fe) deficiency under Zn-contaminated conditions. Our objectives were to determine the effects of root-applied Fe and Zn on plant growth, accumulation of Zn in plant tissues, and development of nutrient deficiencies for B. juncea. In the experiment, B. juncea was supplied 6 levels of iron ethylenediamine dihydroxyphenylacetic acid (Fe-EDDHA; 0.625 to 10.0 mg L?1) and two levels of Zn (2.0 and 4.0 mg L?1) for 3 weeks in a solution-culture experiment. Nutrient solution pH decreased with decreasing supply of Fe and increasing supply of Zn in solution, indicating that B. juncea may be an Fe-efficient plant. If plants were supplied 2.0 mg Zn L?1, plant growth was stimulated by increases in Fe supply, but plant growth was not influenced by Fe treatments if plants were supplied 4.0 mg Zn L?1. Zinc concentration in roots and shoots was suppressed by increasing levels of Fe in solution. Leaf concentrations of Cu, Mn, and P were suppressed also as Fe supply in solutions increased. Iron additions to the nutrient solution were not effective at increasing the Zn-accumulation potential of B. juncea unless plants were supplied the higher level of Zn in solution culture. Even under these conditions, Fe additions were effective only if supplied at low levels in solution culture (1.25 mg Fe L?1). Results suggest that Fe fertility has limited potential for enhancing Zn phytoextraction by B. juncea, even if plants suffer a suppression in growth from Fe deficiency.  相似文献   

9.
Seventeen Mollisols having pH(1:2) in the range of 6.00 to 8.42 were analyzed with five extractants, and the extractable zinc (Zn) ranges were 0.84 to 2.75 mg Zn kg?1 soil for diethylenetriaminepentaacetic acid (DTPA) (pH 7.3), 0.91 to 2.72 mg Zn kg?1 soil for DTPA + ammonium bicarbonate (pH 7.6), 1.82 to 7.18 mg Zn kg?1 soil for Mehlich 3, 1.22 to 3.83 mg Zn kg?1 soil for ethylenediaminetetraacetic acid (EDTA) + ammonium carbonate, and 0.88 to 1.18 mg Zn kg?1 soil for 1 mol L?1 magnesium chloride (MgCl2) (pH 6.0). Zinc extracted by DTPA (pH 7.3) and Mehlich 3 showed significant positive correlation with sand content, whereas only Mehlich 3 showed negative correlation with soil pH. All extractants showed significant positive correlation with each other except for 1 mol L?1 MgCl2‐extractable Zn, which had significant positive correlation with only Mehlich 3– and EDTA + ammonium carbonate–extractable Zn. A greenhouse experiment showed that Bray's percentage yield of rice was poorly correlated to extractable soil Zn but had a significant and negative linear correlation with soil pH (r = ?0.662, significant at p = 0.01). Total Zn uptake by rice had a significant positive correlation with 1 mol L?1 MgCl2– and Mehlich 3–extractable Zn. A proposed parameter (p extractable Zn + p OH?) involving both soil extractable Zn and pH terms together showed significant and positive correlation with Bray's percentage yield and total Zn uptake of rice. The calculated values of critical limits of soil Zn in terms of the proposed parameter were 14.1699 for DTPA (pH 7.3), 13.9587 for DTPA + ammonium bicarbonate, 13.7016 for Mehlich 3, 13.9402 for EDTA + ammonium carbonate, and 14.1810 for 1 mol L?1 MgCl2 (pH 6.0). The critical limits of Zn in rice grain and straw were 17.32 and 22.95 mg Zn kg?1 plant tissue, respectively.  相似文献   

10.
An experiment was conducted to assess the zinc (Zn) availability to wheat in alkaline soils during Rabi 2009–2010. Wheat seedlings in pots having 2 kg alkaline sandy soil per pot were treated with 5, 10 and 15 kg Zn ha?1 as soil and with 0.5 and 1.0% zinc sulfate (ZnSO4) as foliar application. Results showed that Zn increasing levels in soil helped in phosphorus uptake up to boot stage but its conversion to grain portion lacked in Zn treated plants. Potassium (K) uptake also increased up to 6.24% in boot stage with treatment of 10 kg Zn ha?1 + 1.0% ZnSO4 foliar spray. Zinc (Zn) concentration increased in plant tissues with the increasing level of Zn application but this disturbed the phosphorus (P)-Zn interaction and, thus, both of the nutrients were found in lesser quantities in grains compared to the control. Despite of the apparent sufficient Zn level in soil (1.95 mg kg?1), improvement in growth and yield parameters with Zn application indicate that the soil was Zn deplete in terms of plant available Zn. The above findings suggest that the figure Zn sufficiency in alkaline soil (1.0 mg kg?1) should be revised in accordance to the nature and type of soils. Furthermore, foliar application of Zn up to 1.0% progressively increased yield but not significantly; and it was recommended that higher concentrations might be used to confirm foliar application of Zn as a successful strategy for increasing plant zinc levels.  相似文献   

11.
Deficiency of micronutrients increasing in field crops, including upland rice in recent years. The objective of this study was to determine requirement of zinc (Zn), copper (Cu) boron (B) and iron (Fe) for upland rice grown on a Brazilian Oxisol. The levels used were: Zn (0, 10, 20, 40, and 80 mg kg?1), Cu (0, 5, 10, 20 and 40 mg kg?1), B (0, 5, 10, 20 and 40 mg kg?1) and Fe (0, 250, 500, 1000, and 2000 mg kg?1). Plant height, straw yield, grain yield, panicle number and grain harvest index (GHI) were significantly improved with the addition of these micronutrients. Root growth was also improved with the application of micronutrients, except with the addition of B. Maximum grain yield was obtained with the addition of 51 mg Zn, 24 mg Cu, 5 mg B kg?1, and 283 mg Fe kg?1 soil. Similarly, maximum straw yield was obtained with the addition of 38 mg Zn, 17 mg Cu, 6 mg B kg?1, and 1500 mg Fe kg?1 soil. Maximum plant height was obtained with the addition of 54 mg Zn, 10 mg B kg?1, and 1197 mg Fe kg?1 soil. Copper did not affect plant height significantly. Maximum panicle number was obtained with the addition of 22 mg Cu kg?1, 3 mg B kg?1, and 1100 mg Fe kg?1 soil. Zinc did not affect panicle number significantly. Maximum GHI was obtained with the addition of 61 mg Zn kg?1, and 8 mg B kg?1. Zinc was had a linear increase in GHI in the range of 0 to 80 mg kg?1, and Fe showed a negative relationship with GHI.  相似文献   

12.
The partial sterilization of soil eliminates useful microorganisms, resulting in the reduced growth of mycorrhizae-dependent citrus plants, which are often unresponsive to the application of fertilizer. Research was conducted to test the hypothesis that indigenous mycorrhizae (IM) inoculation is as efficient as selected mycorrhizal inoculation under sterile and non-sterile soil conditions. Rhizophagus clarus and indigenous mycorrhiza spores, isolated from citrus orchards, were used as arbuscular mycorrhizae fungi under greenhouse conditions with sterile and non-sterile Çanakçi series (Typic xerofluvent) soils with low phosphorus (P) fertility. Different P (0 and 100 mg kg?1) and zinc (Zn) (0, 5 and 10 mg kg?1) concentrations were used at the start of the experiments. The shoot, root dry weight (RDW), root colonization, and P, Zn, iron (Fe), copper (Cu) and manganese (Mn) concentrations of the shoot were determined; mycorrhizae dependency (MD) was also calculated.

The results indicate that R. clarus and indigenous mycorrhiza in sterile and non-sterile soil conditions considerably increased the growth of citrus plants. Owing to existing beneficial indigenous rhizosphere microorganisms, citrus plant growth without inoculation was better in non-sterile soils than in the sterile soils. In non-sterilized soil, the plant growth parameters of R. clarus-inoculated soils were higher than those of indigenous mycorrhiza-inoculated soils. Mycorrhizae infection increased certain citrus plant growth parameters, such as root infection, biomass and nutrient uptake (P, Zn, Fe, Mn and Cu). In sterile soil, the addition of up to 5 mg kg?1 soil Zn and the inoculation of R. clarus significantly increased plant growth; inoculation with indigenous mycorrhiza produced more dry weight upon the addition of up to 100 mg kg?1 phosphorus pentoxide (P2O5). Under sterile soil conditions, without considering fertilizer addition, MD was found to be higher than that of non-sterile soils. In general, the contribution of the indigenous soil spores is significant. However, indigenous soil mycorrhizae may need to be managed for better efficiency in increasing plant growth and nutrient uptake. The major finding was that the inoculation of citrus seedlings with mycorrhiza is necessary under both sterilized and non-sterilized soil conditions.  相似文献   

13.
Field experiments were conducted at Water Management Research Station, Begopara, Nadia, WB, India, during the rabi seasons of 2008–2009 and 2009–2010 to find out the integrated effect of nitrogen (N), phosphorus (P), potassium (K), farmyard manure (FYM) and zinc (Zn) under the system of rice intensification (SRI) techniques using eight treatments on the fertility changes in soil. The results revealed that the amounts of organic carbon and available N content in soil were found to maintain the highest fertility status with the highest yield in T6 (NPK + FYM 10 tha?1 + Zn 5 kgha?1) and gave the highest N uptake (55.98 kgha?1). The availability of P decreased with the increased level of Zn application and gave the highest P uptake (23.52 kgha?1) in the treatment T5 (NPK + FYM 10 tha?1). The highest Zn content (4.71 mgkg?1) was recorded in the treatment T7 (NPK + FYM 10 tha?1+ Zn 10 kgha?1).  相似文献   

14.
Abstract

Previous studies carried out on metal fractionation have shown that more than 95% of metals are in the solid phase of pig slurries (SPPS), with copper (Cu), and zinc (Zn) being the commonly occurring micronutrients in animal slurries. The input of micronutrients associated with the application of SPPS could be an important pathway for the supply of these essential elements to arable crops in bioavailable forms, especially in calcareous soils, which induce the immobilization of these elements. The aim of this work was to study the effect of application of pig manures (fresh and composted) derived from the SPPS on the micronutrient—iron (Fe), Cu, Magnesium (Mn), and Zn—concentration on amended calcareous soils in horticultural plants (cucumber and Milan cabbage). In addition, the effect of composting and application rates were analyzed. The experiment was conducted in field conditions on a Xerofluvent soil with a clayey‐loam texture. The organic wastes used in this study were uncomposted and composted solid fractions of swine manure slurry (UC‐SPPS and C‐SPPS, respectively) at two different rates (supplying 300 kg N ha?1 and 450 kg N ha?1 respectively). A mineral fertilizer treatment equivalent to 300 kg N ha?1 and a control treatment without fertilization were also included for comparison. The use of SPPS amendment induced a biomass production similar to the mineral fertilizer for cucumber, but higher in Milan cabbage plants, without any yield increment associated with the increased application rate of SPPS or composting. Micronutrient concentration in cucumber and cabbage plants was affected by the SPPS amendment, with an increase of Mn and Zn uptake and a decrease of Cu, compared to the control. The increasing application rate of SPPS did not induce a general increase in the plant uptake of micronutrients; the opposite was true for the crops grown in the C‐SPPS‐amended soils.  相似文献   

15.
Salinity is one of the major environmental stressors which has deleterious effects on the growth, development, and yield of crops. Because of the gradual increase in soil and water salinity in the East Azarbaijan, Iran, Tanacetum balsamita L. cultivation in this region has always been associated with many problems. To study the effect of foliar spray of iron sulfate (FeSO4) (0, 750, and 1500 mg L?1) under sodium chloride (NaCl) salinity (0, 50, and 100 mM) on some physiological characteristics of Tanacetum balsamita L. plants, an experiment was conducted as a factorial based on complete randomized block design with three replications. Total soluble solids (TSS) and essential oil contents were significantly affected by the interaction effects of FeSO4 foliar application and salinity levels. The highest TSS and essential oil content were found in the plants under NaCl0 × FeSO4 1500 mg L?1 treatment combination. Leaf length, leaf fresh and dry weights were influenced by both Fe foliar application and salinity levels. Foliar application of iron (Fe) positively affected leaf length, leaves fresh and dry weights, root fresh and dry weights and peroxidase (POD) content, especially at 1500 mg L?1. Other traits such as leaf length, leaf fresh and dry weights, malondialdehyde (MDA), POD and catalase (CAT) contents were influenced by salinity levels. For POD, MDA, and CAT contents, the highest values were recorded with NaCl 50 and 100. The highest values of leaf length, leaf fresh and dry weights were found in the control plants.  相似文献   

16.
A field experiment with 60 groundnut cultivars, in a calcareous soil having 1.20 mg kg?1 available zinc (Zn), foliar application of 0.2% aqueous solution of zinc sulphate thrice at 40, 55 and 70 days at 500, 500 and 1000 L ha?1, respectively, increased the number of pods, pod yield, shelling and 100 seed mass and seed zinc (Zn) content, significantly. The seeds Zn content in groundnut cultivars ranged 38–70 mg kg?1 with an average of 48 mg kg?1 without Zn and 58 mg kg?1 with Zn. Foliar Zn application increased 22% Zn in seed. This increase was more than 10% in 48 out of 60 cultivars. The cultivars GG 7, GG 20, Tirupati 4, DH 8, JSP 19, TKG 19 A, CSMG 884 and S 206 showed > 50 mg kg?1 Zn, > 10% increase in seed Zn with Zn application and > 250 g m?2 pod yield.  相似文献   

17.
Runoff may cause losses of micronutrients from soils. This can result in environmental problems such as contaminant transfers to water or a decrease in soil fertility. Appropriate soil management may reduce these micronutrient losses. This study examined the effect of applying crop residues to the soil surface on iron (Fe), manganese (Mn), copper (Cu), and zinc (Zn) losses by runoff. Runoff and sediment yield were measured on 1-m2 plots using a rainfall simulator with constant 65 mm h?1 intensity. Eight successive rainfall applications were performed at 65 mm each. Corn (Zea mays L.) straw was applied to plots at rates ranging from 0 to 8 t ha?1. Both total and dissolved concentrations of the micronutrients studied were decreased by corn straw applications. After 520 mm cumulative rainfall, total soil losses ranged from 150 to 15354 kg ha?1 depending on the amount of corn straw applied. Total micronutrient concentrations in runoff were as follows: Fe from 14.98 to 611.12 mg L?1, Mn from 0.03 to 0.61 mg L?1, Cu from 0.10 to 1.43 mg L?1, and Zn from 0.21 to 5.45 mg L?1. The relative contribution of the dissolved fraction to the total micronutrient content loss was low, but varied depending on the nutrient, being less than 1 percent for Fe and Mn and almost 10 percent for Zn. Total and dissolved concentrations in runoff of the studied elements decreased exponentially as the rate of applied corn straw increased. In conclusion, the addition of corn straw to soil reduced micronutrient losses.  相似文献   

18.
The potential of Nostoc 9v for improving the nitrogen (N)2–fixing capacity and nutrient status of semi‐arid soils from Tanzania, Zimbabwe, and South Africa was studied in a laboratory experiment. Nostoc 9v was inoculated on nonsterilized and sterilized soils. Inoculum rates were 2.5 mg dry biomass g?1 soil and 5 mg dry biomass g?1 soil. The soils were incubated for 3 months at 27 °C under 22 W m2 illumination with a photoperiod of 16 h light and 8 h dark. The moisture was maintained at 60% of field capacity. In all soils, Nostoc 9v proliferated and colonized the soil surfaces very quickly and was tolerant to acidity and low nutrient availability. Cyanobacteria promoted soil N2 fixation and had a pronounced effect on total soil organic carbon (SOC), which increased by 30–100%. Total N also increased, but the enrichment was, in most soils, comparatively lower than for carbon (C). Nitrate and ammonium concentrations, in contrast, decreased in all the soils studied. Increases in the concentration of available macronutrients were produced in most soils and treatments, ranging from 3 to 20 mg phosphorus (P) kg?1 soil, from 5 to 58 mg potassium (K) kg?1 soil, from 4 to 285 mg calcium (Ca) kg?1, and from 12 to 90 mg magnesium (Mg) kg?1 soil. Positive effects on the levels of available manganese (Mn) and zinc (Zn) were also observed.  相似文献   

19.
Soil and water samples were analysed for trace metals and As in two watercourses and 14 sampling plots in a salt marsh polluted by mine wastes in SE Spain. Groundwater levels, soil pH and Eh were measured ‘in situ’ for a 12-month period in each sampling plot, and total calcium carbonate was also determined. Low concentrations of soluble metals (maximum Mn 1.089 mg L?1 and maximum Zn 0.553 mg L?1) were found in the watercourses. However, total metal contents were extremely high in the soils of a zone of the salt marsh (maximum 1,933 mg kg?1 of Mn, 62,280 mg kg?1 of Zn, 16,845 mg kg?1 of Pb, 77 mg kg?1 of Cd, 418 mg kg?1 of Cu and 725 mg kg?1 of As), and soluble metals in the pore water reached 38.7 mg L?1 for Zn, 3.15 mg L?1 for Pb, 48.0 mg L?1 for Mn, 0.61 mg L?1 for Cd and 0.29 mg L?1 for As. Variable concentrations with depth indicate a possible re-mobilisation of the metals, which could be related to spatial and temporal variations of water table level, pH and Eh and to the presence of calcium carbonate. A tendency for the Eh to decrease in the warmest months and to increase in the coldest ones was found, especially, in plots that received water with a high content of dissolved organic carbon. Hence, the existence of nutrient effluent-enriched water may modify the physical–chemical conditions of the soil–water system and influence metal mobility.  相似文献   

20.
This study determines the seasonal variability of metal partition coefficients [aluminium (Al), iron (Fe), manganese (Mn), copper (Cu), and zinc (Zn)] and analyses the importance of suspended sediments (SS), dissolved organic carbon (DOC) concentrations, pH, and discharge (Q) on the seasonal variability of metal partition coefficients (KDs) in the headwaters of the Mero River catchment, which drains an agroforestry area in northwestern Spain. Metal partition coefficients were used as an approach to relate dissolved and particulate fractions. Water samples were collected over 3 years (2005–2008) at the catchment outlet. The mean metal dissolved concentrations were: Fe (43.5 μg L?1) > Al (23.3 μg L?1) > Zn (1.8 μg L?1) > Mn (1.2 μg L?1) > Cu (0.3 μg L?1). Partition coefficients followed the order Mn > Al > Fe > Zn > Cu, and their values exhibited low variability. Al, Cu, and Zn partition coefficients presented the greatest values in summer, except during 2007–2008, when the greatest KDs value was observed in autumn, whereas the KDs of Fe showed the greatest values in winter. The KD of Mn has no seasonality. For Al, Cu, and Zn, the seasonal SS concentrations were closely related to Kd. For Fe, Kd was more closely related to DOC concentration than to SS concentration.  相似文献   

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