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1.
It is desirable to know the distribution of phosphorus (P) fractions in soil so that plants may use P efficiently. Here we report the dynamics of inorganic and organic P in P-deficient black and rice soil cropped by soybean, white lupin, and maize supplied with nitrogen (N) inputs by N fixation and urea fertilizer. Inorganic P fractions of the three cropped soils could be ranked as O-P (organic phosphorus) > Al-P (aluminum phosphorus) > Fe-P (iron phosphorus) > Ca10-P (calcium-10 phosphorus) > Ca8-P (calcium-8 phosphorus) > Ca2-P (calcium-2 phosphorus), irrespective of soil type. The potential of various inorganic P fractions to plant nutrition differed between soybean and white lupin. The percentage of total P present as inorganic P was affected by crop, soil type, and N source. In black soil, the change of organic P fraction induced by N fixation was larger than by urea application. The moderately labile organic P (MLOP) concentration was not affected significantly by soil type and crop species, and it was probably the main P source to the inorganic P fraction because the correlation between the two pools was high (r = 0.945; P < 0.05). Crop species differed in their uptake of inorganic and organic P from soil. Though P fraction concentrations varied between black soil and rice soil, their response to crop species and N source was similar. The amounts of P removed from soil were affected by N source. The right choice of crop species and the application a suitable N source may increase crop yield and P uptake by plant in P-deficient soils.  相似文献   

2.
不同类型有机物料的有机磷组成及生物有效性   总被引:2,自引:1,他引:1  
  【目的】  研究不同有机物料的有机磷组成及其作为磷源施用后的供磷能力,为化肥磷的有机替代奠定理论基础。  【方法】  供试有机物料包括粪肥类 (猪粪、羊粪)、绿肥类 (豌豆、苜蓿和绿豆)、秸秆类 (小麦秸秆、玉米秸秆和油菜秸秆)。分析了8种有机物料的全磷、有机磷含量和C/P值,采用Bowman-Cole方法测定了有机磷中的活性 (LOP)、中活性 (MLOP)、中稳性 (MROP) 和高稳性有机磷 (HROP) 4个组分的含量。用供试的8种有机物料进行了小麦盆栽试验,分析了土壤速效磷含量、小麦吸磷量与不同有机物料的有机磷组成、碳/磷 (C/P) 值之间的关系。  【结果】  粪肥、绿肥和秸秆中的全磷含量分别为5.49~5.52、1.19~2.59、0.57~1.07 g/kg,有机物料中有机磷含量占全磷的比例在31.3%~55.2%,除绿豆秸秆外,有机磷含量小于无机磷。有机磷中LOP、MLOP、MROP和HROP的平均比例分别为8.5%、45.2%、41.5%和4.9%。LOP平均含量以粪肥类 (175.5 mg/kg) > 绿肥类 (67.03 mg/kg) > 秸秆类 (25.8 mg/kg);以猪粪、绿豆秸秆的MLOP含量相对较高;MROP含量羊粪 > 猪粪 > 苜蓿秸秆 > 绿豆秸秆 > 豌豆秸秆 > 玉米秸秆 > 油菜秸秆 > 小麦秸秆;HROP在粪肥中的含量显著高于其他类型物料。施用绿肥和粪肥显著增加了小麦的吸磷量和生物学产量,而施用秸秆则不同程度降低了小麦的吸磷量和生物学产量。小麦吸磷量与土壤速效磷含量呈线性正相关关系,与有机物料C/P值呈极显著负相关关系,与LOP、MLOP、MROP呈极显著正相关关系,与HROP相关性不显著;土壤速效磷与有机物料C/P值呈负相关关系。  【结论】  供试有机物料中的全磷含量以粪肥类 > 绿肥类 > 秸秆类,无机磷含量均大于有机磷含量 (绿豆秸秆除外),有机磷以中活性和中稳性有机磷为主。绿肥类和粪肥类物料中含磷量高、且C/P值较低,作为肥料使用能显著增加土壤速效磷含量、小麦生物学产量和吸磷量,可以有效替代一定比例的磷肥。而秸秆类有机物料含磷量较低,且C/P值较高,不适宜作为化肥磷的有机替代物料。  相似文献   

3.
中国长江中下游地区浅水湖泊沉积物有机磷研究   总被引:10,自引:0,他引:10  
Thirteen sediment core samples (0 10 cm) were taken from the seven lakes in the middle and lower reaches of the Yangtze River to determine the contents and distributions of organic phosphorus (P) fractions in the sediments of the shallow lakes in the area. The organic P fractions in the sediments were in the order of moderately labile organic P (MLOP) 〉 moderately resistant organic P (MROP) 〉 highly resistant organic P (HROP) 〉 labile organic P (LOP), with average proportional ratios of 13.2:2.8:1.3:1.0. LOP, MLOP, and MROP were significantly related to the contents of total organic carbon (TOC), water-soluble P (WSP), algal-available P (AAP), NaHCO3-extractable P (Olsen-P), total P (TP), organic P (OP), and inorganic P (IP). However, HROP was significantly related to OP and weakly correlated with TOC, WSP, AAP, Olsen-P, TP or IP. This suggested that organic P, especially LOP and MLOP in sediments, deserved even greater attention than IP in regards to lake eutrophication. In terms of organic P, sediments were more hazardous than soils in lake eutrophication. Although OP concentrations were higher in moderately polluted sediment than those in heavily polluted sediment, LOP and MLOP were higher in the heavily polluted sediment, which indicated that heavily polluted sediment was more hazardous than moderately polluted sediment in lake eutrophication.  相似文献   

4.
Phosphorus availability in terrestrial ecosystems is strongly dependent on soil P speciation. Here we present information on the P speciation of 10 forest soils in Germany developed from different parent materials as assessed by combined wet‐chemical P fractionation and synchrotron‐based X‐ray absorption near‐edge structure (XANES) spectroscopy. Soil P speciation showed clear differences among different parent materials and changed systematically with soil depth. In soils formed from silicate bedrock or loess, Fe‐bound P species (FePO4, organic and inorganic phosphate adsorbed to Fe oxyhydroxides) and Al‐bound P species (AlPO4, organic and inorganic phosphate adsorbed to Al oxyhydroxides, Al‐saturated clay minerals and Al‐saturated soil organic matter) were most dominant. In contrast, the P speciation of soils formed from calcareous bedrock was dominated (40–70% of total P) by Ca‐bound organic P, which most likely primarily is inositol hexakisphosphate (IHP) precipitated as Ca3‐IHP. The second largest portion of total P in all calcareous soils was organic P not bound to Ca, Al, or Fe. The relevance of this P form decreased with soil depth. Additionally, apatite (relevance increasing with depth) and Al‐bound P were present. The most relevant soil properties governing the P speciation of the investigated soils were soil stocks of Fe oxyhydroxides, organic matter, and carbonate. Different types of P speciation in soils on silicate and calcareous parent material suggest different ecosystem P nutrition strategies and biogeochemical P cycling patterns in the respective ecosystems. Our study demonstrates that combined wet‐chemical soil P fractionation and synchrotron‐based XANES spectroscopy provides substantial novel information on the P speciation of forest soils.  相似文献   

5.
塑料大棚内长期施肥对菜田土壤磷素组成及其含量影响   总被引:3,自引:1,他引:3  
对塑料大棚内自1988年开始的蔬菜施肥长期定位试验田土壤磷索组分和含量进行了研究.结果表明,除了长期单独施用氮肥引起耕层土壤全P、有效P降低外.其他施肥处理均能提高土壤中全P和有效P含量.长期施用有机肥土壤闭蓄态P(O-P)含量最高.占无机P总置的35%~47%;不施有机肥土壤磷酸钙(Ca-P)含量最高,占无机P总量的29%~39%.施用有机肥可以显著提高土壤有机P总量,有机肥组各处理土壤活性有机P和中等活性有机P含量均显著高于不施有机肥组各对应处理,而稳定性有机P和高稳定性有机P含量则低于不施有机肥组.长期施用磷肥会增加土壤中无机P积累,且有效性较高的Ca-P、磷酸铝(Al-P)积累程度高于较稳定的O-P、磷酸铁(Fe-P),土壤有效P含量与各组分无机P及其总量、活性有机P、中等活性有机P及有机P总量呈显著正相关.而与稳定性有机P、高稳定性有机P和全P含量的相关性不明显.因此,长期施用有机肥和磷肥能够改变土壤磷索组成.提高磷素有效性.  相似文献   

6.
长期不同供磷水平下南方黄泥田生产力及磷组分特征   总被引:1,自引:0,他引:1  
红壤性水稻土磷素易受铁、铝等固定而有效性低,过量施用磷肥则产生磷素淋失风险,研究不同供磷水平下黄泥田生产力、磷库平衡及磷组分特征,可为磷素高效管理提供依据。本研究基于福建黄泥田连续30年的供磷定位试验,研究连续30年3个供磷水平下[不施磷肥(CK)、30 kg(P_2O_5)·hm~(-2)(P1)、60 kg(P_2O_5)·hm~(-2)(P2)]水稻(1987—2004年为双季稻,2005年始种植单季稻)产量演变规律,并于试验的第31年分析土壤有效磷、全磷、无机磷库与有机磷库组分变化。结果表明,连续30年施用磷肥,与CK相比,早稻、晚稻与单季稻历年平均产量P1处理分别提高64.9%、37.0%与19.9%, P2处理分别提高67.0%、41.2%与20.4%,差异均显著。不同稻作制度下黄泥田磷肥的增产效果为早稻晚稻单季稻。与P1处理相比,P2处理第31年土壤有效磷含量提高190.5%,全磷含量提高32.4%,差异均显著;Al-P、Fe-P、Ca-P含量与无机磷含量均显著提高,Al-P、Fe-P占无机磷比重分别提高2.12个百分点与4.40个百分点,但O-P比重降低9.45个百分点,差异均显著。施磷肥总体提高了活性有机磷(LOP)与中等活性有机磷(MLOP)含量,降低了高稳定性有机磷(HSOP)含量,P2处理表现尤为明显;增施磷肥, LOP与MLOP占有机磷比重增加, HSOP比重降低。籽粒或秸秆产量与Al-P、Fe-P、Ca-P、MLOP、LOP含量呈显著正相关。综上,黄泥田连续30年施磷肥增产效果明显, P1与P2处理的产量无显著差异,但P1处理呈现磷表观亏缺。增施磷肥提高了无机磷Al-P、Fe-P、Ca-P比重,有机磷组分呈现由活性较低的形态向活性较高的形态转化趋势。每茬60 kg(P_2O_5)·hm~(-2)可维持磷素养分表观平衡并保持适宜的有效磷水平。  相似文献   

7.
Abstract

Low‐molecular‐weight (LMW) organic acids are found in soils. They originate from the activities of various microorganisms in soils or may be exuded from the roots of living plants. Several of those organic acids are capable of forming stable organo‐metal complexes with various metal ions found in soil solutions. As a result, these processes may lead to the release of inorganic phosphorus (P) associated with aluminum (Al), iron (Fe), and calcium (Ca) in soil minerals. The release of P from soils by LMW organic acids may be important to the P nutrition of plants. Studies on the release of P from soils by a variety of LMW organic acids showed that, in general, the di‐ and tricarboxylic acids were the most effective in releasing P from two Iowa soils, whereas the monocarboxylic, phenolic, and mineral acids released similar amounts of P. Oxalic, malonic, citric, and, in some cases, malic and tartaric acids were the most effective in releasing inorganic P from the two surface soils studied. There was an inverse relationship between the amounts of P released from soils and the pKa values of the organic acids. The amounts of P released from soils were significantly correlated with the published stability constants for the formation of organic complexes of Al, Fe, or Ca (log KAl, log KFe, or log KCa values). In general, the aliphatic acids containing α‐caboxyl and β‐hydroxyl functional groups or phenolic acids containing ortho‐hydroxyl groups were more effective in causing the release of P from soils than similar organic acids having other functional group combinations.  相似文献   

8.
不同温室蔬菜种植模式下土壤磷素形态分布与转化   总被引:3,自引:0,他引:3  
李婠婠  滕艳敏  李季 《土壤》2020,52(2):271-278
采用蒋柏藩-顾益初无机磷分级浸提法,研究了15a长期有机、综合和常规种植3种温室蔬菜生产体系下石灰性土壤磷形态分布及转化特征。结果表明:种植模式及施肥年限对土壤有机磷含量和各形态无机磷含量均有显著影响,且交互作用显著。随着施肥时间延长,3种种植模式土壤有机磷含量与无机磷形态Ca_2-P、Ca_8-P、Fe-P含量不断升高,Al-P、O-P、Ca_(10)-P含量呈现不规则变动,差异较小;有机模式土壤有机磷含量与无机磷形态Ca_2-P、Ca_8-P、Fe-P含量均高于常规和综合模式,O-P、Ca_(10)-P含量略小于常规和综合模式。在各磷素占比中,中等活性磷源(Ca_8-P、Fe-P、Al-P)潜在磷源(O-P、Ca10-P)有效磷源(Ca_2-P)。表层土中有机磷占全磷的8%~23%,亚表层土中有机磷占全磷的6%~13%。有机模式促进了无机磷各形态之间、有机磷和无机磷形态之间的转化过程,0~20 cm土层的磷素转化比20~40 cm更活跃。  相似文献   

9.
Different tillage systems may affect P dynamics in soils due to differently distributed plant residues, different aggregate dynamics and erosion losses, but quantitative data are scarce. Objectives were to investigate the effect of tillage on the availability of P in a long‐term field trial on loess soils (Phaeozems and Luvisols) initiated from 1990 to 1997. Four research sites in E and S Germany were established with a crop rotation consisting of two times winter wheat followed by sugar beet. The treatments were no‐till (NT) without cultivation, except for seedbed preparation to a depth of 5 cm before sugar beet was sown and conventional tillage (CT) with mouldboard plowing down to 25–30 cm. Soil P was divided into different pools by a sequential extraction method, and total P (Pt) in the single P fractions was extracted by digesting the extracts of the fractionation to calculate the contents of organic P. The Pt content (792 mg [kg soil]–1) in the topsoil (0–5 cm) of NT was 15% higher compared to CT, while with increasing depth the Pt content decreased more under NT than under CT. This was also true for the other P fractions except for residual P. The higher P contents in the topsoil of NT presumably resulted from the shallower incorporation of harvest residues and fertilizer P compared to CT, whereas estimated soil losses and thus also P losses due to water erosion were only small for both treatments. Contents of oxalate‐extractable Fe and organic C were positively related to the labile fractions of inorganic P, while there was a high correlation of the stable fractions with the clay contents and pH. Multiple regression analyses explained 50% of the variability of these P fractions. Overall, only small differences in the P fractions and availability were observed between the long‐term tillage treatments.  相似文献   

10.
长期施肥对红壤性水稻土有机磷组分的影响   总被引:17,自引:5,他引:17  
以19年肥料长期定位试验为背景,应用Bowman和Cole的有机磷分组方法,对红壤性水稻土有机磷组分及其变化进行了研究。结果表明:红壤性水稻土耕层有机磷含量较高,为225.93~322.47mgkg-1,占土壤全磷的28.59%~42.34%。土壤有机磷各组分中以中度活性有机磷含量最高,平均为134.80mgkg-1,占有机磷总量的51 58%;中度稳定性有机磷(92.46mgkg-1)占35.38%;高度稳定性有机磷(20.35mgkg-1)占7.79%;活性有机磷含量最低(13.67mgkg-1),占5.23%;长期施肥对土壤各组分有机磷量产生影响,耗磷处理,主要是中度活性有机磷和活性有机磷下降,降低量以CKNK处理。施磷主要促进中度稳定性有机磷和高度稳定性有机磷的增加,增加幅度以NPK+OMPNPK处理。不同施肥措施对土壤有机磷和无机磷库的耗竭或积累速度是不同的,耗磷条件,土壤有机磷/无机磷的比值上升,施磷使有机磷/无机磷比值下降.土壤供磷强度与有机磷/无机磷的比值呈显著负相关(r=-0.9497* ,r0.05=0.878)。  相似文献   

11.
Abstract

Highly calcareous soils are abundant in Iran. The calcium carbonate equivalent (CCE) of these soils reach up to 650 g kg?1. Although phosphorus (P) fertilizer is being widely used in these soils, little information, if any, is available about P status in such soils. The objectives of this study were to 1) determine inorganic P forms in 18 surface soils of southern Iran, 2) study P readsorption during different stages of fractionation schemes, 3) assess the ability of NaOH to extract aluminum (Al)‐P, and 4) evaluate the relationships between P availability indices and inorganic P forms. Eighteen soil samples with a wide range of physicochemical properties were selected for this study. Inorganic P forms was determined by sequential extraction with NaHCO3, NH4OAc, NH4F, NaOH, citrate dithionite (CD), and H2SO4, which are referred to as Ca2‐P, Ca8‐P, Al‐P, Fe‐P, occluded P (O‐P), and Ca10‐P. Phosphorus readsorption in different stages was determined by 1 M MgCl2. Furthermore, a fractionation scheme without an NH4F step was used to evaluate the ability of NaOH to extract Al‐P. NaHCO3 (Olsen‐P) and MgCl2‐extractable P (Exch‐P) were regarded as P-availability indices. The abundance of different P forms was in the order Ca2‐P<Fe‐P<Al‐P<O‐P<Ca8‐P<Ca10‐P. Ca2‐P was highly correlated with Olsen‐P and Exch‐P. Ca2‐P, Olsen‐P, and Exch‐P showed a relationship with CCE, citrate–bicarbonate–dithionite extractable Fe (Fed), and Al (Ald). Phosphorus readsorption appeared to be important only in the Ca8‐P step, and the content of readsorbed P was related to Ca8‐P, CCE, and clay content of the soils. In the present study, Al‐P and Fe‐P accounted for 10 and 5% of the sum of the inorganic P fractions, respectively, and Fe‐P showed a strong relationship with Feo, whereas Al‐P showed a significant relationship with oxalate‐extractable Al (Alo) and Ald. It was found that one extraction with NaOH is not a good indicator for Fe‐ and Al‐P, and the ability of NaOH to extract Al‐P was reduced with increase in Al‐P content.  相似文献   

12.
With the emphasis on sustainable agriculture, attention has been increasingly turning to recycling of crop residues as a component of fertility management strategies for tropical soils. We assessed the effects of soybean residue (SR) and wheat residue (WR) applied either alone or in combination with fertilizer P (FP) on dynamics of labile P, distribution of P fractions, and P sorption in a semiarid tropical Alfisol by conducting a 16 w long incubation experiment. The amount of P added through crop residues, FP or their combinations was kept constant at 10 mg P (kg soil)–1. Addition of SR or WR resulted in net increase of labile inorganic (Pi) and organic P (Po) and microbial P throughout the incubation period, except that the WR decreased labile Pi during first 2 w due to Pi immobilization. The P immobilization associated with WR addition was, however, offset when fertilizer P was combined with WR. Generally, the increases in labile‐P fractions were larger with the SR and SR+FP than with the WR and WR+FP. The sequential fractionation of soil P at the end of 16 w indicated that a major part of added fertilizer P transformed into moderately labile and stable P fractions as evident from the increased NaOH‐Pi and HCl‐P in the FP treatment. In contrast, the addition of SR and WR alone or in combination with FP favored a build‐up in NaHCO3‐Pi and ‐Po and NaOH‐Po fractions while causing a decrease in NaOH‐Pi and HCl‐P fractions. The addition of these crop residues also effectively decreased the P‐sorption capacity and hence reduced the standard P requirement of the soil (i.e., the amount of P required to maintain optimum solution P concentration of 0.2 mg P l–1) by 24%–43%. Results of the study, thus, imply that soybean and wheat crop residues have the potential to improve P fertility of Alfisols by decreasing P‐sorption capacity and by redistributing soil P in favor of labile‐P fractions and promoting accretion of organic P.  相似文献   

13.
Changes in P fractions using Hedley's sequential fractionation of organic and inorganic soil P, were studied in soils covering a wide range of developmental stages and original materials. A greenhouse experiment was performed in order to make an exhaustive P uptake by Lolium perenne and to study soil phosphorus mobilization from different fractions. Samples were obtained at 30, 60 and 90 days from sowing, with two fertilization rates added as KH2PO4. The exhaustion produced by plants resulted in different patterns of mobilization according to soil characteristics. For control soils the contents of inorganic labile fraction (LIP) decreased at the end of the experience in Mollisol (31%), Vertisol (24%) and Andisol (17%). The mobilization of organic P was greater for Ultisol and Andisol (77 and 75% respectively) than for the other soils. Fertilization affected mainly inorganic P, with a significant increase in contents of LIP in Entisol (46%) and moderately resistant inorganic P (MRIP) in Andisol (15%). Inorganic P/organic P relationship tended to increase during the experiment, while labile P/moderately resistant P increased in Entisol and Mollisol.  相似文献   

14.
In the Mesopotamia region (Argentina), rice is cropped on a wide range of soil types, and the response of rice to fertilizer application has been inconsistent even in soils with very low levels of available phosphorus. Phosphorus transformations in flooded soils depend on soil characteristics that may affect phosphorus availability. This study was conducted to determine which soil characteristics were related to the changes in P fractions during soil flooding. Soils were chosen from ten sites within the Mesopotamia region that are included in five different soil orders: Oxisols, Ultisols, Alfisols, Mollisols, and Vertisols. Soil phosphorus (P) was fractionated by a modified Hedley method before and after a 45 d anaerobic‐incubation period. Changes in the inorganic P extracted with resin depended on soil pH and were related to the exchangeable‐Fe concentration of soils (extracted with EDTA). Inorganic P extracted with alkaline extractants (NaHCO3 and NaOH) increased due to soil flooding. This increase was related to the organic‐C (OC) percentage of soils (r2 = 0.62, p < 0.01), and ranged from 13 to 55 mg kg–1. Even though previous studies showed that P associated with poorly crystalline Fe played an important role in the P nutrition of flooded rice, in this study, there was no relationship between ammonium oxalate–extractable Fe and P changes in soils due to flooding. Our results suggest that in the Mesopotamia region, changes in P fractions due to soil flooding are related to soil OC, soil pH, and soluble and weakly adsorbed Fe.  相似文献   

15.
Shen  Yan  Duan  Yinghua  McLaughlin  Neil  Huang  Shaomin  Guo  Doudou  Xu  Minggang 《Journal of Soils and Sediments》2019,19(7):2997-3007
Purpose

Calcareous soils are characterized by high pH and phosphorus (P) fixation capacity. Increasing application of P fertilizer recently has significantly improved soil P concentration, especially available P (Olsen-P) and inorganic phosphate (Pi) fractions. However, there are few data available on the ability of soils with different initial Olsen-P levels to continuously supply P (i.e., P desorption capacity) to crops without additional P fertilization and on which Pi fraction exerts the greatest influence on P desorption capacity.

Materials and methods

Five soils with different initial Olsen-P levels (0.5, 14.3, 38.4, 55.4, 72.3 mg kg?1, hereafter refer as OP1, OP2, OP3, OP4, and OP5) but similar other soil properties were selected to evaluate the capacity of P desorption and its relationship with Pi fractions. Soil P was sequentially extracted once daily for 16 consecutive days using Olsen solution.

Results and discussion

The content and proportions of dicalcium phosphate fraction (Ca2-P), octacalcium phosphate fraction (Ca8-P), aluminum phosphorus fraction (Al-P), and iron phosphorus fraction (Fe-P) in Pi increased significantly with the increase of initial Olsen-P (P?<?0.01). Applied P fertilizer was mostly stored as Ca8-P in the soil. Soil P desorbed reached an equilibrium after 16 extractions for all soils, and P desorption capacity (12–358 mg kg?1) showed a significant linear relationship with initial Olsen-P (P?<?0.01), with an increase of 4.2 mg kg?1 desorbed P per 1 mg kg?1 increase of initial Olsen-P. Ca2-P exerted the conclusive effect on P desorption in the first four extractions, but Ca8-P played a more important role in the 16 extractions.

Conclusions

Ca8-P was the greatest potential pool for P desorption after Ca2-P was depleted. P desorption capacity was significantly linearly related to initial Olsen-P (P?<?0.01). Different fertilizer use strategies were developed based on P desorption capacity for soils with different initial Olsen-P levels. The present study provided basic data on how to reduce effectively the application amount of chemical P fertilizer.

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16.
Abstract

Plants commonly suffer from phosphorus (P) deficiency in calcareous soils. Plant responses to P application on such soils mostly show poor correlation with their soil test P values. Experiments were conducted on 24 different soil samples under laboratory and greenhouse conditions to illustrate the relationship of various inorganic P fractions in different calcareous soils with P uptake by plants, P extraction by iron‐impregnated filter paper, and P soil test values estimated by 0.5M NaHCO3 and ammonium bicarbonate diethylene triamine penta‐acetic acid. Total P in the 24 soils ranged from 652 to 1245 mgkg?1 with a mean of 922 mgkg?1. A major proportion (98%) of inorganic P was in HCl‐P (Ca‐bound) form. The HCl‐P (Ca‐bound) ranged from 296 to 729 with a mean of 480 mgkg?1. The iron (Fe) and aluminum (Al)‐P (NaOH‐P) ranged from 0.92 to 12 mgkg?1 with a mean of 1.57 mgkg?1. The Fe‐P (citrate‐dithionite bicarbonate) ranged from 0.22 to 4.40 mgkg?1 with a mean of 5.99 mgkg?1. Data regarding P release from the soil matrix obtained by desorption with iron‐impregnated filter paper was best described by the Elovich equation. Range of slope and intercept values were found to be 5.48 to 17.3 and 17.23 to 56.27 mgkg?1, respectively. Intercept values calculated for the Elovich equation may be related to labile P initially available for plant uptake in soils. Intercept values calculated for the Elovich equation correlated (r=0.77) significantly (p<0.01) with NaHCO3 extractable (Olsen‐P)P. Significant correlation (p<0.05) of intercept with CDB‐P (r=0.44) and of slope with HCl‐P (0.43) suggested that the initially available P, regulated through CDB‐P, is replenished by HCl‐P [calcium (Ca) bound].  相似文献   

17.
【目的】研究不同含磷量的小麦秸秆还田对土壤磷素有效性的影响及其机理,为秸秆还田促进砂姜黑土磷素高效利用提供理论支撑。【方法】采用室内模拟培养试验方法,供试土壤为砂姜黑土。高磷和低磷小麦秸秆取自长期定位试验的施磷和空白对照小区,小麦秸秆含磷量分别为2.17、0.51 mg/kg。培养试验设不添加秸秆对照(CK)、添加低磷小麦秸秆(LS)、添加高磷小麦秸秆(HS) 3个处理,保持70%田间持水量,25℃下恒温培养90天。在培养0、3、7、15、30、60、90天时,测定土壤Olsen-P、无机磷组分、有机磷组分、磷酸酶活性、解磷菌数量、土壤微生物量磷(MBP),计算土壤MBP的周转量和周转率。【结果】土壤Olsen-P含量随培养时间增加,在培养第15天达到稳定。培养90天时,HS处理Olsen-P含量比CK提高了59.4%,而LS处理土壤Olsen-P含量比CK降低了23.9%(P<0.05)。培养90天时,HS和LS处理土壤Ca10-P和Fe-P含量均显著低于CK处理,而Ca8-P含量显著高于CK处理,HS处理的Ca2  相似文献   

18.
山东省三大土类的有机磷含量平均为61.59mg kg-1,约占全磷含量的12.37%,其中潮土的有机磷含量极显著高于褐土和棕壤。三大土类土壤不同活性有机磷中,以中稳性活性有机磷(MLOP)为主,平均占有机磷总量的76.37%,3大土类间MLOP、HROP差异极显著,MROP、LOP差异显著;4种不同活性有机磷以活性有机磷(LOP)的有效性最高,是反映土壤磷素有效性的主要指标之一,与土壤肥力密切相关。通过3大土类两个产量水平的有机磷与解磷微生物的数量、强度和各种酶的活性的相关性分析,探讨了土壤有机磷通过土壤微生物和磷酸化酶的生物活性进行转化的机制,为3大土类和两个产量水平的土壤培肥提供了理论依据。  相似文献   

19.
Phosphorus (P) deficiency is one of the main problems limiting crop growth in red soils of southern China. The primary objective of this study was to examine P availability as a function of soil acidity. Soils were sampled from a long-term fertilization experiment and are referred as low-P (No P fertilization) and high-P (120 kg P2O5 ha–1). Both low-P and high-P treatments were incubated adjusting soil pH to seven levels from 3.0 to 6.5 for 10, 20, 30 and 45 days. The pH, DIP, and Olsen-P were determined after each incubation period, and inorganic P fractions were measured at the end of incubation. For both low-P and high-P treatments, DIP decreased with rising pH value and increased with decreasing soil pH. Olsen-P, Ca-P (Ca2-P, Ca8-P, and Ca10-P) and Al-P increased significantly with soil pH in low-P treatment. In high-P, Olsen-P increased with pH between 3.4 and 5.0 and was stable at higher pH. Moreover, Ca-P and Al-P increased significantly but Fe-P decreased with soil pH increase. The redundancy analysis showed that Ca-P, Al-P, and pH had positive effects on Olsen-P, but Occluded-P showed a negative correlation with Olsen-P in both soils. Our results confirmed that soil P availability was influenced by pH and that the changes in DIP and Olsen-P were linked to changes of inorganic fractions from occluded to Ca- and Al-bound forms. Managing soil acidity is a key issue regarding the availability of P in red soils of China and our results suggest that at least a pH of 5.0 should be targeted.  相似文献   

20.
Summary Potential P and C mineralization rates were determined in a 12-week laboratory incubation study on subarctic forest and agricultural soil samples with and without N fertilizer added. There was no significant difference in net inorganic P produced between N fertilized and unfertilized soils. The forest soil surface horizons had the highest net inorganic P mineralized, 32 mg P kg-1 soil for the Oie and 17 mg P kg-1 soil for the Oa. In the cropped soils net inorganic P immobilization started after 4 weeks and lasted through 12 weeks of incubation. Cumulative CO2–C evolution rates differed significantly among soils, and between fertilizer treatments, with the N-fertilized soils evolving lower rates of CO2–C than the unfertilized soils. Soils from the surface horizons in the forest evolved the highest rates of CO2–C (127.6 and 89.4 mg g-1 soil for the Oie and Oa horizons, respectively) followed by the cleared uncropped soil (42.8 mg g-1 soil C), and the cropped soils (25.4 and 29.0 mg g-1 soil C). In vitro soil respiration rates, or potential soil organic matter decomposition rates, decreased with increasing time after clearing and in accord with the degree of disturbance. Only soils with high potential C mineralization rates and high organic P to total P ratios, mineralized P by the end of the study. Mineralizable P appeared to be associated with readily mineralizable organic C.  相似文献   

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