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1.
Abstract

Literature dealing with general properties of soil K and with K relationships in Atlantic Coastal Plain Soils was discussed. Potassium, among major and secondary nutrient elements, is the most abundant in soils. It, among mineral cations required by plants, is largest in non‐hydrated size. Potassium has a polarizability equal to .88 Å3 and a low hydration energy of 34 kcal g?1 ion?1. The major K forms in soils are water soluble, exchangeable, nonexchangeable, and mineral. Various dynamic interrelationships exist between these forms with the reaction kinetics between the various phases determining the fate of applied K.

Many Atlantic Coastal Plain soils contain high levels of total K. Most of the total K in these soils is contained in mineral forms such as micas and K‐feldspars. These K forms are slowly released to solution and exchangeable forms that are available to plants. Many researchers have noted a lack of crop response to K fertilization on Atlantic Coastal Plain soils. This lack of response has been ascribed to the high indigenous levels of mineral and non‐exchangeable K in the soils which would become available to crops. Some researchers have also attributed the lack of response to K accumulations in subsoil from leaching of applied K. If the physical and chemical conditions were favorable in the subsoil horizons, e. g., no pan formation and no severe Al toxicity, plant roots could absorb K from the subsoil horizons.  相似文献   

2.
Abstract

Exchangeable potassium (K) is the readily available form but when this pool is not sufficient, plants must be supplied from less labile forms of this nutrient. In this study, the contribution of nonexchangeable K to plant nutrition and the uptake rate of this nutrient in successive harvests were investigated. A greenhouse experiment was performed sowing annual ryegrass (Lolium multiflorum sp) on four agricultural soils with a wide range in exchangeable K concentration. The soils were a) Acuic Argiudol, b) Entic Hapludol, c) Typic Argiudol (Ordoñez and M. Juarez). Five harvests were conducted resowing after each one. Soil K extractable with 0.01 M CaCl2, exchangeable and nonexchangeable K was determined. Plant analyses were conducted to asses total K. The highest nonexchangeable K contribution to the total K uptaken by plants (in percentage) was observed in the Acuic Argiudol soil due to its low exchangeable K concentration. For the Typic Argiudol soils, this contribution varied according to exchangeable K concentration (Ordoñez soil) or according to the clay content and the mineralogy (M. Juarez). For all soils, the highest plant uptake rate was for the first harvests corresponding to the uptake of soluble K and the K located in the most labile positions in the exchange complex. This fact is confirmed by the high correlation obtained between the uptake rate and the amount of K extracted with CaCl2 (p<0.05). For subsequent harvests, a progressive decrease of K uptake rate was observed. In the fifth harvest plant uptake mostly depends on the nonexchangeable K concentration (p<0.05). The Acuic Argiudol soil, presents a special behavior ? given that it reaches the minimum rate in the third harvest due to the low concentration of all K forms of this soil.  相似文献   

3.
Abstract

Chemical and physical characteristics of soil aggregates from Clarion loam (fine‐loamy, mixed, mesic Typical Hapludoll) and Edina silt loam (fine, montmorillonitic, mesic Typic Argialboll) soil were evaluated to compare two alternate farming practices. Aggregate size distribution was measured for the 0‐to‐3 mm and 0‐to‐76 mm fractions collected from within existing ridges to a soil depth of 0.15 m prior to planting corn (Zea mays L.), after the first cultivation, at anthesis, and after harvest in 1990. Selected physical and chemical properties were determined for air‐dry aggregates in six size classes (0‐to‐0.5, 0.5‐to‐1.0, 1.0‐to‐2.0, 2.0‐to‐3.0, 3.0‐to‐4.0, and 4.0‐to‐5.0 mm) collected from the two Iowa soils prior to planting. Temporal changes in aggregate size distribution were observed for both soils, presumably because of combined rainfall and crop management effects. Physical and chemical properties of soil aggregates showed large differences between locations and within size fractions when compared to the bulk soil. Clarion loam had relatively more consistent exchangeable cation concentrations compared to Edina silt loam, presumably because of sustained incorporation of manure and municipal sludge at that site. Soil aggregation and aggregate properties can be used as indicators to evaluate the effects of alternate fanning practices.  相似文献   

4.
Annual potassium (K) balances have been calculated over a 40‐year period for five field experiments located on varying parent materials (from loamy sand to clay) in south and central Sweden. Each experiment consisted of a number of K fertilizer regimes and was divided into two crop rotations, mixed arable/livestock (I) and arable only (II). Annual calculations were based on data for K inputs through manure and fertilizer, and outputs in crop removal. Plots receiving no K fertilizer showed negative K balances which ranged from 30 to 65 kg ha?1 year?1 in rotation I, compared with 10–26 kg ha?1 year?1 for rotation II. On sandy loam and clay soils, the K yield of nil K plots (rotation I) increased significantly with time during the experimental period indicating increasing release of K from soil minerals, uptake from deeper soil horizons and/or depletion of exchangeable soil K (Kex). Significant depletion of Kex in the topsoil was only found in the loamy sand indicating a K supply from internal sources in the sandy loam and clay soils. On silty clay and clay soils, a grass/clover ley K concentration of ～2% (dry weight) was maintained during the 40‐year study period on the nil K plots, but on the sandy loam, loam and loamy sand, herbage concentrations were generally less than 2% K.  相似文献   

5.
Abstract

Nonexchangeable potassium (K) release kinetics of six major benchmark soil series of India as affected by mineralogy of clay and silt fractions, soil depth and extraction media was investigated. The cumulative release of nonexchangeable K was greater in smectitic soils (353 mg K kg?1 at 0‐ to 15‐cm depth and 296 mg K kg?1 at 15‐ to 30‐cm depth, averaged for 2 soils and 3 extractants) than in illitic (151 mg K kg?1 at 0‐ to 15‐cm depth and 112 mg K kg?1 at 15‐ to 30‐cm depth) and kaolinitic (194 mg K kg?1 at 0‐ to 15‐cm depth and 167 mg K kg?1 at 15‐ to 30‐cm depth) soils. Surface soils exhibited larger cumulative K release in smectitic and illitic soils, whereas subsurface soils had larger K release in kaolinitic soils. Among the extractants, 0.01 M citric acid extracted a larger amount of nonexchangeable K followed by 0.01 M CaCl2 and 0.01 M HCl. The efficiency of citric acid extractant was greater in illitic soils than in smectitic and kaolinitic soils. Release kinetics of nonexchangeable K conformed fairly well to parabolic and first‐order kinetic models. The curve pattern of parabolic diffusion model suggested diffusion controlled kinetics in all the soils, with a characteristic initial fast rate up to 7 h followed by a slower rate. Greater nonexchangeable K release rates in smectitic soils, calculated from the first‐order equation (b=91.13×10?4 h?1), suggested that the layer edge and wedge zones and swelling nature of clay facilitated the easier exchange. In contrast to smectitic soils, higher release rate constants obtained from parabolic diffusion equation (b=39.23×10?3 h?1) in illitic soils revealed that the low amount of exchangeable K on clay surface and larger amount of interlayer K allowed greater diffusion gradients, thus justifying the better fit of first‐order kinetic equation in smectitic soils and parabolic diffusion equation in illitic soils.  相似文献   

6.
We investigated the question of whether exchangeable K+ is a reliable factor for K+ availability to plants on representative arable soils (Aridisols) rich in K+-bearing minerals. Five soils with different textures were collected from different locations in Pakistan and used for pot experiments. The soils were separated into sand, silt, and clay fractions and quartz sand was added to each fraction to bring it to 1 kg per kg whole soil, i.e., for each fraction the quartz sand replaced the weight of the two excluded fractions. On these soil fraction-quartz mixtures wheat, elephant grass, maize, and barley were cultivated in a rotational sequence. Growth on the sand mixture was very poor and except for the elephant grass all species showed severe K+-deficiency symptoms. Growth on the mixture with silt and clay fractions was much better than on the sand fraction; there was no major difference in growth and K+ supply to plants whether grown on silt or clay, although the clay fraction was rich and the silt fraction poor in exchangeable K+. On both these fractions the plant-available K+ supply was suboptimal and the plants showed deficiency symptoms except for the elephant grass. This plant species had a relatively low growth rate but it grew similarly on sand, silt, and clay and did not show any K+ deficiency symptoms, with the K+ concentration in the plant tops indicating a sufficient K+ supply regardless of which soil fraction the plants were grown in. The reason for this finding is not yet understood and needs further investigation. It is concluded that on soils rich in mica, exchangeable K+ alone is a poor indicator of K+ availability to plants and that mica concentrations in the silt and clay fraction are of greater importance in supplying crops with K+ than exchangeable K+.  相似文献   

7.
Abstract

Our purpose was to determine the influence of the textural fraction and its mineralogical characteristics on the contents of the exchangeable (Ki) and nonexchangeable (Knoi) forms of soil potassium (K). Contributions of each textural fraction on Ki were as follows: 73–80% for clay, 8–18% for silt, and 2–10% for sand. The clay fraction relative to the contribution to Ki was not the same for all the soils studied. Thus, not only the quantity of clay must be taken into account, but also the cation exchange capacity (CEC) of the involved minerals. For Knoi, the total contribution showed a greater dispersion, the corresponding figures being as follows: clay 35–68%, silt 25–52%, and sand, 4–25%. Therefore, clay was not always the main contributor. In some soils, silt was the most important fraction due to the presence of muscovite.  相似文献   

8.
The effect of total electrolyte concentration (TEC) and sodium adsorption ratio (SAR) of water on ESR‐SAR relationships of clay (Typic Haplustert), clay loam (Vertic Haplustept) and silt loam (Lithic Haplorthent) soils was studied in a laboratory experiment. Twenty four solutions, encompassing four TEC levels viz., 5, 10, 20, and 50 mmolc l—1 and six SAR levels viz., 2.5, 5, 10, 15, 20, and 30 mmol1/2l—1/2 were synthesized to equilibrate the soil samples using pure chloride salts of calcium, magnesium, and sodium at Mg:Ca = 1:2. SAR of equilibrium solution decreased as compared to the equilibrating solution and more so in waters of low salt concentration and high SAR. At low electrolyte concentration, high SAR values were not attained in the equilibrium solution because of addition of calcium and magnesium from the mineral dissolution and from the exchange phase. Irrespective of TEC, exchangeable sodium in all the soils increased by about 4.5 to 5‐fold and irrespective of SAR, it increased by about 1.4‐ to 1.8‐fold. A positive interaction of TEC and SAR influenced the ESP build‐up and CEC played a major role in the visual disparity in sodication of these soils. At higher TEC levels, considerable increase in ESP was observed when it was corrected for anion exclusion and more so in silt loam followed by clay loam and clay soils. The values for Gapons' constant were in the range 0.0110—0.0176, 0.0142—0.0246, and 0.0189—0.0344 mmol—1/2l1/2 in clay, clay loam, and silt loam soils, respectively. Increase in TEC from 5 to 50 mmolc l—1 resulted in 5.84, 8.33, and 9.77 % decrease in Gapons' constant of clay, clay loam, and silt loam soils, respectively. The soils exhibited differential affinity for Ca2+, Mg2+ or Na+ under different quality waters. Regression coefficients of ESR‐SAR relationship were lower for low TEC as compared with high TEC waters. The exchange equilibrium was strongly affected by TEC of the solution phase. Variation in soil pH was gradual with respect to TEC and SAR of equilibrating solution and no sharp change was observed. Soluble salt concentration was doubled upon equilibration with low salt waters at all SAR levels in all the soils. However, the salt concentration remained unchanged upon equilibration with high salt waters. Considering pH 8.5 a boundary between soil salinity and sodicity, ESP values attained at TEC 5 mmolc l—1 were 7.34, 8.02, and 14.32 for clay, clay loam, and silt loam soils, respectively.  相似文献   

9.
Abstract

Coastal bermudagrass yields were increased by 3.1 Mg ha‐1 with K applications of 300 kg ha‐1 yr‐1 in a 7‐year study on Olivier silt loam at Baton Rouge, but available soil K depletion occurred even though K applications exceeded K removal in the forage. At lower rates of K application, K removal exceeded K applications, causing severe depletion of available soil K. Applying 600 kg of K ha‐1 exceeded both the crop K requirement and K removal in the forage, resulting in increased levels of available soil K. Ninety percent of the maximum yield was obtained at about 100 kg of K ha‐1. Potassium concentrations in the forage averaged 9.2 and 13.4 g kg‐1 at K rates of 100 and 300 kg ha‐1, respectively. Apparent recovery of fertilizer K decreased from 53 to 47% as K applications increased from 37 to 300 kg ha‐1. The Olivier silt loam supplied 105 kg of K ha‐1 annually where no K was applied. The study indicates that K applications must be sufficient to produce yields very near the maximum yield in order to avoid depletion of available soil K by high‐yielding Coastal bermudagrass.  相似文献   

10.
Abstract

The relationship of Cu and Zn fractionation in soils to plant growth was investigated on a Sassafras sandy loam (fine‐loamy, siliceous, mesic Typic Hapludult) and a Joppa gravelly sandy loam (loamy‐skeletal, siliceous, mesic Typic Hapludult). Pot studies were conducted in the greenhouse exposing corn (Zea mays cv. Silver Queen) to concentrations of 0, 100, 200, and 400 mg brass powder/kg soil. The corn was grown over a two week period, during which time individual plant heights were taken to note differences in plant growth. Data showed that plant height was reduced when the concentration of brass powder in the soil was increased. Total and fractionated Cu and Zn levels in the soils were analyzed and compared to height. Regression equations showed a more explicit relationship between height and exchangeable Cu levels rather than other Cu and Zn levels in the two soils. Additionally, a more pronounced effect was seen in plants grown on the Sassafras sandy loam, which was attributed to differences in soil physicochemical properties.  相似文献   

11.
Abstract

Many soils in Alberta contain insufficient amount of available P and fertilizer P is needed for optimum crop yields. Fields experiments were conducted at two sites (Lacombe ‐ Black Chernozem silt loam and Botha ‐ Thin Black Chernozem loam) in central Alberta to determine the hay yield response of alfalfa (Medicago sativa leyss. cv. Rambler) to P fertilizer applied annually (0, 10, 20, 30, 40, and 60 kg P ha‐1) or once initially (60, 120, and 180 kg P ha‐1). In the initial application triple superphosphate was incorporated into soil prior to sowing of alfalfa in 1974 and in the annual application the P fertilizer was spread on soil surface for three years at Lacombe and for five years at Botha beginning in the spring of 1975. The hay yield increased with P application, but its magnitude of response to added P was lower at Botha than at Lacombe. The residual effect of large single P applications on hay yield lasted at least for five years.  相似文献   

12.
Abstract

Interrelations between soil pH and exchangeable sodium percentage (ESP) were examined using soils from the Burdekin River area in tropical Queensland. Highly significant correlations were found but the goodness of fit differed between groups of soil profile classes. In general, Typic Natrustalfs of the flood plains had better relationships (r2 = 0.85) between these soil properties than did the Chromusterts (r2 = 0.50). The regression ESP = 1.935 × 10‐5 pH6.205 (r2 = 0.61; n= 288) for all soils and depths underestimated ESP in Typic Natrustalfs groupings and overestimated this soil property in the Chromusterts.

By using the appropriate regression, pH levels associated with non‐sodic, sodic and strongly sodic horizons have been defined. Either laboratory or field determined estimates of pH may be used but the laboratory determined value is preferred. It is expected the predictive models will remain valid until soil ESP or pH levels are significantly modified as a consequence of agricultural development.  相似文献   

13.
Abstract

Potassium in soils from selected plots of the Broadbalk Experiment at Rothamsted, and Rotation I experiment at Saxmundham, U.K. was measured by five methods: the boiling nitric acid extractions of Haylock and Maclean, electro‐ultrafiltration, release to Ca‐saturated ion exchange resin, and a new procedure using extraction by HCl under reflux. All. the methods showed clearly the Gifferences between the two soil types, and between the differently fertilized plots on the basis of amounts, and 1n some cases rates of release, of different categories of soil K (exchangeable, fixed and native). The quantity of exchangeable K measured by each method, except that by Ca‐resin, gave significant correlations with the K balance of the soils, and yield and/or K offtake of winter wheat grown on the plots. The new HCl ‐reflux method gave the closest correlations. The amount and rate of release of fixed (available but not exchangeable) K estimated by HCl‐reflux was also correlated with yield and offtake.  相似文献   

14.
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15.
Abstract

A greenhouse leaching column study was conducted to compare the effects of surface‐applied langbeinite (LB), phosphogypsum (PG), Ca‐ silicate slag (SS), and calcitic lime (CL) on subsoil Al and growth of alfalfa (Medicago sativa L. ‘Florida 77') in Toula silt loam soil (Typic Fragiudult). Langbeinite was found to be more effective than PG in the reduction of subsoil exchangeable Al, apparently through SO4 2‐‐induced Al precipitation. This study demonstrated that high exchangeable Al levels are not always indicative of Al toxicity in the soil solution phase. The primary factors limiting alfalfa growth in the Toula soil were found to be surface soil pH and Mn toxicity rather than subsoil Al toxicity. The liming materials, SS and CL, effectively corrected the surface soil Mn and pH problems, but had no effect on subsoil chemical properties.  相似文献   

16.
In the USA a suggested method for correcting late season K deficiencies in cotton (Gossypium hirsutum L.) is by in-row deep placement of K fertilizer. Experiments were conducted on three Alabama soils (southeastern USA) for 3 years to evaluate cotton response to K fertilizer when surface broadcast with and without in-row subsoiling (to 38 cm depth) or deep placed in the in-row subsoil channel. Potassium was applied at rates ranging from 0 to 84 kg K ha−1. Deep placement was achieved with a fertilizer applicator developed to distribute dry fertilizer at three depths down the back of the subsoil shank. All three soils also had deep placement treatments of 1680 kg ha−1 agricultural limestone with and without 84 kg K ha−1. Soils were an Emory silt loam (fine-silty, siliceous Fluventic Umbric Dystrochrepts), a Norfolk sandy loam (fine-loamy, siliceous Typic Kandiudults), and a Lucedale sandy clay loam (fine-loamy, siliceous Rhodic Paleuduts). All three soils had medium soil test K concentrations in the plow layer and medium or low concentrations of K at greater depths. The Norfolk soil had a well-developed traffic pan and in-row subsoiling increased seed cotton yields by an average of 22% during the 3 years of the study. Cotton responded to K fertilization in 2 out of 3 years at each location (6 out of 9 site-years) regardless of the method of K application. Annual applications of 84 kg K ha−1 increased 3 year average seed cotton yields by 17%, 10% and 19% on the Emory, Norfolk and Lucedale soils, respectively. Deep placement of agricultural limestone with or without K fertilizer for cotton did not increase cotton yields.  相似文献   

17.
Abstract

Winter wheat (Triticum aestivum L.) occupies large hectarage and is important in crop rotations on the highly weathered, low organic matter silt loam soils common in southern Illinois and the southern midwest United States region. Sulfur (S) is an essential element with some potential for deficiency, but it is not commonly applied to winter wheat grown on these soils. This study was conducted to determine if S nutrition is limiting winter wheat growth and grain yield. Interactive effects of topdressed fertilizer S (0 and 28 kg S/ha), tillage (disk‐till, DT and no‐till, NT), and wheat variety on plant growth, nutrient concentration, and grain yield were investigated for three crop years on two soils in southern Illinois; Cisne silt loam (fine, montmorillonitic, mesic Mollic Albaqualf), Brownstown site, and Grantsburg silt loam (fine‐silty, mixed, mesic Typic Fragiudalf), Dixon Springs site. Grain yield was unaffected by S application although flag leaf and whole plant S concentrations increased. Lack of yield response to S application was consistent each year on both soils and across all varieties and tillage systems. Equivalent yields were produced with both tillage systems at Brownstown, but slightly lower yield occurred with no‐till at Dixon Springs. Plant S concentrations and soil sulfate levels indicated sufficient S was available from sources other than fertilizer S, including extractable soil S and atmospheric deposition. Wheat variety consistently influenced plant nutrient composition and grain yield more than tillage or application of S fertilizer. If, in the future, wheat grain production, atmospheric S deposition, and extractable soil S remain at levels measured in this study, then S fertilizer applications would not be expected to increase winter wheat grain yield.  相似文献   

18.
本文研究了黄土区（陕西部分）土壤钾的形态,按毫克/100克土计,有机钾0.36-5.04,水溶性钾0.24-2.37,代换性钾3.61-16.96,有效钾3.85-19.33,非代换性钾64.45-149.77,结构钾1,840.3-2.538.3,全钾为1.920-2.640。有效钾为非代换性钾的11.42%,结构钾的0.53%和全钾的0.51%。水溶性钾和代换性钾分别是有效钾的8.2%和91.8%。通过主成分分析可知,土壤各种形态的钾与有机质呈正相关:水溶性钾、代换性钾、非代换性钾与有机态钾,代换性钾和非代换性钾与粉粒和粘粒也呈正相关,但都与沙粒呈负相关.钾的释放符合于幂回归方程（y=ax-b）.释放量从北向南是逐渐增加的.幼年土壤和轻黑垆土耕作层释放量高于其他层次,但是粘黑垆土和黑土的粘化层的释放量高于其它层次。  相似文献   

19.
Abstract

A greenhouse experiment was conducted to study the minimal exchangeable potassium (minimal K) status of fifteen smectite dominant soils and its relationship with K uptake and plant mobilization rate of soil reserve K. Exchangeable K reached minimal level decreasing about 35% from initial K status after 350 days of continuous cropping. Soils with high clay content and initial K status showed higher minimal exchangeable K. Cumulative K uptake by six successive crops varied from 160 mg kg‐1 to 823 mg kg‐1 and plant mobilization of soil reserve K varied from 0.151 mg kg‐1 day‐1 to 1.880 mg kg‐1 day‐1 among soils. Minimal K explained well the variation in total K uptake (r=0.85) and plant mobilization rate (r=0.83) as compared to initial exchangeable K status of soils (r=0.67 and 0.59, respectively) suggesting that the former is a better index of K supplying capacity of soils than the later.  相似文献   

20.
Purpose

The aim of this study was to quantify the contents and stocks of exchangeable and nonexchangeable fractions of potassium (K), calcium (Ca), and magnesium (Mg) after one and three successive Pinus taeda crops without fertilization and to predict the soil supply for further cultivations.

Materials and methods

The soil was analyzed in layers up to 80 cm in two Pinus forests, one at the end of the first cultivation and other at the end of the third successive crop, in a subtropical region in southern Brazil. Stocks of exchangeable and semi-total fractions of K, Ca, and Mg in the soil were calculated, and the potential number of crop rotations of Pinus without fertilization was estimated.

Results and discussion

After three Pinus crops, there was an average reduction of 46.9, 90.8, and 45.5% of exchangeable K, Ca, and Mg fractions respectively. Semi-total Ca content reduced in all depths, and semi-total K contents, in turn, only decreased until 20 cm of depth. The semi-total Mg contents have not been modified over the cultivations. Considering crop management with the export of plant twigs and needles and relying just on the availability of exchangeable Ca, the stocks of these nutrients in the soil would be sufficient for only one more Pinus cultivation, even when considering the absorption of nutrients on an 80-cm soil depth profile.

Conclusions

The management adopted in the region must be modified, replacing the nutrients exported via harvesting, especially Ca. Thus, the establishment of new cultivation of Pinus without fertilization may have its yield impaired, especially by the Ca availability.

  相似文献   

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