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1.
Abstract

Relative suitability of different extraction procedures for estimating available zinc (Zn) and copper (Cu) in soils was assessed using DTPA, 0.1 N HCl, ammonium acetate+EDTA, and double acid (HCl+ H2SO4) as extractants and rice as a test crop in Neubauer experiment. The relationships between Zn concentration and uptake of Zn by rice plants and Zn extracted by the different methods showed that DTPA‐TEA, pH 7.3, could very suitably be used to assess Zn availability in soils. However, 0.1 N HCl was better for assessing the Cu availability in soils to the rice plants. Water‐soluble and exchangeable fractions of Zn and Cu had significant positive correlations with Zn and Cu concentrations, respectively obtained by all the four extractants tested. The results also showed that DTPA and ammonium acetate+EDTA extracted organically bound Zn, whereas DTPA, 0.1 N HCl and ammonium acetate+EDTA extracted organically bound Cu. Water‐soluble, exchangeable and organic matter bound fractions exhibited significant relationships with Zn and Cu concentrations, their uptake and rice dry matter yield.  相似文献   

2.
Abstract

Five soil extractants, namely, 0.005 M diethylene triamine pentaacetic acid (DTPA) (pH 7.3), 0.005 M DTPA+1 M ammonium bicarbonate (pH 7.6), Mehlich 3, 0.01 M ethylene diamine tetraacetic acid (EDTA)+0.05 M ammonium carbonate (pH 8.6), and 1 M magnesium chloride (MgCl2) (pH 6.0), were evaluated to predict the response of wheat to zinc (Zn) application in Mollisols. These extractants could be arranged in the following decreasing order of their Zn extracting power: Mehlich 3>0.005 M DTPA+1 M ammonium bicarbonate>0.01 M EDTA+0.05 M ammonium carbonate>0.005 M DTPA>1 M MgCl2. The critical limits of Zn in soil, below which the yield response to late sown wheat (var. UP‐2338) to Zn application could be expected, were 0.57 mg 0.005 M DTPA (pH 7.3) extractable and 1.72 mg Mehlich 3–extractable Zn kg?1 soil. The critical limit of Zn in whole shoot at 60 days after emergence was found to be 26.1 mg Zn kg?1 plant tissue. The DTPA and Mehlich 3–extractable soil Zn also correlated significantly and positively with Zn concentration in whole shoot at 60 days after emergence and total Zn uptake by wheat at harvest.  相似文献   

3.
Twenty-four surface soils (0–15 cm) were collected from Tal land soils (vertisols) in the southern part of Bihar state in India. Six extractants were used to predict the extractability and their suitability for measuring available zinc (Zn) in these soils. Pot experiment with chickpea (Cicer arietinum cv. C-235) as test crop was conducted with five levels of Zn (0, 2.5, 5.0, 7.5, and 10.0 mg kg?1) to determine critical levels of Zn in soils and chickpea. The efficiency rating of different extractants in extracting available Zn from soils followed the order ethylenediaminetetraacetic acid (EDTA)–ammonium carbonate [(NH4)2CO3] > diethylenetriaminepentaacetic acid (DTPA)–ammonium bicarbonate (NH4HCO3) > DTPA– calcium chloride (CaCl2) > DTPA–sodium bicarbonate (NaHCO3) > magnesium nitrate [Mg (NO3)2] > magnesium chloride (MgCl2). The DTPA-CaCl2-extractable Zn was significantly and positively correlated with clay, organic carbon, cation exchange capacity, dry-matter yield, and plant Zn concentration and uptake but significantly and negatively correlated with soil pH. These properties attributed 87% variability in DTPA-CaCl2-extractable Zn.  相似文献   

4.
Seventeen Mollisols having pH(1:2) in the range of 6.00 to 8.42 were analyzed with five extractants, and the extractable zinc (Zn) ranges were 0.84 to 2.75 mg Zn kg?1 soil for diethylenetriaminepentaacetic acid (DTPA) (pH 7.3), 0.91 to 2.72 mg Zn kg?1 soil for DTPA + ammonium bicarbonate (pH 7.6), 1.82 to 7.18 mg Zn kg?1 soil for Mehlich 3, 1.22 to 3.83 mg Zn kg?1 soil for ethylenediaminetetraacetic acid (EDTA) + ammonium carbonate, and 0.88 to 1.18 mg Zn kg?1 soil for 1 mol L?1 magnesium chloride (MgCl2) (pH 6.0). Zinc extracted by DTPA (pH 7.3) and Mehlich 3 showed significant positive correlation with sand content, whereas only Mehlich 3 showed negative correlation with soil pH. All extractants showed significant positive correlation with each other except for 1 mol L?1 MgCl2‐extractable Zn, which had significant positive correlation with only Mehlich 3– and EDTA + ammonium carbonate–extractable Zn. A greenhouse experiment showed that Bray's percentage yield of rice was poorly correlated to extractable soil Zn but had a significant and negative linear correlation with soil pH (r = ?0.662, significant at p = 0.01). Total Zn uptake by rice had a significant positive correlation with 1 mol L?1 MgCl2– and Mehlich 3–extractable Zn. A proposed parameter (p extractable Zn + p OH?) involving both soil extractable Zn and pH terms together showed significant and positive correlation with Bray's percentage yield and total Zn uptake of rice. The calculated values of critical limits of soil Zn in terms of the proposed parameter were 14.1699 for DTPA (pH 7.3), 13.9587 for DTPA + ammonium bicarbonate, 13.7016 for Mehlich 3, 13.9402 for EDTA + ammonium carbonate, and 14.1810 for 1 mol L?1 MgCl2 (pH 6.0). The critical limits of Zn in rice grain and straw were 17.32 and 22.95 mg Zn kg?1 plant tissue, respectively.  相似文献   

5.
Abstract

Zinc availability was studied using five soils from Hawaii which had histories of massive phosphorus applications. Heavy phosphate fertilization usually increased extractable Zn, irrespective of the extractant used. The extra extractable Zn associated with the added P probably came from Zn as an accessory element in the fertilizer. Treble superphosphate commonly used in Hawaii contains about 1400 ppm Zn. The Zn content of phosphate fertilizers must be considered before making statements about the effect of fertilizer P on Zn solubility and availability in soils.

Two solutions (0.1N HCl and 0.005M DTPA) were compared as Zn extractants for Hawaii soils. DTPA extracted less Zn than 0.1N HCl. Zinc extracted by repeated HCl treatment was more closely related to the labile Zn pool (E‐values and L‐values) than was DTPA‐extractable Zn. The results suggest that 0.1N HCl extractable Zn, Zn E‐value and Zn L‐value measured the quantity of a single fraction of soil Zn.

Repeated extraction of soil with 0.1N HCl seems to be a suitable procedure for evaluating the Zn status of acid, highly weathered soils of Hawaii.  相似文献   

6.
Abstract

Zinc (Zn) deficiencies have been identified in Venezuela with increasing frequency in recent years. However, there are no established critical values for available Zn in the acid soils of this country. Greenhouse studies were initiated to evaluate five extractants, DTPA, DTPA‐HCl, Na‐EDTA, 0.1N hydrochloric acid (HCl), and Mehlich 1 to predict Zn availability in 14 acid soils with corn as the test crop. Significant and positive correlations were found between Zn extracted among the five extractants. Zinc extracted was not related with soil pH and organic matter content, but with the cation exchange capacity and clay content. The Na‐EDTA extractant was found to be the most suitable as an indicator of Zn‐deficient acid soils, the critical Zn value being 2.4 mg#lbkg‐1.  相似文献   

7.
A reliable soil test is needed for estimating mercury (Hg) availability to crop plants. In this study, four extraction procedures including 0.1 M hydrochloric acid (HCl), 1 M ammonium acetate (NH4OAc) (pH 7.0), 0.005 M diethylenetriaminepentaacetic acid (DTPA), and 0.1 M calcium chloride (CaCl2) (pH5.0) were compared for their adequacy in predicting soil Hg availability to crop plants of a rice–cabbage–radish rotation system. The amounts of Hg extracted by each of the four procedures increased with increasing equilibrium time. The optimal time required for extraction of soil Hg was approximately 30 min, though it varied slightly among the four extractants. The amounts of Hg extracted decreased with increasing soil/solution ratio, and a soil/solution ratio of 1:5 appeared to be adequate for soil Hg availability tests. The amounts of Hg extracted increased in the order of NH4OAc < CaCl2 < DTPA < HCl in silty loam soil (SLS) soil, and the order was NH4OAc < CaCl2 ≈ DTPA < HCl in yellowish red soil (YRS) soil. Significant positive correlations among the four extractants were obtained in SLS soil. In contrast, the correlations were poor in YRS soil, especially for HCl. There were significant correlations between concentrations of Hg in edible tissue of three plants and the amounts of soil Hg extractable to the four extractants for soil–rice system and soil–radish system, but not for soil–Chinese cabbage system. The 0.1M HCl extraction overall provided the best estimation of soil‐available Hg and could be used to predict phytoavailability of Hg in soil–crop systems.  相似文献   

8.
Abstract

Alfisols, Vertisols, Inceptisols, Aridisols, Mollisols, and Entisols were sampled (0–30 cm) from 32 locations across Ethiopia. The soils were analyzed for copper (Cu), zinc (Zn), manganese (Mn), and iron (Fe) contents using 0.005 M diethylene triamine pentaacetic acid (DTPA), 0.05 M hydrochloric acid (HC1), and 0.02 M ethylene diamine tetraacetic acid (EDTA) extractants. EDTA extracted more of each micronutrient than DTPA, which extracted greater amounts than HC1. The quantities of EDTA and DTPA‐extractable micronutrients were significantly correlated, and were in the order: Mn>Fe>Cu>Zn. The order of HCl‐extractable micronutrients was Mn>Fe>Zn>Cu. Micronutrient contents of Mollisols, Vertisols, and Alfisols were usually greater than those of the other soils, and Entisols usually had the lowest micronutrient contents. The contents were mostly positively correlated with clay and Fe2O3 contents, but negatively correlated with soil pH and A12O3contents. While comparison of DTPA‐ and EDTA‐extractable micronutrients with critical levels showed that most soils had adequate amounts of the micronutrients for crops, the amounts extracted by HC1 were below critical levels in most soils. Since the critical levels that were used in the comparisons were not established in Ethiopia, calibration of the soil contents of these micronutrients with crops grown in Ethiopia is required to identify the most suitable extractant(s).  相似文献   

9.
Zinc (Zn) deficiency is a persistent problem in flooded rice (Oryza sativa L.). Severe Zn deficiency causes loss of grain yield, and rice grains with low Zn content contribute to human nutritional Zn deficiencies. The objectives of this study were to evaluate the diethylenetriaminepentaacetic acid (DTPA) extraction method for use with reduced soils and to assess differences in plant availability of native and fertilizer Zn from oxidized and reduced soils. The DTPA‐extractable Zn decreased by 60% through time after flooding when the extraction was done on field‐moist soil but remained at original levels when air‐dried prior to extraction. In a pot experiment with one calcareous and one noncalcareous soil, moist‐soil DTPA‐extractable Zn and plant Zn uptake both decreased after flooding compared with the oxidized soil treatment for both soils. In the flooded treatment of the calcareous soil, both plant and soil Zn concentrations were equal to or less than critical deficiency levels even after fertilization with 50 kg Zn ha?1. We concluded that Zn availability measurements for rice at low redox potentials should be made on reduced soil rather than air‐dry soil and that applied Zn fertilizer may become unavailable to plants after flooding.  相似文献   

10.
Abstract

Three different chemical extractants were evaluated as to their extraction efficiency for copper (Cu), zinc (Zn), lead (Pb), aluminium (Al), iron (Fe), chromium (Cr), manganese (Mn), potassium (K), magnesium (Mg), and calcium (Ca) on forest soil profiles from the Romanian Carpathians. The extractants were hot 14 M nitric acid (HNO3), 0.05 M hydrochloric acid (HCl), and 0.1 M sodium pyrophosphate. By comparing amounts extracted by 0.05 M HCl and 0.1 M sodium pyrophosphate relative to that dissolved by hot 14 M HNO3, some conclusions were drawn concerning the chemical forms of the metals in the extractable pool. The amount released by 0.05 M HCl was generally less than 10% of the HNO3‐extractable fraction but showed considerable variation among the elements studied. The relative amount extracted by pyrophosphate increased with organic‐matter content of the soils for Cu, Zn, Pb, Al, Fe, and Cr; stayed more or less constant for Mn, K, and Mg; and decreased for Ca. These findings are discussed with respect to the different binding forms of the metals in the soil and the processes affecting their mobility. From the present results, the metals were ranked as follows with respect to their ability to form organic complexes in natural soils: Cu>Cr, Pb>Ca>Al>Fe, Zn, Mn, K>Mg. However, the use of cold dilute HCl as a fractionation step may be questionable in cases of soils with a high content of substances possessing large neutralization capacity for protons.  相似文献   

11.
Ethylendiamintetraacetic acid (EDTA) is persistent in the environment. The presence of EDTA in soil may alter the mobility and transport of Zn, Cd and Ni in soils because of the formation of water soluble chelates, thus increasing the potential for metal pollution of natural waters. Mobility of metals is related to their extractability. To investigate metal extractability affected by EDTA, Zn, Cd and Ni were added to Vertisol and Alluvial soil at rates of 50, 2 and 5 mg kg-1, respectively. Both natural and metal amended soils were treated with Na2EDTA at rates of 0; 0.2 and 0.5 mg kg-1. After five months of incubation soil samples were extracted with 0.1 N HCl, 0.005 M DTPA + 0.01 M CaCl2 + 0.1 M TEA (0.005 M Diethylenetriaminepentaacetic acid + 0.01 M Calcium cloride + 0.1 M Triethanolamine) and 1 M Mg(NO3)2, the latter of which extracts the exchangeable from of metald (Zn, Cd and Ni).

According to experiment results, Zn, Cd and Ni in all extraction increased with increasing rates of EDTA in the natural and metal amended soils.  相似文献   

12.
Abstract

A field experiment was conducted to determine whether Zn applied for pathogen control could accumulate to a level which would be toxic to snapbeans, cucumbers, or corn. Zinc sulfate (ZnSO4) was applied at rates varying from 0 to 363 kg Zn/ha on a Flainfield loamy sand to approximate 3, 9, 27 and 81 years of fungicidal treatment.

Even at the high rate of Zn, yields of snapbeans, cucumbers, or corn generally were not reduced. As rates of applied Zn increased, there was a corresponding increase in the level of Zn in the leaf tissue of all crops grown. At the high Zn rate, snapbean and cucumber leaf tissue accumulated over 350 ppm Zn. Available soil Zn was extracted with 0.1N HCl, EDTA, or DTPA. Highly significant correlations were observed between the Zn removed by each extractant and plant tissue Zn, thus, indicating that the various extractants were equally effective in predicting Zn uptake.

Very little downward movement of Zn was observed. Two and one‐half years after application, the Zn had leached to a depth of only 30 cm in the soil profile at the higher Zn rates.

These data indicate that application of Zn‐containing fungicides and bactericides should not cause a Zn toxicity problem on the Plainfield sand in the foreseeable future.  相似文献   

13.
In this study, complexation extractants ammonium bicarbonate diethylene triamine pentaacetic acid (AB-DTPA), diethylene triamine pentaacetic acid (DTPA), and ethylene diamine tetraacetic acid (EDTA) and mild cation-exchange extractants calcium chloride (CaCl2) and ammonium nitrate (NH4NO3) were used to evaluate the bioavailability of soil cadmium (Cd) to cacao in the field. Among the five extractants, the extractable Cd generally followed the order EDTA > DTPA > AB-DTPA > CaCl2 > NH4NO3. Correlation analysis was done between the extractable Cd in soil and total Cd content of cacao tissues (nibs, shells, leaves, and pods). The Cd extracted by CaCl2 and NH4NO3 was significantly (P < 0.05) correlated with some of the tissues but their Pearson correlation coefficients were weak. In contrast, extractants AB-DTPA, DTPA, and EDTA showed stronger, significant correlations to the Cd concentration in all four tissues. Overall, regression analysis demonstrated that AB-DTPA, DTPA, or EDTA can be used to predict bioavailable Cd in soils for cacao. Of these, AB-DTPA and DTPA both showed the strongest correlations compared to EDTA. However, the ease of preparation and the superior shelf-life of DTPA over AB-DPTA make it the preferred reagent for Cd bioavailability extractions from cacao soils and is currently being used to develop cost-effective soil treatments to reduce bioavailable Cd to cacao plants.  相似文献   

14.
Abstract

Twenty surface soil samples were collected from Nainital Tarai (foothills of Himalya) where “Khaira”; disease (Zn deficiency of rice) is prevalent. Rice (Oryza sativa L. variety IR‐8) was grown in pots for 8 weeks after transplanting. Experiments were conducted to determine the suitability of five soil Zn extractants: dilute acid (HCl + H2SO4) mixture; DTPA‐(NH4) 2CO3, pH 7.3; dithizone; NH4OAc, pH 4.6; and 2N MgCl2 to predict Zn deficiency. Critical values for soil available Zn were established for rice by the old and new Cate and Nelson procedures1.

Zinc extracted from the soils with dithizone; NH4OAc, pH 4.6; 0.2N MgCl2. and DTPA‐(NH4) 2CO3 pH 7.3 was significantly correlated with the uptake of Zn by the rice plants. The correlation between Zn extracted with the dilute acid (HCl + H2SO4) mixture and plant Zn was not statistically significant. The ex‐tractants which extracted greater quantities of Zn gave higher critical values and vice versa. It is concluded that all extracting solutions except the dilute acid (HCl + H2SO4) mixture were found to he suitable for predicting available Zn in rice soils of Tarai.  相似文献   

15.
This research was carried out in order to find out the effect of zinc application on the methods which can be used to determine available iron content of paddy soils. For this purpose, an experiment was carried out in greenhouse conditions by growing maize. The effect of increasing rates of zinc application on biological indexes of maize plants was determined. Eight chemical extraction methods for available iron content of soils were used and these methods are: 0.005 M DTPA+0.01 M CaCl2+0.1 M TEA; 0.005 N HCl+0.025 N H2SO4; 1 N NH4Oac; 0.01 N Na2EDTA+1 N NH4Oac; 2 N MgCl2; 0.01 M Na2EDTA +1 M (NH4)2CO3; 0.01 N Na2EDTA and 0.005 M DTPA+NH4HCO3. The relationships between biological indexes and chemical extraction methods were determined at the end of the experiment. The highest correlation coefficient was determined with the method 0.005 M DTPA+0.01 M CaCl2+0.1 M TEA. The iron content of maize plants decreased with zinc application and dry matter content increased with zinc application.  相似文献   

16.
Greenhouse and field experiments were conducted to determine the influence of nitrogen (N) fertilization and DTPA‐extractable soil zinc (Zn) on Zn concentration in wheat (Triticum aestivum L., cv. Pioneer 2375) grain. Application of zinc sulfate (ZnSO4) in the range of 0 to 8 mg Zn kg‐1 increased linearly DTPA‐extractable Zn in an incubated calcareous soil from 0.3 to 5.0 mg kg‐1. Application of these rates of ZnSO4 to the same soil under greenhouse conditions increased Zn concentration of wheat grain from 26 to 101 mg kg‐1. The influence of 134 kg urea‐N ha‐1 on Zn concentration in wheat grain at eight field sites, with DTPA‐extractable soil Zn levels ranging from 0.3 to 4.9 mg kg‐1, was studied. Nitrogen fertilizer increased wheat‐grain yields in four of the eight experiments but had little effect on grain‐Zn concentration. Grain‐Zn concentration ranged from 31 to 45 mg kg‐1 in N‐fertilized plots at the various sites and was related (r=0.74*) to DTPA‐extractable soil Zn.  相似文献   

17.
Abstract: The objective of this study was to determine how the extractant Mehlich 3 (M3) compared with other methods currently used in Ireland for determination of copper (Cu) and zinc (Zn) in soils. Samples from eight different mineral soil types, four of sandstone/shale and four of limestone origin, were analyzed for copper and zinc using M3 and conventional extractants. Herbage samples were taken from the soils and analyzed for Cu and Zn. Mehlich 3 results showed good correlation with ethylenediamine‐tetraacetic acid (EDTA)– and diethylenetriamine‐pentaacetic acid (DTPA)–extractable Cu and Zn. Inclusion of soil properties in multiple regression models improved the coefficients of determination. All extractants were equal in their ability to predict Cu and Zn herbage content. Differences between sandstone/shale and limestone soils in relation to herbage content were also found, with the better relationship found in sandstone/shale soils.  相似文献   

18.
Abstract

Speciation study of microelements in soils is useful to assess their retention and release by the soil to the plant. Laboratory and greenhouse investigations were conducted for five soils of different agro‐ecological zones (viz., Bhuna, Delhi, Cooch‐Behar, Gurgaon, and Pabra) with diverse physicochemical properties to study the distribution of zinc (Zn) among the soil fractions with respect to the availability of Zn species for uptake by rice plant. A sequential extraction procedure was used that fractionated total soil Zn into water‐soluble (WS), exchangeable (EX), specifically adsorbed (SA), acid‐soluble (AS), manganese (Mn)‐oxide‐occluded (Mn‐OX), organic‐matter‐occluded (OM), amorphous iron (Fe)‐oxide‐bound (AFe‐OX), crystalline Fe‐oxide‐bound (CFe‐OX), and residual (RES) forms. There was a wide variation in the magnitude of these fractions among the soils. The studies revealed that more than 90% of the total Zn content occurred in the relatively inactive clay lattice and other mineral‐bound form (RES) and that only a small fraction occurred in the forms of WS, EX, OM, AFe‐OX, and CFe‐OX. Rice (Oryza sativa L.) cultivars differ widely in their sensitivity to Zn deficiency. Results suggested that Zn in water‐soluble, organic complexes, exchange positions, and amorphous sesquioxides were the fractions (pools) that played a key role in the uptake of Zn by the rice varieties (viz., Pusa‐933‐87‐1‐11‐88‐1‐2‐1, Pusa‐44, Pusa‐834, Jaya, and Pusa‐677). Isotopic ally exchangeable Zn (labile Zn) was recorded higher in Typic Ustrochrept of Pabra soil, and uptake of Zn by rice cultivars was also higher in this soil. The kinetic parameters such as maximum influx at high concentrations (Imax) and nutrient concentration in solution where influx is one half of Imax (Km) behaved differentially with respect to varieties. The highest Imax value recorded was 9.2×10?7 µmol cm?2 s?1 at the 5 mg kg?1 Zn rate for Pusa‐933‐87‐1‐11‐88‐1‐2‐1, and the same was lowest for Pusa‐44, being 4.6×10?7 µmol cm?2 s?1 at the 5 mg kg?1 Zn rate. The Km value was highest for Pusa‐44 (2.1×10?4µmol cm?2 s?1) and lowest for Pusa‐933‐87‐1‐11‐88‐1‐2‐1 (1.20×10?4µmol cm?2 s?1). The availability of Zn to rice cultivars in Typic Ustrochrepts of Bhuna and Delhi soils, which are characterized by higher activation energy and entropy factor, was accompanied by breakage of bonds or by significant structural changes.  相似文献   

19.
Desilication and leaching are processes that accompany plinthilization, leading to nutrient depletion. Soils from 12 profiles in a plinthitic landscape were analyzed for extractable micronutrients [iron (Fe), zinc (Zn), manganese (Mn), and copper (Cu)]. Soils of the landscape from crestal to lower‐slope position contain plinthite in the profile, whereas those of the valley floor are devoid of plinthite. The micronutrients were extracted using diethylenetriaminepentaacetic acid (DTPA) and 0.1 M hydrochloric acid (HCl). The results showed that 0.1 M HCl extracted more of the micronutrients than DTPA. The DTPA‐extractable Fe, Zn, Mn, and Cu in all the soils ranged from 1.15 to 12.44 (mean, 3.69); 0.71 to 2.75 (mean, 1.86); trace 12.44 (mean, 3.35), and trace 3.76 (mean, 0.63) mg kg?1, respectively. The DTPA‐extractable micronutrient contents were generally greater than the critical available level (4.5 mg kg?1 for Fe, 0.8 mg kg?1 for Zn, 1.0 mg kg?1 for Mn, and 0.2 mg kg?1 for Cu). The 0.1 M HCl‐extractable micronutrients in the landscape ranged from 8.00 to 30.40 (mean, 15.19); 0.30 to 6.49 (mean, 1.35); 1.00 to 27.20 (mean, 7.74); and 0.26 to 15.0 (mean, 2.77) mg kg?1 for Fe, Zn, Mn, and Cu, respectively. Both DTPA‐ and 0.1 M HCl‐extractable micronutrients were generally lower in the plinthitic horizons than in the nonplinthitic horizons and higher in the Ap than the subsoil horizons. Correlation analysis showed a significant relationship between DTPA‐Fe and DTPA‐Mn, Cu, and organic carbon (r = 0.913**, 0.411**, and 0.385**). There was a significant and positive relationship between 0.1 M HCl‐extractable Mn and organic carbon (C), total nitrogen (N), and available phosphorus (P) (r = 0.413**, 0.337**, and 0.350**, respectively).  相似文献   

20.
Abstract

Zinc of index corn leaves samples from 91 Minnesota sites on numerous soil types was correlated with soil Zn extracted by four routine procedures. The EDTA?(NH4)2CO3 ‐ extractable soil Zn was more closely correlated with leaf Zn than soil zinc extracted by 0.1N HCl, EDTA‐NH4OAc, or by NH4OAc ‐ dithizone. Soil pH, CaCO3 equivalent, extractable P, and organic matter of both acid and calcareous soils were negatively correlated with leaf Zn. When EDTA ? (NH4)2CO3 ‐ extractable Zn was included with routine soil tests, a prediction equation for corn leaf Zn was formulated and compared with analytical values. However, the use of 1.4 ppm EDTA ? (NH3)2CO3, ‐ extractable soil Zn alone as a critical value was equally effective in predicting leaf Zn.  相似文献   

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