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1.
The influence of 15 annual applications of composted (CM) or stockpiled (SM) beef feedlot manure with straw (ST) or wood-chip (WD) bedding on electrical conductivity (EC), soluble cations and anions (Na, K, Ca, Mg, SO4-S, Cl), sodium adsorption ratio (SAR), potassium adsorption ratio (PAR), and pH of a clay loam soil (0–15 cm) in southern Alberta was examined in an irrigated barley silage cropping system. Manure type (CM versus SM) had a significant effect on certain soil salinity parameters. Calcium, Mg, Na, K, and SO4-S were significantly (p ≤ 0.05) greater for SM- than CM-amended soils for certain bedding materials and rates. Electrical conductivity, concentration of soluble cations and anions (Na, K, SO4-S, Cl), SAR, PAR, and pH in the surface soil were greater for ST than WD bedding. Two exceptions were Ca and Mg, where soil concentrations were generally greater for WD than ST. Salinity parameters were greater with increased application rate, and greater for amended than unamended soils. Overall, bedding had considerably more significant effects on soil salinity parameters compared to manure type. Wood-chip bedding may be a management tool for feedlots to lower EC, soluble cations and anions, and pH of surface soils.  相似文献   

2.
Loading of chemical elements in precipitation at the Solling For the period 1969–1976 (NH4, NO3: 1971–1976) monthly values of concentrations and flows of the ions NH4, H, Na, K, Ca, Mg, Fe, Mn, Al, Cl, NO3, SO4, P and organic bound N in precipitation are passed on. From the correlations between elements the following main ion sources are concluded: sea water (Na, Cl), combustion processes (SO4, NO3, NH4), lime dust after dissolution by H2SO4 and HNO3 (Ca, Mg), soil dust after dissolution by H2SO4 and HNO3 (Al, Fe), leaching from plants (K, NO3, SO4, Mg, Ca), biogenic contaminations (P, organic N, K, NH4, NO3). Seasonal variations in the concentrations are most evident for Na and Cl, less for NH4, SO4 and NO3. During the measuring period the flux of NH4 is significantly increased; for H and SO4, less for NH4, Mg, Ca and Fe, the increasing trend was interrupted in winter 1973/74 (oil crisis). Consequences for sampling are discussed.  相似文献   

3.
Abstract

Two lysimeter experiments were conducted on annual leaching losses of calcium (Ca), potassium (K), sodium (Na), chloride (Cl), sulphate‐sulphur (SO4‐S), and magnesium (Mg) (one experiment only) from a sandy soil in central England during 1988–1995 to provide information on typical nutrient losses under arable agriculture below 1.2 m (Experiment 1) or 1.5 m (Experiment 2). Total annual losses, in the absence of manure additions, were highly dependent on the amount of drainage; flow‐weighted average concentrations were similar between years within experiments. Concentrations, averaged over the duration of the experiments were 74 and 78 mg L‐1 Ca, 17 and 27 mg L‐1 Na, 11 and 8 mg L‐1 K, 74 and 77 mg L‐1 Cl, and 57 and 38 mg L‐1 SO4‐S for the two experiments respectively; Mg concentration was 17 mg L‐1. Applications of chicken litter were made to some of the lysimeters in the last three years, and all nutrients showed increased leaching as a result. Application rates akin to disposal (rather than for crop fertilization) produced the largest losses. Following a total application of 125 t ha‐1 over three years, average concentrations in water draining below 1.5 m in the final year were 57 and 277 mg L‐1 Ca, 22 and 75 mg L‐1 Cl, 7 and 14 mg L‐1 K, 22 and 57 mg L‐1 Na, 27, and 125 mg L‐1 SO4‐S for the untreated and manured soils, respectively.  相似文献   

4.
Bulk precipitation was sampled every 2 weeks for more than 2 yr in a lowland catchment in the eastern part of the Netherlands and dissolved constituents were determined. This paper discusses only concentrations of the main constituents: S04, NH4, Cl, NO3, Na, Ca, H, Mg, and K (in decreasing order) and tries to delineate specific source regions for these ion species. Despite the complex character of precipitation chemistry and the rather long sampling interval, statistical evaluation (cluster- and discriminant analyses) of the data provided discriminating results. Four sources could be distinguished: seaspray supplying major part of Na, Mg, and CI; industrial activities (Ruhr area) contributing excess amounts of Cl and SO4 in association with NH4; rural activities supplying N03, while K, Ca and excess amounts of Na and Mg mainly derive from local dust. No clear source area could be detected for H, but it was shown that SO2-emission is the main source of acidification of precipitation at the study catchment.  相似文献   

5.
  【目的】  聚盐能力是评价盐生植物对盐碱地生物改良能力的一个重要参考指标。针对不同的盐碱地类型,有目的地选择生物量大且聚盐能力强的盐生植物,是实现盐碱地快速改良的关键。比较不同盐生植物的盐离子吸收类型及能力,可为盐碱地生物改良选择适宜的植物材料提供参考。  【方法】  试验选取7种藜科盐生植物进行人工种植试验,包括野榆钱菠菜(Atriplex aucheri)、高碱蓬(Suaeda altissima)、盐地碱蓬(Suaeda salsa)、盐角草(Salicornia europaea)、红叶藜(Chenopodium rubrum)、驼绒藜(Ceratoides latens)和四翅滨藜(Atriplex canescens)。试验地土壤以粉粘粒为主,根层土壤(0—40 cm)平均含盐量为45.57 g/kg。在生育末期采样测定植物地上部生物量和Na+、K+、Ca2+、Mg2+、Cl–、SO42–浓度。  【结果】  7种藜科植物地上部生物量为野榆钱菠菜(35077 kg/hm2)>盐地碱蓬(19507 kg/hm2)>高碱蓬(16160 kg/hm2)>驼绒藜(12421 kg/hm2)>四翅滨藜(10798 kg/hm2)>红叶藜(10134 kg/hm2)>盐角草(9576 kg/hm2)。高碱蓬、野榆钱菠菜、盐地碱蓬、盐角草和红叶藜5种植物组织内Na+、Cl–和SO42–浓度显著高于其他离子(P<0.05),而驼绒藜和四翅滨藜体内K+、Cl–和Na+浓度较高。7种藜科植物地上部Na+、Cl–和SO42– 3种盐离子累积总量为野榆钱菠菜(3835 kg/hm2)>盐地碱蓬(3145 kg/hm2)>盐角草(2749 kg/hm2)>高碱蓬(2253 kg/hm2)>红叶藜(615 kg/hm2)>四翅滨藜(367 kg/hm2)>驼绒藜(220 kg/hm2)。  【结论】  盐生植物可在重度盐碱地上存活并产生一定的生物量,野榆钱菠菜、盐地碱蓬、盐角草和高碱蓬均表现出较强的吸盐能力,但对不同离子的吸收累积能力不同。盐地碱蓬地上部SO42–吸收量显著高于其他几种植物,适宜于硫酸盐或氯化物–硫酸盐盐渍土的改良;盐角草对Cl–表现出极强的吸收能力,适宜氯化物盐渍土的改良。  相似文献   

6.
Abstract

The objective of this work was to appraise the double acid (0.05N HCl+0.025N H2SO4) extraction agent for assessing the availability of Ca, Mg, and K in organic soils. The evaluation was done by determining the relation and interactions between the concentrations of Ca, Mg and K extracted from soils and those found in onion and alfalfa tissues.

The extraction procedure was found to give good relations (r 0.848**) between the concentrations of Ca and Mg extracted from soils and those present in onion and alfalfa tissues, though interactions between the amounts of Ca and Mg extracted from soils were found.

A differentiation among soils was found upon relating the amounts of soil extracted K to its concentration in onion and alfalfa tissues. Soil extracted K was shown to be related to its preponderance (K x 100/K Ca Mg) over other extracted bases (r = 0.975**). A critical preponderance of 11% K was identified for alfalfa. The critical preponderance of K in crops appraises some of the interactions among available soil cations and, consequently, is suggested as an improved approach for predicting crop response to potassium fertilization.  相似文献   

7.
Abstract

An experiment was carried under controlled conditions to investigate the influence of the anions, H2PO4 . and Cl on the ionic equilibria, selectivity and effective diffusion of Rb, K, Na, Ca, Mg in two Indiana soils.

Additon of anions to the soils increased the concentration of cations in soil solution. In both the soils receiving H2PO4 , lower cation concentrations were found in the soil solution than in those receiving Cl . Additon of H2PO4 and Cl reduced the ion selectivity coefficient, k, for various homovalent (Rb/K, Rb/Na, K/Na, Ca/Mg) and mono‐divalent ion pairs (Rb/Ca, Rb/Mg, K/Ca, K/Mg). In Zanesville soil treatments receiving H2PO4 had lower k values for mono‐divalent cations than treatments receiving Cl. However, no such conclusions could be drawn for Raub soil. Soils treated with H2PO4 had higher k values for homovalent cations than Cl treated soils. The differences in the selectivity of adsorption in these two soils might be attributable to the differences in the type and nature of exchange materials and cation concentrations on the exchange phase.

Addition of H2PO4 or Cl enhanced the magnitude of effective diffusion coefficient. (De) of all the cations under considerations. The magnitude of effective diffusion coefficient for cations was lower for H2PO4 treated soils than Cltreated soils. Such a reduction in De is related to the reduction in cation concentration in soil solution thereby increasing the buffer capacity for the ions under consideration.  相似文献   

8.
Abstract

The rationale for this experiment was to determine forage nutrient concentrations as affected by biosolids fertilization. We studied the effects of single applications of two exceptional quality biosolids to bahiagrass (Paspalum notatum) pasture with regard to satisfying beef cattle nutrient requirements. Twenty‐five 0.8‐ha pastures were divided into five blocks. Two biosolids were applied as normal and double agronomic rates. The control plot received NH4NO3. Forages were analyzed for calcium (Ca), phosphorus (P), magnesium (Mg), potassium (K), sodium (Na), crude protein (CP), and in vitro organic matter digestibility (IVOMD), and soils were analyzed for Mehlich I extractable Ca, P, Mg, and K. Single (agronomic or twice this) applications of biosolids to pastures had little effect on Ca, P, Na, and K forage concentrations, but forage Mg was elevated in several treatments late in the season. Crude protein concentrations were elevated above the control for all biosolids treatments late in the season, whereas only small differences were observed at early sampling times. Trends were similar for IVOMD. In general, all treatments were associated with soils with adequate Ca, P, and Mg concentrations, while soil K was uniformly low. In relation to grazing beef cattle requirements, all treatments resulted in generally adequate forage levels of Ca, P, Mg, K, CP, and IVOMD, however, Na (<0.06%) was deficient.  相似文献   

9.
Summary

A simple, single‐step extraction with LiEDTA for the estimation of CEC and exchangeable bases in soils has been developed. Multivalent cations are stripped from the soil adsorption sites by the strongly chelating agent EDTA, and are replaced by Li. In soils without CaCO3 or water soluble salts, exchangeable divalent cations (Ca, Mg) are chelated by EDTA and exchangeable monovalent cations (Na, K) are replaced in a single extraction step using 0.25–2.5 g of soil and 10.0 ml of extractant.

In calcareous soils the CEC can be determined in the same way, but for the extraction of exchangeable Ca and Mg, another separate extraction is needed because dissolution of calcite by EDTA is unavoidable. This extraction is done with as much NaEDTA as needed to extract only exchangeable Ca and Mg in a 1:2 (m/V) soil/alkaline‐50% (V/V) aethanolic solution to minimize dissolution of calcite.

In gypsiferous soils gypsum is transformed into insoluble BaSO4 and soluble CaEDTA by LiBaEDTA thus avoiding interference of Ca from dissolution of gypsum, which renders the traditional methods for determining CEC unsuitable for such soils. To determine exchangeable Ca and Mg, Na4EDTA is used as for calcareous soils.

In saline/sodic soils replacement of Na by Li is incomplete but the Na/Li‐ratio at the complex after extraction is proportional to the molar Na/Li‐ratio in the extracts, so that the CEC and original exchangeable sodium (ESP) content can be calculated. Additional analysis of Cl and, if necessary, SO4 in the extracts of saline soils can be used to correct for the effect of dissolution of the salts on the sum of exchangeable cations.

This new method is as convenient as the recently developed AgTU (silverthiourea), but is better suitable for calcareous and gypsiferous soils.  相似文献   

10.
Effect of NaCl and Na2SO4 on dry matter production, mineral content and organic compounds of spinach and lettuce . In water culture experiments the effect of 2,5 meq and 25 meq NaCl and Na2SO4 respectively on dry matter production and content of mineral elements, chloroplasts pigments and carbohydrates in lettuce (salt sensitive) and spinach (salt tolerant) has been studied. With increasing Na-supply the dry matter production was decreased in lettuce and increased in spinach. With increasing Na-supply in both species the content of K, Mg and Ca in the leaves decreased. This decrease was more pronounced with sulfate as accompanying anion (Na2SO4) and induced already deficiency in Ca and Mg. This induced deficiency of Mg was reflected especially in lettuce in lower contents of chloroplasts pigments. In both plant species there was no effect of the Na salt treatments on the content of phosphorus or nitrogen in roots or leaves. The carbohydrate content in both species was strongly affected by the Na salt treatments. Irrespectively of the accompanying anion this effect occured already at the low Na supply and before the dry matter production was influenced. In leaves and roots of lettuce the contents of glucose, fructose and sucrose was considerably decreased; this decrease was less expressed in the starch content. In spinach the Na supply only decreased the carbohydrate content in the roots whereas in the leaves especially the sucrose content was increased. This different effect of Na on carbohydrate content in spinach and lettuce could be an indication of different action of Na on carbohydrate metabolism, namely inhibited synthesis in lettuce and inhibited translocation in spinach. The results demonstrate that in studies on the effect of increasing Na salt concentrations besides the osmotic effects also the ion specific effects have to be carfully considered. These ion specific effects are competition of Na+ with other cations during uptake and the influence of Na on the cell metabolism, especially on the pathway of carbohydrates. The authors thanks Mrs. Hwie Juen Tjandraatmadja for her engaged help in various laboratory works.  相似文献   

11.
It has been considered that natural peat soils and swamp forest ecosystems in the tropics are quite oligotrophic. This concept seems to be related to the low mineral contents in the soil solid phase of the peat soils. However, some nutritional elements such as K, Mg, Ca, and/or P may be abundant in the soil solution phase and could easily migrate in peat soils. In order to analyze the nutritional environment of peat soils, chemical composition of the soil solid phase and soil solution was compared.

This study was carried out in Naman Forest Reserve, Sibu and in/around Sg. Talau Peat Research Station, Mukah, Sarawak, Malaysia. In both areas, each of the three study sites with a different depth of underlying mineral layer was selected for sampling of soil and soil solution. All the soils studied except for one shallow peat profile were classified into Oligotrophic peat based on Fleischer’s criteria. The soil solution collected monthly showed the following characteristics in its composition.

1. Concentrations of Al, Si, and Fe were higher in the soil solution from the shallow peat than in that from the deep peat, reflecting the effect of underlying mineral layers on the soil solution composition.

2. Concentrations of Na, Mg, and Cl in the soil solution and Na and Mg contents in the soil solid phase reflected the distance from the sea. In the Naman series, accumulation of K and Ca in the soil solution was larger in the surface layer in the deep peat than in the shallow peat, though such clear trend was not observed for the K content in the soil solid phase.

3. The concentrations of N and P were fairly high in the soil solution in all the profiles except for P in the profile near the center of the peat dome. Dissolved P consisted mostly of ortho-phosphate, whereas a larger part of N was in the organic form.

4. At the Sago plantation farm on deep peat, depletion of K and P was observed during the rainy season. Such instability in the concentrations in the soil solution was attributed to forest clear-cutting and subsequent disturbance of nutrient cycling.

In general, the concentrations of N, P, K, and Ca in the soil solution were not low even in the Oligotrophic peat. However, in taking account of the fact that the peat soils showed low mineral contents in the available forms and that the bulk density was also quite low, the potential capacity to supply K, Ca, and/ or P was not necessarily high in spite of the apparent high intensity observed for the soil solution composition. Therefore, from the viewpoint of nutrient dynamics, the potential for the use of reclaimed peat land was considered to be rather limited especially under low input management.  相似文献   

12.
Ion relations, water content, leaf water potential, and osmotic adjustment were determined for cultivated barley (cv Harrington) and wild barley grown under mixed sulphate (SO4) salts with varied calcium (Ca) supply using a hydroponic system. Salinity induced significant increases of leaf, stem and root sodium (Na) concentrations in both species. Salt‐stressed wild barley roots accumulated more Na than shoots, and transport of Na from roots to shoots was low compared to Harrington. Cultivated barley had lower Ca concentrations than wild barley, especially in the low Ca salt treatment. Although potassium (K/Na) and Ca/Na ratios were higher in control wild barley plants than in Harrington, they declined under salt stress, irrespective of Ca supply. Major osmotica in wild barley leaves were K, sugars, organic acids, and quaternary ammonium compounds, while in Harrington they were cations, including Na, K and Mg, and anions such as phosphate (PO4) and SO4. Wild barley maintained better water status than Harrington under low Ca salt treatment. Supplemental Ca improved water status more in Harrington than in wild barley. Lack of osmotic adjustment to salinity in wild barley apparently resulted from its ion exclusion. Low Ca salt treatment caused Ca deficiency, Na toxicity, and loss of turgor in Harrington. In the high Ca salt treatment, Harrington had improved water and ion relations, as well as positive turgor.  相似文献   

13.
Abstract

An adequate supply of available Ca in the soil solution of the pegging zone during fruit development is required for production of high yields of high quality peanuts (Arachis hypogaea L.). On low Ca soils, application of gypsum during early bloom is recommended in order to ascertain adequate availability of Ca. Reaction of gypsum in soils under leaching conditions vary considerably and play an important role in fruit development and yield of peanuts. A laboratory study was conducted in leaching soil columns to investigate the effects of one gypsum amendment on leaching of Ca, K, Mg, and SO4 to a depth of 8 cm (fruiting zone of peanut). Six soils of varying physical and chemical properties representative of major peanut growing soils in Georgia were utilized. Following leaching with 15 cm water through gypsum‐amended soil columns, 50% to 56% and 74% to 77% of applied Ca and SO4, respectively, were leached below 8 cm in the sandy‐Carnegie, Dothan, Fuquay and Tifton soils. The respective values for the sandy clay loam‐Greenville and Faceville soils were 28% to 36% and 58% to 69%. Lower initial Ca status and greater leaching of Ca from the applied gypsum in the sandy soils as compared to sandy clay loam soils suggest greater beneficial effects of supplemental gypsum application for peanut production in the former soils than in the latter soils. Leaching of K or Mg (as percentage of Mehlich 1 extractable K or Mg) in gypsum‐amended treatment was considerably greater in sandy soils than that in the sandy clay loam soils. In view of the reported adverse effects of high concentrations of soil K and Mg in the fruiting zone on the yield and quality of peanuts, greater leaching of K and Mg from the fruiting zone in gypsum amended sandy soils enable them to maintain a favorable cation balance for the production of high yields of quality peanuts.  相似文献   

14.
Abstract

A nutritional survey of 23 commercial peach orchards was carried out in the Murrumbidgee Irrigation Areas (M.I.A.) of New South Wales during three growing seasons (1961–62, 1962–63 and 1963–64). Sampling sites were chosen to provide the widest possible coverage of peach orchards of above average productivity. Leaf and soil samples were taken from each site for chemical analysis.

The lighter textured (loamy sand) soils were found to have low reserves of N, P, Ca, Mg and K which could limit growth and yield. The heavier textured colluvial (sandy loam) and alluvial (clay loam) soils contained adequate reserves of most nutrients except N and P. Colluvial soils were particularly low in P. On all soils organic matter contents were very low, generally being below 1.0%.

Leaf N, P, K and B contents decreased during the growing season from October to April. In contrast, leaf Ca, Mg, Na and Cl contents increased over the same period. Since there was a tendency for the leaf N and P contents to decrease slightly during January, this month is suggested as being the most suitable for the collection of leaf samples for diagnostic purposes. Despite the low reserves of some nutrients as indicated by soil analysis, generally satisfactory levels of leaf N, P, K, Ca, Mg, Na, Cl, B, Fe, Mn, Cu and Zn were found.  相似文献   

15.
Abstract

Forage intake with potassium/(calcium + magnesium) [K/(Mg + Ca)] values in excess of 2.2 are associated with grass tetany and Mg deficiencies in ruminants. This study was conducted to determine the degree to which forage K and Mg concentrations and K/(Ca + Mg) ratios could be predicted from soil bicarbonate (HCO3) extractable phosphate‐phosphorus (PO4‐P), and saturation extract Ca, Mg, K, sodium (Na), and nitrate‐nitrogen (NO3‐N) concentrations. Crested wheatgrass (Agropyron spp) strains and cultivars representing four ploidy levels were grown in the greenhouse on eight calcareous soils with different saturation extract Ca, Mg, K and K/Mg ratios. The plants were harvested three times. Soil solution K/(Ca + Mg) and K/Mg ratios were the only measured soil parameters that showed a consistent correlation with plant K/(Ca + Mg) ratios. Bicarbonate extractable soil P was positively related to plant P and K uptake in the first harvest, but was not related in the second and third harvests nor was soil P related to plant Ca or Mg content. There was a tendency for the higher ploidy level entries to have higher plant K/(Ca + Mg) ratios. It was concluded that soil K/(Ca + Mg) ratios can be used to predict relative forage K/(Ca + Mg) ratios for grasses grown under similar conditions.  相似文献   

16.
《Journal of plant nutrition》2013,36(7):1191-1200
Abstract

Kosteletzkya virginica (L.) Presl. is a perennial dicot halophytic species that grows in brackish portions of coastal tidal marshes of the mid-Atlantic and southeastern United States. It was introduced into Northern Jiangsu, China, by the Halophyte Biotechnology Center (University of Delaware, Newark, DE) as a species with potential to improve the soil and develop ecologically sound saline agriculture. Fifteen major and minor elements [calcium (Ca), magnesium (Mg), phosphorus (P), sodium (Na), potassium (K), iron (Fe), manganese (Mn), zinc (Zn), lead (Pb), cadmium (Cd), aluminum (Al), copper (Cu), lithium (Li), cobalt (Co), and vanadium (V)] in roots, stems, leaves, and seeds of Kosteletzkya virginica and saline soils were measured in the study. Concentrations of Al, Fe, Zn, Mn, V, and Pb were the highest in soils, whereas concentrations of Na, Li, Cu, Ca, and Mg were the highest in the roots, stems, and leaves, respectively, and concentrations of K and P were the highest in the seeds. Potassium, P, Mg, and Ca were the main constituents in the seeds, and concentrations of Fe, Li, Mn, Zn, and Cu in seeds were relatively high. However, concentrations of Na and Al were very low in the seeds. The K/Na ratio in the seeds was 34.26, and the Ca/P ratio was 0.52, which was less than the maximum tolerable value for the human diet. These proportions were considered to be an advantage from a nutritional point of view. From roots to stems to leaves, increases in K/Na, Ca/Na, and Ca/Mg ratios could mitigate salt stress of the growth habitat of Kosteletzkya virginica. These results suggest that Kosteletzkya virginica is a halophytic species with potential as a rich source of mineral-element supply, and its products could be used for development of food, fodder, health care products and industrial raw materials.  相似文献   

17.
Abstract

For Southeastern forest soils amounts of P, K, Ca, Mg, and Mn extracted by 0.05 N HCl + 0.025 N H2SO4 (double‐acid) were significantly correlated with amounts extracted by 0.2 N NH4Cl + 0.2 N HOAc + 0.015 N + NH4F + 0.012 N HCl (new‐Mehlich). The new‐Mehlich consistently removed more nutrients than the double acid.

Both P and Mn extracted by the two solutions were significantly correlated with their concentrations in the foliage of loblolly pine (Pinus taeda L.).  相似文献   

18.
In the arid sand dune ecosystem of Nizzana, northwestern Negev, Israel, three perennial species were investigated for concentrations of the elements C, N, S, P, Ca, Mg, K, Na and Cl. From the dune tops (crests) to the dune valleys six different ecotopes (habitats) were discerned where the sampling took place. The soil conditions are known due to previous investigations of H.-P. Blume and his coworkers. The species Anabasis articulata and Cornulaca monacantha (both Chenopodiaceae) showed considerable variation of element contents according to the ecotopes. In some ecotopes of the dune valleys they showed higher contents of sodium and chloride than in the ecotopes of the proper dune, and by Na/K ratios of > 1 they indicated slightly halophytic character. The glycophyte Thymelaea hirsuta (Thymelaeaceae) exhibited very low element concentrations which practically did not change between the ecotopes. The conclusion was drawn that Thymelaea is characterized by a higher selectivity of ion uptake than the two other species.  相似文献   

19.
Abstract

Ca, Mg, Na, K and P contents of 3 plant tissues obtained by H2SO4‐H2O2‐Li2SO4‐Se peroxidation digestion were compared with those determined by mixed acid (HNO3‐H2S04‐HC104) and dry ashing procedures. Differences between methods were not consistent between elements or tissue types but the mixed acid digestion generally yielded higher Ca, Mg and P values than did dry ashing and peroxidation. Tissue K contents estimated by both wet digestion techniques were not significantly (P ≤0.05) different. Differences in Na values between digestion methods were highly inconsistent between tissue types and the precision of the Ma data was poor. N contents determined by peroxidation digestion and a conventional Kjeldahl method agreed closely.  相似文献   

20.
To elucidate the influence of airborne materials on the ecosystem of Japan??s Yakushima Island, we determined the elemental compositions and Sr and Nd isotope ratios in streamwater, soils, vegetation, and rocks. Streamwater had high Na and Cl contents, low Ca and HCO3 contents, and Na/Cl and Mg/Cl ratios close to those of seawater, but it had low pH (5.4 to 7.1), a higher Ca/Cl ratio than seawater, and distinct 87Sr/86Sr ratios that depended on the bedrock type. The proportions of rain-derived cations in streamwater, estimated by assuming that Cl was derived from sea salt aerosols, averaged 81?% for Na, 83?% for Mg, 36?% for K, 32?% for Ca, and 33?% for Sr. The Sr value was comparable to the 28?% estimated by comparing Sr isotope ratios between rain and granite bedrock. The soils are depleted in Ca, Na, P, and Sr compared with the parent materials. At Yotsuse in the northwestern side, plants and the soil pool have 87Sr/86Sr ratios similar to that of rainwater with a high sea salt component. In contrast, the Sr and Nd isotope ratios of soil minerals in the A and B horizons approach those of silicate minerals in northern China??s loess soils. The soil Ca and P depletion results largely from chemical weathering of plagioclase and of small amounts of apatite and calcite in granitic rocks. This suggests that Yakushima??s ecosystem is affected by large amounts of acidic precipitation with a high sea salt component, which leaches Ca and its proxy (Sr) from bedrock into streams, and by Asian dust-derived apatite, which is an important source of P in base cation-depleted soils.  相似文献   

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