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1.
Potassium replenishment capacity of eight soil series with varying illite content of their clay fraction were studied at their minimal exchangeable K through green house experiments. Higher minimal K levels were found in soils with high initial K status. Maximum K uptake values were associated with high minimal K. The % illite also had a significant relationship with minimum K levels. Average daily rates of K replenishment of soils varied between 0.25 and 0.67 mg kg?1 soil after reaching minimum K. The K replenishment rates were found highly correlated with minimal exchangeable K (0.96**). Amount of clay failed to attain the level of significance with K replenishment rate. Soils with higher illite content in their clay showed high K replenishment rates.  相似文献   

2.
Abstract

Eighteen soils from northwestern Switzerland were used to study the value of seven universal extractants (CaCl2; DB‐DTPA; Mehlich 1, 2, and 3; Morgan‐Wolf; and NH4OAc‐EDTA) for predicting plant available potassium (K) as compared to a bioassay (a modified Neubauer test with winter rye). These extractants were evaluated on the basis of K uptake by the bioassay test and the soil K status. In order to create the sufficiency level of exchangeable K for plant growth, soils were treated with 0, 20, 40, 80, and 160 mg K/kg of soil. The range of K uptake by the bioassay tests was between 89.2 and 403.0 mg/kg of soil for the control pots, and 136.6 to 495.8 for the K treatments with optimal conditions for plant growth. The average amounts of K extracted by the seven universal extractants, in ascending order, were: CaCl2 < Morgan‐Wolf < Mehlich 1 < Mehlich 2 < NH4OAc‐EDTA < Mehlich 3 < DB‐DTPA. The highest simple correlation with K uptake versus the bioassay test was obtained with the DB‐DTPA (r = 0.89) extractant and the lowest with the Mehlich 1 (r = 0.53) extractant. The DP‐DTPA, NH4OAc‐EDTA and Mehlich 3‐K procedures showed an advantage over K procedures based on water soluble and exchangeable K pools in the investigated soils in order to predict the amount of plant‐available K. A simple regression and the Cate‐Nelson graphic method offer the possibility of assessing the soil‐K status using K values obtained by these universal extractants and to calibrate them against K forms as follows: exchangeable, water soluble, and non‐exchangeable.  相似文献   

3.
The plant minimal exchangeable K (EPl,min) defines the lower accessible limit of the most available pool of soil K to plants. It is also an index of long‐term K reserve in soils. However, its estimation by the classical method of exhaustion cropping is laborious. This study aimed at comparing EPl,min values obtained by the exhaustion cropping method with EPl,min values estimated by an alternative approach based on the cationic exchange capacity (CEC) of the infinitely high selective sites for K (i.e., always saturated with K) in the K‐Ca exchange (EK‐Ca,min). A set of 45 soil samples, corresponding to the various fertilization K treatments of 15 long‐term K fertilization trials, was used in this study. The selected soil samples presented a wide range of texture, CEC, and exchangeable K. The plant minimal exchangeable K was found more or less independent of the K treatment, whereas EK‐Ca,min increased when the soil exchangeable K content increased. The plant minimal exchangeable K was systematically lower than EK‐Ca,min, showing that EK‐Ca,min is at least partially available to the plant. Hence, EK‐Ca,min is not a surrogate of EPl,min. Conversely, the plant minimal exchangeable K was strongly, positively correlated to soil CEC (measured at soil pH; r2 = 0.90***). This soil property can consequently be used as a proxy of EPl,min.  相似文献   

4.
This study has been taken up to generate information on potassium status in maize rhizosphere soils differing in their clay content at different levels of added potassium. Soils with larger amounts of clay showed greater amounts of water soluble and ammonium acetate extractable K (NH4OAc K) in both the rhizosphere as well as non-rhizosphere. In the absence of added K (control), non-rhizosphere samples showed higher water soluble and NH4OAc K ranging from 8.0 to 28.9 mg kg?1 and from 132.5 to 294.0 mg kg?1, respectively compared to rhizosphere samples where water soluble K varied between 6.0 and 26.5 mg kg?1 and NH4OAc K from 125.0 to 262.5 mg kg?1. The difference in K content between rhizosphere and non-rhizosphere which could have been resulted from plant K uptake was significantly related with clay content (r = 0.98**) in control whereas at 150 mg kg?1 K addition this relationship was found to be non significant (r = 0.64NS). Electro ultra filtration (EUF) fractions also showed similar differences in K contents in soil between rhizosphere and non-rhizosphere.  相似文献   

5.
There were two objectives in the study: 1) To determine exchangeable K and non-exchangeable K in soils with different potassium depletion levels and mineralogy as plant sources 2) To establish a relationship between the mineralogy vs exchangeable K (Ke) and non-exchangeable K (Kne) mobilization. An extraction experiment of soils was carried out in a greenhouse, with a total of 6 consecutive crops of ryegrass. Different supply rates for plant K were determined by Ke and Kne mobilization according to the soil intensity of use. The contribution of the Ke was greater and generated higher amount of K uptake during maximum availability period (from 0 to the 1st harvest) than in the later period when soil K was already depleted. For this the initial exchangeable K and the illite concentration of soils accounted for almost 100% (R2 = 0.981 P=0.01) of the K taken up by ryegrass. For the following period (from the 2nd harvest to the 6th), Kne forms became more important. Plant K supply was not only a result of initial exchangeable K and illite concentration but presumably also of primary K-bearing minerals.  相似文献   

6.
Biochar has been suggested as a possible means for enhancing soil fertility, including soil potassium (K). However, understanding of the effects of biochar on soil K dynamics remains limited. In this study, a pot trial was conducted to investigate the influence of biochar application (0, 5, 10, and 25 g kg?1 soil) on soil K dynamics and crop K uptake under a winter wheat–maize rotation in two types of soil (an Alfisol, which contained a high initial available K and an Entisol, which contained a high abundance of 2 : 1 K‐bearing minerals). Changes in soil K in various forms following biochar application and cropping were determined, and their contributions to plant K uptake were evaluated. Soil microbial activity, especially the development of K‐dissolving bacteria (KDB), was evaluated to obtain insights into its effects on the weathering of K‐bearing minerals in the soils. During the wheat growth period, crop K uptake was more enhanced (13.6–40.5% higher) in the Alfisol than in the Entisol due to the higher availability of water‐soluble and exchangeable K, while K fixation occurred in the Entisol because of the higher content of 2 : 1 K‐bearing minerals. During the maize period, crop K uptake was generally higher in the Entisol soil due to the release of non‐exchangeable K. In addition, biochar application enhanced the growth of KDB in both soils, which was associated with changes in soil pH and water‐soluble K. However, improved mineral K release was observed only in the Entisol. It is concluded that biochar application could be a feasible soil amendment to improve soil K availability, but crop K uptake responses may vary depending on soil types. Soils abundant in 2 : 1 K‐bearing minerals tend to prolong biochar effects on crop K uptake. Biochar application enhanced the growth of KDB, which may facilitate mineral K weathering in soils with abundant K‐bearing minerals.  相似文献   

7.
Potassium (K+) directly released from primary K‐bearing minerals can contribute to plant nutrition. The objective of this research was to assess short‐term K+ release and fixation on a range of intensively cropped calcareous soils. Potassium sorption and desorption properties and the contributions of exchangeable‐K+ (EK) and nonexchangeable‐K+ (NEK) pools to K+ dynamics of the soil‐solution system was measured using a modified quantity‐to‐intensity (Q : I) experiment. Release and fixation of K+ were varied among soils. The relation between the change in the amount of NEK during the experiment and the initial constrain was linear, and soil ability for K+ release and fixation (β) for all soils varied from 0.041 to 0.183, indicating that 4% to 18% of added K+ converted to NEK when fixation occurred. The equilibrium potential buffering capacity (PBC) for K+ derived from Q : I experiments had significant correlation (r = 0.75, p < 0.01) with β, indicating that PBC depends not only on exchange properties but also on release and fixation properties. The depleted soils showed higher β value than the other soils, indicating much of the added K+ was converted to NEK in case of positive constraint. The range of the amount of EK which was not in exchange equilibrium with Ca (Emin) in the experimental conditions was large and varied from 0.68 to 9.00 mmol kg–1. On average, Emin amounted to 64% of EK. This fraction of EK may not be available to the plant. The parameters obtained from these short‐term K+ release and fixation experiments can be used in plant nutrition.  相似文献   

8.
9.
Inorganic nitrogen (N) in soils is a primary component of soil‐plant N buffering. This study was conducted to determine if non‐exchangeable ammonium‐nitrogen (NH4‐N) could serve as an index of potentially mineralizable organic N which is an important sink in N buffering. Four long‐term winter wheat (Triticum aestivum L.) experiments that had received annual fertilizer N at 0 to 272 kg N ha‐1 were used. Soils from these experiments were extracted by four 10 mL portions of 2M potassium chloride (KC1) at room temperature followed by extraction with 20 mL of 2M hot KC1. Extraction at 100°C for four hours using 3 g soil and 20 mL 2M KC1 was found to be the most effective. Hot KC1‐extractable NH4‐N minus room temperature KCl‐extractable NH4‐N was considered non‐exchangeable NH4‐N. Non‐exchangeable NH4‐N was correlated with the long‐term N rates, and believed to be a reliable index of potentially mineralizable organic N. The relationship was linear for NH4‐N where the lowest N rate had the lowest extractable N. The mean non‐exchangeable NH4‐N concentration ranged from 8.42 to 16.34 mg kg‐1; whereas, nitrate‐nitrogen (NO3‐N) ranged from 0.07 to 1.87 mg kg1. Total inorganic N extracted was similar to that mineralized in a 42‐day aerobic water saturated incubation. In addition, using a linear‐plateau model, extractable NH4‐N was highly correlated with long‐term average yield (R2=0.92). For the soils evaluated, this method provided a rapid measure of potentially mineralizable N.  相似文献   

10.
Abstract

The Egnér‐Riehm method for estimating plant‐available soil phosphorus (P) has been used as the standard soil testing method in Portugal for making fertilizer recommendations. However, this method does not accurately reflect the available P status for wheat in some representative soils from the South Region of the country. Therefore, a pot experiment was established with four Luvisols (LVx, LVv, and two different LVh soils) from the South Region of Portugal in order to evaluate the Egnér‐Riehm, Bray I, Bray II, Olsen, and Anion Exchange Resin (AER) methods for their ability to estimate available P in those soils. Wheat (Triticum aestivum L., cv. Panda) was used as test the crop. The experiment was arranged into a randomized complete block design with three replications and five rates (0, 50, 100,150, and 200 mg kg‐1) of P added to each soil. Critical soil P levels for LVx were established in case for Bray I (27.9 mg kg‐1), Bray II (33.5 mg kg‐1), Egnér‐Riehm (25.4 mg kg‐1), and AER (14.7 mg kg‐1) soil test procedures. Regarding the other soils, the critical soil P levels could not be estimated. The obtained results confirm that the development of an universal soil test P exti action is of great importance, and that further research should be conducted in order to evaluate routine soil fertility tests in different pedoclimatic environments.  相似文献   

11.
The effect of red mud (10 g kg–1), a by‐product of the alumina industry, zeolite (20 g kg–1), a naturally‐occurring hydrous aluminosilicate, and lime (3 g kg–1) on metal lability in soil and uptake by fescue (Festuca rubra L.) (FEST) and amaranthus (Amaranthus hybridus L.) (AMA) was investigated in four different soils from Austria. The soil collection locations were Untertiefenbach (UNT), Weyersdorf (WEY), Reisenberg (REI), and Arnoldstein (ARN). The latter was collected in the vicinity of a former Pb‐Zn smelter and was highly polluted with Pb (12300 mg kg–1), Zn (2713 mg kg–1), and Cd (19.7 mg kg–1) by long‐term deposition. The other soils were spiked with Zn (700 mg kg–1), Cu (250 mg kg–1), Ni (100 mg kg–1), V (100 mg kg–1), and Cd (7 mg kg–1) salts in 1987. The two plant species were cultivated for 15 months. Ammonium nitrate (1 M) extraction was used in a soil : solution ratio of 1:2.5 to assess the influence of the amendments on the labile metal pools. The reduction of metal extractability due to red mud was 70 % (Cd), 89 % (Zn), and 74 % (Ni) in the sandy soil (WEY). Plant uptake in this treatment was reduced by 38 to 87 % (Cd), 50 to 81 % (Zn), and 66 to 87 % (Ni) when compared to the control. Sequential extraction revealed relative enrichments of Fe‐oxide‐associated metal fractions at the expense of exchangeable metal fractions. Red mud was the only amendment that decreased lability in soil and plant uptake of Zn, Cd, and Ni consistently. Possible drawbacks of red mud application (e.g., As and Cr concentration) remain to be evaluated.  相似文献   

12.
Abstract

Increasing soil bulk density has been shown to reduce root growth and decrease K uptake by soybeans (Glycine max L. Merrill). Changing soil bulk density also affects soil buffer power, b, and effective diffusion coefficient, De, which affect K influx. The relative decrease in K uptake due to reduced root growth as compared to reduced K influx is not known. Addition of P may affect root growth and P influx properties of plant roots. The objectives of this paper were (1) to use the Cushman mechanistic model to simulate the effect of changing soil bulk density and soil P on K uptake by soybeans, and (2) to determine the parameters that are changed by changes in bulk density and added P and their effect on K uptake. Plant and soil data of an experiment where Williams soybeans were grown for 21 days in pots of Raub (Aquic Argiudoll) silt loam with factorial treatments of two rates of K (0 and 100 mg K kg‐1 soil), two rates of P (0 and 100 mg P kg‐1 soil), and two bulk densities (1.25 and 1.45 g cm‐3 ) were used to verify the model. Plant and soil parameters for the model were measured independently of the verification experiment. Predicted K (y) uptake agreed with observed uptake (x) (y = 1.09x‐0.19; r = 0.97) for the P x K factorial and (y = 1.19X‐0.22; r = 0.90) for the K x soil bulk density factorial treatments. In a sensitivity analysis, the model predicted a maximal K influx at a soil bulk density of 1.38 g cm‐3. The greatest effect of soil bulk density on K uptake was due to reduction of root growth. Increased K uptake as a result of P addition was because of the effect on root growth.  相似文献   

13.
Abstract

Six profiles, derived from Precambrian Basement Complex rocks (mainly gneiss), Cretaceous sediments (mainly shale and sandstone), and Quaternary alluvium, and which are typical of the major agricultural soils in the Lower Benue Valley (Nigeria) were studied with the objective to determine their overall potassium (K) reserves and any relationship between these and other soil properties including their parent materials. Total K in the soils varies from 0.13–27.1 g kg‐1 with average 6.64 g kg‐1. This correlates positively with the clay, and negatively with the sand contents of the soils and is also influenced by their parent materials. The order of abundance according to parent material is: alluvium‐ > Basement Complex (gneiss)‐ ≈ shale‐ > sandstone‐derived soils. The concentrations of readily available K (RAK) in the soils are quite low, accounting for only between 0.30 and 7.8% of the total K in the soils and less than 4.0% of their exchange capacities. Based on critical limits established for many Nigerian soils, the soils derived from sandstone are clearly deficient in RAK, while soils developed from gneiss, shale and alluvium parent materials have moderate to sufficient levels for a wide range of crops. Non‐exchangeable or moderately available K (MAK) in the soils is also relatively low (0.020–8.59 mmolc kg‐1); while the sandstone‐derived soils have the least MAK, the alluvial soils have the most levels. However, the potassium supplying power (KSP) of the soils may be considered to be generally high. Although this bears no particular relationship to soil parent materials, the sandstone‐derived soils have the lowest KSP. The bulk of the total K reserves in the soils (55–88%) exists as difficultly available or structural K (DAK). The alluvial soils first, then the gneiss‐ and shale‐derived soils next have the highest contents of DAK, while the highly weathered sandstone soils have the lowest. Simple correlation analysis shows that, irrespective of parent material and K form, clay content and CEC are the most important soil properties influencing the overall K supplying status of these soils. It is concluded that in major agricultural soils of the Lower Benue Valley of Nigeria K exists mostly in the lattice structures of K‐bearing minerals, with accumulations in the subsurface horizons. Its plant‐available or supplying status is low on sandstone‐derived soils and moderate to sufficient on soils derived from Basement Complex rocks, shales and alluvium.  相似文献   

14.
Accurate estimation of the available potassium (K+) supplied by calcareous soils in arid and semi‐arid regions is becoming more important. Exchangeable K+, determined by ammonium acetate (NH4OAc), might not be the best predictor of the soil K+ available to crops in soils containing micaceous minerals. The effectiveness of different extraction methods for the prediction of K‐supplying capacities and quantity–intensity relationships was studied in 10 calcareous soils in western Iran. Total K+ uptake by wheat grown in the greenhouse was used to measure plant‐available soil K+. The following methods extracted increasingly higher average amounts of soil K+: 0.025 M H2SO4 (45 mg K+ kg?1), 1 M NaCl (92 mg K+ kg?1), 0.01 M CaCl2 (104 mg K+ kg?1), 0.1 M BaCl2 (126 mg K+ kg?1), and 1 M NH4OAc (312 mg K+ kg?1). Potassium extracted by 0.01 M CaCl2, 1 M NaCl, 0.1 M BaCl2, and 0.025 M H2SO4 showed higher correlation with K+ uptake by the crop (P < 0.01) than did NH4OAc (P < 0.05), which is used to extract K+ in the soils of the studied area. There were significant correlations among exchangeable K+ adsorbed on the planar surfaces of soils (labile K+) and K+ plant uptake and K+ extracted by all extractants. It would appear that both 0.01 M CaCl2 and 1 M NaCl extractants and labile K+ may provide the most useful prediction of K+ uptake by plants in these calcareous soils containing micaceous minerals.  相似文献   

15.
The availability of various boron (B) fractions in soil to M.26 apple (Malus spp.) rootstock was examined. The study was carried out in a greenhouse on soils with diverse chemical and physical properties. The following B fractions were determined: (i) B in soil solution, (ii) B non‐specifically adsorbed on soil surface, (iii) B specifically adsorbed on soil colloid surfaces, (iv) B occluded in Mn oxyhydroxides, (v) B occluded in noncrystalline aluminum (Al) and iron (Fe) oxides, (vi) B occluded in crystalline Al and Fe oxides, (vii) B fixed with soil silicates, and (viii) total soil B. In the studied soils there were: 0.07–0.17 mg kg‐1 B in soil solution, 0.01–0.03 mg kg‐1 B non‐specifically adsorbed on soil surface, 0.04–0.08 mg kg‐1 B specifically adsorbed on soil colloid surfaces, 0.28–0.67 mg kg‐1 B occluded in manganese (Mn) oxides, 4.03–17.22 mg kg‐1 B occluded in noncrystalline Al and Fe oxides, 8.93–50.62 mg kg‐1 B occluded in crystalline Al and Fe oxides, 12.2–42.5 mg kg‐1 B fixed with soil silicate, and 52.9–82.2 mg kg‐1 total B. Simple correlation analysis showed positive correlation between B contents in M.26 apple rootstocks and amounts of B in soil solution (r=0.77), B non‐specifically adsorbed on soil colloid surfaces (r=0.65), B specifically adsorbed on soil surface (r=0.76) and B occluded in Mn oxyhydroxides (r=0.77). No relation was found between plant B contents and amounts of B occluded in non‐crystalline and crystalline Al and Fe oxides, B fixed with soil silicates and total B. The results indicated that extraction of B by 0.1 M NH2OH HCl solution adequately represented amounts of B in soil solution, B non‐specifically and specifically adsorbed on soil compound surfaces and B occluded in Mn oxyhydroxides to assess availability of B to apple trees.  相似文献   

16.
Abstract

A previous study indicated that agricultural biosolid applications increased the concentration of EPA3050‐digestible trace elements in soils on Pennsylvania production farms but could not indicate potential trace‐element environmental availability. This study was conducted to determine if biosolid application had altered the distribution of trace‐elements among operationally defined soil fractions and the relationship of trace element concentrations in soil and crop tissues. Biosolid‐amended and unamended soils from production farms in Pennsylvania were extracted using a modified Bureau Communautaire de Référence (BCR) sequential fractionation technique and analyzed for chromium (Cr), copper (Cu), nickel (Ni), lead (Pb), and zinc (Zn). Trace‐element concentrations in crop tissues (soybean silage, sudangrass, corn grain, alfalfa hay, and orchardgrass hay) from the same farms were also determined. Fractionation results indicated that the proportion of Cr, Cu, Ni, Pb, and Zn that is potentially bioavailable is quite small in unamended soils. Biosolid applications significantly (P≤0.1) increased concentrations of Cu in all soil fractions (average increase over unamended soil=1.14, 8.27, 6.04, and 5.84 mg kg?1 for the exchangeable, reducible, oxidizable, and residual fractions, respectively), Ni (0.41, 1.65 mg kg?1 for the reducible and residual fractions, respectively), Pb (5.12 and 1.49 mg kg?1 for the reducible and residual fractions, respectively), and Zn (8.28, 7.12, 4.44, and 8.98 mg kg?1 for the exchangeable, reducible, oxidizable, and residual fractions, respectively) but did not significantly increase Cr in any soil fraction. Concentrations of Cu in all soil fractions were significantly (P≤0.01) correlated with concentrations of Cu in orchardgrass tissue (r=0.70, 0.66, 0.76, and 0.69 for the exchangeable, reducible, oxidizable, and residual soil fractions, respectively). Concentrations of exchangeable and reducible Zn were significantly correlated with Zn in sudangrass tissue (r=0.81 and 0.67), and reducible Zn was significantly correlated with Zn concentrations in orchardgrass tissue (r=0.65). Application of biosolids had little effect on bioavailability of Cr, Ni, or Pb, whereas higher loadings of Cu and Zn led to a shift toward the more labile soil fractions. Loadings of Cu and Zn were much smaller than cumulative loadings permitted under U.S. Environmental Protection Agency (USEPA) Part 503 regulations. Chemical soil fractionation was able to detect increases in labile soil Cu and Zn that relate to increased phytoavailability.  相似文献   

17.
Abstract

The nitrification inhibitor dicyandiamide (DCD) offers potential for improving efficiency of N applications to cotton grown on sandy soils of the southeastern Coastal Plain. Research has indicated that cotton is sensitive to DCD. The purpose of this greenhouse experiment was to investigate the effect of DCD on growth and nutrient uptake of DPL 90 cotton grown for 73 days in pots containing a typical Coastal Plain soil (Norfolk sandy loam, Typic Paleudult). Nitrogen (50 mg kg‐1) as NaNO3 or urea, and DCD (0, 2.5, 5, 10, 15 and 20 mg kg‐1) were applied to the soil at first true leaf and plants were harvested 58 days later. Sodium nitrate increased leaf dry weight and total dry weight of plants 9.1 and 6.0%, respectively, over urea fertilized plants. Leaf area, dryweight, and stem dry weight were reduced linearly with DCD. Fertilization with urea increased concentrations of leaf P, K, and Mn and reduced the concentration of Mg in leaf tissue. Dicyandiamide increased leaf N, P, and K concentrations but reduced concentrations of Ca, Mg, and Mn. Uptake rates (μg‐1 g‐1 fresh root day‐1) of Ca and Mg were increased 7.5 and 13.7%, respectively, with NaNO3 vs. urea, while P uptake rate was 15.5% greater for urea‐fertilized plants vs. NaNO3‐fertilized plants. Dicyandiamide reduced Ca and Mg uptake rates. Phosphorus uptake rates were increased by DCD when urea was the N source. The effects of DCD on cotton growth and nutrient uptake generally resulted from the compound itself and were not an indirect result of nitrification inhibition. Although significant reductions in plant growth did not occur unless DCD exceeded that normally applied with recommended N rates on this soil, these results suggest a need for caution when applying DCD to cotton grown on sandy soils.  相似文献   

18.
Determining potassium (K) fertilizer requirement using sorption isotherms is considered more accurate than conventional soil K tests. A total of 59 surface soil samples were used to establish K exchange isotherm. To evaluate K requirement sorption test, a glasshouse experiment using perennial ryegrass (Lolium perenne, cv. Roper) was carried out on 10 soil samples. The experiment was laid out as a completely randomized design with four replications and four K levels (K0, K20, K40, K80). Concentrations of K in solution established by adding K in the pots estimated from the sorption curve ranged from 20 to 80 mg K l?1 including check treatment (no K). Dry matter yield of ryegrass in most soils approached maximum as adjusted K levels were increased to 20 mg K l?1. The amounts of K required to bring the soils to 20 mg l?1 in soil solution varied among soils and ranged from 99 to 399 mg kg?1, on average 205 mg kg?1 soil. It was found that a useful regression model for the prediction of standard K requirement (K20) included the combination of plant available K extracted by NH4OAc (Av-K) and clay content: K20 = ?41 ? 0.63 Av-K + 9.0 Clay (R2 = 0.61, p < 0.001, n = 59).  相似文献   

19.
土壤非交换态钾与结构态钾能够区分吗?   总被引:2,自引:0,他引:2  
Nonexchangeable K (NEK) is the major portion of the reserve of available K in soil and a primary factor in determining soil K fertility. The questions of how much NEK is in soils and how to quantify total NEK in soils are so far still unclear due to the complicated effects of various minerals on K fixation. In this study, the NEK in 9 soils was extracted with sodium tetraphenylboron (NaBPh4) for various time periods longer than 1 d. The results showed that the NEK extracted by NaBPh4 gradually increased with time, but showed no more increase after the duration of extraction exceeded 10--20 d. As the temperature increased from 25 to 45 oC, the duration to obtain the maximum extraction of NEK was reduced from 20 to 10 d, and the maximum values of NEK released at both temperatures was almost the same for each soil. The maximum NEK (MNEK) of the 9 soils extracted by NaBPh4 varied from 3 074 to 10 081 mg kg-1, accounting for 21%--56% of the total soil K. There was no significant correlation between MNEK released by NaBPh4 and other forms of K, such as NH4OAc-extracted K, HNO3-extracted K and total K in soils, which indicates that NEK is a special form of K that has no inevitable relationship to the other forms of K in soils. The MNEK extraction by NaBPh4 in this study indicated that the total NEK in the soils could be differentiated from soil structural K and quantified with the modified NaBPh4 method. The high MNEK in soils made NEK much more important in the role of the plant-available K pool. How to fractionate NEK into different fractions and establish the methods to quantify each NEK fraction according to their bioavailability is of great importance for future research.  相似文献   

20.
Profiles of semi-arid-zone soils in Punjab, northwestern India, were investigated for different forms of copper (Cu), including total Cu, diethylenetriaminepentaacetic acid (DTPA)–extractable Cu, soil solution plus exchangeable Cu, Cu adsorbed onto inorganic sites, Cu bound by organic sites, and Cu adsorbed onto oxide surfaces. When all soils were considered, total Cu content ranged from 7 to 37 mg kg?1, while DTPA-extractable and soil solution plus exchangeable Cu contents ranged from 0.30 to 3.26 mg kg?1 and from 0.02 to 0.43 mg kg?1, respectively. Copper adsorbed onto inorganic sites ranged from 0.62 to 2.6 mg kg?1 and that onto oxide surfaces ranged from 2.0 to 13.2 mg kg?1. The Cu bound by organic sites ranged from 1.2 to 12.2 mg kg?1. The magnitudes of different forms of Cu in soils did not exhibit any consistent pattern of distribution. Organic matter and size fractions (clay and silt) had a strong influence on the distribution of different forms of Cu. The content of all forms of Cu was generally greater in the fine-textured Alfisols and Inceptisols than coarse-textured Entisols. Soil solution plus exchangeable Cu, Cu held onto organic sites, and and Cu adsorbed onto inorganic sites (crystalline) had significant positive correlations with organic carbon and silt contents.The DTPA Cu was positively correlated with organic carbon, silt, and clay contents. Total Cu content strongly correlated with silt and clay contents of soils. Among the forms, Cu held on the organic site, water soluble + exchangeable Cu, and Cu adsorbed onto oxide surface were positively correlated with DTPA-extractable Cu. The DTPA-extractable Cu and soil solution plus exchangeable Cu seems to be good indices of Cu availability in soils and can be used for correction of Cu deficiency in the soils of the region. The uptake of Cu was greater in fine-textured Inceptisols and Alfisols than coarse-textured Entisols. Among the different forms only DTPA-extractable Cu was positively correlated with total uptake of Cu.  相似文献   

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