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1.
Abstract

Studies with 42 soils selected to obtain a wide range in properties showed that air‐dry and moist soils have substantial capacities for sorption of H2S from air (averages, 9.8 and 12.5 g S kg‐1 soil, respectively). Soil properties influencing the capacities of air‐dry soils for sorption of H2S included sand and clay contents, DCB‐soluble Mn, exchangeable Na, DCB‐soluble Fe, and total DCB‐soluble metals. The corresponding capacities of moist soils were influenced by sand and clay contents, DCB‐soluble Mn, and surface area. It was possible to closely predict the H2S sorption capacities of both air‐dry and moist soils (R2 = 0.804 and 0.918, respectively) from consideration of their properties.  相似文献   

2.
Gas Chromatographie studies showed that air-dry and moist soils have the capacity to sorb dimethyl sulfide (CH3SCH3), dimethyl disulfide (CH3SSCH3). carbonyl sulfide (COS) and carbon disulfide (CS2), but do not sorb sulfur hexafluoride (SF6). Moist soils sorb larger amounts of CH3SCH3. CH3SSCH3. COS or CS2, than do air-dry soils, but the capacity of moist (or air-dry) soils for Sorption of these gases is much smaller than their capacity for sorption of H2S. SO2 or CH3SH. The ability of moist soils to sorb COS is considerably greater than their ability to sorb CH3SCH3, CH3SSCH3 or CS2. and sorption of COS by moist soils is accompanied by release of small amounts of CS2.Experiments with sterilized (autoclaved) soils indicated that soil microorganisms are partly responsible for the sorption of CH3SCH3. CH3SSCH3. COS and CS2 by moist soils. Support for this conclusion was obtained from experiments showing that the rate of sorption of these gases by moist soils increases with time.The work reported provides further evidence that soil is an important natural sink for gaseous atmospheric pollutants, but indicates that soils have little, if any, potential value for removal of CH3SCH3. CH3SSCH3. COS or CS2, from industrial emissions polluted by these gases. The finding that soils have no capacity for sorption of SF6 is significant in relation to use of this gas as a tracer for atmospheric research and as an internal standard for gas Chromatographie studies of evolution and sorption of gases by soils.  相似文献   

3.
Sulphate sorption by variable charge soils   总被引：2，自引：0，他引：2  
The sorption of sulphate (SO2?4) by three variable charge soils from the Canary Islands (Spain) was studied. Sulphate sorption decreased with increasing pH. Only negligible amounts of SO2?4 were sorbed above pH 6.5. When the soils were washed with an indifferent electrolyte (0.01 M KCl), more SO2?4 was recovered than had been sorbed. This indicated a release of native SO2?4 Sulphate replaced hydroxyl ions (OH) and co-ordinated H2O molecules, as well as very small amounts of silicate (Si). No measurable amount of phosphate (P) was released. On average hydroxyl release accounted for 50% of SO2?4 sorbed, the rest being accounted for by the increase in negative charge as measured by K+ adsorption. The results presented here are consistent with the sorption of SO2?4 through a ligand exchange mechanism, but in a different plane of sorption to that of phosphate.  相似文献   

4.
Abstract

Soil series of extensive acreage were selected to evaluate their S‐supplying power under greenhouse conditions using alfalfa in one study and corn and grain sorghum as test crops in a second study. The soils were divided into two major groups by textural classification for statistical evaluations. The addition of sulfur significantly increased dry matter yields and sulfur content of the plant material on all soils through the course of these studies. Significant predictors of sulfur uptake include extractable SO4‐S and organic matter. Organic matter was a significant predictor of the percent yield response above the check yields on soils receiving S applications using corn and grain sorghum as test crops. Based on this equation, yield response would be expected in this greenhouse study with an organic matter content of 2.6% or less.  相似文献   

5.
In view of growing concern about sulfur (S) deficiency, we attempted to study the effect of soil characteristics on the adsorption and translocation of S in soils. Laboratory experiments were conducted with five surface soils collected from three regions in the state of Orissa (Eastern India). In an adsorption study, all the soils were equilibrated with graded doses of potassium sulfate (K2SO4). Freundlich adsorption isotherms provided good fit to S adsorption data. Free Fe2O3 and Al2O3 in the soils were primarily responsible for retaining added S in soils. Further, studies on the movement of sulfate‐S in 30‐cm plexiglass columns, where radio‐labeled S along with water (5 cm) was applied as gypsum and K2SO4, showed that K2SO4‐S migrated deeper than gypsum‐S. Sulfur moved deeper in case of initially water‐saturated soils than in initially air‐dry soils.  相似文献   

6.
Abstract

A refined scheme for the semi micro chemical analysis of sulfur fractions in soils is presented. Pyrite is analyzed, as iron, after extraction in HNO3. Non‐pyrite iron is excluded by a pretreatment with HF/H2SO4. Water‐soluble sulfate and jarosite [KFe3(SO4)2(OH)6], the other dominant sulfur fractions in acid sulfate soils, are analyzed turbidimetrically, as sulfate, after successive extractions by EDTA.3Na (water soluble plus exchangeable SO4) and by hot 4 M HCl (jarosite). These methods are simpler, less bulky and more specific than most existing procedures.

Introduction of elemental sulfur analysis permits estimation of organic sulfur fraction as well. Sums of individual sulfur fractions agree well with separate total sulfur determinations.

The proposed analysis of pyrite permits also distinction of the components Fe2O3, FeO and FeS2 in soils and rocks2.  相似文献   

7.
Abstract

The influence of soil organic matter on selenite sorption was investigated in the selenite adsorption capacity and the surface particle charge change by ligand exchange reaction using the hydrogen peroxide (H2O2) treatment and the ignition treatment of two Andosols. The removal of organic carbon (C) in soils accelerated selenite sorption, implying that organic matter of soils had negative influence on the selenite adsorption on the soils. Positive charge decrease on soil particles, concomitant proton consumption, and release of silicon (Si), sulfate (SO4 2‐), and organic C were observed in selenite sorption by the soils. The development of surface particle negative charge with selenite sorption was smaller in the H2O2‐treated soil than in the original soils and was scarcely observed in the ignition‐treated soil. It can be assumed that the increase of negative charge by selenite sorption was attributed to new negative sites borne by released insoluble organic matter and negative charge development directly by selenite sorption was small.  相似文献   

8.
Growth chamber experiments of canola (Brassica napus L.) and spring wheat (Triticum aestivum L.) were conducted using three soils testing low in extractable sulfate (9–12 mg/kg). Experiments were designed to determine how the three soils compared in plant available sulfur (S) and to test the effects of various rates of potassium sulfate (K2SO4) and gypsum on the elemental composition and dry matter yield of the two crops. Based upon plant response, the Queens sandy loam soil appeared to have the least amount of plant available S of the three soils. There was no yield increase associated with S applied to either crop. Canola plants in each soil responded to increased applications of S with greater S uptake and considerably lower nitrogen:sulfur (N:S) ratios. Of the three soils used, only the wheat plants grown in the Queens soil responded to S applications through increased S uptake and a lower N:S ratio. Both sources of S were equally effective in providing available S to the plants.  相似文献   

9.
With the reduction of sulfur levels in high‐analysis nitrogen (N) and phosphorus (P) fertilizers and in atmospheric deposition, sulfur (S) fertilization may become more important, especially with intensive cropping systems. When high clay content is likely to limit root development into the subsoil, low extractable sulfate‐sulfur (SO4‐S) levels in the topsoil may suggest possible plant response to S fertilization. Even though ammonium sulfate [(NH4)2SO4] is widely used and readily available for plant uptake, field data are limited on the use of (NH4)2SO4 as an S source for soybeans [Glycine max (L.) Merr.]. A study was initiated to determine the effect of S fertilization as (NH4)2SO4 on: (i) the yield, seed weight, grain quality, and leaf and whole‐plant nutrient concentrations of four soybean cultivars grown on soils with high clay content subsoils; and (ii) selected soil chemical characteristics. Sulfur rates were 0, 28, 56, and 84 kg/ha, and soybean cultivars were two Maturity Group IV beans, DeSoto and Douglas, and two Maturity Group V beans, Bay and Essex.

The study was conducted on a Parsons silt loam soil (fine, mixed, thermic, Mollic Albaqualf) in 1986 and 1987, and on a Cherokee silt loam (fine, mixed, thermic, Typic Albaqualf) in 1987. Sulfur application did not significantly affect soybean yield or seed protein or oil concentrations. For whole plants, S concentration increased and N:S ratios decreased with increasing S fertilization. Similar trends were found in soybean leaves. Although N:S ratios of both whole plant and leaf tissue were lowered with S fertilization, the values generally were not below 20:1 which is above cited critical levels. Fertilization with (NH4)2SO4 increased the levels of extractable SO4‐S in the soil, especially in the 15–30 cm depth. The first‐year accumulation of soil SO4‐S with increasing S fertilization appeared to be more at a site that was lower in organic matter.  相似文献   

10.
The retention of dissolved organic matter in soils is mainly attributed to interactions with the clay fraction. Yet, it is unclear to which extent certain clay‐sized soil constituents contribute to the sorption of dissolved organic matter. In order to identify the mineral constituents controlling the sorption of dissolved organic matter, we carried out experiments on bulk samples and differently pretreated clay‐size separates (untreated, organic matter oxidation with H2O2, and organic matter oxidation with H2O2 + extraction of Al and Fe oxides) from subsoil horizons of four Inceptisols and one Alfisol. The untreated clay separates of the subsoils sorbed 85 to 95% of the dissolved organic matter the whole soil sorbed. The sorption of the clay fraction increased when indigenous organic matter was oxidized by H2O2. Subsequent extraction of Al and Fe oxides/hydroxides caused a sharp decrease of the sorption of dissolved organic matter. This indicated that these oxides/hydroxides in the clay fraction were the main sorbents of dissolved organic matter of the investigated soils. Moreover, the coverage of these sorbents with organic matter reduced the amount of binding sites available for further sorption. The non‐expandable layer silicates, which dominated the investigated clay fractions, exhibited a weak sorption of dissolved organic matter. Whole soils and untreated clay fractions favored the sorption of ”︁hydrophobic” dissolved organic matter. The removal of oxides/hydroxides reduced the sorption of the lignin‐derived ”︁hydrophobic” dissolved organic matter onto the remaining layer silicates stronger than that of ”︁hydrophilic” dissolved organic matter.  相似文献   

11.
Abstract

The extraction of a field‐moist soil with DTPA will result in a level of extractable iron (Fe) lower than that of the air‐dried soil. Soil gas‐phase carbon dioxide (CO2) levels may be considerably higher than ambient atmospheric levels, especially in wet soils in the field. This study was undertaken to determine whether gas‐phase CO2 level influences the quantity of Fe extracted by DTPA. Three moist calcareous soils were incubated for 21 days, each at three different partial pressures of CO2, after which the moist soils were extracted with DTPA. A sample of each soil was also air dried, and was subsequently extracted with DTPA. In each case, DTPA‐extractable Fe from the moist sample was lower than that from the air‐dried sample; however, DTPA‐extractable Fe increased with increasing CO2 partial pressure of in the moist soils. DTPA‐extractable Fe concentration for a given soil following air drying was not significantly influenced by the CO2 partial pressure during incubation of the originally field‐moist soil. DTPA‐extract pH of the moist soils followed the same trend as soil‐solution pH (i.e., as CO2 concentration of the soil gas‐phase increased, soil solution pH and DTPA extract pH both decreased); however, the slope of the pH versus log PCO2 curve was less pronounced in the DTPA extract due to the buffering capacity of the triethanolamine. From this study, it is concluded that elevated soil gas‐phase CO2 partial pressure does not contribute to the lower level of DTPA‐extractable Fe observed when the extraction is performed on a field‐moist versus an air‐dried soil; increased CO2 partial pressure actually resulted in a slight increase in concentration of DTPA‐extractable Fe obtained from a field‐moist soil.  相似文献   

12.
Abstract

Fertilizer recommendations need to be based on reliable soil sulfate determinations. Airdrying samples changes irreversibly many properties of soils with variable charge and might affect the extractable sulfate. In this study, sulfate extracted from air‐dry and field‐moist samples was compared. Two extracting solutions [water and 00.1 M Ca(H2PO4) 2] and two quantification methods (turbidimetry and ion chromatography) were assayed on A and B horizon samples of five Humic Acrisols from southeast Mexico. Air drying increased water‐extractable sulfate in Ah horizons, whereas in Bt horizons, it increased the 00.1 M Ca(H2PO4)2‐extractable sulfate. Airdrying increased dissolved organic carbon contents in all samples and increased soil acidity and oxalate extractable iron in 70 and 60% of the samples, respectively. Results showed larger coefficients of variation in air‐dried samples. Turbidimetry resulted less sensible than ion chromatography. To enhance sensitivity and reproducibility, particularly organic soil samples should be analyzed field‐moist and by ion chromatography.  相似文献   

13.
Abstract

Although over 40% of excretal S is returned to intensively sheep ‐grazed pastures as faecal S, limited information is available on faecal S fractions, their water solubility and temporal distribution. This study reports results obtained from sheep faeces returned to grazed pastures which have received long‐term annual sulphate applications for 15–20 years. Five freshly‐voided sheep faecal samples (<100 g moist faeces per sample) per sampling were randomly collected at approximately one month intervals over a one‐year growing season. Faeces were fractionated into total S, inorganic SO4 2‐, ester SO4 2‐, Hi‐reducible S and C‐bonded S. Results obtained showed that faecal total S, ester SO4 2‐ Hi‐reducible S and C‐bonded S fractions varied significantly throughout the year. Carbon‐bonded S was the dominant (>80%) faecal S fraction, regardless of faecal total S content or the time of year faecal samples were deposited. Faecal ester SO4 2‐ and inorganic _SO4 2‐fractions accounted for 3.3–7.1% and 0.1–14% of faecal total S respectively. Thus approximately 3.4–21.1% of faecal total S was estimated to be potentially leached or readily available to pasture plants. The Hi‐reducible faecal S fraction was significantly‐correlated (r = 0.59***; *** = P ≤ 0.001) with HCl‐extractable faecal inorganic S, which was considered to represent faecal total SO4 2‐ (ester SO4 2‐ and inorganic SO4 2‐ fractions).

The solubility of different faecal S fractions was determined by sequential extraction of ground (< 1 mm) faeces three times (30 minutes per extraction) with water or 0.01 M Ca(H2PO4)2 solution (1: 5 ratio of faecal DM: extractant). Both amounts of water‐extractable and Ca(H2PO4)‐extractable faecal S fractions were found to vary significantly throughout the year. Ca(H2PO4)2 tended to extract more inorganic faecal S than water, attributed to the presence of phosphate and the low pH (pH=4) of Ca(H2PO4)2 extractant. A significant proportion (15–25%) of faecal S was extracted by water and most (70%) of this water‐extractable faecal S was in the organic S fraction. Water‐extractable inorganic faecal S probably originated from the faecal total SO4 2‐ fraction as shown by their significant correlation (r = 0.45** ‐0.63***; ** = P≤ 0.01; *** = P≤ 0.001). Some of the faecal S in water extracts may also originate from the faecal C‐bonded S fraction, as a significant correlation was obtained between C‐bonded faecal S and either water‐extractable faecal organic S (r = 0.53–0.57***; *** = P ≤ 0.001) or water‐extractable faecal inorganic S (r = 0.40–0.41*; * = P ≤ 0.05).

Significant amounts of faecal inorganic SO4 2‐ and ester SO4 2‐ fractions were removed by Ca(H2PO4)2 extractant. The Ca(H2PO4)2‐extractable faecal inorganic S was significantly correlated (r = 0.73***; *** = P ≤ 0.001) with water‐extractable faecal inorganic S.  相似文献   

14.
Abstract

The objective of this study was to evaluate the usefulness of measures of mineralized sulfur (S), soil sulfate‐sulfur (SO4‐S), concentration of S in plant tissue, and the N: S ratio in plant tissue as predictors of the need for S in a fertilizer program for corn (Zea mays L.). Data to evaluate the use of plant analysis for S as a predictor were obtained from ten sites where various rates of N and S were applied to corn. Regression analysis was used to relate the S concentration in the ear leaf tissue as well as the N: S ratio in the same tissue to relative yield when the rate of applied N was held constant at a rate of 168 kg/ha. These measures of S in plant tissue were not significantly related to relative yield at sites where there was no response to fertilizer S as well as sites where added S increased yield.

Data from the same sites were used to assess the ability of soil tests to predict the need for fertilizer S. A measurement of extractable SO4‐S in the surface soil (0–15 cm) was not reliable for predicting the need for S for corn grown on soils with a silt loam texture.

Static incubation techniques were used to evaluate the amount of S mineralized from soil collected from seven sites. The amount of SO4‐S measured after four and twelve weeks of incubation was curvilinearly related (p <.05) to yield increase from a S fertilizer. Net mineralized S was less than 2.1 and 3.7 ppm SO4‐S after four and twelve weeks of incubation, respectively, for soils taken from sites where response to fertilizer S was obtained. Data collected in this study indicate that a measure of mineralized S could improve the ability to predict S needs for corn production on soils with a silt loam texture and a low organic matter content.  相似文献   

15.
Abstract

An automated turbidimetric method has been developed for the rapid and accurate determination of sulfate. The method is practical and useful for accurately measuring total sulfur in plant tissues, and extractable sulfate in soils. The principle of intermittent reagent addition is used which eliminates drift and sensitivity changes caused by coating of BaSO4 on tubing and cell walls. Also, the appropriate chemistry is used to minimize interactions of the wash with the sample at a sampling rate of 30/H. The sensitivity of the method is excellent with a working range of 0 to 15 ppm sulfur for soils. For plant digests the sample solutions are diluted to 0–35 ppm S. The precision as determined by repeated analysis of a soil sample extract was 0.58% RSD with a mean of 9.26 pg/g extractable SO= 4‐S. On another soil sample using a different extractant and extraction procedure the RSD was 0.64%, mean of 9.26 μg/g. Multiple automated sulfur analyses on a plant tissue digest resulted in an RSD of 0.41% for a sample containing 0.21% S. The automated turbidimetric method for sulfate has excellent precision and sensitivity in plant tissue and soil analyses where gravimetric BaSO4 assays are not practical.  相似文献   

16.
Abstract

A pot experiment was conducted with a coarse‐textured calcareous soil (pH‐H2O 8.3) to study the effect of single and combined application of N and S fertilizers on soil pH, Fe, Mn, Zn, and P mobilization, and on growth and micronutrient uptake by com (Zea mays L.). Increasing amounts of elemental sulfur were mixed with the soil. To stimulate S oxidation, the treated soils were incubated for six weeks at field capacity. Nitrogen was applied as NH4NO3 (100, 200, and 400 mg N/kg). After six weeks, dry matter yields were recorded and shoots were analyzed for Fe, Mn, Zn, and P. At the end of the experiment, soil pH and the DTPA‐extractable micronutrients were determined. The results showed that: a. Soil pH was decreased by 0.2, 0.5, and 0.9 unit as a result of increasing S applications.

b. Applied sulfur and N fertilizer had increased the availability of micronutrients to following crops.

c. Application of N and/or S resulted in increased dry matter yields.

d. Manganese uptake tended to be higher as amounts of N applied increased; this was most evident at the higher S application rates. This effect was, however, reversed for Fe, Zn, and P uptake.

e. Under our experimental conditions, promising results were achieved on improving micronutrient availability and uptake when 400 mg N/kg was combined with 3 g S/kg.

  相似文献   

17.
Abstract

Corn (Zea mays L.) grown on sandy Coastal Plain soils may be subject to sulfur (S) deficiency due to the low levels of available S in the soil. The diagnosis of S deficiency in the field is sometimes ambiguous since mineralization of soil organic matter or root growth into the subsoil may supply adequate S to the crop. Yield response to S fertilizers has been more frequent since incidental additions of S to the soil by air pollution and fertilizer applications have been reduced. This study was conducted to identify S deficiency in corn grown on sandy Coastal Plain soils and to determine the effects of S source, rate and method of application on grain yield. Irrigated corn was grown on Norfolk loamy sand and Tifton loamy sand near Leesburg and Moultrie, Georgia, respectively in 1987. Grain yields were increased with addition of 11 kg S ha‐1 compared to the check treatment. Increased rates of S up to 88 kg ha‐1 did not increase grain yields above the 11 kg ha‐1 rate. There was no difference between banded or broadcast application of (NH4)2SO4 or between elemental S and (NH4)2SO4 as S sources. Earleaf S concentrations of 1.6 g kg‐1 and extractable soil S concentrations of 4.0 to 8.7 mg kg‐1 were associated with S deficiency. Visual symtoms of S deficiency were observed in the check treatments throughout the growing season at both experimental sites. The results indicate that visual symptoms and tissue analysis can be used to identify S deficiency. Extractable soil S may be useful in determining the possible response to S fertilizer especially if the subsoil is sampled.  相似文献   

18.
Abstract

The rates of applied phosphorus required for 90% maximum yield of Desmodiim intortum cv. Greenleaf were calculated from pot experiments using 24 fertilized and unfertilized soils from the Atherton Tableland, Queensland, Australia.

Phosphorus required was highly correlated (r2 = 0.94) with the phosphorus sorbed (P sorbed) by the soils at a supernatant solution P concentration of 0.08 ppm. P sorbed was found to be a function of phosphorus buffer capacity at 0.08 ppm ("PBC") and phosphorus extractable by acid (0.005 M H2S04) or bicarbonate (0.5 M NaHCO3). PBC was highly correlated (r2 = O.84) with a phosphorus sorption index ("PSI") derived from one addition of 500 μg P g‐1 soil.

Combining PSI with acid or bicarbonate extractable P in a multiple regression equation allowed the estimation of phosphorus required with multiple correlation coefficients of R2 = 0.80 and R2 = 0.83 respectively.  相似文献   

19.
Abstract

The study aims at determining the cobalt retention properties of various soil components. Therefore, cobalt (Co) sorptions and extractions were carried out using an Oxisol sample before (untreated) and after successive removal of organic matter and active manganese (Mn) oxides (H2O2‐treated) and iron (Fe) oxides (H2O2+CBD‐treated). A synthetic goethite was included for comparison. Sorption of the four sorbents was determined over a range of Co concentrations (initially 10‐8 M to 10‐4 M), pH values (3 to 8) and reaction times (2 hours to 504 hours). The Co species sorbed was Co(ll), since oxygen exclusion during sorption had no effect on the amount sorbed. The pH‐dependent sorption curve (sorption edge) was shifted to lower pH at decreasing initial Co concentration and increasing reaction time. The displacements, in particular of the sorption edges corresponding to the lowest initial Co concentrations, to successively higher pH following removal of Mn oxides, organic matter and Fe oxides could be attributed to sorption onto sites of decreasing Co affinity [Mn oxides (and organic matter) > Fe oxides > kaolinite]. Extractions of sorbed Co at pH 5.5–7.5 with 2 M HCI showed that the extractability decreased with increasing sorption time and decreasing initial Co concentration. The untreated and H2O2‐treated soil samples retained sorbed Co at least as firmly as the synthetic goethite, whereas the H2O2+CBD‐treated sample (kaolinite) was clearly less effective. The results emphasized the importance of the soil Mn and Fe oxides for Co retention in soils but also the necessity of taken interior sorption sites into consideration.  相似文献   

20.
The chile pepper plant seldom responds to N and P fertilizers on fertile soils. Surplus industrial H2SO4 and elemental S have created interest in “mining”; calcareous soils for additional supplies of P, Ca, Mg and micronutrients. The effect of variable S, on the growth of chile and broccoli was evaluated holding other nutrients constant. Growth of chile and broccoli plants was significantly increased in the greenhouse and chile yield increased in the field. Incremental S additions increased the water extractable and desorbable Ca + Mg and P contents of soil. The total N and K content of chile plant grown in the greenhouse increased, and then decreased, P decreased, as S rates increased. Yield of dry red chile with constant N peaked at 16.5 g S m‐2 and then decreased with increasing S in the field. Rroccoli responded more to S application than to directly applied foliar micronutrient solutions (Fe and 7n), and responded much better to (NH4)2SO4 + S than to Ca(NO3)2 at equivalent N rates. Increased soluble Ca + Mg content of the soil in the presence of S was thought to influence plant absorption of NH4 and/or K.  相似文献   

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