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1.
Abstract

Fly ash, a by‐product of coal combustion, is often stored in landfills. Stabilization of fly ash deposits can be hindered by phytotoxic levels of B and soluble salts in the ash. Two greenhouse studies were conducted with the objective of improving cover crop establishment on landfills containing fly ash. In one experiment, eight cover crop species were screened for tolerance to fly ash and fly ash‐amended soil, as measured by seedling emergence and early shoot growth. Hairy vetch, red clover, and tall fescue were identified as having the best potential for stabilization of fly ash deposits. Another experiment determined if amending fly ash with a co‐compost, produced from municipal refuse and sewage sludge, would improve the establishment and growth of tall fescue and Korean lespedeza. The co‐compost had no effect on fescue alone, but increased emergence and early growth of lespedesa and a fescue‐lespedeza mixture.  相似文献   

2.
Abstract

Alkaline‐treated wastewater sludges with varying doses of fly ash were added to a clay soil at rates equivalent to 100 t (dry weight) raw sludge ha?1 soil, and the variations in ammonium, nitrate, and total nitrogen contents were monitored throughout an incubation period of 360 days at 28°C. The results showed that inhibition of organic nitrogen mineralization occurred in soil amended with fly ash–containing sludge during the first 90 days of incubation. After the total incubation period of 360 days, the inhibition effects of alkaline sludge amendments totally disappeared. In fact, mineralization was enhanced in alkaline pasteurized sludges containing 80% and 120% fly ash. The overall results indicated that application of sludges amended with fly ash may prolong the use (3 to 6 months) of nitrogen from the organic nitrogen pool in sludge.  相似文献   

3.
An alternative use of solid organic and inorganic residues as fertilizers from a Kraft pulp industry was studied. Residues of inorganic nature, such as ashes, fly‐ashes, dregs, grits, as well those rich in organic matter, primary sludge and brown stock rejects, were examined for plant growth enhancement. These residues, all alkaline in nature, used in different concentrations together with soil, bark, organic soil or mixed with a nutrient solution, were tested on the growth of Monterey pine (Pinus radiata), Eucalyptus globulus, rice (Oryza sativa. cv. ‘Diamante’), and duckweed (Lemna minor) under greenhouse and in‐vitro conditions, respectively. Responses varied according to plant species, type, and waste content in combination with substrate. For Monterey pine, substrates including ash, fly‐ash, and dregs promoted growth; in Eucalyptus seedlings dregs and fly‐ash were also beneficial. Primary sludge and ash were favorable for rice growth. Duckweed increased frond number and plant biomass when grown in water containing fly‐ash and primary sludge extracts, combined with nutrient salts.  相似文献   

4.
Vicia faba, in a pot experiment with sandy and clayey soils under greenhouse conditions, was checked for growth response to different amendments with coal alkaline fly ash or cocomposted fly ash mixed with lignocellulosic residues. Soil microbial populations, pH and electrical conductivity as well as heavy metal uptake by plants were monitored. At rates of five and ten percent (on a dry matter basis) in both soils, neither fly ash alone nor cocomposted fly ash exerted any negative effect. Plant biomass production was not influenced in either clayey or sandy soil. Alkaline fly ash did not promote microbial growth when applied alone to the soils. However, cocomposted fly ash generally increased bacterial and actinomycetes counts in both soils. Fungi were not affected by ash. Due to the increase of soil pH by alkaline fly ash or cocomposted fly ash, plant uptake of heavy metals was depressed in the sandy soil. Heavy metal mobility did not cause change in the clayey soil where a high buffering capacity mitigated the effects of fly ash amendments.  相似文献   

5.
Major impediments to the land application of coal combustion byproducts (fly ash) for crop fertilization have been the presence of heavy metals and their relatively low and imbalanced essential nutrient concentration. Although nutrient deficiencies, in particular N, P, and K, may be readily augmented by adding organic wastes such as sewage sludge and animal manure, the indiscriminate application of mixtures to crops can cause excessive soil alkalinity, imbalanced nutrition (P, Mg), phytotoxicities (B, Mn, ammonia, nitrite), and unspecified contamination of the food chain by elements such as As. In this study, nutrient availability data and linear programming (LP) were used to solve these problems by formulating fly ash-biosolid triple mixtures which complied with both plant and soil fertilization requirements, and met existing U.S.A. environmental regulations for total As application in sewage sludge (EPA-503). Thirteen different fly ash samples were LP-formulated with sewage sludge, poultry manure, CaCO3, and KCl to yield 13 unique mixtures, which were then evaluated in greenhouse pot experiments. Results indicated that normal growth and balanced nutrition of sorghum (Sorghumbicolor L.) and soybean (Glycine max (L.) Merr.) crops were achieved in all mixtures, comparable to a balanced fertilizer reference treatment, and significantly better than the untreated control. Phytotoxic levels of B, NH3, NO2 -, overliming problems, and excessive As levels which were previously encountered from indiscriminate use of these waste materials, were all well controlled by LP-formulated mixtures. Most fly ash quantities in mixtures were limited by either available B (< 4 kg ha-1) or total As (< 2 kg ha-1) restrictions during formulation, while the most alkaline fly ash was limited by its high calcium carbonate equivalence (CCE = 53.9%). These results confirmed that fly ash land application should not be at arbitrary fixed rates, but should be variable, depending on the soil, crop, and particularly the fly ash chemistry.  相似文献   

6.
Agronomic use of coal combustion by-products is often associated with boron (B) excess in amended soils and subsequently in plants. A greenhouse study with corn (Zea mays L.) as test plant was conducted to determine safe application rates of five fly ashes and one flue gas desulfurization gypsum (FDG). All by-products increased soil and corn tissue B concentration, in some cases above toxicity levels which are 5 mg hot water soluble B (hwsB) kg?1 soil and 100 mg B kg?1 in corn tissue. Acceptable application rates varied from 4 to 100 Mg ha? for different by-products. Leaching and weathering of a high B fly ash under ponding conditions decreased its B content and that of corn grown in fly ash amended soil, while leaching of the same fly ash under laboratory conditions increased fly ash B availability to corn in comparison to the fresh fly ash. Hot water soluble B in fly ash or FDG amended soil correlated very well with corn tissue B. Hot water soluble B in fly ash amended soil could be predicted based on soil pH and B solubility in ash at different pH values but not so in the case of FDG. Another greenhouse study was conducted to compare the influence of FDG and Ca(OH)2 on B concentration in spinach (Spinacia oleracea L.) leaves grown in soil amended with the high B fly ash. The Ca(OH)2 significantly decreased tissue B content, while FDG did not affect B uptake from fly ash amended soil.  相似文献   

7.
Dispersion of saline–sodic soils was rather difficult to leach. Therefore, negative effects of freeze–thaw on soil physical properties should be reduced by inexpensive and practical methods. This study investigates the effect of freeze–thaw cycles (3, 6, and 9) on wet aggregate stability, bulk density, and permeability coefficient in three soils with different electrical conductivity and exchangeable sodium percentage levels (soil I: 5.30 dS m−1, 47.51%; soil II: 42.80 dS m−1, 55.45%; soil III: 36.30 dS m−1, 59.34%) which consist of different proportions of sewage sludge and fly ash by volume (10%, 20%, and 30%). The experiment was conducted under laboratory conditions using disturbed and non-cropped soil samples mixed with sewage sludge and fly ash. Soils mixed with sewage sludge produced higher aggregate stability and permeability coefficients and lower bulk density values as compared to the soils mixed with fly ash. Sewage sludge added with a rate of 30% eliminated the negative effects of freeze–thaw processes on wet aggregate stability. Freeze–thaw processes did not affect the bulk density of the soils II and III, which were mixed with sewage sludge. However, fly ash addition decreased the bulk density of these soils very significantly after nine freeze–thaw cycles. Addition of sewage sludge or fly ash with rates of 20% and 30% significantly increased the permeability coefficients in soil I after nine freeze–thaw cycles. Results indicated that addition of sewage sludge and/or fly ash to saline–sodic soils could be alternative way for reducing negative effects of freezing–thawing on soil wet aggregate stability, bulk density, and permeability coefficient.  相似文献   

8.
Eight fly ash samples collected from South African power stations were evaluated for various chemical properties, liming potential and metal species release under incubation. All fly ashes had alkaline pH ranging from 10.97 to 12.75 with much wider variations of electrical conductivity (range 0.46–8.27 dS m?1). Their total P content ranged from 553.3 to 1514 mg P kg?1 and Olsen extractable P from 130 to 345.5 mg P kg?1. Application of two of the fly ashes to three different soils showed a high ability to neutralize acidity, resulting in an average of 41% change in pH after 8 weeks of incubation. Across all three soils, the fly ash incorporation increased extractable P content from a P-deficient level to levels above 25 mg P kg?1 in two of the three soils. Except for Cu, all metal species (Cr, Pb, Ni and Fe) showed significantly (P ≤ 0.05) low extractability under fly ash treated soils compared to the soil alone control. These results suggest that the South African fly ashes studied are effective liming materials and can provide essential elements such as P with minimum risk of soil contamination from metal species release.  相似文献   

9.
Abstract

Incineration reduces sewage sludge volume, but management of the resulting ash is an important environmental concern. A laboratory incubation study and greenhouse pot experiments with lettuce (Lactuca sativa L.) and corn (Zea mays L.) were conducted to examine the potential for recycling elements in sewage sludge incinerator ash in agricultural systems. Ash rates in both the laboratory and greenhouse were 0, 0.95, 3.8, 15.2, and 61.0 g/kg soil (Typic Hapludoll). Ash was also compared to equivalent rates of citrate soluble P from superphosphate fertilizer in a soil‐less growth medium. During soil: ash incubation, Olsen P and DTPA extractable copper (Cu), zinc (Zn), cadmium (Cd), and lead (Pb) increased with incubation time at the higher ash rates. Release rates diminished rapidly, however, and the limited release of these elements after 280 days was associated with decreasing pH. In the greenhouse, ash amendment increased extractable soil P, plant tissue P, and the growth of lettuce and corn. Ash was a less effective P source than superphosphate fertilizer in the soil‐less growth medium and Olsen P levels were more consistent with these differences than Bray P. Ash increased extractable soil levels and plant tissue concentrations of calcium (Ca), magnesium (Mg), sodium (Na), Cu, and Zn, but extractable soil manganese (Mn) and plant tissue Mn decreased. Ash increased soil pH and extractable SO4‐S. DTPA extractable Cd and Pb increased, but chromium (Cr) and nickel (Ni) decreased. Lettuce accumulated higher amounts of these trace metals than corn, but tissue concentrations were at control levels or below detection limits in both crops.  相似文献   

10.
Lai  K. M.  Ye  D. Y.  Wong  J. W. C. 《Water, air, and soil pollution》1999,113(1-4):261-272
Previous studies showed that coal fly ash could stabilize sewage sludge by reducing metal availability, but fly ash may cause an adverse effect on soil microbial activities. Therefore, an experiment was performed to evaluate the effects of amendment of soil with anaerobically digested dewatered sewage sludge, stabilised with alkaline coal fly ash, on soil enzyme activity and the implications for soil nutrient cycling. Sewage sludge was amended with 0, 5, 10, 35 and 50% w/w of fly ash, and then the ash-sludge mixtures were incubated with a sandy soil at 1:1 (v/v). Dehydrogenase activity decreased with an increase in fly ash amendment level and the time of incubation. Soil receiving 5% ash-sludge amendment had a higher dehydrogenase activity than other treatments. Soil receiving 10% ash-sludge mixture had the highest urease activity and in general, urease activity decreased with increasing incubation time. Phosphatase activity was the highest at 5% ash-sludge mixture amended soil and no general trend was observed with time. Water-soluble Zn, Mn and Cu contents were suppressed by the addition of fly ash. The present experiment indicated that addition of 10% ash-sludge mixture should have a positive benefit on the activity of soil microorganisms, N and P nutrient cycling, and reduce the availability of heavy metals.  相似文献   

11.
Abstract

A field experiment investigating amendments of organic material including farmyard manure, paper factory sludge and crop residues combined with fly ash, lime and chemical fertilizer in a rice-peanut cropping system was conducted during 1997–98 and 1998–99 at the Indian Institute of Technology, Kharagpur, India. The soil was an acid lateritic (Halustaf) sandy loam. For rice, an N:P:K level of 90:26.2:33.3 kg ha?1 was supplied through the organic materials and chemical fertilizer to all the treatments except control and fly ash alone. The required quantities of organic materials were added to supply 30 kg N ha?1 and the balance amount of N, P and K was supplied through chemical fertilizer. Amendment materials as per fertilization treatments were incorporated to individual plots 15 days before planting of rice during the rainy season. The residual effects were studied on the following peanut crop with application of N:P:K at 30:26.2:33.3 kg ha?1 through chemical fertilizer alone in all treatments, apart from the control. An application of fly ash at 10 t ha?1 in combination with chemical fertilizer and organic materials increased the grain yield of rice by 11% compared to chemical fertilizer alone. The residual effect of both lime and fly ash applications combined with direct application of chemical fertilizer increased peanut yields by 30% and 24%, respectively, compared to chemical fertilizer alone. Treatments with fly ash or lime increased P and K uptake in both the crops and oil content in peanut kernel compared to those without the amendments. Alkaline coal fly ash proved to be a better amendment than lime for improving productivity of an acid lateritic soil and enriching the soil with P and K.  相似文献   

12.
This laboratory-scale study investigated initially the potential of heavy metal removal from a metal-finishing wastewater using fly and bottom ash from a power plant as coagulants. It was found that the maximum heavy metal content in the ash–sludge mix was obtained at a fly ash-to-bottom ash ratio of 1.5:1 and a stirring time of 3 h, which resulted in heavy metal removal (i.e., Cr, Ni, Cu, Zn, Cd, and Pb) in excess of 99%, with effluent concentrations below the corresponding regulatory standards of Thailand. Furthermore, the feasibility of using fly ash as an admixture to stabilize and solidify the ash–sludge mix generated previously was explored. Results indicated that the stabilization/solidification process can achieve a high level of heavy metal removal efficiency from the ash–sludge mix. The optimum ratio regarding chromium leaching was found to be 1:0.75:0.75 (cement:fly ash:ash–sludge). In addition, the compressive strength and the chromium leaching concentration of the solidified sludge were within acceptable levels for secure landfill disposal and/or use as a construction material.  相似文献   

13.
The influences of fly ash and fly‐ash–quicklime‐treated‐sludge mixtures (with fly‐ash doses of 40%, 80%, and 120% on dry‐weight basis) on the microbial numbers in soil and leachate were investigated by using 60 cm soil columns. Heterotrophic bacteria and total coliform numbers were determined in soil and leachate samples following an artificial rainfall event. The results indicated that land application of untreated sludge and fly‐ash–sludge mixtures appear to introduce large numbers of bacteria to leachates and soil. Although the numbers in leachates and soils were found to decrease with increasing ash ratios, they were still all significantly above the control levels. Application of alkaline‐stabilized and pasteurized sludge did not increase bacterial numbers significantly in soil and leachate. Distribution of heterotrophic bacteria through soil profile clearly showed no increase in soils amended with alkaline‐stabilized and pasteurized sludges. Additionally, no significant inhibitory effect of lignite fly ash on soil microbial population was observed.  相似文献   

14.
An artificial soil mix was prepared from coal fly ash and sewage sludge and an experiment was performed to evaluate their effects on soil microbial respiration. Coal fly ash at 0%, 5%, 10%, 35% and 50% w/w was mixed with dewatered sewage sludge and then each ash-sludge mixture was incubated with a sandy soil at 1:1 v/v at 28°C for 42 days. All treatments showed the same carbon dioxide production pattern with a peak production at day 7 to day 14. Addition of ash-sludge mixtures to soil resulted in an increase in carbon dioxide production but the production rate decreased according to the ash amendment rate. The high pH of coal fly ash and the dilution effect of the sludge were the major reasons for the decrease. However, the ecological dose 50% values sharply increased from 26% at day 3 to 39% ash at day 14. This indicates the rapid acclimatization of microorganisms to the fly ash-sludge mixtures. Therefore, a brief stabilization period may be required for the establishment of soil microbial populations in soil amended with ash-sludge mixtures.  相似文献   

15.
A greenhouse and laboratory study was undertaken to quantify the P-sorption capacity of high pH, high calcium, coal-combustion, waste materials and determine the amount of P fertilization necessary to overcome that P-sorption ability. Three different waste materials (bottom ash, bottom ash/fly ash mixture, and bottom ash/scrubber sludge mixture) were selected based upon their handling properties and their ability to support plant growth. A steady state was apparently established within 18 hr after adding P. Phosphorus sorption behavior was typical of precipitation rather than surface adsorption for all ash materials. The combination of high pH and readily available Ca in the bottom ash and bottom/fly ash mixture favored rapid precipitation of calcium phosphates. The β-tricalcium phosphate that apparently formed in these materials would not provide adequate P for plant growth, and fertilizing with more than 1000 kg P ha?1 would be necessary to provide the needed concentrations. The calcareous bottom ash/sludge mixture would maintain a sufficient P concentration to support plant growth because of its relatively low pH. As leaching and exposure to CO2(g) proceed in the other two ash materials, equilibrium with calcite would be established and P fixing would be a smaller hindrance to plant growth.  相似文献   

16.
The impact of plants (Phalaris arundinacea L.) on the leakage of ammonium, cadmium, copper, nitrate, phosphate, and zinc from sulfidic mine tailings covered with wood fly ash and sewage sludge was investigated. Either ash or sludge was placed in contact with the tailings, and ash layers of either low or high compactness were used. It was revealed that an ash/sludge cover effectively decreased the metal leaching from the tailings regardless of the order in which the materials were applied. Plants decreased the amount of leachate and the concentrations of ammonium and phosphate. The presence of ash below the sludge decreased the plant uptake of copper and zinc and nitrate leakage. However, when the ash was added as a thin (1.5 cm) porous layer, roots and air reached the tailings and caused high metal leakage. The results support the use of a vegetated ash/sludge cover in the treatment of mine tailings, provided that the sealing layer is firm enough to prevent root penetration.  相似文献   

17.
Lei  Na  Han  Jichang  Mu  Xingmin  Sun  Zenghui  Wang  Huanyuan 《Journal of Soils and Sediments》2019,19(5):2374-2380
Purpose

According to the specific conditions of the region, we sought to determine appropriate soil materials for improving soil conditions after the reclamation of hollow villages into cultivated land and for quickly restoring agricultural production.

Materials and methods

The test plot consisted of seven treatments with an area of 5 m?×?6 m (30 m2) each, and each treatment included three replicates. The plot was filled with raw soil (old wall soil) from an abandoned homestead in Yuzihe Village, Yaotou Town, Chengcheng County, Shaanxi Province, China. The test design was completely randomised with seven treatments: fly ash (T1), organic fertiliser (chicken manure) (T2), improver (ferrous sulphate) (T3), fly ash?+?organic fertiliser (T4), improver?+?organic fertiliser (T5), fly ash?+?improver (T6) and no fertilisation measures (T0). The modified materials were mixed evenly with raw soil then applied to a depth of 0–30 cm onto the test plot.

Results and discussion

After adding the various modified materials, the soil bulk density decreased by 6.52–14.49% and total soil porosity, capillary porosity and non-capillary porosity increased by 7.09–15.75%, 3.14–12.67% and 15.57–38.47%, respectively. The soil permeability coefficient increased by 5.75–10.75×. Organic matter, total nitrogen, available phosphorus and available potassium in reclaimed hollow village soil increased by 12.50–66.44%, 15.15–20.00%, 6.58–64.62% and 18.24–26.82%, respectively, relative to that of T0. Only T4, T2, T6 and T5 significantly increased maize yield and water use efficiency compared with T0. The other treatments did not significantly improve maize yield or water use efficiency.

Conclusions

Organic fertiliser and fly ash composite was an appropriate amendment for improving reclaimed soil in a hollow village in a loess hilly gully region.

  相似文献   

18.
Abstract

This study was carried out to examine the characteristics and potential utilization of synthetic soil aggregates (SSA) produced by mixing acidic “Kunigami Mahji” soil in Okinawa, Japan, with waste materials, such as coal fly ash, used paper and starch, as media for crop growth. A series of different SSA were produced by incorporating various percentages (i.e. 0, 20, 40, 60, 80 and 100%) of coal fly ash into the “Kunigami Mahji” soil with used paper and starch. The particle density and bulk density of the original “Kunigami Mahji” soil were 2.67 and 1.23 g cm?3, respectively. The increased percentages of added coal fly ash, used paper and starch significantly decreased the particle and bulk densities of SSA compared with the original “Kunigami Mahji” soil because of the low particle and bulk densities of the coal fly ash (2.10 and 0.96 g cm?3, respectively). The SSA particle density varied between 2.39 and 2.14 g cm?3, and bulk density varied between 0.72 and 0.81 g cm?3, depending on the additional percentages of coal ash from 20–100%. Maximum water-holding capacity and saturated hydraulic conductivity were increased with the formation of SSA with coal fly ash, used paper and starch binder compared with the original “Kunigami Mahji” soil. The saturated hydraulic conductivity values of the SSA increased because of their low bulk density compared with the original soil. The addition of coal fly ash, used paper and starch to the acidic (pH = 4.62) “Kunigami Mahji” soil to form SSA increased the pH (6.70–9.96), electrical conductivity, exchangeable cation concentration and cation exchange capacity. The addition of coal fly ash up to 60% increased the aggregate strength. The growth and yield of komatsuna and soybean crops with SSA as a crop growth medium was assessed. Both crops showed the highest growth and yield when grown with SSA containing 20% of coal fly ash. Synthetic soil aggregates containing more than 20% of coal fly ash reduced plant growth and yield. Therefore, SSA produced from “Kunigami Mahji” soil with 20% of coal fly ash, used paper and starch can be successfully used as a medium for crop growth.  相似文献   

19.
Laboratory column studies were used to predict the effect on the leachability of lead when using fly ash or a fly ash/sludge mixture as a cover for a lead tailings site. A high pH fly ash cover produced a leachate with a pH 12. This was sufficiently high to allow for the formation of lead hydroxide complexes which are slightly soluble. Therefore, the leachate had an average lead concentration of about 5 mg L-1, while the pH in the leachate from the column with only tailings was 7.8 and a lead concentration below the detection limit (≤0.1 mg L-1). The fly ash cover changed the availability of the remaining lead, making it less available. Rainfall rate did not affect the fly ash cover, but did have an effect on the fly ash/sludge cover.  相似文献   

20.
Wong  J. W. C.  Jiang  R. F.  Su  D. C. 《Water, air, and soil pollution》1998,106(1-2):137-147
A greenhouse pot experiment was conducted to investigate the boron (B) release capacity of coal fly ash and sewage sludge mixtures, and the accumulation of B in Agropyron elongatum after two consecutive growing seasons. Sludge was amended with fly ash at application rates of 0, 5, 10, 35, and 50% (w/w), and each mixture was then mixed with a loamy soil at either 1:1 or 1:5 (v/v). Both water soluble B (WS-B) and hot water soluble B (HWS-B) increased with increasing fly ash amendment rate. Shoot B concentrations also increased significantly according to the rate of ash amendment. The ash-sludge mixture improved plant growth with the highest total dry weight yield at 10% ash amendment rate. Boron toxicity symptoms in leaf tips were observed at 35% and 50% ash amendment rate at both soil mixing ratios. Hot water soluble B and WS-B decreased significantly after consecutive cropping of Agropyron especially at low ratio of mixure with soil i.e., 1:5 (v/v). However, soil available B contents at ≥ 35% ash application rate and 1:1 (v/v) soil mixing ratio were still excessive for normal plant growth, suggesting that deleterious effects on plant growth would be experienced in later seasons owing to the high amounts of residual B.  相似文献   

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