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1.
Beryllium enters the environment principally from coal combustion. Be contents in the ashes from a Czechoslovak power plant were determined. The ashes used in the experiment were as follows: coarse (> 2.0 mm) and fine (2.0 to 0.2 mm) fraction from dump, and fine (< 0.2 mm) fraction from electrostatic precipitators. It was discovered that the acidic and the alkali aqueous extracts of these ashes contain various concentrations of Be (1 to 17% of total concentration). Wastewater has shown 3.15 and 3.4 μg Be L?1. Thus, secondary long-term Be pollution emerges from the slag and ash dumps.  相似文献   

2.
Two strains of Pediococcus pentosaceus were isolated from refrigerated pork and found to produce antimicrobial substances that may inhibit foodborne pathogens and have potential as natural food preservatives. They were named P. pentosaceus L and S. The antimicrobial substances were purified to electrophoretical homogeneity by chloroform extraction and designated pentocins L and S with molecular masses (M) of 27 and 25 kDa, respectively. Both pentocins also had broad inhibition spectra and were thermostable. They inhibit the growth of tested spore-forming G+ and G- strains and the germination of Bacillus subtilis ATCC 10225, B. subtilis ATCC 10254, and Bacillus cereus ATCC 11778 spores. The inhibition activities decreased as the glucose in the medium decreased from 8.0 to 2.0%.  相似文献   

3.
魏峰  董元华 《土壤》2011,43(5):698-702
本文沿着DDT从1874年合成到将在2020年淘汰的轨迹和趋势,第一次依据历史重大事件并结合SCI文献数量将DDT的发展分为4个历史阶段,着重探讨了这种“万能杀虫剂”带来的3个争论:DDT对人类的健康影响、禁用还是使用DDT、以及如何评价DDT.本文从DDT由人类的“宠儿”变成“弃儿”的历史演变中分析得出了一些启示,并...  相似文献   

4.
In grassland farming, especially on coarse‐textured soils, K can be a critical element. On these soils, the actual K management as well as fertilizer history to a large extent determine the leaching of K. The effects of four fertilizer regimes on the nutrient balances and leaching of K from grassland grown on a sandy soil were investigated. The swards differed in the source and level of N input and K fertilizer: no fertilizer N + 166 kg K ha?1 year?1 (Control), 320 kg inorganic N ha?1 + 300 kg K ha?1 year?1 (MIN 320), 320 kg N + 425 kg K ha?1 year?1 in form of cattle slurry (SLR 320) and a grass–clover sward + 166 kg K ha?1 year?1 (WCL 0) without any inorganic N input. In a second experimental phase, cores from these swards were used in a mini‐lysimeter study on the fate of K from urine patches. On cut grassland after 6 years K input minus removal in herbage resulted in average K surpluses per year of 47, 39, 56 and 159 kg K ha?1 for the Control, MIN 320, WCL 0 and SLR 320, respectively. Related leaching losses per year averaged 7.5, 5, 15 and 25 kg K ha?1. Losses of urinary‐K through leaching were 2.2–4.5 and 5.7–8.4% of the K supplied in summer and autumn applications, respectively. Plant and soil were the major sinks for K from fertilizer or urine. High levels of exchangeable K in the soil and/or large and late fertilizer or urine applications stimulated leaching of K.  相似文献   

5.
Lactic acid bacteria were screened from feces of newborn baby and from dongchimi. Selection criteria employed included the ability of strains to withstand environmental conditions such as low pH, high bile concentration, and oxygen. The isolates were applied to the juice of various vegetables, and fermentabilities of isolates were compared. Strains F20-3, F35-3, and F35-6 showed high stability compared to the other strains at pH 3.0 and 2.3. Strains D1 and D2 showed the highest survival at pH 3.0 and survived at 1% high bile concentration. The selected strains were able to survive at low pH and relatively high bile concentration and were not affected by oxygen. The growth of isolates was >10(7) cfu/mL in natural media, and strains were not affected by the pH values of the vegetables. Therefore, isolated strains are thought to survive through the intestinal ecosystem and are considered to be suitable for application of the fermented product using various vegetables for their functionality. The isolates were identified as Lactobacillus plantarum and Lactobacillus fermentum.  相似文献   

6.
Pyrazine formation from serine and threonine.   总被引：4，自引：0，他引：4  
The formation of pyrazines from L-serine and L-threonine has been studied. L-Serine and L-threonine, either alone or combined, were heated at 120 degrees C as low temperature for 4 h or at 300 degrees C as high temperature for 7 min. The pyrazines formed from each reaction were identified by GC/MS, and the yields (to the amino acid used, as parts per million) were determined by GC/FID. It was found that pyrazine, methylpyrazine, ethylpyrazine, 2-ethyl-6-methylpyrazine, and 2,6-diethylpyrazine were formed from serine, whereas 2,5-dimethylpyrazine, 2,6-dimethylpyrazine, trimethylpyrazine, 2-ethyl-3,6-dimethylpyrazine, and 2-ethyl-3, 5-dimethylpyrazine were formed from threonine. Mechanistically, it is proposed that the thermal degradation of serine or threonine is composed of various complex reactions. Among these reactions, decarbonylation followed by dehydration is the main pathway to generate the alpha-aminocarbonyl intermediates leading to the formation of the main product, such as pyrazine from serine or 2, 5-dimethylpyrazine from threonine. Also, deamination after decarbonylation generates more reactive intermediates, alpha-hydroxycarbonyls. Furthermore, aldol condensation of these reactive intermediates provides alpha-dicarbonyls. Subsequently, these alpha-dicarbonyls react with the remaining serine or threonine by Strecker degradation to form additional alpha-aminocarbonyl intermediates, which then form additional pyrazines. In addition, decarboxylation and retroaldol reaction may also involve the generation of the intermediates.  相似文献   

7.
Tricin (5,7,4'-trihydroxy-3',5'-dimethoxyflavone) occurs in its glycosidic form in rice bran and other grass species such as wheat, barley, and maize. Tricin is considered sufficiently safe for clinical development as a cancer chemopreventive agent, therefore it can be used for cancer prevention. This study established a new method for the preparation of tricin from bamboo leaves as an alternative to traditional methods such as chemical synthesis via the Baker-Venkata-Raman reaction between acetylsyringic acid and phloroacetophenone. Tricin was prepared from an antioxidant product that was derived from bamboo leaves (AOB) by extraction with aqueous ethanol. A concentrated solution of this product was obtained and then processed by polystyrene (AB-8) resin column chromatography and preparative high-performance liquid chromatography (HPLC) with 30% (v/v) acetonitrile in 1% (v/v) acetic acid as the mobile phase. The collected tricin-rich fraction was further sequentially purified by dialysis membrane separation and drowning-out crystallization methods. The purity was assessed by analytical HPLC with 25% (v/v) acetonitrile in 1% (v/v) acetic acid as the mobile phase, and the chemical confirmation was evaluated by infrared, mass, nuclear magnetic resonance, and ultraviolet spectroscopies. Tricin (3.09 g) was prepared from 174 g of a crude column chromatography fraction obtained from 5 L of AOB concentrated solution. The present method is appropriate for preparing quantities of pure tricin, which can be used for the quantification of tricin in various plant herbs and further for pharmaceutical/biomedical applications and evaluation.  相似文献   

8.
Chitin and chitosan--value-added products from mushroom waste   总被引：2，自引：0，他引：2  
Accumulation of chitinous material in Agaricus bisporus stalks was determined during postharvest storage at 4 and 25 degrees C. The chitinous material was extracted after alkali treatment and acid reflux of alkali insoluble material and analyzed for yield, purity, degree of acetylation (DA), and crystallinity. The total glucosamine content in mushroom stalks increased from 7.14% dry weight (DW) at harvest (day 0) to 11.00% DW and 19.02% DW after 15 days of storage at 4 degrees C and 5 days of storage at 25 degrees C, respectively. The yield of crude chitin isolated from stalks stored at 25 degrees C for 5 days was 27.00% DW and consisted of 46.08% glucosamine and 20.94% neutral polysaccharides. The DA of fungal chitin was from 75.8 to 87.6%, which is similar to commercially available crustacean chitin. The yield of crude fungal chitin of 0.65-1.15% on a fresh basis indicates the potential for the utilization of these mushroom byproducts.  相似文献   

9.
Heritage apple (Malus domestica Borkh. hybrids) and pear (Pyrus communis L. hybrid) trees grow in villages throughout Terceira Island, Azores, Portugal. Some of these pears have different names but similar morphology. The objective of this study was to determine synonymy, homology, and phylogeny of apples and pears from Terceira and to examine potential relationships of the island pears with standard apples and pears of Portuguese or American descent. Nine apple microsatellite markers were used to determine genetic relationships. Distance- and parsimony-based cluster analysis grouped these genotypes into separate apple and pear clades. The Terceira apples were divided into two clades: the maçā and the reineta-reinette. Among the 17 heritage apple genotypes, seven unique accessions were identified and four groups of synonyms, or possibly clones, were detected including: ‘Reineta Agosto’ and ‘Reineta Verde’ from Altares; ‘Reineta Castanha’ and ‘Reineta Verde Miuda’; ‘Maçā Pêra,’ ‘Maçā Calhau’, ‘Pêro Branco’ from Salga and from Terra-Chā and ‘Maçā Marmelo’; and the five genotypes ‘Maçā Sao Joao’, ‘Malápio Rosa’, ‘Maçā Gaspar’, ‘Maçā Branca’ and ‘Maçā Pato’. In addition, two homonyms were detected. ‘Pêro Vermelho’ from Terra Chā was a separate genotype from a tree from Doze Ribeiras of the same name, but Pêro Branco from Terra Chā appears to be a clone that can be distinguished by an additional allele at CH1F07a from a tree with that name from Salga. One pair of apple clones, ‘Reineta Agosto’ and ‘Reineta Verde’ from Altares appear to be derived from an unreduced gamete of ‘Golden Delicious.’ Another apple genotype ‘Maçā Acida’ could be a sibling of the ‘Maçā Pêra’ clonal group. Other tested standard apples from the US genebank were unrelated to Terceira genotypes. Of the seven heritage pears, five unique genotypes and one pair of synonyms were detected. ‘Pêra Papo Pintassilgo’ from Raminho and ‘Pêra Vermelha’ from the nursery of Serviço de Desenvolvimento Agario da Terceira (SDAT) were synonyms. ‘Passans du Portugal’ was related to ‘Pêra Cabaca’ but other standard pears from the US genebank were unrelated to Terceira genotypes. Future studies will include additional apple and pear cultivars from other Islands of the Azores and continental Portugal, and wild Asian species to further explore genetic relationships.  相似文献   

10.
Fate of N from Green Manures and Ammonium Sulfate   总被引：4，自引：0，他引：4  
By means of ^15N tracer technique the fate of N in ammonium sulfate,milk vetch,sesbania and azolla,and the availability of their residual N were studied in a microplot experiment.Results showed that a) at the end of the first crop of early rice,both plant recovery and loss of N from ammonium sulfate were the highest whereas those from azolla were the lowest with those from milk vetch and sesbania in between;the sequence was reversed in terms of recovery of N in soil;the net residual N from ammonium sulfate was very low,about 1/7-1/4 of that from green manures,indicating that chemical N fertilizer contributes little to the soil N reserve;b) plant recovery of the residual N was low and it did not always decrease with time;the total plant recovery (from the second to the fifth crops) of the residual N from various test fertilizers was only 8-11% of the total N originally applied;c) the plant recovery of the residual N from ammonium sulfate was the highest,followed by those from milk vetch and sesbania,and that from azolla was the lowest,no matter in which cropping season (from the second to the fifth);N availability ratio showed the same trend,indicating that chemical N fertilizer helps renovate soil organic N,maintain and increase availability of soil N.  相似文献   

11.
Pulping of blue agave waste, from the production of tequila, was evaluated by both chemical and biomechanical pulping processes. Two conventional and two organosolv systems were used to pulp the agave waste under a standard set of conditions. The soda-ethanol process was superior in terms of delignification and pulp properties in comparison to the soda and ethanol organosolv processes for pulping of agave waste; however, the kraft process gave the best strength properties. In general, the strength of the agave waste pulps was rather poor in comparison to wood and other agro-based pulps; however, the tear strength was relatively high. This result is typical of poorly bonded sheets and may be due to the coarseness of the agave fibers and/or loss of hemicelluloses in the steaming process for the tequila production. Fungal treatment of the agave waste with Ceriporiopsis subvermispora reduced the energy consumption for mechanical refining but gave biomechanical pulps with inferior strength properties. The blue agave chemical pulps should be suitable for blending with softwood kraft pulps for publication grade paper.  相似文献   

12.
Almost all the lignite ash from the coal thermal power plants in Maemoa, Lumpang Province, Thailand is disposed of as solid wastes. However, the number of reclaimed sites for the disposal of the wastes is not sufficient to handle the large amount of wastes. Therefore, the development of a technique for the utilization of lignite ash is essential to preserve the environment and to recycle the waste materials. Lignite ash is composed of inorganic compounds mainly present as glasses resulting from fusion during their combustion. The chemical composition of these glasses is similar to that of volcanic glass in nature and changes easily to zeolite-like substances by hydrothermal treatment with an alkali. Henmi (1987) reported the synthesis of hydroxysodalite, a kind of zeolite, from waste coal ash. Zeolites are crystalline, hydrated aluminosilicates with a three-dimensional crystal structure and have the attractive cation-exchange properties in agricultural applications (Ming and Mumpton 1989). In the present study, attempts were made to synthesize zeolitelike substances from lignite ash from Thailand, in order to develop a new method for the disposal of industrial wastes. Although the synthesis of zeolite-like substances from waste coal ash had been reported in different countries after the publication of Henmi (1987), this method was applied for the first time in Thailand for the treatment of lignite ash.  相似文献   

13.
The biodegradation of polyaromatic hydrocarbons (PAHs) has been well documented; however, the biodegradation of PAHs in contaminated soil has proved to be problematic. Sorption of PAHs to soil over time can significantly decrease their availability for extraction much less than for biodegradation. In this study the ability of various organic solvents to extract PAHs from coal tar-contaminated soil obtained from former manufactured gas plant (MGP) sites was investigated. Solvents investigated included acetone/hexane, dichloromethane, ethanol, methanol, toluene, and water. The extraction of MGP soils with solvents was investigated using soxhlet extraction, multiple soxhlet extractions, sonication, and brief agitation at ambient temperature with a range of solvent concentrations. Of particular interest was the documentation of the recalcitrance of PAHs in weathered MGP soils to extraction and to bioremediation, as well as to demonstrate the ease with which PAHs extracted from these soils can be biodegraded. The efficiency of extraction of PAHs from MGP soils was found to be more dependent upon the choice of solvent. The environmentally-benign solvent ethanol, was shown to be equal to if not better than acetone/hexane (the EPA recommended solvent) for the extraction of PAHs from MGP soils, brief contact/agitation times (minutes) using small quantities of ethanol (2 volumes or less) can achieve nearly quantitative extraction of PAHs from MGP soils. Moreover aqueous slurries of an MGP soils experienced less than 10% biodegradation of PAHs in 14 days while in the same period about 95% biodegradation was acieved using PAHs extracted from this soil by ethanol and subsequently added to aqueous bacterial suspensions.  相似文献   

14.
The influence of a recent forest fire on the iron oxide phases, present in the A and the B horizon of a brown earth from Corsica, was examined by X-ray diffraction and chemical analysis. In the B horizon goethite and lepidocrocite, in the A horizon maghemite and hematite were identified. From the Al/(Al+Fe) ratio, which was determined for all four minerals by XRD, it was concluded that goethite was the precursor of hematite and lepidocrocite the precursor of maghemite respectively. The proportion of maghemite formed in the A horizon was calculated from the difference in Fed between the untreated sample and that free of maghemite. Because of substantial dissolution of clay minerals even after 5 citrate-bicarbonate treatments, it was not possible to determine Ald correctly.  相似文献   

15.
In a pot experiment a water extract from ryegrass (Lolium perenne) containing 21 mg/L selenium (Se) was sprayed on ryegrass, and the uptake of Se was compared with the uptake of Se applied as sodium selenite. The amount of Se recovered from the plants (0 to 53 mg/kg) was a linear function of the amount of Se applied (0 to 130 g/ha), both for the Se in the extract and for the sodium selenite. A total of 2.8 times more Se was recovered from the plants sprayed with the extract than from the plants sprayed with sodium selenite. When the plants were washed with Triton X‐100 the difference was still higher: from the ryegrass sprayed with the extract 5.3 times more Se was recovered from the grass sprayed with the extract than from the grass sprayed with sodium selenite.  相似文献   

16.
A pot experiment was conducted using a Candler fine sand (hyperthermic, uncoated, Typic Quartzipsamments) amended with either citrus leaves or compost, to measure the nitrogen (N) mineralization and its availability to two citrus rootstock seedlings. A rapid increase in NH4‐N concentration was evident in the soil amended with citrus leaves as compared to compost during the initial 14 to 20 d. Subsequently, the concentration of NH4‐N decreased in the citrus leaves amended soil. The extractable NO3‐N concentration was greater in the soil amended with citrus leaves as compared to compost, throughout the 270 d duration of the study. The N concentrations and N uptake by Cleopatra mandarin (CM) and Swingle citrumelo (SC) seedlings grown in citrus leaf amended soil were very similar to those in urea amended soil. Therefore, mineralization of N from dry ground citrus leaves was quite rapid. The N concentrations in both rootstock seedlings were much lower in the compost amended and unamended soils as compared to those in either citrus leaves or urea amended soils. Rapid mineralization of N from cirrus leaves added to sandy soil, resulting in an increased availability of N, suggested that the contribution of N from shed leaf mineralization must be considered while developing N rate recommendations for improving N use efficiency.  相似文献   

17.
畜禽养殖非点源污染及其生态控制   总被引：18，自引：1，他引：18       下载免费PDF全文
畜禽养殖产生的非点源污染对水环境影响的严重性日益受到人们的重视。论述了畜禽养殖非点源污染的形成、危害及负荷计算综合非点源污染及其控制措施的研究进展,从区域合理布局、优化管理和生态工程技术3个方面提出畜禽养殖非点源污染控制的方法和关键问题。  相似文献   

18.
In the evaluation of the risk of pesticide leaching to groundwater, the soil surface is usually assumed to be level, although important crops like potato are grown on ridges. A fraction of the water from rainfall and sprinkler irrigation may flow along the soil surface from the ridges to the furrows, thus bringing about an extra load of water and pesticide on the furrow soil. A survey of the literature reveals that surface-runoff from ridges to furrows is a well-known phenomenon but that hardly any data are available on the quantities of water and pesticide involved. On the basis of a field experiment with additional sprinkler irrigation, computer simulations were carried out with the Pesticide Emission Assessment at Regional and Local scales model for separate ridge and furrow systems in a humic sandy potato field. Breakthrough curves of bromide ion (as a tracer for water flow) and carbofuran (as example pesticide) were calculated for 1-m depth in the field. Bromide ion leached comparatively fast from the furrow system, while leaching from the ridge system was slower showing a maximum concentration of about half of that for the furrow system. Carbofuran breakthrough from the furrow system began about a month after application and increased steadily to substantial concentrations. Because the transport time of carbofuran in the ridge soil was much longer, no breakthrough occurred in the growing season. The maximum concentration of carbofuran leaching from the ridge-furrow field was computed to be a factor of six times as high as that computed for the corresponding level field. The study shows that the risk of leaching of pesticides via the furrow soil can be substantially higher than that via the corresponding level field soil.  相似文献   

19.
Screening accessions in a germplasm bank aids in the identification of plants with unusual properties ranging from agronomic traits to functional and compositional traits of the seed itself. Results from this study confirm the presence of a wide variation in the thermal and functional properties of starch from several landraces of corn in the Argentinean germplasm. Thermal properties of starch measured using differential scanning calorimetry (DSC) identified several corn landraces with properties of potential commercial interest. The pasting and textural properties of gels obtained from starch of different corn landraces also exhibited considerable variability. The degree of variation in thermal and functional properties of corn reported in this study is comparable to the thermal properties of starch from several other crop species. These corn races show promise for further regeneration to create inbred lines with unusual traits. The potential for further improvement of corn races exists not only based on thermal properties, but directly for specific functional attributes as well. Correlation analyses suggest that the variability in thermal and functional attributes are a function of amylose content, granule size distribution and, possibly, differences in the structural makeup of amylose and amylopectin. The strong correlation observed between the thermal properties and pasting and textural properties will allow for the estimation of starch properties from small sample sizes.  相似文献   

20.
The availability of phosphatic fertilizers applied to soil may be governed by the fixation of phosphate to soil and the release of phosphate fixed be soil. The fixation of phosphate by soil has been studied by many researchers. On the other hand, the studies on the release of phosphate from soil are very few.  相似文献   

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