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1.
二种钾肥对海泡石钝化修复镉污染土壤效应影响的研究   总被引：2，自引：0，他引：2  
为了揭示钾肥对Cd污染土壤钝化修复效果的影响,为土壤钝化修复过程中合理施钾肥提供理论依据。本文选取不同剂量(含量以K2O计算,分别为0.1 g·kg~(-1)、0.2 g·kg~(-1)和0.3 g·kg~(-1))的KCl和K_2SO_4作为典型钾肥,以海泡石(10 g·kg~(-1))作为钝化材料,通过油菜盆栽试验,研究了两种钾肥在海泡石钝化条件下对Cd污染土壤修复效应的影响。结果表明:K_2SO_4显著增加了油菜的生物量,其增幅为6.06%~10.05%。与单施海泡石钝化相比,在海泡石钝化时施用KCl和K_2SO_4两种钾肥,油菜地上部茎叶Cd含量分别增加16.38%~60.73%和15.62%~25.19%;施用KCl和K_2SO_4对土壤p H未产生显著性影响,却显著地增加了土壤有效态Cd含量,其增幅分别为25.51%~34.65%和18.5%~24.96%。添加海泡石可使土壤的Zeta电位向负值方向移动,提高土壤对Cd的负载能力;但添加海泡石下施用KCl和K_2SO_4均能提高土壤的Zeta电位,降低土壤对Cd的负载能力。等温吸附试验同样表明,添加KCl和K_2SO_4均能降低海泡石对Cd的吸附量,在水溶液中海泡石对Cd的最大吸附量为5.30 mg·kg~(-1),添加KCl和K_2SO_4后吸附量分别降低至2.87 mg·g~(-1)和4.92 mg·g~(-1)。KCl和K_2SO_4显著改善了土壤中K、Mn、Cu和Zn等营养元素的有效态含量。从上述结果可以发现,在海泡石钝化修复Cd污染土壤过程中,施K_2SO_4对钝化效果的影响小于施KCl。  相似文献   

2.
Potassium (K+) directly released from primary K‐bearing minerals can contribute to plant nutrition. The objective of this research was to assess short‐term K+ release and fixation on a range of intensively cropped calcareous soils. Potassium sorption and desorption properties and the contributions of exchangeable‐K+ (EK) and nonexchangeable‐K+ (NEK) pools to K+ dynamics of the soil‐solution system was measured using a modified quantity‐to‐intensity (Q : I) experiment. Release and fixation of K+ were varied among soils. The relation between the change in the amount of NEK during the experiment and the initial constrain was linear, and soil ability for K+ release and fixation (β) for all soils varied from 0.041 to 0.183, indicating that 4% to 18% of added K+ converted to NEK when fixation occurred. The equilibrium potential buffering capacity (PBC) for K+ derived from Q : I experiments had significant correlation (r = 0.75, p < 0.01) with β, indicating that PBC depends not only on exchange properties but also on release and fixation properties. The depleted soils showed higher β value than the other soils, indicating much of the added K+ was converted to NEK in case of positive constraint. The range of the amount of EK which was not in exchange equilibrium with Ca (Emin) in the experimental conditions was large and varied from 0.68 to 9.00 mmol kg–1. On average, Emin amounted to 64% of EK. This fraction of EK may not be available to the plant. The parameters obtained from these short‐term K+ release and fixation experiments can be used in plant nutrition.  相似文献   

3.
A potassium fertilizer field trial was carried out on a coarse silty loamy soil, low in exchangeable K+ in the Zhejiang Province (People's Republic of China). Potassium fertilizer applications increased the leaf area, the chlorophyll concentration, and the CO2 assimilation of cotton grown on this K+ deficient soil. Potassium increased the activity of the cytochrome oxidase and nitrate reductase, increased the stomatal conductance and decreased the transpiration. The leaf tissue of K+ deficient plants was flaccid, the cuticle of leaves poorly developed and contrasted much with the leaves well supplied with K+ which were characterized by a full turgor and a well developed cuticle. According to these physiological effects of K+, potassium fertilizer application increased lint yield and improved cotton and seed quality.  相似文献   

4.
Abstract

Release of native and added K+ and NH+ 4 from two soils was monitored during a 166 day incubation/leaching experiment. One soil (Brookston) represented a major soil series In Ontario whereas the other (Harriston) was suspected having a relatively large fixation capacity. Treatments were imposed involving addition of 50 μM g‐1 soil of K+(KCl) or NH+ 4 (NH4Cl) only or one added after the other on successive days. The addition of either K+ or NH+ 4 on day 2 tended to inhibit the release of the other added on day I. Also the addition of either K+ or NH+ 4 on day 1 tended to inhibit the sorption or fixation of the other on day 2. The release rate of K+ during the 10 to 166 day period was almost constant and not affected by the addition of NH+ 4. Alternatively, the addition of K+ on day 2 slowed the release rate of NH+ 4 measured by NO? 3 appearance from day 10 to 40 but had no effect thereafter. At the end of the experiment considerably more K+ than NH+ 4 was retained suggesting that K+ was more firmly fixed. However, the continuing nitrification of NH+ 4 must be contrasted with periodic removal of K+ by leaching with 0.01 M CaCl2 solution since the equilibrium between exchangeable and fixed ions was affected. There were no notable differences between the two soils inspite of a considerable difference in clay content.  相似文献   

5.
In order to assess the effectiveness of foliar‐applied potassium (K+, 1.25%) using different salts (KCl, KOH, K2CO3, KNO3, KH2PO4, and K2SO4) in ameliorating the inhibitory effect of salt stress on sunflower plants, a greenhouse experiment was conducted. Sodium chloride (150 mM) was applied through the rooting medium to 18 d–old plants and after 1 week of salt treatment; different K+‐containing salts were applied twice in 1‐week interval as a foliar spray. Salt stress adversely affected the growth, yield components, gas exchange, and water relations, and also caused nutrient imbalance in sunflower plants. However, foliar‐applied different sources of potassium improved shoot and root fresh and shoot dry weights, achene yield, 100‐achene weight, photosynthetic rate, transpiration rate, stomatal conductance, water‐use efficiency, relative water content, and leaf and root K+ concentrations of sunflower plants grown under saline conditions. Under nonsaline conditions, improvement in shoot fresh weight, achene yield, 100‐achene weight, photosynthetic and transpiration rates, and root Na+ concentration was observed due to foliar‐applied different K sources. Of the different salts, K2SO4, KH2PO4, KNO3, and K2CO3 were more effective than KCl and KOH in improving growth and some key physiological processes of sunflower plants.  相似文献   

6.
Abstract

Groundnut (Arachis hypogae L.) is the most important oilseed crop of India and it is abundantly grown under rainfed conditions in vertisols of Western India. The objective of this work was to study the effect of potassium (K) basal and foliar fertilization on yield, nutrient concentration in tissue and quality parameters of groundnut. Two varieties, GAUG‐1 (bunch type) and GAUG‐10 (spreading type) were grown during Kharif (rainfed) and Rabi (irrigated) seasons at Junagadh, Gujarat. The experiment compared two foliarapplied K fertilizers (KCl and K2SO4) at two different doses (0.5 and 1.0%) with basal KCl application (0 and 50 kg K2O ha?1). Field soil was highly calcareous (pH 8.2, NH4OAc extractable K 188 kg ha?1 with 40% lime reserve) Vertic ustochrept. The results showed a significant response in pod yield with foliar and soil‐applied potassium as compared to the control treatment. Pod yields were significantly higher when basal and foliar applications were combined. The best results were achieved with foliar application of 1% KCl together with a basal fertilization with 50 kg K2O ha?1. Response to foliar‐applied K was higher in rainfed kharif crop than in irrigated rabi crop. Groundnut variety GAUG‐10 out yielded GAUG‐1. Foliar K application increased plant tissue concentration of K. Foliar fertilization with KCl and K2SO4 did not cause leaf burn. Potassium application improved the crop harvest index and grain quality parameters of boldness, protein and oil contents. Response to K in quality parameters of protein and oil contents of seed was more consistent with foliar applied K2SO4 . The results confirmed that the practice of foliar K nutrition when used as a supplement and not a substitute for standard soil fertilization, is beneficial for groundnut crop in Western India.  相似文献   

7.
Potassium (K) is one of the major mineral elements required for normal growth of cotton. However, understanding the effect of controlled‐release K fertilizer on leaf photosynthesis and K use efficiency (KUE) of cotton is currently limited. A two‐year pot experiment was consecutively conducted in 2014 and 2015 with three kinds of K fertilizer including K2SO4, KCl, and polymer‐coated KCl (CRK), each at four application rates (0.00, 0.86, 1.73, and 2.59 g K plant−1, respectively). For each type of K fertilizer, the yield and K uptake of cotton increased but the KUE decreased with higher K fertilizer application. The release characteristics of K from CRK corresponded well to the K requirements during cotton growth. Plant‐available soil K, as well as leaf SPAD values, net photosynthetic rate (Pn), maximal photochemical efficiency (Fv/Fm), and effective quantum yield of photosystem II (ΦPSII) in CRK treatments were increased after full bloom stage compared to conventional K fertilizers under the same potassium application rate. Consequently, the CRK treatments significantly increased lint cotton yields by 8.1–32.7% and 3.7–20.8%, while the KUE increased by 15.5–54.8% and 14.5–45.4% compared to KCl and K2SO4 treatments, respectively. The results indicate that the application of CRK is intensively recommended to replace conventional potassium fertilizers for gaining greater yields and higher KUE of cotton.  相似文献   

8.
湖南烟区土壤含氯状况及烤烟施氯效应   总被引：13，自引：1，他引：13  
对湖南省主要烟区3329个土壤样品中水溶性氯含量的测定结果表明,湖南省主要烟区土壤水溶性氯含量平均为16.6.mg/kg,在烤烟生长适宜的含氯范围内。不同烟区土壤中水溶性氯含量差异较大,湘西、湘中烟区,水溶性氯含量较低的土壤所占比例较大。田间试验表明,适量的氯素营养有利于提高烤烟旺长期叶片中的叶绿素含量和植株根系活力,提高烤烟生长前期Nrase的活性;在氯含量较低的土壤上,施入烟草的钾肥总量中,氯化钾所占比例为15%～30%时(以K2O计),烟叶可增产5.2%～16.9%,产值增加1911.0～7348.5元/hm2,中上等烟比例提高10.2～11.5个百分点,烟叶的品质也得到改善,不会造成土壤氯的积累。在湖南省乃至南方一些土壤氯含量较低的地区,在烟草上可考虑适当施用一定量的氯化钾部分代替硫酸钾,以降低肥料投入成本,提高烟叶的经济效益。  相似文献   

9.
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10.
Summary Methods of determining exchangeable K+ of soil by mixing extracting solutions and analysing the soil suspension with ion‐selective electrodes were developed and evaluated on 30 samples of soils. From preliminary comparisons of the K+ extracted by BaCl2 and NH4OAc solutions and by batch and leaching treatments of soils, we established that suspensions of 5 g soil in 100 ml 0.5 m BaCl2 and single batch treatments of 1 h should be used. The exchangeable K+ was determined with a K‐selective, valinomycin‐based PVC membrane electrode and electrochemical cells that did or did not include a liquid junction (the reference electrode being a double‐junction reference electrode assembly with a 10 m LiOAc salt bridge solution or a Cl‐selective electrode, respectively). The Ba‐exchangeable K+ values were sensibly the same whether a liquid junction was involved or not, a result that can be attributed to the beneficial effects of the salt bridge and the ionic strength of the extractant. Comparisons of these Ba‐exchangeable results with those obtained by various combinations of batch or leaching treatments, BaCl2 or NH4OAc extractants and filtrate analysis by the ion‐selective electrode method or atomic absorption spectrometry showed they were all highly correlated (r≥ 0.996). The selectivity of the K+‐selective electrode (kpotKNH4 = 0.004) significantly reduced the interference from indigenous soil NH4+ in the BaCl2 suspensions. Overall, the results show potentiometric measurements of K+ in soil suspensions can provide a simple, rapid, and reliable means of determining exchangeable K+ in soils.  相似文献   

11.
Background and aims : Most physiological and biochemical studies on salt stress are NaCl‐based. However, other ions (e.g., K+, Ca2+, Mg2+, and SO 4 2 - ) also contribute to salt stress in special circumstances. In this study, salt stress induced by various salts was investigated for a better understanding of salinity. Methods : Arabidopsis thaliana plants were stepwise acclimated to five iso‐osmotic salts as follows: NaCl, KCl, Na2SO4, K2SO4, and CaCl2. Results and Conclusions : Exposure to KCl and K2SO4 led to more severe toxicity symptoms, smaller biomass, and lower level of chlorophyll than exposure to NaCl and Na2SO4, indicating that Arabidopsis plants are more sensitive to potassium salts. The strongly reduced growth was negatively correlated with the accumulation of soluble sugars observed in KCl‐ and K2SO4‐treated plants, suggesting a blockage in the utilization of sugars for growth. We found that exposure to KCl and K2SO4 suppressed or even blocked sucrose degradation, thus leading to strong accumulation of sucrose in shoots, which then probably inhibited photosynthesis via feedback inhibition. Moreover, K+ was more accumulated in shoots than Na+ after corresponding potassium or sodium salt treatments, thus resulting in decreased Ca2+ and Mg2+ concentrations in response to KCl and K2SO4. However, K2SO4 caused more severe toxicity symptoms than iso‐osmotic KCl, even when the K+ level was lower in K2SO4‐treated plants. We found that Na2SO4 and K2SO4 induced strong accumulation of tricarboxylic acid intermediates, especially fumarate and succinate which might induce oxidative stress. Thus, the severe toxicity symptoms found in K2SO4‐treated plants were also attributed to SO 4 2 - in addition to the massive accumulation of K+.  相似文献   

12.
Potassium nutrition of tobacco on a potassium fixing alluvial soil A field experiment was conducted to study the effects of K-fertilization on potassium uptake by tobacco and the K-dynamics in an alluvial soil rich in clay and carbonate content. It was observed that the amount of exchangeable potassium and the concentration of K in the soil solution increased on fertilization. There were only small changes in exchangeable potassium and significant reduction in the concentration of K in the soil solution during the growth period. Uptake of potassium by plants increased during first month due to its high concentration in soil solution. Decrease in the concentration of potassium after one month caused a rapid reduction in the uptake of potassium by plants (Figure 1). K Fertilization decreases the K-Ca and K-Mg potentials especially during the first month (Table 2) which increase again during the experimental period (because of the slow release of K from the solid phase and its rapid uptake by plants). Where as the concentration of potassium in the soil solution is closely related with K-Ca and K-Mg potentials on the one hand and with K-uptake by plants on the other, no relationship was observed between exchangeable potassium content and K-uptake (Figure 2). The potassium exchange curves of soils from K0 and K5 treatments show that the extent of K-adsorption is greater in K0 soil. A major part of K adsorbed during the shaking experiment can be easily removed by CaCl2 solution in K5soil, where as in K0 soil a part of adsorbed potassium exists in nonexchangeable form. Illite is the dominant clay mineral in this soil which show wedge type structures (expansible at edges).  相似文献   

13.
The volcanic soils of Kamchatka are characterized by low and very low values of their potential potassium buffer capacity. The largest amount of readily exchangeable potassium (-ΔK 0) is observed in the surface layers of the natural soils and is due to the active biogenic accumulation. The soddy horizons have a high content of strongly fixed potassium (K X ). The main factors determining the content of the labile potassium and its mobility are the contents of physical clay, humus, and exchangeable potassium. The extremely nonuniform distribution of all the potassium status parameters throughout the soil profile reflects the discrete character of the volcanic pedogenesis. The low values of the potential buffer capacity for the potassium (PBCK) at the high values of the equilibrium potassium potential (AR 0) and the medium content of the labile potassium in the light-textured synlithogenic soils simultaneously indicate both the good potassium supply of the plants and the incapability of the soils to resist potassium exhaustion under agricultural production conditions for a long time.  相似文献   

14.
Annual potassium (K) balances have been calculated over a 40‐year period for five field experiments located on varying parent materials (from loamy sand to clay) in south and central Sweden. Each experiment consisted of a number of K fertilizer regimes and was divided into two crop rotations, mixed arable/livestock (I) and arable only (II). Annual calculations were based on data for K inputs through manure and fertilizer, and outputs in crop removal. Plots receiving no K fertilizer showed negative K balances which ranged from 30 to 65 kg ha?1 year?1 in rotation I, compared with 10–26 kg ha?1 year?1 for rotation II. On sandy loam and clay soils, the K yield of nil K plots (rotation I) increased significantly with time during the experimental period indicating increasing release of K from soil minerals, uptake from deeper soil horizons and/or depletion of exchangeable soil K (Kex). Significant depletion of Kex in the topsoil was only found in the loamy sand indicating a K supply from internal sources in the sandy loam and clay soils. On silty clay and clay soils, a grass/clover ley K concentration of ～2% (dry weight) was maintained during the 40‐year study period on the nil K plots, but on the sandy loam, loam and loamy sand, herbage concentrations were generally less than 2% K.  相似文献   

15.
Changes in 15N abundance and amounts of biologically active soil nitrogen   总被引：1，自引：0，他引：1  
 Estimation of the capacity of soils to supply N for crop growth requires estimates of the complex interactions among organic and inorganic N components as a function of soil properties. Identification and measurement of active soil N forms could help to quantify estimates of N supply to crops. Isotopic dilution during incubation of soils with added 15NH4 + compounds could identify active N components. Dilution of 15N in KCl extracts of mineral and total N, non-exchangeable NH44 +, and N in K2SO4 extracts of fumigated and non-fumigated soil was measured during 7-week incubation. Samples from four soils varying in clay content from 60 to 710 g kg–1 were used. A constant level of 15N enrichment within KCl and K2SO4 extracted components was found at the end of the incubation period. Total N, microbial biomass C and non-exchangeable NH4 + contents of the soils were positively related to the clay contents. The mineralized N was positively related to the silt plus clay contents. The active soil N (ASN) contained 28–36% mineral N, 29–44% microbial biomass N, 0.3–5% non-exchangeable NH4 + with approximately one third of the ASN unidentified. Assuming that absolute amounts of active N are related to N availability, increasing clay content was related to increased N reserve for crop production but a slower turnover. Received: 7 July 1998  相似文献   

16.
Abstract

For depletions of soil exchangeable potassium of between 15 and 50%, potassium concentrations in ryegrass and strawberry leaf were linearly related to pARO K√BCO where ARO K is the equilibrium potassium activity ratio and BCO is the slope, measured at ARO K of the curve relating the quantity of labile potassium and the activity ratio. Potassium supplying power as measured by pARO K√BCO could also be expressed as a function of the equilibrium activity ratio and the mineral component of the cation exchange capacity of the soil.  相似文献   

17.
Pig slurry in quantities of 200, 400, 500, 600, 800, and 1000 m3 ha-1 year-1 was added to two calcareous soils, which differed in concentration and type of clay minerals. The soils were cultivated with two successive crops of pepper and tomatoes grown in containers. A control was given no slurry. The soils were analysed after harvesting for exchangeable K+. Differences in exchangeable K+ were studied in relation to the concentration and type of clay minerals. The soil with the higher clay content and of the illite type retained K in the exchangeable form to a much greater extent than the soil with the low clay content. In the soil with the lower clay content, of the interstratified illitic — montmorillonite type, very little K was incorporated into the exchange complex. The exchange capacity being low, the amount of K added had little effect on the level of exchangeable K+.  相似文献   

18.
The effect of sodium chloride (NaCl), sodium sulfate (Na2SO4), and potassium chloride (KCl) on growth and ion concentrations of faba bean (Vicia faba L. cv. Troy) was studied. After 14 or 15 d of isoosmotic treatment with 100 mM NaCl or 75 mM Na2SO4, respectively, plants developed toxicity symptoms. These symptoms were characterized by local and nonchlorotic wilting spots, which later turned to black, necrotic spots. In contrast to NaCl or Na2SO4 treatment, plants treated with 100 mM KCl did not show these symptoms. The symptoms occurred on those leaves that accumulated highest concentrations of Na+ and showed highest Na+ : K+ ratios. Our results indicate that Na+ toxicity inducing K+ deficiency is responsible for the spot necrosis of faba bean. Additionally, chlorotic symptoms occurred. The concentrations of Na+ and Cl– were determined in chlorotic leaves and in isolated chloroplasts. The reduction of chlorophyll in leaves after NaCl exposure may be explained in terms of high Cl– concentrations in the chloroplasts and appears to depend on high Na+ concentrations. Chlorotic toxicity symptoms can be avoided by additional Mg2+ application.  相似文献   

19.
Nonexchangeable K+ constitutes a slowly available reserve that may significantly influence K+ fertility of soils. Laboratory and greenhouse experiments were conducted to characterize the K+ supply and nonexchangeable K+–release kinetics in 10 calcareous soils using 0.01 M CaCl2 and 0.01 M oxalic acid extractions. Total K+ uptake by wheat (Triticum aestivum L.) grown in the greenhouse was used to measure plant‐available K+. The release of K+ was characterized by an initial fast rate followed by a slower rate. The nonlinear relationship in the early stages of the K+ release may be attributed to the edge sites, and release of K+ from interlayer exchange sites may be responsible for the second part of the K+ release. Kinetics of K+ release was described best with power function, which showed the best fit of the four models tested. Parameters of kinetics models in 0.01 M CaCl2 were significantly related to K+ uptake by wheat. Potassium release was also correlated to initial NH4OAc‐extratable K+ and to HNO3‐extractable K+.  相似文献   

20.
Pot-culture studies of intensive cropping without potassium (K) application, taking three successive crops of rice on Sonakhali (Inceptisol) and Ranibundh (Alfisol) soils, revealed that all the forms of soil K declined after the third crop compared to the corresponding initial soil status. A similar trend was also found for nonexchangeable K extracted sequentially and termed as Step K and CR-K (constant rate K). The CR-K contents showed little variations with cropping. Except for the potential buffering capacity of the soil for K at equilibrium (PBCK 0) values, all the quantity/intensity (Q/I) parameters, namely activity ratio of potassium (ARK e), labile K (–ΔK0), specifically held K (KX), and total labile pool of K (KL) values, decreased in both the soils as they were subjected to repeated cropping. The PBCK 0 values changed to a smaller extent in both the soils. In both soils, the threshold levels for release of intermediate K in terms of activity ratio, exchangeable K, and K concentration in soil solution decreased after the third cropping as compared to the initial status. The dry-matter weight of rice, K concentration, and K uptake decreased with the cropping sequence. The difference in values of each parameter between initial status and the third crop was much wider in Inceptisol than in Alfisol.  相似文献   

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