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1.
Cobaltous sulfate heptahydrate (CoSO4·7H2O) was incorporated as filler into diglycidyl ether of bisphenol A (DGEBA) based epoxy resin system, to prepare organic-inorganic polymer hybrid materials. Mechanical tensile studies and dynamic mechanical analysis (DMA) were carried out in order to study the static and dynamic mechanical properties of the prepared hybrid films. Mechanical tensile studies were carried out at room temperature, at a test speed of 30 mm/min. Highest tensile strength of 24.74±2.42 MPa was achieved for 4.44 wt% filler level (FL), along with an increase in the value of Young’s modulus. Storage modulus (E′), loss modulus (E″), damping factor (tan δ) were obtained by DMA studies. Glass transition temperature (Tg) was obtained for pure epoxy and filled epoxy, for various FLs varying from 0.28 wt% to 5.00 wt%. Pure epoxy showed highest Tg value compared to filled epoxy hybrids. Highest storage modulus of 9.5 GPa was obtained for 2.22 wt% FL, which also showed highest loss modulus peak. Parameters like effectiveness coefficient (C) and crosslink density were calculated from the storage modulus data. Loss modulus and tan δ curves were analyzed to study the energy dissipation properties of prepared hybrid films. Activation energy (Ea) value for glass transition was obtained from damping factor (tan δ), which showed highest Ea value of 630.5 kJmol-1, for 4.44 wt% FL. DMA studies for various FLs were carried out at different test frequencies in order to study the changes in dynamic mechanical properties of the prepared hybrid materials with respect to frequency  相似文献   

2.
Surface properties of fibrous and ground cotton and linen were investigated by inverse gas chromatography (IGC) and the contact angle with different liquids was also measured on fabrics composed of both fibers. Results proved that dispersion component of surface tension (γ s d ) determined by IGC depends not only on the surface energy, but also on several factors influencing the adsorbability of probe molecules on the cellulosic substrates. For cotton samples, the trapping of n-alkanes among waxy molecules in the outer layer of fibers can be presumed. This effect results in larger γ s d for cotton fibers than for linen in spite of the higher wettability of the linen fabrics. Besides the surface energy and trapping effects, the grinding also influences the γ s d values. Specific enthalpy of adsorption (ΔH A ab ) of polar probes could be determined on all linen samples, but only on the ground cotton sample. Lewis acid-base character calculated for linen and ground cotton samples depends on the same effects as the γ s d does. The similar ΔH A ab values of chloroform (acidic) and THF (basic) measured on each of the samples support the conclusion that the surface character is amphoteric, which is also proved by the high ΔH A ab values of the amphoteric ethyl acetate and acetone probes.  相似文献   

3.
Statistical copolymers of 2-hydroxy-3-benzophenoxy propyl methacrylate (HBPPMA) and benzyl methacrylate (BzMA) in different feed ratios were synthesized by free radical copolymerization method at 60 °C in presence of AIBN initiator. The compositions of copolymer were estimated from 1H-NMR technique. The monomer reactivity ratios of HBPPMA and BzMA were calculated as r1 (rHBPPMA)=0.51±0.076 and r2 (rBzMA)=1.07±0.140 for Kelen-Tüdos method, and was estimated as r1=0.37±0.0006 and r2=0.64±0.0485 according to Fineman Ross equation. The average values estimated from the two methods showed that monomer reactivity ratio of benzyl methacrylate was a slightly high in comparison to HBPPMA. The copolymer system showed an azeotropic point, which is equal to M BzMA =m BzMA =0.43. DSC measurements showed that the Tg’s of poly(HBPPMA) and poly(BzMA) were 84 °C and 73 °C, respectively. The Tg in the copolymer system decreased with increase in benzyl methacrylate content. The decomposition temperature of poly(BzMA) and poly(HBPPMA) occurs in a single stage at about 207 °C and 260 °C, respectively. Those of HBPPMA-BzMA copolymer systems are between decomposition temperatures of two homopolymers. The dielectric constant, dielectric loss factor and electrical conductivity were investigated depend on the frequency of the copolymers. The highest dielectric constants depending on all the studied frequencies were recorded for the poly(HBPPMA) and the copolymer containing the highest HBPPMA unit. The dielectric constant for P(HBPPMA) and P(BzMA) at 1 kHz are 6.56 and 3.22, respectively. Also, those of copolymer systems were estimated between these two values. Similarly, poly(HBPPMA) and copolymers, which are prepared under the same conditions show the dissipation factor and conductivity as well.  相似文献   

4.
In this article, the thermo-mechanical characterization of poly(butylene terephthalate)/poly(tetramethylene oxide) (PBT/PTMO) is studied by thermal analysis, dynamic mechanical analysis, and uniaxial tensile tests. The results of poly(ether esters) show that the melting temperature is equal to T m =193 °C, which is 31 °C, lower than that of the melting temperature of poly(butylene terephthalate) (PBT). Its glass transition temperature, T g is equal to -61 °C, determined by DMA. The melting and cooling temperatures (T m , T c ) after aging at T0+48 h and T0+week are virtually unchanged. Moreover, the results of the tensile tests show that the effect of the low deformation rate reduces the friction resulting from the sliding mechanisms between the amorphous and crystalline parts.  相似文献   

5.
In order to prepare antimicrobial regenerated cellulose fibers from blended spinning solutions, three non-water soluble polymeric guanidine derivatives, polyhexamethylene guanidine dodecyl benzene sulfonate (PHGDBS), polyhexamethylene guanidine dodecyl sulfate (PHGDSA), and polyhexamethylene guanidine laurylsulfonate (PHGLSO) were synthesized. And the chemical structure of these agents was verified by element analysis, Fourier transform infrared spectroscopy (FTIR), and proton nuclear magnetic resonance (1H-NMR). The antimicrobial activity of the three agents as well as cellulose films containing PHGDBS was also studied. The results showed that the compounds we prepared had strong properties against both bacterial and fungus, including Staphylococcus aureus (S. aureus), Escherichia coli (E. coli), Candida albicans, and Aspergillus niger. Moreover, it was found that three antimicrobial agents were insoluble in water but they can dissolve in solvents of cellulose such as 1-butyl-3-methylimidazolium chloride ([BMIM]Cl) and N-methylmorpholine-N-oxide monohydrate (NMMO·H2O). Meanwhile, it was also proved that [BMIM]Cl had little effect on the antimicrobial properties of these agents. The cellulose films containing only 1.0 wt% PHGDBS showed 99.94 % and 96.95 % bacterial reduction rates for S. aureus and E. coli, respectively. Moreover, still over 91 % of bacterial reduction was maintained after 15 laundering cycles. It suggests that the three agents will be suitable to prepare antimicrobial regenerated cellulose fibers or films.  相似文献   

6.
Based on data collected from rice fields under drying–wetting cycle condition, the procedure of dual-crop coefficient (K cd) approaches was calibrated and validated to reveal its feasibility and improve its performance in rice evapotranspiration (ET c) estimation. It was found that K cd based on FAO-recommended basal crop coefficients (K cb) underestimated dual-crop coefficients in monsoon climate region in East China. The recommended coefficient (K cp) value of 1.2 was not high enough to reflect the pulse increase of rice ET c after soil wetting. The K cb values were calibrated as 1.52 and 0.63 in midseason and late season, and the K cp value was adjusted as 1.29 after soil wetting in rice field under drying–wetting cycle condition. The dual-crop coefficient curves based on locally calibrated K cbCal and K cpCor matched well with the measured crop coefficients and performed well in calculating rice evapotranspiration from paddy fields under drying–wetting cycle condition. So it can be concluded that the procedure of dual-crop coefficient method is feasible in rice ET c estimation, and locally calibrated K cb and K cp can improve its performance remarkably.  相似文献   

7.
In the present work, oil adsorption, desorption, and resorption of poly(lauryl methacrylate-co-hydroxyethyl methacrylate) P(LMA-co-HEMA) were evaluated with different oils by a gravimetric method. Adsorption kinetics were modeled using pseudo-first-order and pseudo-second-order equations. Polymer network parameters of P(LMA-co-HEMA) regarding average molecular weight (Mc) between two crosslink piontss can be calculated by oil absorbency at equilibrium (Q e ), the solubility parameter (δ) and polymer-solvent interaction parameter (χ) with Flory-Huggins relation. The results showed pseudo-second-order model has a better fit to the oil adsorption kinetic data The desorption can be analyzed by fitting a prediction of exponential-like decay to the deswelling curves. A typical oil desorption exhibited two stages: a burst release driven by concentration gradient, and a slow release controlled by diffusion and the elastic recovery of polymer networks. For reusability, the resorption behavior of P(LMA-co-HEMA) was also investigated. It was worth noting that oil resorption was faster than the first adsorption due to potential passages. Moreover, the adsorption capacity was not significantly changed after regeneration.  相似文献   

8.
PLA/PLA-g-ABS blends were prepared and evaluated for mechanical properties performance. Firstly, carboxylic acid functionalized ABS particles were synthesized by grafting polymethacrylic acid (PMAA) onto ABS particle surface using potassium persulfate as an initiator. The reaction was followed by FTIR analysis. The resultant carboxylated ABS was melt mixed with virgin PLA in an internal mixer to obtain PLA/PLA-g-ABS blends. The obtained PLA/PLA-g-ABS blends were subject to injection molding to obtain specimens for testing evaluation. It was found that impact resistance values significantly outperformed neat PLA by 60 %, 87 %, and 150 % for PLA/PLA-g-ABS 10 wt%, PLA/PLA-g-ABS 20 wt%, and PLA/PLA-g-ABS 30 wt%, respectively. A significant increase in impact strength was contributable to ABS rubber which exhibited even dispersion and good interfacial adhesion. The impact strength was dependent on the percent loading of PLAg-ABS; the more the PLA/PLA-g-ABS the higher the impact strength value. In a similar manner, tensile strength increases when loaded with PLA/PLA-g-ABS albeit at lesser effect. Considering the percent elongation, a massive increase in percent elongation was recorded in case of PLA/PLA-g-ABS 20 wt% and PLA/PLA-g-ABS 30 wt%, implying that these blends were extremely flexible and tough when compared to neat PLA, control, and PLA/PLA-g-ABS 10 wt%.  相似文献   

9.

Background

The rice Pi2/9 locus harbors multiple resistance (R) genes each controlling broad-spectrum resistance against diverse isolates of Magnaporthe oryzae, a fungal pathogen causing devastating blast disease to rice. Identification of more resistance germplasm containing novel R genes at or tightly linked to the Pi2/9 locus would promote breeding of resistance rice cultivars.

Results

In this study, we aim to identify resistant germplasm containing novel R genes at or tightly linked to the Pi2/9 locus using a molecular marker, designated as Pi2/9-RH (Pi2/9 resistant haplotype), developed from the 5′ portion of the Pi2 sequence which was conserved only in the rice lines containing functional Pi2/9 alleles. DNA analysis using Pi2/9-RH identified 24 positive lines in 55 shortlisted landraces which showed resistance to 4 rice blast isolates. Analysis of partial sequences of the full-length cDNAs of Pi2/9 homologues resulted in the clustering of these 24 lines into 5 haplotypes each containing different Pi2/9 homologues which were designated as Pi2/9-A5, ?A15, ?A42, ?A53, and -A54. Interestingly, Pi2/9-A5 and Pi2/9-A54 are identical to Piz-t and Pi2, respectively. To validate the association of other three novel Pi2/9 homologues with the blast resistance, monogenic lines at BC3F3 generation were generated by marker assisted backcrossing (MABC). Resistance assessment of the derived monogenic lines in both the greenhouse and the field hotspot indicated that they all controlled broad-spectrum resistance against rice blast. Moreover, genetic analysis revealed that the blast resistance of these three monogenic lines was co-segregated with Pi2/9-RH, suggesting that the Pi2/9 locus or tightly linked loci could be responsible for the resistance.

Conclusion

The newly developed marker Pi2/9-RH could be used as a potentially diagnostic marker for the quick identification of resistant donors containing functional Pi2/9 alleles or unknown linked R genes. The three new monogenic lines containing the Pi2/9 introgression segment could be used as valuable materials for disease assessment and resistance donors in breeding program.
  相似文献   

10.
The phenolic compounds, color and antioxidant capacity of gluten-free pasta prepared with non-conventional flours such as chickpea (CHF), unripe plantain (UPF), white maize (WMF) and blue maize (BMF) were analyzed. Fifteen phenolic compounds (five anthocyanins, five hydroxybenzoic acids, three hydroxycinnamic acids, one hydroxyphenylacetic acid and one flavonol) were identified in pasta prepared with blue maize, and 10 compounds were identified for samples prepared with white maize. The principal component analysis (PCA) led to results describing 98% of the total variance establishing a clear separation for each pasta. Both the proportion (25, 50 and 75%) and type of maize flour (white and blue) affected the color parameters (L*, C ab *, h ab and ΔE* ab ) and antioxidant properties (DPPH, ABTS and FRAP methods) of samples, thus producing gluten-free products with potential health benefits intended for general consumers (including the population with celiac disease).  相似文献   

11.
Water management is an important factor in regulating soil respiration and the net ecosystem exchange of CO2 (NEE) between croplands and atmosphere. However, how water management affects soil respiration and the NEE of paddy fields remains unexplored. Thus, a 2-year field experiment was carried out to study the effects of controlled irrigation (CI) during the rice season on the variation of soil respiration and NEE, with flooding irrigation (FI) as the control. A decrease of irrigation water input by 46.39% did not significantly affect rice yield but significantly increased irrigation water use efficiency by 0.99 kg m?3. The soil respiration rate of CI paddy fields was larger than that of FI paddy fields except during the ripening stage. Natural drying management during the ripening stage resulted in a significant increase of the soil respiration rate of the FI paddy fields. Variations of NEE with different water managements were opposite to soil respiration rates during the whole rice growth stages. Total CO2 emission of CI paddy fields through soil respiration (total R soil) increased by 11.66% compared with FI paddy fields. The increase of total R soil resulted in the significant decrease of total net CO2 absorption of CI paddy fields by 11.57% compared with FI paddy fields (p < 0.05). There were inter-annual differences of soil respiration and the NEE of paddy fields. Frequent alternate wetting and drying processes in the CI paddy fields were the main factors influencing soil respiration and NEE. CI management slightly enhanced the rice dry matter amount but accelerated the consumption and decomposition of soil organic carbon and significantly increased soil respiration, which led to the decrease of net CO2 absorption. CI management and organic carbon input technologies should be combined in applications to achieve sustainable use of water and soil resources in paddy fields.  相似文献   

12.
Phthorimaea operculella (Zeller) is one of the most common insect pests of cultivated potato in tropical and subtropical regions. In this research, a potential strategy to improve the insecticidal activity of plant essential oils for the effective management of P. operculella was studied. The insecticidal and residual effects of nanofiber oil (NFO) and pure essential oil (PEO) of Cinnamomum zeylanicum were assessed on PTM under laboratory conditions. The nanofibers were made by the electrospinning method using polyvinyl alcohol (PVA) polymer. The morphological characteristics of the nanofibers were evaluated by scanning electron microscopy and Fourier transform infrared spectroscopy. The chemical constituents of cinnamon essential oil (EO) were detected by GC/MS. Fumigant toxicity of NFO and PEO were evaluated on different growth stages (egg, male and female adults) of P. operculella. SEM and FTIR analyses confirmed the presence of EO on the nanofiber structure. The yield of the EO from C. zelanicum on the nanofibers was 1.86%. GC/MS analysis showed that cinnamaldehyde was the primary constituent (69.88%) of cinnamon EO. LC50 values of C. zelanicum EO and NFO were 4.92 and 1.76 μl/l air for eggs, 0.444 and 0.212 μl/l air for female adults, and 0.424 and 0.192 μl/l air for male adults, respectively. Fumigant bioassays revealed that NFO was more toxic than C. zeylanicum oil against at all stages of P. operculella. The residual effect of PEO and NFO was evaluated against the egg stage of the P. operculella. NFO lost insecticidal effectiveness 47 days after application, while the efficacy of PEO decreased 15 days after application. Our results suggest that NFO of C. zeylanicum can be used as an effective new tool for the management of P. operculella.  相似文献   

13.
Air temperature (Ta) is commonly used for modeling rice phenology. However, since the growing point of rice is under water during the vegetative and the early part of the reproductive period, water temperature (Tw) is likely to have a greater influence on crop developmental rates than Ta during this period. To test this hypothesis, we monitored Tw, Ta, and crop phenology in three commercial irrigated rice fields in California, USA. Sampling locations were set up on along a transect from the water inlet into the field. (Water warms up as it moves into the field.) Ta averaged 22.7 °C across sampling locations within each field, but average seasonal Tw increased from 22 °C near the inlet to 23.4 °C furthest away from the inlet. Relative to Tw furthest from the inlet, low Tw near the inlet delayed time to panicle initiation (PI 5 days) and heading (HD 8 days) and the appearance of one yellow hull on the main stem panicle (R7 9 days). Using Tw instead of Ta when the active growing point is under water until booting (midway between PI and HD) in a thermal time model improved accuracy (root-mean-square error, RMSE) for predicting time to PI by 2.5 days and HD by 1.6 days and R7 by 1.8 days. This model was further validated under more typical field conditions (i.e., not close to cold water inlets) in six locations in California. Under these conditions, average Tw was 2.6 °C higher than Ta between planting and booting, primarily due to higher daily maximum Tw values. Using Tw in the model until booting improved RMSE by 1.2 days in predicting time to HD. Using Tw instead of Ta during this period could improve the accuracy of rice phenology models.  相似文献   

14.
15.
In this study, decoloration of Direct Blue 71 (DB71) and Direct Red 23 (DR23) has been discussed by using Multiwalled Carbon Nanotubes (MWCNTs) and Hydrogen peroxide under UV radiation. The purpose of this study is removal of organic compounds by using carbon nanotubes that are effective adsorbents for different types of pollutants, due to their porous nature and large surface area. It also causes catalytic decomposition of hydrogen peroxide. Adsorption rate was investigated under various parameters (initial dye concentration, salt, temperature and pH). The main objective of this study is to appraise the synergic effect between H2O2 and MWCNTs under UV radiation. The dye adsorption results of spectrophotometer, showed that by decreasing the dye concentration from 0.2 g/l to 0.05 g/l with the optimal value of MWCNTs 0.2 g/l and hydrogen peroxide 2 g/l at pH=4 and 6 cm distance from the UV lamp, the dye removal increased.  相似文献   

16.
In this study, the tetramido macrocyclic iron complex (Fe-TAML) was successfully synthesized, and then it was characterized using 1H nuclear magnetic resonance (1H NMR), electrospray ionization mass spectrometry (EIS-MS) and elemental analysis. An activated peroxide system was established for low-temperature bleaching of cotton by combining the synthesized catalyst (Fe-TAML) with hydrogen peroxide. Experimental results showed that the Fe-TAML/H2O2 bleaching system exhibited effective bleaching performance in the use of 2 μM Fe-TAML, 20 g/l H2O2, 1 g/l NaHCO3, 2 g/l scouring agent and 2 g/l wetting agent at 60 °C for 60 min. In comparison with the conventional bleaching system, the Fe-TAML/H2O2 system provided bleached cotton with a superior degree of whiteness, higher tensile strength and acceptable water absorbency. The application of Fe-TAML was expanded and the activated peroxide system may provide a green approach for the cotton bleaching.  相似文献   

17.

Background

The DEFECTIVE IN OUTER CELL LAYER SPECIFICATION 1 (DOCS1) gene belongs to the Leucine-Rich Repeat Receptor-Like Kinase (LRR-RLK) subfamily. It has been discovered few years ago in Oryza sativa (rice) in a screen to isolate mutants with defects in sensitivity to aluminum. The c68 (docs1–1) mutant possessed a nonsense mutation in the C-terminal part of the DOCS1 kinase domain.

Findings

We have generated a new loss-of-function mutation in the DOCS1 gene (docs1–2) using the CRISPR-Cas9 technology. This new loss-of-function mutant and docs1–1 present similar phenotypes suggesting the original docs1–1 was a null allele. Besides the aluminum sensitivity phenotype, both docs1 mutants shared also several root phenotypes described previously: less root hairs and mixed identities of the outer cell layers. Moreover, our new results suggest that DOCS1 could also play a role in root cap development. We hypothesized these docs1 root phenotypes may affect gravity responses. As expected, in seedlings, the early gravitropic response was delayed. Furthermore, at adult stage, the root gravitropic set angle of docs1 mutants was also affected since docs1 mutant plants displayed larger root cone angles.

Conclusions

All these observations add new insights into the DOCS1 gene function in gravitropic responses at several stages of plant development.
  相似文献   

18.

Background

Kongyu 131 is an elite japonica rice variety of Heilongjiang Province, China. It has the characteristics of early maturity, superior quality, high yield, cold tolerance and wide adaptability. However, there is potential to improve the yield of Kongyu 131 because of the relatively few grains per panicle compared with other varieties. Hence, we rebuilt the genome of Kongyu 131 by replacing the GRAIN NUMBER1a (Gn1a) locus with a high-yielding allele from a big panicle indica rice variety, GKBR. High-resolution melting (HRM) analysis was used for single nucleotide polymorphism (SNP) genotyping.

Results

Quantitative trait locus (QTL) analysis of the BC3F2 population showed that the introgressed segment carrying the Gn1a allele of GKBR significantly increased the branch number and grain number per panicle. Using 5 SNP markers designed against the sequence within and around Gn1a, the introgressed chromosome segment was shortened to approximately 430 Kb to minimize the linkage drag by screening recombinants in the target region. Genomic components of the new Kongyu 131 were detected using 220 SNP markers evenly distributed across 12 chromosomes, suggesting that the recovery ratio of the recurrent parent genome (RRPG) was 99.89%. Compared with Kongyu 131, the yield per plant of the new Kongyu 131 increased by 8.3% and 11.9% at Changchun and Jiamusi, respectively.

Conclusions

To achieve the high yield potential of Kongyu 131, a minute chromosome fragment carrying the favorable Gn1a allele from the donor parent was introgressed into the genome of Kongyu 131, which resulted in a larger panicle and subsequent yield increase in the new Kongyu 131. These results indicate the feasibility of improving an undesirable trait of an elite variety by replacing only a small chromosome segment carrying a favorable allele.
  相似文献   

19.
The effect of essential oil (EO) from anise (Pimpinellia anisum) on the mortality of young larvae of Colorado potato beetles has been studied. In our bioassays, P. anisum EO significantly increased the mortality of the second instar larvae of L. decemlineata. Significantly different values of LD50 and LD90 were established for acute (LD50 = 1.76, and LD90 = 8.29) as well as chronic toxicity (LD50 = 0.45, and LD90 = 1.01). Decrease of both values over experimental period was evident, which showed that the larval mortality was slow and cumulative. The composition of EO used for biological experiments was also assessed. The main component detected in EO from P. anisum was anethole (79.87%), followed by anisaldehyde (7.74%), estragole (5.88%) and β-linalool (1.07%). Within five days, residual concentration of EO decreased from 3.87 mg/g of dry weight immediately after foliar applications to 0.9 mg per g of dry weight. The effect of this slow evaporation could be explained by dominant presence of anethole or by the type of formulation and the addition of oil and tween. Results of our study demonstrate that EO from P. anisum has insecticidal properties that may lead to the development of new organic products for the control of Colorado potato beetles.  相似文献   

20.
Drought occurs throughout the world, affecting people more than any other major natural hazards. An important requirement for mitigating the impact of drought is an effective method of forecasting future drought events. This study investigated the applicability of Adaptive neuro-fuzzy inference system (ANFIS) for drought forecasting and quantitative value of drought indices, the Standardized Precipitation Index (SPI) and Standardized Precipitation Evapotranspiration Index (SPEI). Khanhhoa Province Vietnam with three meteorological stations was selected as the study area. The sea surface temperature anomalies (SSTA) events at NinoW and Nino4 zones were selected as input variables to forecast drought. Fifteen ANFIS forecasting models for SPI/SPEI (1, 3, 6, and 12 months) were trained and tested. The results show the performance of the ANFIS forecasting models for SPI/SPEI of all stations is equivalent and most ANFIS forecasting models for SPEI are better than SPI; the performance of the ANFIS forecasting models for SPI/SPEI-12 is better than other ANFIS models for SPI/SPEI-1 to SPI/SPEI-6; the models with high performance are M10–M13; model with the highest performance is M12 model. The results of this research showed that ANFIS forecasting models with SSTAs events as input variables can forecast longer term than SPI and precipitation as input variables. The ANFIS forecasting model with SSTA events as input variables can be successfully applied and provide high accuracy and reliability for drought forecasting.  相似文献   

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