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1.
ABSTRACT

Long-term fertilization tests evaluated rice (Oryza sativa) productivity in relation to application of nitrogen (N)-phosphorus (P)-potassium (K) (120-34.9-66.7 kg ha? 1, respectively) during 1967–1972 and N-P-K (150-43.7-83.3 kg ha? 1, respectively) during 1973–2000. The comparison treatments (NP, PK, and NK) and the control (not fertilized) were selected for calculating nutrient efficiency. Rice grain yield increased at a 17.78 kg ha? 1 yr? 1 in the control, mainly due to development of improved cultivars. Phosphorus management was found to be important for indigenous fertility and rice productivity in this paddy soil. Yield increased significantly with P fertilization. Without N fertilization (PK), rice productivity increased 56.85 kg ha? 1 yr? 1 from 62% of NPK at the initial stage to 74% after passing 34 years, which might be affected by increasing biological N fixation with P accumulation in soil. In NK treatment, rice yield increased at a relatively low rate (37.82 kg hr? 1 yr? 1) from the same rice productivity with that of NPK in 1967 to 91% after 34 years. In comparison, yield increased at a high rate (62.82 kg hr? 1 yr? 1) without K fertilization (NP) from ca. 90% of NPK and might exceed the yield of NPK after 64 years of long-term fertilization. Therefore, K fertilization level might be readjusted after long-term fertilizing in paddy soil.  相似文献   

2.
A field plot experiment on fertilization with N, Mg and P in Scots pine forest was established. The experiment had a factorial design with three levels of N (0, 30 and 90 kg ha?1), two levels of Mg (0 and 1.5 kg ha?1) and two levels of P (0 and 5.3 kg ha?1). The application was done annually. There was a significant growth increase for the two N treatments. During a period of 5-years the mean increase in volume increment was 2.3 and 4.5 m3 ha?1 for the 30 N and 90 N kg ha?1 yr?1 treatments, respectively. This represents a percentage increase in volume increment of 53 and 102% compared to the untreated control plots. No significant growth effect of P and Mg application was detected, either alone or in combination with N. The needle nutrient concentrations have been followed along with the annual measurements. An increase in N-concentration was detected after the first growing season in the N treated trees. After five years the Mg concentrations in the needles are lower in these treatments. The one year old needles have concentrations as low as 0.05% Mg. No visible deficiency symptoms have been observed. The field experiment effects demonstrates that N is still the most limiting nutrient under these conditions and that there is a relative large potential for N accumulation in these forest types without negative effects.  相似文献   

3.
On acid sandy soils of Niger (West Africa) fertilizer N recovery by pearl millet (Pennisetum glaucum L.) is often more than 100 per cent in years with normal or above average rainfall. Biological nitrogen fixation (BNF) by N2-fixing bacteria may contribute to the N supply in pearl millet cropping systems. For a long-term field experiment comprising treatments with and without mineral fertilizer (F) and with and without crop residue application (CR) a N balance sheet was calculated over a period of six years (1983-1988). After six years of successive millet cropping total N uptake (36-77 kg N ha?1 yr?1) was distinctly higher than the amount of fertilizer N applied (30 kg N ha?1 yr?1). The atmospheric input of NH4-N and NO3-N in the rainwater was about 2 kg N ha?1 yr?1, 70 % in the form of NH4-N. Gaseous NH3 losses from urea (broadcast, incorporated) were estimated from other experiments to amount to 36 % of the fertilizer N applied. Nitrogen losses by leaching (15 to > 25 kg N ha?1 yr?1) were dependent on the treatment and on the quantity and distribution of single rainfall events (>50 mm). Decline in total soil N content (0-60 cm) ranged from 15 to 48 kg N ha?1 yr?1. The long-term N balance (1983-1988) indicated an annual net gain between 6 (+CR-F) and 13 (+CR+F) kg N ha?1 yr?1. For the control (-CR-F) the long-term N balance was negative (10 kg N ha?1 yr?1). In the treatment with crop residues only, the N balance was mainly determined by leaching losses, whereas in treatments with mineral fertilizer application the N balance depended primarily on N removal by the millet crop. The annual net gain in the N balance increased from 7 kg ha?1 with mineral fertilizer to 13 kg ha?1 in the combination mineral fertilizer plus crop residues. In both the rhizosphere and the bulk soil (0-15 cm), between 9 and 45% of the total bacterial population were N2-fixing (diazotrophic) bacteria. The increased N gain upon crop residue application was positively correlated with an increase in the number of diazotrophic and total bacteria. The data on bacterial numbers suggest that the gain of N in the longterm N balance is most likely due to an N input by biological nitrogen fixation. In addition, evidence exists from related studies that the proliferation of diazotrophs and total bacteria in the rhizosphere due to crop residue application stimulated root growth of pearl millet, and thus improved the phosphorus (P) acquisition in the P deficient soil.  相似文献   

4.
We estimated the total inorganic fluxes of nitrogen (N), sulfur (S), chloride (Cl?, sodium (Na+, calcium (Ca2+, magnesium (Mg2+, potassium (K+ and hydronium (H+. The resistance deposition algorithm that is programmed as part of the CALMET/CALPUFF modeling system was used to generate spatially-distributed deposition velocities, which were then combined with measurements of urban and rural concentrations of gas and particle species to obtain dry deposition rates. Wet deposition rates for each species were determined from rainfall concentrations and amounts available from the National Acid Deposition Program (NADP) monitoring network databases. The estimated total inorganic nitrogen deposition to the Tampa Bay watershed (excluding Tampa Bay) was 17 kg-N ha?1 yr?1 or 9,700 metric tons yr?1, and the ratio of dry to wet deposition rates was ～2.3 for inorganic nitrogen. The largest contributors to the total N flux were ammonia (NH3 and nitrogen oxides (NO x at 4.6 kg-N ha?1 yr?1 and 5.1 kg-N ha?1 yr?1, respectively. Averaged wet deposition rates were 2.3 and 2.7 kg-N ha?1 yr?1 for NH4 + and NO3 ?, respectively.  相似文献   

5.
Carbon sequestration in 30 yr old Norway spruce in south Sweden following manipulation of nutrient and water availability is presented. The site has an annual precipitation of 1100 mm and a deposition of about 20 kg N and 25 kg S per ha?1 yr?1. The soil type is a poorly developed podzol. Treatment include irrigation; artificial drought; ammonium sulphate addition; nitrogen-free-fertilization and irrigation with liquid fertilizers including a complete set of nutrients. The experiment has a randomized block design with four replicates per treatment. A comprehensive investigation of the above ground C storage on an areal basis was made at the start of the experiment and after 3 yr of treatment. After 3 yr of treatment with simulated N-S deposition using ammonium sulphate (100 kg N, 114 kg S ha?1 yr?1), C accumulation rates in the above ground compartments had increased by 37%. Similarly, irrigation caused increased C accumulation rates by 25%, whereas simulated drought during the vegetation period during 2 yr followed by 1 yr of recovery caused a 15% reduction of the C accumulation rates. Irrigation combined with liquid fertilization (100 kg N ha?1 yr?1), including all important nutrient elements, led to 65% increase in C accumulation rates compared to the control. The C sequestration of the latter treatment gradually increased and, during yr 5 of treatment, 8.6 Mg C ha?1 accumulated in stems and branches, compared to 3.6 Mg ha?1 for the control. It is concluded that there is a strong interaction between N-deposition and C accumulation rates in Norway spruce in south Sweden. The C accumulation rates are also sensitive to water availability. The study indicates a great potential to cultivate Norway spruce in south Sweden as a renewable energy source. A shift in energy source from fossil fuels to renewable energy sources will directly reduce the net emissions of CO2 to the atmosphere.  相似文献   

6.
The concentration of ammonium and nitrate in precipitation has increased during this century. The deposition of N compounds (wet + dry) is reaching 30 to 40 kg ha?1yr?1 in many areas in Central Europe and above 20 kg in the southern parts of Scandinavia. In extreme situations throughfall data indicate depositions above 60 kg ha?1yr?1 in Central Europe and above 40 kg ha?1yr?1 in south Sweden. Very high depositions are observed on slopes at forest edges and adjacent to areas with animal farms and manure spreading. In areas with low N deposition almost all deposited N (>95%) will be absorbed in the tree canopies or in the soil. In areas with high deposition an increased outflow is observed which in some cases reach 10 to 15 kg ha-lyr-1. The increased output is an indication of N saturation of the ecosystem and it leads to acidification effects in soils, soilwater, groundwater and surface waters.  相似文献   

7.
Critical loads for nitrogen deposition on forest ecosystems   总被引：2，自引：0，他引：2  
Critical loads for N deposition are derived from an ecosystem's anion and cation balance assuming that the processes determining ecosystem stability are soil acidification and nitrate leaching. Depending on the deposition of S, the parent soil material, and the site quality critical N deposition rates will range between 20 to 200 mmol m?2 yr?1 (3 to 14 kg ha?1 yr?1) on silicate soils and reach 20 to 390 mmol m?2 yr?1 (3 to 48 kg ha?1) on calcareous soils.  相似文献   

8.
Critical loads for N and S on Dutch forest ecosystems have been derived in relation to effects induced by eutrophication and acidification, such as changes in forest vegetation, nutrient imbalances, increased susceptibility to diseases, nitrate leaching, and Al toxicity. The criteria that have been used are N contents in needles, nitrate concentrations in groundwater (drinking water), and NH4/K ratios, Ca/Al ratios, and Al concentrations in the soil solution. Assuming an equal contribution of N and S, all effects seem to be prevented at a total deposition level below 600 molc ha?1 yr?1 due to N uptake by stemwood and acid neutralization by base cation weathering. The most serious effects will probably be prevented at total deposition levels between 1500 and 2000 molc ha?1 yr?1. The current average deposition in the Netherlands is 4900 molc ha?1 yr?1.  相似文献   

9.
Forest soils may become an increasingly important source of N2O, due to disturbances to the forest ecosystem (e.g. fertilization to increase growth, or atmospheric deposition of air-borre nitrogen compounds such as NH3, NO3 and NOx). A lysimeter experiment was used to study the effects of different amounts of N input [0 (control), 30 kg (Medium) and 90 kg (High) N ha?1 y?1 as NH4NO3] on fluxes of N2O, measured by the close chamber method. The estimated annual N2O flux were about 0.4 kg N2O-N ha?1 for control, 0.9 kg N2O-N ha?1 for medium N and 1.8 kg N2O-N ha?1 for high N treatments. The relation between the estimated annual N2O flux and fertilizer dose showed an almost perfect proportionality between fertilizer dose and the increase in N2O flux. This is important, since one crucial question is wether we can extrapolate results from high N-doses to situations with low amounts of N inputs prevailing in forests exposed to moderate input of N. The increase in N2O fluxes from the control to the fertilised treatments corresponds to 1.7% of the annual N input in the medium N treatments and 1.6% of the annual input in the high N treatment.  相似文献   

10.
Experimental additions of ammonium sulphate to a nitrogen-poor dry heathland have been carried out since 1989. There are four nitrogen treatments: a control (receiving artificial rain only), a low treatment which receives an additional 7.7 kg N ha?1 yr?1, a high treatment receiving 15.4 kg N ha?1 yr?1 and an alternating treatment which receives either the control or the high nitrogen additions, in alternate years. The estimated background deposition at the study site is 13–18 kg N ha?1 yr?1, a value similar to the critical load that has been suggested for the conversion of lowland heath to grassland. Over the past 5 years there have been significant stimulations in shoot growth, flowering, canopy density and litter production. Flowering, in particular, strongly reflects nitrogen additions in the alternating treatment. Current models of the response of dry Calluna heathlaud to enhanced nitrogen deposition suggest that higher tissue nitrogen levels will occur and will be accompanied by heightened sensitivity to secondary stresses. This may in turn lead to canopy breakdown and replacement by grassland. The application of nitrogen at deposition rates only slightly in excess of the critical load over five years has produced small, non-significant increases in shoot nitrogen content. However, there is clear evidence of a large positive effect on shoot growth, flowering, litter production and canopy density of Calluna. The observation of these responses at the application rates used in this study supports the current proposals for critical loads of nitrogen for lowland heaths.  相似文献   

11.
Twenty fertilization experiments were set up in 1985 and 1986 in the Vosges mountains, using mostly calcareous or Mg fertilizers, in order to verify whether fertilization can attenuate defoliation and yellowing recently recorded in Silver fir and Norway spruce. In the Ardennes, a fertilization experiment set up in Norway spruce stands prior to the appearance of yellowing was assessed. In these areas, the total acid deposition is about 2 kg eq H+ ha−1 yr−1. Nitrogen deposition is much more important in the Ardennes (52 kg N ha−1 yr−1 in form of wet and dry deposition) than in the Vosges (16 kg N ha−1 yr−1). The results in the eight adult stands showed no uniform reaction to the treatments. Spontaneous improvement, further deterioration independently of the treatment, as well as a positive reaction to fertilization were observed. Additional N or P fertilization sometimes had a beneficial effect on Ca or Mg treatments. The selection of the stands with the best response turns out to be difficult, as the nutrient contents of needles alone seem not to be a satisfactory criterion for selection. Young plantations reacted positivley to the treatments. Soluble Mg fertilizer leads to an immediate response. Low solubility Ca-Mg fertilizers (Ca-Mg lime) did not produce reactions until three years after the application. In the Ardennes, in a 40 yr old spruce stand suffering from severe Mg deficiency, a Ca and Ca-phosphate fertilization applied 5 yr before yellowing appeared had positive effects on crown density, discoloration and wood production. Conversely, a single N fertilization in this experiment, as well as in a young plantation in the Vosges, had a marked negative effect on Mg nutrition, even at low levels.  相似文献   

12.
Twenty fertilization experiments were set up in 1985 and 1986 in the Vosges mountains, using mostly calcareous or Mg fertilizers, in order to verify whether fertilization can attenuate defoliation and yellowing recently recorded in Silver fir and Norway spruce. In the Ardennes, a fertilization experiment set up in Norway spruce stands prior to the appearance of yellowing was assessed. In these areas, the total acid deposition is about 2 kg eq H+ ha–1 yr–1. Nitrogen deposition is much more important in the Ardennes (52 kg N ha–1 yr–1 in form of wet and dry deposition) than in the Vosges (16 kg N ha–1 yr–1). The results in the eight adult stands showed no uniform reaction to the treatments. Spontaneous improvement, further deterioration independently of the treatment, as well as a positive reaction to fertilization were observed. Additional N or P fertilization sometimes had a beneficial effect on Ca or Mg treatments. The selection of the stands with the best response turns out to be difficult, as the nutrient contents of needles alone seem not to be a satisfactory criterion for selection. Young plantations reacted positivley to the treatments. Soluble Mg fertilizer leads to an immediate response. Low solubility Ca-Mg fertilizers (Ca-Mg lime) did not produce reactions until three years after the application. In the Ardennes, in a 40 yr old spruce stand suffering from severe Mg deficiency, a Ca and Ca-phosphate fertilization applied 5 yr before yellowing appeared had positive effects on crown density, discoloration and wood production. Conversely, a single N fertilization in this experiment, as well as in a young plantation in the Vosges, had a marked negative effect on Mg nutrition, even at low levels.  相似文献   

13.
Atmospheric deposition of N and S on terrestrial and aquatic ecosystems causes effects induced by eutrophication and acidification. Effects of eutrophication include forest damage, NO3 pollution of groundwater and vegetation changes in forests, heathlands and surface waters due to an excess of N. Effects of acidification include forest damage, groundwater pollution, and loss of fish populations due to Al mobilization. Critical loads (deposition levels) for N and S on terrestrial and aquatic ecosystems in the Netherlands related to these effects have been derived by empirical data and steady-state acidification models. Critical loads of N generally vary between 500 and 1500 mol c ha?1 yr?1 for forests, heathlands and surface waters and between 1500 and 3600 for phreatic groundwaters. Critical loads of total acid (S and N) vary between 300 to 500 mol c ha?1 yr?1 for phreatic groundwaters and surface waters and between 1100 to 1700 mol ha?1 yr?1 for forests. On the basis of the various critical loads a deposition target for total acid of 1400 mol c ha?1 yr?1 has been set in the Netherlands from which the N input should be less than 1000 mol c ha?1 yr?1. This level, to be reached in the year 2010, implies an emission reduction of 80–90% in SO2, NO x and NH3 in the Netherlands and of about 30% in neighboring countries compared to 1980 emissions.  相似文献   

14.
Organic amendments recycle nutrients, but N2O emissions are both environmental and agronomic concerns. We conducted a 4-year field experiment to determine no-till barley (Hordeum vulgare L.) yield and nutrient uptake and soil N2O emissions following a single application of six amendment treatments: (1) no amendment (Check); (2) synthetic N fertilizer (Fert); (3) fresh beef cattle feedlot manure (ManureF); (4) beef cattle feedlot manure compost (CompostR); (5) beef cattle feedlot manure composted with cattle mortalities (CompostM); and (6) separated solids from anaerobically digested cattle feedlot manure (ADM). Barley grown in Year 1 (2006), Year 2 (2007), and Year 4 (2009) (with Year 3 (2008) under fallow) had higher grain yields from ManureF (4.73 Mg ha?1) in Year 2 and ADM (6.30 Mg ha?1) in Year 4 (p < 0.05) than other treatments. The grain N and P contents were not affected (p > 0.05), but N uptake over 3 years (112.8 kg N ha?1 yr?1), and P uptake in Year 1 (19.1 kg ha?1 yr?1) and Year 2 (14.3 kg ha?1 yr?1) from ManureF, were higher (p < 0.05×) than other treatments. The cumulative N2O emissions from ManureF in Year 1 (1.488 kg N ha?1) and from ADM in Year 2 (1.072 kg N ha?1) were higher (p < 0.05) than other treatments while the fraction of applied N emitted as N2O was small (0.00 to 0.79%) and not affected by treatment. However, the percentages of applied N emitted as N2O from compost and ADM were similar to synthetic fertilizer and livestock manure.  相似文献   

15.
Critical acid loads for Dutch forests were derived using a multi-layer steady-state model that includes canopy interactions, nutrient cycling, mineral weathering and N transformations. Values were calculated for combinations of 12 tree species and 23 soil types for a 10×10 km grid. Critical acid loads thus derived increased with decreasing soil depth. Nearly 90% of the values varied approximately between 1500 and 4000 molc ha?1 yr?1 at 10 cm soil depth and between 750 and 2000 molc ha?1 yr?1 at the bottom of the rootzone. Separate critical loads calculated for N and S at the bottom of the rootzone varied between approximately 300 and 1000 molc ha?1 yr?1 for N and between 150 and 1250 molc ha?1 yr?1 for S. Using deposition data of 1990, a median reduction of the deposition by approximately 75% was calculated to achieve the critical loads at the bottom of the rootzone. The overall uncertainty in this value was estimated to be about 10%, although it can be much larger for specific soil types such as clay and peat soils. For N a larger reduction deposition percentage was calculated than for S, especially for coniferous forests with a high present N input.  相似文献   

16.
Ponderosa pines (Pinus ponderosa Dougl. ex. Laws) 21 to 60 yr old were used to assess the relative importance of environmental stressors (O3, drought) versus an enhancer (N deposition) on foliar retention, components of aboveground growth, and whole tree biomass allocation. Sites were chosen across a well-described gradient in ozone exposure (40 to 80 ppb per h, 24 h basis, 6 month growing season) and nitrogen deposition (5 to 40 kg ha-1 yr-1) in the San Bernardino Mountains east of Los Angeles, California. A high level of chlorotic mottle indicated high O3 injury at sites closest to the pollution source, despite potential for the mitigating effects of N deposition. At the least polluted site, foliar biomass was evenly distributed across three of the five needle-age classes retained. At the most polluted site, 95% of the foliar biomass was found in the current year's growth. High N deposition and O3 exposure combined to shift biomass allocation in pine to that of a deciduous tree with one overwintering needle age class. Based on whole tree harvests, root biomass was lowest at sites with the highest pollution exposure, confirming previous chamber exposure and field studies. Aboveground growth responses in the high-pollution sites were opposite to those expected for O3 injury. Needle and lateral branch elongation growth, and measures of wood production increased with increasing proximity to the pollution source. An enhancement of these growth attributes suggested that N deposition dominated the ponderosa pine response despite high O3 exposure.  相似文献   

17.
Abstract

A three-year experiment was carried out at three different sites in northern Germany to investigate the effects of combined sulphur (S, up to 50 kg S ha?1 year?1) and nitrogen (N, up to 300 kg N ha?1 year?1) fertilization on dry matter (DM) yield and forage quality. There was an interaction effect of site, year, S and N fertilization. The greatest DM yield increment relative to yield at the start of the experiment (1997) with no S and N applied was 10.2 t DM ha?1 at Ostenfeld (arable grassland). Cattle slurry when applied to provide 50 kg N ha?1 and 10 kg S ha?1 did not noticeably increase yield. The S content in forage decreased significantly over the years without S fertilization. At 300 kg N ha?1 and 0 kg S ha?1, crude protein (CP) contents achieved 173 g kg?1 DM and were diluted due to higher DM yields with S fertilization. The true protein content (TP% of CP) differed significantly at 300 kg N ha?1. TP achieved 93% with 50 and 87% with 0 kg S ha?1 year?1, respectively. In conclusion, with N fertilizer intensities in the range of 300 kg N ha?1, it is necessary to apply 25 kg S ha?1 to improve forage yield and quality. On the other hand, with N fertilization levels below 300 kg N ha?1, S fertilization could be omitted.  相似文献   

18.
The effects of four treatments upon the N content of rice crop and soil in 1m2 irrigated microplots were compared: (1) PK fertilization + Sesbania rostrata (inoculated stems) ploughed in as green manure when it was 52 days old. (2) PK fertilization + S. rostrata (non-inoculated stems) ploughed in as green manure. (3) PK fertilization + ammonium sulphate (60kg N ha?1). (4) PK fertilization alone (control).The application of chemical N fertilizer (treatment 3) increased the grain yield by 169 g m?2 (1.69t ha?1). whereas incorporating S. rostrata as green manure resulted in a grain yield increase of 372 g m?2 (3.72t ha?1). N2 fixed by S. rostrata was estimated to be at least 26.7 g m?2 (267kg N ha?1), one third being transferred to the crop and two thirds to the soil.  相似文献   

19.
Abstract

Four rates of straw (0, 4, 8 and 12 t ha?1 yr?1) were incorporated in a field experiment with continuous spring barley. The experiment was conducted on a sandy soil (5.5% clay) and a sandy loam soil (11.2% clay). After eight years, the straw incorporation was combined with catch-crop growing with and without winter application of animal slurry and also spring fertilization with mineral fertilizer (0, 50, 100 or 125 kg N ha?1 yr?1). The combined experiment was conducted for three lyears on the sandy soil and for four years on the sandy loam soil. The effects on barley dry matter yield and N uptake are presented together with the long-term effects of the straw incorporations on crop growth and soil C and N. Grain yield on the sandy loam was unaffected by straw incorporation. On the sandy soil the highest straw application rates reduced grain yield in the unfertilized barley. When the barley received mineral fertilizer at recommended levels (100 kg N ha?1 yr?1), grain yield on this soil was also unaffected by the high straw rates. Including a catch crop had a positive effect on the grain yield of barley on both soils. The total N uptake in grain and straw generally increased with straw application up to 8 t ha?1 yr?1. With the highest straw application rate (12 t ha?1 yr?1), the total N uptake decreased but still exceeded N uptake in barley grown with straw removal. The barley accumulated higher amounts of N when a catch crop was included. The total N uptake in the barley was significantly higher after animal slurry application. The extra N uptake, however, was much lower than the amounts of N applied with the slurry. Incorporation of straw had only a small influence on N uptake after slurry application. The straw, therefore, was not able to store the applied N during winter. In the two four-year periods before the combined experiment, grain yield on the sandy loam was generally negatively affected by straw incorporations. In the second period, N uptake began to show a positive effect of the straw. On the sandy soil, grain yield and N uptake during the whole period were generally positively affected by the straw incorporations except for the highest straw rate (12 t ha?1 yr?1). The sandy loam soil showed higher increases in C and N content after the repeated straw incorporations and catch-crop growing than the sandy soil. When application of animal slurry was combined with the catch crop, no further increases in soil C and N were found relative to soil where a catch crop was grown without slurry application. Large amounts of the N applied with the slurry may therefore have been lost by denitrification or nitrate leaching.  相似文献   

20.
Although water chemistry of precipitation and lakes in Nova Scotia is dominated by C1 from sea salt, correction for marine influence reveals that the dominant anion in acidified lakes is SO4. Atmospheric deposition of non-marine SO4 (SO4) and NO3- for the period 1977–1980 at 4 stations in southwest Nova Scotia averaged 47 meq SO4 * m?2 yr?1 and 21 meq NI3-m?2 yr?1 compared with 38 and 13 meq, respectively, for the average of 3 stations in the northeastern third of the province. Precipitation pH increased from 4.5 to 4.8 along the same axis. Almost 50% of the SO4 deposition occurred when storms came from the southwest, indicating low pressure tracks which pass south of major Canadian sources of S. SO4 * deposition in metropolitan Halifax (1982 bulk data) was 87 meq m?2 yr?1, due to local emissions of ca. 28 300 tonne S in the area, as well as LRTAP. Concurrent deposition of NO3-N was 15 meq m?2 yr?1 (2.1 kg ha?1 yr ?1). Loadings from SO4 deposition in the Halifax area amount to 42 kg ha?1 yr?1 and clearly exceed the federal guideline (M.O.I., 1983) of 20 kg ha?1 yr?1. Water chemistry of southwest, northeast, and Halifax area lakes show the same general SOI trends as observed for atmospheric deposition. In addition we find a positive relationship between SOI concentrations in the urban lakes and proximity to the center of the urban area.  相似文献   

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