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1.
Minerals of the pedogenic chlorite group were studied in the clay fractions isolated from the mineral horizons of podzolic and gleyic peat-podzolic soils. In the AE and E horizons of the podzolic soil, pedogenic chlorites are thought to develop from vermiculite, whereas in the E horizon of the gleyic peat-podzolic soil, they can be formed from smectite minerals. For estimating the degree of chloritization (the degree of filling of the interlayer space of 2: 1 minerals with Al hydroxides), a numerical criterion was is proposed. The difference between the values of this criterion before and after the treatment of the preparations with NH4F indicated that the degree of chloritization in the pedogenic chlorites decreases in the following sequence: the E horizon of the podzolic soil > the AE horizon of the podzolic soil > the E horizon of the gleyic peat-podzolic soil. Another numerical criterion was proposed to estimate the degree of polymerization of Al-hydroxy complexes in pedogenic chlorites. This criterion was based on the thermal stability of soil chlorites and represented the temperature at which an increase in the intensity of the 1.0-nm peak after heating the K-saturated preparations exceeds 50% of its initial value. According to this criterion, the degree of polymerization of the Al-hydroxy interlayers in pedogenic chlorites decreases in the following sequence: the E horizon of the podzolic soil > the E horizon of the gleyic peat-podzolic soil ≥ the AE horizon of the podzolic soil. The distinct interrelation between the soil properties and the degrees of chloritization and polymerization of the Al-hydroxy interlayers attests to the modern origin of the pedogenic chlorites.  相似文献   

2.
The biotite changes in the 1–5 μm fraction after its occurrence in the F, H, AE, and E horizons of a pale-podzolic soil for five years under conditions of a model field experiment were assessed by X-ray diffraction analysis. It was found that the main changes of the biotite in all the horizons included the degradational transformation of its crystal lattice to interstratified mica-vermiculite structures and vermiculite. The intensity of this process gradually decreased from the F horizon down the profile in parallel with the decrease in the amount of roots and the abundance and activity of microbiota. Chloritized structures were present among the products of the biotite weathering in the H, AE, and E horizons; the degree of chloritization gradually increased from the H horizon to the E horizon. The main identified products of the biotite weathering in the AE and E horizons formed during the 5 years of the model experiment were identified in the clay and fine-silt fractions from these horizons of the native pale-podzolic soils. Therefore, the vermiculite, soil chlorite, and mixed-layer illite-vermiculite minerals in the soils studied could be considered as products of the recent soil functioning. The obtained results and literature data showed that the weathering of biotite resulted in the formation of K- and Al-buffer systems.  相似文献   

3.
In the sandy soils of northeast Thailand, root development is generally limited to the topsoil (0–20 cm depth) but a simple slotting intervention (20–40 cm) significantly increased the root frequency in the slotted material (Eslot) compared with the undisturbed subsoil (E horizon). The aim of this study was to investigate the consequences of slotting on the soil structure by analysing at different scales the pore characteristics of the original soil profile and of the soil material inside the slot. These characteristics were studied using bulk density measurements, image analysis of thin sections and mercury porosimetry. Our results showed that the total porosity of the E horizon and Eslot material was similar when measured in 100 cm3 cylinders, but that the pore size distribution had been changed by slotting. The unaltered E horizon contained mainly small pores characterized by a narrow distribution related to close packing of the sand grains, associated with some biological macropores probably with poor continuity as they did not contain roots despite their size. On average, pores were larger in the Eslot material, with a broader distribution resulting from looser packing of the sand grains but with fewer biological macropores. Although slotting reduced the number of biological pores, the looser packing appeared to be more favourable to root development than the presence of macropores in the E horizon. Finally, the comparison of the porosity in the different horizons with the porosity of the Eslot material, indicated the significance of the closeness of the sand packing on root development.  相似文献   

4.
Short‐rotation forestry (SRF) on arable soils has high potentials for biomass production and leads to long‐term no‐tillage management. In the present study, the vertical distributions of soil chemical and microbial properties after 15 y of SRF with willows and poplar (Salix and Populus spp.) in 3‐ and 6‐year rotations on an arable soil were measured and compared to a pertinent tilled arable site. Two transects at different positions in the relief (upper and lower slope; transect 1 and 2) were investigated. Short‐rotation forestry caused significant changes in the vertical distribution of all investigated soil properties (organic and microbial C, total and microbial N, soil enzyme activities), however, the dimension and location (horizons) of significant effects varied. The rotation periods affected the vertical distribution of the soil properties within the SRF significantly. In transect 1, SRF had higher organic‐C concentrations in the subsoil (Bv horizon), whereas in transect 2, the organic‐C concentrations were increased predominantly in the topsoil (Ah horizon). Sufficient plant supply of P and K in combination with decreased concentrations of these elements in the subsoil under SRF pointed to an effective nutrient mobilization and transfer from the deeper soil horizons even in the long term. In transect 1, the microbial‐C concentrations were higher in the B and C horizons and in transect 2 in the A horizons under SRF than under arable use. The activities of β‐glucosidases and acid phosphatases in the soil were predominantly lower under SRF than under arable use in the topsoil and subsoil. We conclude, that long‐term SRF on arable sites can contribute to increased C sequestration and changes in the vertical distribution of soil microbial biomass and soil enzyme activities in the topsoil and also in the subsoil.  相似文献   

5.
Shallow soil A horizon (topsoil) caused by soil erosion and soil movement from cultivation is known to reduce soil and crop productivity. The reduction may be related to limitation of root growth. A field study was conducted to investigate the effects of topsoil thickness on distributions of root density and growth. Soybeans [Glycine max (L.) Merr.] were grown on plots of Mexico silt loam (fine, montmorillonitic, mesic Mollic Endoaqualfs) with topsoil thicknesses of 0, 12.5, 25.0, and 37.5 cm above the Bt horizons. Root density was measured 60 and 90 days after planting using a minirhizotron video‐camera system. Root density was significantly reduced as topsoil thickness decreased from 37.5 to 0 cm. Mean density and net change of the density across profile between 30 and 60 days of growth had a linear function of topsoil thickness. The reduction and lower activity induced by shallow topsoil were attributed to detrimental properties in the Bt horizons. Root distribution pattern and rooting depth were not significantly affected by topsoil thickness. The roots appeared to be accumulated on the upper layers of the Bt horizons. Roots growing in thicker topsoil were more active than roots growing without topsoil. High soil moisture content during the growing season may mitigate the detrimental effects of shallow topsoil, inhibit root penetration, and enhance root activity.  相似文献   

6.
Major weathering sequences in soils are well established; however, knowledge on rates of mineral transformations remains unknown, because it is often difficult to date precisely soil processes. This work was carried out on soils developed on recent (< 188 y) sand dunes on the W coast of Oléron Island (France). The coast has been protected against marine and wind erosion by constructing five consecutives barriers close to the coastline since 1820 (1820, 1864, 1876, 1889, 1948) defining the maximum age of the soil parent material, as before the areas between the barriers were under water. Soils on the older dunes have low clay content (> 94% of sand) and exhibit a bleached E horizon that overlies a yellowish brown B horizon. The process responsible for their formation is podzolization promoted by the high permeability of the material and complexing organic matter produced by coniferous vegetation. Initial mineralogy of C horizons is homogenous and constituted of chlorite, illite, illite/smectite mixed‐layer minerals, and kaolinite, quartz, calcite (≈ 8% related to shell fragments), and feldspars. The initial clay‐mineral assemblage of the E horizons is dominated by illite (well‐crystallized WCI and poorly crystallized PCI) and chlorite. With progressive podzolization, poorly crystallized illite is first transformed to illite/smectite mixed‐layer minerals and in a further step into smectite. In addition, transformation of well‐crystallized illite leads to formation of ordered illite/smectite mixed‐layer minerals in the E horizons, which is not commonly described in soils. In the B horizons, illite/smectite mixed‐layer minerals are present with traces of smectite, as well as Al and Fe oxi‐hydroxides as revealed by DCB and oxalate chemical extractions. This chronosequence illustrates that over short distances and short time (< 188 y) intense mineral weathering and soil development occur. Major clay‐mineral changes occur between 132 and 188 y in agreement with development of the pine forest producing acidic litter.  相似文献   

7.
A model for soil crumbling, called the capillary crumbling model (CCM) was introduced by Aluko and Koolen [Aluko, O.B., Koolen, A.J., 2000. The essential mechanics of capillary crumbling of structured agricultural soils. Soil Till. Res. 55, 117–126]. According to the CCM, the optimum soil water content for tillage (θOPT) may be defined as the water content at which the capillary bonding strength between aggregates is minimum. The objective of this study was to evaluate the CCM for the arable layer of 10 agricultural soils (sandy loam to clay textures) from semi-arid regions in western Iran. The results were compared with conventional soil workability limits such as 0.85 of the soil plastic limit (0.85θPL), Proctor critical water content (θProctor), 0.6 or 0.7 of water content at matric suction of 50 hPa (0.6–0.7θ50 hPa), and the Kretschmer optimum water content (θKretschmer = θPL − 0.15(θLL − θPL)) where θLL is the soil liquid limit. Repacked soil cores were prepared from intact soil aggregates (0.50–4.75 mm) to 0.9 of the critical bulk density (to represent the soil conditions before tillage). Tensile strength and matric suction of the cores were determined at different soil water contents obtained by slow drying. The CCM provided evidence for the physics and mechanics of crumbling in the studied soils. It revealed that effective stresses are the dominant inter-aggregates forces, at least for the wet range of soil water content. A fall in strength of inter-aggregate bonds (i.e. tensile strength) was recorded due to water emptying from structural pores in a narrow range of matric suction (hOPT) which was consistent with the model. With increasing soil organic matter and clay contents the fall became more distinct, indicating increased structural stability. The θOPT values determined by the CCM were found in the hOPT range 551–612 hPa corresponding to 0.91–0.79θPL, which was in agreement with published values for the soil workability limit. Negative correlations between hOPT and clay and organic matter contents clearly confirmed the increasing effect of soil structure on the enlargement of inter-aggregate pores. High correlations were observed between θOPT and 0.85θPL, θProctor or 0.7θ50 hPa. The results showed that the CCM might be recommended as a physically based method for the determination of θOPT. Considering the 1:1 relationships between θOPT and 0.85θPL or θProctor, and easy determination of θPL and θProctor, use of these indices is recommended in situations where the CCM is not applicable.  相似文献   

8.
Evaluation of the stoichiometry of base cations (BCs, including K+, Na+, Ca2+, and Mg2+) and silicon (Si) (BCs:Si) during soil mineral weathering is essential to accurately quantify soil acidification rates. The aim of this study was to explore the differences and influencing factors of BCs:Si values of different soil genetic horizons in a deep soil profile derived from granite with different extents of mineral weathering. Soil type was typic acidi-udic Argosol. Soil samples were collected from Guangzhou, China, which is located in a subtropical region. To ensure that the BCs and Si originated from the mineral weathering process, soil exchangeable BCs were washed with an elution treatment. The BCs:Si values during weathering were obtained through a simulated acid rain leaching experiment using the batch method. Results showed that soil physical, chemical, and mineralogical properties varied from the surface horizon to saprolite in the soil profile. The BCs:Si values of soil genetic horizons during weathering were 0.3-3.7. The BCs:Si value was 1.7 in the surface horizon (A), 1.1-3.7 in the argillic horizon (Bt), and 0.3-0.4 in the cambic (Bw) and transition (BC) horizons, as well as in horizon C (saprolite). The general pattern of BCs:Si values in the different horizons was as follows: Bt > A > Bw, BC, and C. Although BCs:Si values were influenced by weathering intensity, they did not correlate with the chemical index of alteration (CIA). The release amounts of Si and BCs are the joined impact of soil mineral composition and physical and chemical properties. A comprehensive analysis showed that the BCs:Si values of the soil derived from granite in this study were a combined result of the following factors: soil clay, feldspar, kaolinite, organic matter, pH, and CIA. The main controlling factors of BCs:Si in soils of different parent material types require extensive research. The wide variance of BCs:Si values in the deep soil profile indicated that H+ consumed by soil mineral weathering was very dissimilar in the soils with different weathering intensities derived from the same parent material. Therefore, the estimation of the soil acidification rate based on H+ biogeochemistry should consider the specific BCs:Si value.  相似文献   

9.
Flocculation tests and permeability measurements were carried out for silt and clay fractions separated from surface and subsurface horizons of four paddy soils. There was not much difference in the flocculating power between A1(OH)2.2C10.8 and CaSO4. Their flocculation value, 0.3 to 3 mM, was attained by adding the reagents at the rate of 0.24 to 2.4 mmol/100 g of the silt and clay. The flocculation with A1(OH)2.2C10.8 or CaSO4 did not affect the sediment volume of the silt and clay. This sediment volume was smaller for the surface than for the subsurface horizons of each soil, suggesting that soil organic matter and repetition of wetting and drying contribute to the stable aggregation of the silt and clay in the surface horizon. The permeability was higher for the silt and clay fractions separated from the surface horizon than that from the subsurface horizon, and the addition of 2.5 to 4.2 mmol of A1(OH)2.2C10.8 or CaSO4/100g of the silt and clay increased its permeability by 1.5 to 4 times. The effect of A1(OH)2.2C10.8 was more lasting than that of CaSO4 and was recognized even after 200 ml of water passed through 1 g of the silt and clay. The effect of the flocculating reagent on the permeability was more or less enhanced by air-drying the treated silt and clay.  相似文献   

10.
The fractional composition of aluminum compounds was studied in soil solutions obtained using vacuum lysimeters from loamy podzolic soils on two-layered deposits. The concentration of aluminum was estimated in brooks and a river draining the area with a predominance of these soils. In soil solutions, the concentration of aluminum was experimentally determined in the following compounds: (1) organic and inorganic monomers, (2) stable complexes with HAs and FAs together with polymers, and (3) the most stable complexes with HAs and FAs together with fine-crystalline and colloidal compounds. The total Al concentration in soil solutions from forest litter was 0.111–0.175 mmol/l and decreased with depth to 0.05 mmol/l and lower in solutions from the IIBD horizons. More than 90% of the Al in the solutions was bound into complexes with organic ligands. Some amount of Al in solution could occur in aluminosilicate sols. The translocation of Al complexes from the litter through the AE horizon to the podzolic horizon was accompanied by an increase in the ratio between the Al concentration in fraction 2 and the C concentration in the solution. The concentrations of Altot in the surface waters varied in the range from 0.015 to 0.030 mmol/l. Most of the Al came to the surface waters from the litter and AE horizons and partially from the podzolic horizon due to the lateral runoff along the waterproof IIBD horizon. Approximate calculations showed that the recent annual removal of Al from the AE and E horizons with the lateral runoff was 7 to 560 mg (3–21 mmol) from 1 m2.  相似文献   

11.
D.C. Bain 《Geoderma》1977,17(3):193-208
The dominant mineral in the clay fractions from the basal horizons of a podzol developed on till derived mainly from chlorite-schists in Argyllshire is oxidized, iron-rich chlorite. Towards the profile surface, the chlorite decreases in amount, becoming absent in the A2 horizon in which the dominant mineral is a complex dioctahedral interstratified phase formed from dioctahedral mica and composed of mica and vermiculite. The absence of any trioctahedral mineral in the A2 horizon together with the marked loss of iron and magnesium from the clay fraction from this horizon indicates that the chlorite, a thuringite, has been destroyed, the only detectable product being goethite. In other apparently similar soils chlorite persists throughout the profiles. As the Eredine podzol contains translocated humus in the B2 horizon, it is suggested that during podzolization, organic solutions percolated downwards from the surface, formed complexes with iron and aluminium from the chlorite structure, removing them to the B2 horizon, and thus eventually dissolved out the chlorite from the A2 horizon.  相似文献   

12.
Aluminum concentrations in organoaluminum complexes, mineral polymers, Al(H2O) 6 3+ , Al(OH)(H2O) 5 2+ , Al(OH)2(H2O) 4 + , AlH3SiO 4 2+ , and Al(OH)3(H2O) 3 0 extracted with 0.001 M CaCl2 from the main genetic horizons of a podzolic soil on two-layered deposits were determined experimentally and calculated from thermodynamic equations. It was found that aluminum bound in organic complexes was predominant in extracts from the AE horizon, and mineral polymer aluminum compounds prevailed in extracts from the E and IIBD horizons. In the AE horizon, organoaluminum compounds were a major source of aluminum, which passed into solution predominantly by exchange reactions. In the E horizon, aluminum hydroxide interlayers in soil chlorites were the main source of aluminum, which passed into solution by dissolution reactions. In extracts from the IIBD horizon, aluminum was solubilized by the dissolution of aluminosilicates inherited from the parent rock.  相似文献   

13.
Microbial populations from dried, remoistened and undried forest organic horizons were allowed to thoroughly recolonize sterilized forest organic horizons; oxygen uptake was followed during recolonization. Microbial damage due to air drying was in the order litter (L) > fermentation (F) > humus (H). Species diversity, as indicated by diminished O2 uptake, was reduced in all horizons which had been air dried, with greatest damage in the litter horizon. Samples of these forest organic soil materials, designated for the study of microbially driven processes, should not be air dried.  相似文献   

14.
The podzolization process is studied through lipids in nine characteristic podzol horizons. Organic matter accumulates particularly with aluminium in the Bh horizon, while the hard, cemented Bs horizon below this is formed mainly by iron oxides. The low soil pH seems to have no great influence on the preservation of lipids as reflected by the absolute amounts present and the presence of bacterial lipid markers throughout the profile. Independent of soil pH, lipids accumulate in organically enriched horizons. Albeit, high molecular weight organic compounds accumulate to a relatively greater extent than lipids in these horizons. A lipid signal related to the aerial parts, i.e. leaves and flowers, of Calluna is observed only in the O horizon. This ‘n‐alkane, steroid and triterpenoids’ signal is quickly lost in the underlying Ah horizon due to (bacterial) oxidation. The other total lipid extracts obtained are dominated by root‐derived compounds. In subsoil horizons rich in organic matter, i.e. the Ahb and Bh horizons, root‐derived friedooleanan and steroid compounds dominate the total lipid signal. Degraded horizons, poor in organic matter, i.e. the E2, Bhs, Bs and B/C horizons, are dominated by C22 and C24ω‐hydroxy acids, long‐chain (> C20) n‐alkanoic acids with a strong even‐over‐odd predominance and C22 and C24n‐alkanols. Steroid and root‐derived triterpenoids with a friedooleanan structure have been removed from these horizons through degradation. Based on total organic carbon content and lipid composition, the formation of an E1 horizon has started, but is not yet complete. In the Ahb horizon, a contribution from buried vegetation to the total lipid signal is still present, although degradation and an input from roots have significantly altered the original signal. Overall, lipid data indicate that degradation (microbial oxidation) is an important process that should be taken into account, in addition to leaching, when describing podzolization processes in soils.  相似文献   

15.
Installation of pipeline utilities (oil, natural gas, water) in central Canada prior to the 1970s often resulted in extensive mixing of topsoil with subsoil materials within the easements due to largely unregulated construction practices. The main objectives of this study were (1) to develop a simple field protocol for the rapid delineation of the zone of topsoil disturbance (or topsoil–subsoil mixing) around buried utilities on agricultural land in southern Ontario, and (2) to characterize the zone of topsoil disturbance in the vicinity of an existing pre-1970s pipeline in terms of agronomically important soil properties. The study was carried out at six farm sites chosen along a pipeline easement (30+ years old) in southern Ontario. Soil organic carbon content, CaCO3 content and pH were found to be useful in delineating the zone of topsoil disturbance around the buried utility. Standardized laboratory techniques for determination of these three soil attributes were used to analyse surface soil samples (Ap horizons) taken at 1·5 m intervals along 45·7 m long transects oriented perpendicular to the easement. In addition, rapid field tests for these same three variables were adopted/developed and tested, and two portable instruments were evaluated for their usefulness for in situ soil property measurements. In particular, a Minolta™ CR-310 Chroma Meter was successfully used to relate moist soil colour to the organic carbon content of the surface soil. The chromaticity coordinate a* (CIE L*a*b* colour space notation) was shown to provide good estimates of organic carbon content for soils of medium to fine texture in this region of Ontario. The zone of topsoil disturbance was most often characterized by an appreciable increase in per cent CaCO3 equivalent and pH, and a decrease in organic carbon content (dilution), over the pipeline trench when compared to off-easement areas. The zone of topsoil disturbance was usually a minimum of 15 m wide (i.e. the approximate width of the original trench and workspace areas during construction), and frequently much wider due most likely to wet soil conditions at the time of construction, agricultural tillage translocation of topsoil over time, and other factors. It is recommended that rapid on-site determinations of the zone of topsoil disturbance should be based primarily on field estimates of CaCO3 content (10 per cent HCl) and organic carbon content (a* chromaticity coordinate using a portable colorimeter). Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

16.
《Pedobiologia》2014,57(3):181-189
Management of forest sites has the potential to modulate soil organic matter decomposition by changing the catalytic properties of soil microorganisms within a soil profile. In this study we examined the impact of forest management intensity and soil physico-chemical properties on the variation of enzyme activities (β-glucosidase, β-xylosidase, α-glucosidase, phenol oxidase, N-acetyl-glucosaminidase, l-leucine aminopeptidase, phosphatase) in the topsoil and two subsoil horizons in three German regions (Schorfheide-Chorin, Hainich-Dün, Schwäbische Alb). The sandy soils in the Schorfheide-Chorin (SCH) showed lower ratios of the activity of carbon (C) acquiring enzymes (β-glucosidase) relative to nitrogen (N) acquiring enzymes (N-acetyl-glucosaminidase + l-leucine aminopeptidase), and activity of C acquiring enzymes relative to phosphorous (P) acquiring enzymes (phosphatase) than the finer textured soils in the Hainich-Dün (HAI) and Schwäbische Alb (ALB), indicating a shift in investment to N and P acquisition in the SCH. All enzyme activities, except phenol oxidase activity, decreased in deeper soil horizons as concentrations of organic C and total N did, while the decrease was much stronger from the topsoil to the first subsoil horizon than from the first subsoil to the second subsoil horizon. In contrast, phenol oxidase activity showed no significant decrease towards deeper soil horizons. Additionally, enzyme activities responsible for the degradation of more recalcitrant C relative to labile C compounds increased in the two subsoil horizons. Subsoil horizons in all regions also indicate a shift to higher N acquisition, while the strength of the shift depended on the soil type. Further, our results clearly showed that soil properties explained most of the total variance of enzyme activities in all soil horizons followed by study region, while forest management intensity had no significant impact on enzyme activities. Among all included soil properties, the clay content was the variable that explained the highest proportion of variance in enzyme activities with higher enzyme activities in clay rich soils. Our results highlight the need for large scale studies including different regions and their environmental conditions in order to derive general conclusions on which factors (anthropogenic or environmental) are most influential on enzyme activities in the whole soil profile in the long term at the regional scale.  相似文献   

17.
Although Andosols are relatively resistant to water erosion, they can be severely affected by changes in land use, resulting in accelerated erosion and loss of soil organic matter (SOM). We hypothesized that if the contents of specific components of SOM and organo–metallic complexes (humic acids –HAs–, fulvic acids –FAs–, sodium pyrophosphate extractable carbon –Cp–, aluminium –Alp–, and iron –Fep–) consistently tend towards certain ratios in A and B horizons, they could be used to identify soils denuded by erosion. To test this hypothesis, we investigated the vertical distribution of humus components and certain ratios, namely C‐HA/C‐FA, C‐FA/total organic C (TOC), Cp/TOC and (Fep + Alp)/C‐FA, in representative profiles of andic soils located in natural ecosystems with different degrees of human disturbance. Furthermore, we analysed these parameters in the topsoil of a natural protected area and in adjacent soils under different land use scenarios (natural reserve vs. traditional exploitation). We found that the ratios of C‐HA/C‐FA and, to a lesser extent, of C‐FA/TOC and Cp/TOC changed with depth in the selected soil profiles, but the values were characteristic of each type of soil horizon. The values of these ratios in the topsoils of the disturbed areas were closer to a B horizon than an A horizon. This pattern may be superimposed on pre‐existing gradients, such as those related to the type of natural vegetation. The use of these indices emerges as a possible land use and erosion indicator.  相似文献   

18.
Minerals with large specific surface areas promote the stabilization of soil organic matter (SOM). We analysed three acidic soils (dystric, skeletic Leptic Cambisol; dystric, laxic Leptic Cambisol; skeletic Leptic Entic Podzol) under Norway spruce (Picea abies) forest with different mineral compositions to determine the effects of soil type on carbon (C) stabilization in soil. The relationship between the amount and chemical composition of soil organic matter (SOM), clay content, oxalate‐extractable Fe and Al (Feo; Alo), and dithionite‐extractable Fe (Fed) before and after treatment with 10% hydrofluoric acid (HF) in topsoil and subsoil horizons was analysed. Radiocarbon age, 13C CPMAS NMR spectra, lignin phenol content and neutral sugar content in the soils before and after HF‐treatment were determined and compared for bulk soil samples and particle size separates. Changes in the chemical composition of SOM after HF‐treatment were small for the A‐horizons. In contrast, for B‐horizons, HF‐soluble (mineral‐associated) and HF‐resistant (non‐mineral‐associated) SOM showed systematic differences in functional C groups. The non‐mineral associated SOM in the B‐horizons was significantly depleted in microbially‐derived sugars, and the contribution of O/N‐alkyl C to total organic C was less after HF‐treatment. The radiocarbon age of the mineral‐associated SOM was younger than that of the HF‐resistant SOM in subsoil horizons with small amounts of oxalate‐extractable Al and Fe. However, in horizons with large amounts of oxalate‐extractable Al and Fe the HF‐soluble SOM was considerably older than the HF‐resistant SOM. In acid subsoils a specific fraction of the organic C pool (O/N‐alkyl C; microbially‐derived sugars) is preferentially stabilized by association with Fe and Al minerals. Stabilization of SOM with the mineral matrix in soils with large amounts of oxalate‐extractable Alo and Feo results in a particularly stable and relatively old C pool, which is potentially stable for thousands of years.  相似文献   

19.
Changes in biotite (fraction 1–5 μm) after exposure in the T2, H, Eih, and E horizons of peatypodzolic gleyic soil under conditions of a model field experiment were studied by X-ray diffraction. It was found that the main transformations of the biotite in all horizons included the degradation of its crystal lattice into regularly interstratified biotite-vermiculite and randomly interstratified biotite-smectite structures and vermiculite. The transformation intensity decreased down the profile simultaneously with a reduction in the content of organic matter, roots, and microbiota population and activity. Chloritized structures were also present among the biotite weathering products in the E horizon. The main identified products of biotite weathering formed in horizons Eih and E over a five-year period of the model experiment were detected in the clay and fine silt fractions of these horizons and in native peaty-podzolic gleyic soils. This suggests that vermiculite and soil chlorite in the soils studied are products of soil functioning. It follows from the results, with consideration for literature data, that the weathering of biotite results in the formation of a potassium-buffering system.  相似文献   

20.
In this paper we address total glomalin‐related soil protein (T‐GRSP) as a possible indicator of differences in forest soils related to reactive nitrogen and forest composition. We focused especially on the relationship between T‐GRSP (g kg−1), soil organic carbon (SOC), and reactive nitrogen (Nr) availability among different categories of temperate forests and different horizons. Our study included 105 sampling sites divided into 5 categories, which vary in elevation and tree species composition (coniferous, deciduous, mixed). We detected significantly higher T‐GRSP and SOC in the F+H horizon under conifers. We assume that this observation might be attributed to suppression of decomposition of T‐GRSP and SOC by nature of coniferous litter. The lack of significant differences in T‐GRSP/SOC among the categories and the positive correlations between T‐GRSP and SOC in most of the categories confirmed the strong relationship of T‐GRSP with SOC. We found a significantly higher content of T‐GRSP in the F+H horizon for all studied forest categories. However, the contribution of T‐GRSP to SOC is significantly higher in the A horizon, which might be caused by stabilization of glomalin by mineral fraction, including clay minerals or by the belowground origin of glomalin. We found the increase of SOC with increasing Nr in the A horizon for most categories of forest. T‐GRSP follows this trend in the case of deciduous forests (decid), mixed forest (mixed), and mountain forests (mount). On the other hand, we detected a decrease of T‐GRSP with increasing Nr in the F+H horizon of coniferous forests (conif). Moreover the T‐GRSP/SOC decreases with the increase of Nr in the A horizon of conif, mixed and mount, which points to the higher sensitivity of forest with prevalence of coniferous trees. Our observations have confirmed an ecosystem‐specific relationship between T‐GRSP, SOC and Nr. We concluded that T‐GRSP in combination with T‐GRSP/SOC has the potential to reveal qualitative changes in soil organic matter (SOM) connected with increasing Nr.  相似文献   

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